CN107083683A - A kind of preparation method of hydrophilic smooth organic silicone finishing agent - Google Patents
A kind of preparation method of hydrophilic smooth organic silicone finishing agent Download PDFInfo
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
- D06M15/647—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing polyether sequences
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
- C08G77/04—Polysiloxanes
- C08G77/12—Polysiloxanes containing silicon bound to hydrogen
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G81/00—Macromolecular compounds obtained by interreacting polymers in the absence of monomers, e.g. block polymers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/50—Modified hand or grip properties; Softening compositions
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- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
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- Compositions Of Macromolecular Compounds (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to textile field, more particularly to a kind of preparation method of hydrophilic smooth organic silicone finishing agent, following steps are specifically included：Use octamethylcy-clotetrasiloxane（D4）With vinyl closure agent under acidic catalyst effect, containing hydrogen silicone oil synthesis is carried out；By this containing hydrogen silicone oil and propylene based polysiloxane oxygen ether addition polymerization, a kind of organic solvent is added, end ring oxygen polyether silicone oil is made；Then reacted with polyetheramine, synthesis of ternary block silicone oil；A kind of multifunction finishing agent is added, increases its hydrophily, feel and stability.The finishing agent of the present invention has moment hydrophilic effect, assigns fabric excellent fine and smooth, smooth, soft feel, and its feel nearly reaches traditional amido silicon oil effect.Good hydrophilic property, hence it is evident that improve factory process stability, return something for repairs and return metachromia and wear dress ornament, while efficiently solving traditional silicon oil yellow becomes problem, be applicable to light color and white fabrics, and composition of raw materials is without materials such as APEO, is truly realized environmental protection production.
Description
Technical field
The present invention relates to a kind of synthesis of hydrophilic silicone on textile, especially super smooth feeling, moment be hydrophilic, Gao Wen
The oily preparation method and application of the novel organosilicon of qualitative aspect.
Background technology
With economic growth, people not only need excellent to textile comfortableness requirement also constantly lifting in terms of feel
Smooth ice-cold, fine and smooth, resilience, fluffy, soft feeling；Need in terms of comfortableness to breathe freely, moisture absorbing and sweat releasing, environmental protection.Traditional amino silicone
Oil has declined, at present, and amino modified and ternary polymerization silicone oil is in market share larger proportion, and amino-modified silicone oil is most of
Although can assign fabric excellent soft, fluffy, smooth feel, substantially hydrophilic relatively slow, gas permeability is general.Quaternary ammonium salt changes
Property organosilicon hydrophily preferably, but also somewhat there is some distances, particularly slippery in feel；Even some are handled by organosilicon
Fabric afterwards places a period of time, and its feel and hydrophily are decreased obviously.
Patent of invention CN105155280A provides a kind of synthetic method of smooth organosilicon, and product feel is made and substantially can
The market demand is met, but hydrophily is very slow, and gas permeability is not good, there is certain discoloration, hardly hydrophilic after placement, has influence on dress
Comfortableness.
Patent of invention CN102942697A provides a kind of preparation method of main chain hydrophilic modifying amido silicon oil, and method includes end
The synthesis of epoxy silicon oil intermediate, end epoxy silicon oil and amine terminated polyether block polymerization.Sintetics has excellent hydrophily,
But smooth degree still can not meet market high standard demand.
The content of the invention
In order to improve above-mentioned technological deficiency, the present invention provides a kind of preparation of hydrophilic super cool sliding organic silicone finishing agent
Method.Suitable for cellulose fibre and blend fibre, assign fabric excellent smooth, fine and smooth sense, moment is hydrophilic, continues resistance to
Long；More have the chemical stabilities such as splendid acid and alkali resistance, salt, dyestuff concurrently and resistant to shearing is physical.Discoloration is small, do not glue rod, return metachromia
It is good, demulsification, the floating oil of amido silicon oil are solved the problems, such as, is that big production and processing provides a favorable security.
The present invention, which is adopted the following technical scheme that, to be realized：
1）Containing hydrogen silicone oil is synthesized
Use octamethylcy-clotetrasiloxane（D4）With vinyl closure agent component under acidic catalyst effect, containing hydrogen silicone oil is synthesized；
2）The synthesis of end ring oxygen polyether silicone oil
By pi-allyl poly(oxygen-silicon) alkoxy ether and step 1）In obtained containing hydrogen silicone oil in organic solvent, the bar of platinum chloride catalyst
Addition polymerization is carried out under part, then vacuum pumps solvent；
3）Ternary polymerization silicone oil
By polyetheramine and step 2）In obtained end ring oxygen polyether silicone oil under the conditions of organic solvent material, reaction is made ternary and is total to
Silicone oil；
4）By multifunction finishing agent and 3）In obtained ternary polymerization silicone oil be combined, lift correlated performance.
Preferably, step 1）Described in double-seal head agent be vinyl double seal head.
Preferably, step 1）Described in reaction temperature be 27-30 DEG C.
Preferably, step 1）Described in acidic catalyst be the concentrated sulfuric acid, consumption be D4 2-4%.
Preferably, step 1）Described in the reaction time be 4-6h.
Preferably, step 2）Described in ethers be ethylene glycol monobutyl ether, ethylene glycol ether.
Preferably, step 2）Described in pi-allyl poly(oxygen-silicon) alkoxy ether molecular structural formula be CH2=CHCH2O
(C2H4O)m(C3H6O)nCH2(CHCH2) O, wherein m is 1-55, and n is 1-30.
Preferably, step 2）Described in pi-allyl poly(oxygen-silicon) alkoxy ether molecular weight for 400,800,1000,1500,
2000 one or several kinds of combinations.
Preferably, step 2）Described in containing hydrogen silicone oil molal quantity：Pi-allyl poly(oxygen-silicon) alkoxy ether molal quantity is 1:1-
1:2 ratio.
Preferably, step 3）Described in organic solvent be isopropanol, ethylene glycol, the one or more combination of propane diols.
Preferably, step 3）Described in end ring oxygen polyether silicone oil molal quantity：Polyetheramine molal quantity is 1:0.5-1:1 ratio
Example.
Preferably, step 4）Described in functional finishing agent be that polyester polyethers, polyurethane, hydrophilic wax disk(-sc) one or two are mixed
Compound.
Preferably, step 4）Described in multifunction finishing agent molal quantity：Ternary polymerization silicone oil molal quantity is 1:9-1:7.
Primary raw material of the present invention is pi-allyl poly(oxygen-silicon) alkoxy ether, polyetheramine, multifunction finishing agent etc., pi-allyl polyoxy
Silane oxygen ether molecular structural formula is CH2=CHCH2O (C2H4O) m (C3H6O) nCH2 (CHCH2) O, wherein wherein m is 1-55, n
For 1-30.Group-C2H4O, is mainly responsible for hydrophily；- C3H6O, is responsible for feel.And polyetheramine（PEA）Molecular formula is
NH2CH2CH2NHCH2CH2 (CH2CH2O) a (CH2CHCH20) bCH2CH2NHCH2CH2NH2, wherein a are 5-20, and b is 1-
10.Group-CH2CH2O is mainly responsible for hydrophily, and-CH2CHCH20 is mainly responsible for feel；By to m in above two raw material,
N, a, b are selected, and find pi-allyl poly(oxygen-silicon) alkoxy ether molecular weight for 400-2000, and polyetheramine molecular weight is 500-
1500.So as to ensure that the existing excellent feel of final product, and with good hydrophily.Then addition multipotency can be whole again
Agent is managed, hydrophily is further lifted, also favorably ensured to place hydrophilic provide.
The hydrophilic smooth organic silicone finishing agent of the present invention, have on cellulose fibre and blend fibre it is excellent it is smooth,
Fine and smooth feel, substantially good hydrophilic property, moment are hydrophilic, and feel and hydrophily persistently retain after placement；Splendid physics and chemistry are answered
With stability, extremely low discoloration, it is good to move back soft metachromia of returning, low foam.Factory's actual production is especially suitable for, is that hydrophilic silicone is being weaved
The important breakthrough that product are arranged, with wide market prospects.
Embodiment
The present invention is described in further detail with reference to specific implementation row, but is only that a part implements row.
Embodiment 1：
（1）The first step, by 40g D4 and 0.42g vinyl list closure agents（Vinyldimethylethoxysilane）It is added to reaction
Kettle, control temperature adds 2.4g strong sulfuric acid response 4h, adds soda ash and neutralized at 25-35 DEG C, continues to react 3h, obtains
Micro- yellow transparent containing hydrogen silicone oil, viscosity is 45cps.
（2）Second step, adds 2.5g pi-allyl poly(oxygen-silicon) alkoxy ethers（Molecular weight is 400）, 4.6g ethylene glycol monobutyl ethers
(content 50%), is warming up to 110 DEG C, adds 0.03g chloroplatinic acids（1% is interpreted as with isopropanol floride）, controlling reaction temperature is 110-120
DEG C, 2h is reacted, vacuum drawn ethylene glycol monobutyl ether is opened.Transparent end epoxidized polyether silicone oil can be obtained, viscosity is 800-900cps.
（3）3rd step, adds 14g polyetheramines, 28g isopropanols（Content 40%）, control temperature is at 80-85 DEG C, reaction 4h,
Ternary polymerization silicone oil can be obtained.
（4）4th step, adds 6g aqueous polyurethanes, and 60-80 DEG C of reaction 0.5-1h cools to 35 DEG C, discharging, you can
To hydrophilic smooth silicone oil CQ-1.
Embodiment 2：
（1）The first step, by 40g D4 and 0.54g vinyl double seal heads（Tetramethyl divinyl disiloxane）It is added to reaction
Kettle, control temperature adds 1.6g strong sulfuric acid response 5h, adds soda ash and neutralized at 25-35 DEG C, continues to react 3h, obtains
Transparent containing hydrogen silicone oil, viscosity is 30cps.
（2）Second step, adds 6.2g pi-allyl poly(oxygen-silicon) alkoxy ethers（Molecular weight is 1000）, 3.8g ethylene glycol monobutyl ethers
(content 50%), is warming up to 110 DEG C, adds 0.03g chloroplatinic acids（1% is interpreted as with isopropanol floride）, controlling reaction temperature is 110-120
DEG C, 2h is reacted, vacuum drawn ethylene glycol monobutyl ether is opened.Transparent end epoxidized polyether silicone oil can be obtained, viscosity is 900-1100cps.
（3）3rd step, adds 10g polyetheramines, 19.6g isopropanols（Content 40%）, control temperature is at 80-85 DEG C, reaction
4h, can obtain ternary polymerization silicone oil.
（4）4th step, adds 8g moisture absorbing and sweat releasing agent（Polyester polyethers）, 60-80 DEG C is reacted 0.5-1h, cools to 35 DEG C,
Discharging, you can obtain hydrophilic smooth silicone oil CQ-2.
Embodiment 3：
（1）The first step, by 40g D4 and 0.36g vinyl double seal heads（Tetramethyl divinyl disiloxane）It is added to reaction
Kettle, control temperature adds 0.8g strong sulfuric acid response 6h, adds soda ash and neutralized at 25-35 DEG C, continues to react 3h, obtains
Transparent containing hydrogen silicone oil, viscosity is 15cps.
（2）Second step, adds 5.6g pi-allyl poly(oxygen-silicon) alkoxy ethers（Molecular weight is 1500）, 4.6g ethylene glycol monobutyl ethers
(content 50%), is warming up to 110 DEG C, adds 0.03g chloroplatinic acids（1% is interpreted as with isopropanol floride）, controlling reaction temperature is 110-120
DEG C, 2h is reacted, vacuum drawn ethylene glycol monobutyl ether is opened.Transparent end epoxidized polyether silicone oil can be obtained, viscosity is 1200-1300cps.
（3）3rd step, adds 12g polyetheramines, 16.8g isopropanols（Content 40%）, control temperature is at 80-85 DEG C, reaction
4h, can obtain ternary polymerization silicone oil.
（4）4th step, adds the hydrophilic wax disk(-sc)s of 2g, and 60-80 DEG C of reaction 0.5-1h cools to 35 DEG C, discharging, you can obtain parent
The refreshing silicone oil CQ-3 of neatly.
Embodiment 4：
Comparison study is tested：
（1）Material：CQ-1, CQ-2, CQ-3, the hydrophilic ice-feeling silicone oil A in market, market hydrophilic soft slide the white pure cotton drawing of silicone oil B, 40s
Frame cloth.
（2）Technique：One immersing and rolling, liquid carrying rate 80%, 160 DEG C bake 2min, fully moisture regain, evaluate performance.
（3）Result of the test：
Feel contrast is shown in Table 1
| Title | Softness | Slippery | Sophistication | Resilience sense | Fluffy degree |
| CQ-1 | 4.5 | 4.5 | 4.0 | 4.5 | 4.0 |
| CQ-2 | 5.0 | 4.5 | 5.0 | 4.5 | 4.5 |
| CQ-3 | 4.0 | 4.5 | 4.0 | 4.0 | 3.5 |
| The hydrophilic ice-feeling silicone oil A in market | 3.5 | 4.0 | 3.5 | 4.0 | 4.0 |
| Market hydrophilic soft slides silicone oil B | 4.0 | 4.0 | 4.0 | 4.0 | 3.5 |
As shown in Table 1, the hydrophilic smooth organic silicone finishing agent prepared through the present invention, the 40s cotton lycra cloths after treating, with excellent
Different softness, smooth degree, fine and smooth sense, resilience and fluffy degree；Existing products in markets is met and exceeded.
Hydrophily contrast is shown in Table 2
| Title | Hydrophily after moisture regain | Hydrophily after one month | Hydrophily after half a year |
| CQ-1 | 0-1s | 2-3s | 6-8s |
| CQ-2 | 0-1s | 3-4s | 7-9s |
| CQ-3 | 0-1s | 2-3s | 5-6s |
| The hydrophilic ice-feeling silicone oil A in market | 5-6s | 8-9s | 20-25s |
| Market hydrophilic soft slides silicone oil B | 1-2s | 6-8s | 15-20s |
As shown in Table 2, contrasted with market hydrophilic silicone oil A, B, hydrophilic smooth organic silicone finishing agent of the invention has excellent parent
It is aqueous, moment water suction, and with good placement protracted hydrophilicity；Assign the splendid moisture absorption of fabric, the dress ornament breathed freely, perspired
Property, meet the market demand.
Stability contrast is shown in Table 3
| Title | CQ-1 | CQ-2 | CQ-3 | The hydrophilic ice-feeling silicone oil A in market | Market hydrophilic soft slides silicone oil B |
| PH=3 | It is stable | It is stable | It is stable | It is stable | It is stable |
| PH=11 | It is stable | It is stable | It is stable | It is stable | It is stable |
| Glauber salt（20g/L） | It is stable | It is stable | It is stable | It is stable | It is stable |
| Dyestuff（2%） | It is stable | It is stable | It is stable | Precipitation | It is stable |
| Color fixing agent（20g/L） | It is stable | It is stable | Precipitation | Precipitation | It is stable |
| Shear 3000r/min | It is stable | It is stable | It is stable | Floating oil | It is stable |
| Move back and soft return dye effect | Bright in color light | Bright in color light | Typically | Coloured light is dim | Typically |
As shown in Table 3, hydrophilic smooth silicone oil of the invention has excellent stability, and with the good compatibility of other auxiliary agents；
And it is good to move back soft metachromia of returning, reduction dye-works processing risk meets big production requirement.
Consolidated statement 1, table 2, the data information of table 3, which can be seen that, implements hydrophilic smooth organic silicone finishing agent prepared by row 1
The various combination properties of CQ-2 show the most outstanding.
Claims (12)
1. a kind of preparation method of hydrophilic smooth organic silicone finishing agent, it is characterised in that：The preparation method includes following step
Suddenly：
1）Containing hydrogen silicone oil is synthesized
Use octamethylcy-clotetrasiloxane（D4）With vinyl closure agent under acidic catalyst effect, containing hydrogen silicone oil is synthesized；
2）End ring oxygen polyether silicone oil is synthesized
By pi-allyl poly(oxygen-silicon) alkoxy ether and step 1）In obtained containing hydrogen silicone oil in organic solvent, platinum chloride catalyst condition
Lower carry out addition polymerization, then vacuum pump solvent；
3）Ternary polymerization silicone oil
By polyetheramine and step 2）In obtained end ring oxygen polyether silicone oil under the conditions of organic solvent material, reaction is made ternary and is total to
Silicone oil；
4）By multifunction finishing agent and 3）In obtained ternary polymerization silicone oil be combined, lift correlated performance.
2. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 1）
Described in D4 and vinyl closure agent, at a certain temperature, add acidic catalyst, consumption is D4 1-6%, reacts 2-8h,
Obtain water white transparency thick liquid.
3. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 1）
Described in closure agent should contain a certain proportion of vinyl closure agent, such as vinyl list end socket or vinyl double seal head and other envelopes
Head agent is used with.
4. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 1）
Described in acidic catalyst be formic acid, acetic acid, sulfuric acid in one or two kinds of.
5. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 2）
Described in organic solvent for ethylene glycol monobutyl ether, ethylene glycol ether, glycol monoethyl ether, one kind of ethylene glycol monoethyl ether or
Several combinations of person.
6. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 2）
Described in pi-allyl poly(oxygen-silicon) alkoxy ether molecular structural formula be CH2=CHCH2O(C2H4O)m(C3H6O)nCH2(CHCH2) O, its
Middle m is 1-55, and n is 1-30.
7. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 2）
Described in pi-allyl poly(oxygen-silicon) alkoxy ether molecular weight be 400,800,1000,1500,2000 one or several kinds of groups
Close.
8. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 2）
Described in containing hydrogen silicone oil molal quantity：Pi-allyl poly(oxygen-silicon) alkoxy ether molal quantity is 0.5:1-2:1 ratio.
9. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 3）
Described in organic solvent be isopropanol, ethylene glycol, propane diols, monobutyl ether, single ether, the one or more combination of single propyl ether.
10. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 3）
Described in end ring oxygen polyether silicone oil molal quantity：Polyetheramine molal quantity is 1:2-2:1 ratio.
11. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 4）
Described in multifunction finishing agent for moisture absorbing and sweat releasing agent, aqueous polyurethane, nonionic penetrant, one kind of hydrophilic wax material or
A variety of mixtures.
12. a kind of preparation method of hydrophilic smooth organic silicone finishing agent according to claim 1, it is characterised in that step 4）
Described in multifunction finishing agent molal quantity：Ternary polymerization silicone oil molal quantity is 1:9-1:2.
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107556478A (en) * | 2016-07-01 | 2018-01-09 | 信越化学工业株式会社 | Siloxanes and its manufacture method containing aminoalkyl |
| CN108660771A (en) * | 2018-06-13 | 2018-10-16 | 广东传化富联精细化工有限公司 | A kind of preparation method of polyurethane-modified organosilicon moisture control agent microemulsion |
| CN111139652A (en) * | 2020-01-08 | 2020-05-12 | 东阳市德圣印染助剂有限公司 | Novel hydrophilic finishing agent for spinning |
| CN111304925A (en) * | 2020-03-25 | 2020-06-19 | 中山市天信助剂实业有限公司 | Block polyether amino silicone oil softening agent and preparation method thereof |
| CN112048067A (en) * | 2020-09-10 | 2020-12-08 | 广东宏昊化工有限公司 | Polyurethane modified amino polyether silicone oil and preparation method and application thereof |
| CN113430835A (en) * | 2021-06-18 | 2021-09-24 | 广东宏昊化工有限公司 | Liquid ammonia-like hydrophilic silicone oil compound and preparation method thereof |
| CN115787301A (en) * | 2022-11-18 | 2023-03-14 | 杭州传化精细化工有限公司 | Polyurethane modified organic silicon softener and preparation method and application thereof |
| CN116003804A (en) * | 2022-12-31 | 2023-04-25 | 浙江汉邦新材料股份有限公司 | Hydrophilic dustproof silicone oil finishing agent for fabric and preparation method thereof |
| CN117468239A (en) * | 2023-10-26 | 2024-01-30 | 清远市宏图助剂有限公司 | Amino acid modified polysiloxane fabric color fixing agent, preparation method and application thereof |
| CN117700757A (en) * | 2023-12-18 | 2024-03-15 | 宁波润禾高新材料科技股份有限公司 | Cool sense polysiloxane material, preparation method and application |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617863A (en) * | 2012-03-30 | 2012-08-01 | 广东工业大学 | Preparation method of hydrophilic block polyether aminosilicone |
| CN105504298A (en) * | 2016-01-14 | 2016-04-20 | 上海氟聚化学产品有限公司 | Ternary polymerization block polyether amino silicon oil softening agent and preparing method thereof |
-
2017
- 2017-05-22 CN CN201710363036.XA patent/CN107083683A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102617863A (en) * | 2012-03-30 | 2012-08-01 | 广东工业大学 | Preparation method of hydrophilic block polyether aminosilicone |
| CN105504298A (en) * | 2016-01-14 | 2016-04-20 | 上海氟聚化学产品有限公司 | Ternary polymerization block polyether amino silicon oil softening agent and preparing method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 《简明化学试剂手册》编写组编: "《简明化学试剂手册》", 31 January 1991, 上海科学技术出版社出版 第1版 * |
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| CN107556478A (en) * | 2016-07-01 | 2018-01-09 | 信越化学工业株式会社 | Siloxanes and its manufacture method containing aminoalkyl |
| CN108660771A (en) * | 2018-06-13 | 2018-10-16 | 广东传化富联精细化工有限公司 | A kind of preparation method of polyurethane-modified organosilicon moisture control agent microemulsion |
| CN111139652A (en) * | 2020-01-08 | 2020-05-12 | 东阳市德圣印染助剂有限公司 | Novel hydrophilic finishing agent for spinning |
| CN111304925A (en) * | 2020-03-25 | 2020-06-19 | 中山市天信助剂实业有限公司 | Block polyether amino silicone oil softening agent and preparation method thereof |
| CN112048067A (en) * | 2020-09-10 | 2020-12-08 | 广东宏昊化工有限公司 | Polyurethane modified amino polyether silicone oil and preparation method and application thereof |
| CN113430835A (en) * | 2021-06-18 | 2021-09-24 | 广东宏昊化工有限公司 | Liquid ammonia-like hydrophilic silicone oil compound and preparation method thereof |
| CN115787301A (en) * | 2022-11-18 | 2023-03-14 | 杭州传化精细化工有限公司 | Polyurethane modified organic silicon softener and preparation method and application thereof |
| CN116003804A (en) * | 2022-12-31 | 2023-04-25 | 浙江汉邦新材料股份有限公司 | Hydrophilic dustproof silicone oil finishing agent for fabric and preparation method thereof |
| CN117468239A (en) * | 2023-10-26 | 2024-01-30 | 清远市宏图助剂有限公司 | Amino acid modified polysiloxane fabric color fixing agent, preparation method and application thereof |
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