CN107227099A - A kind of air compressor wear resistant fire-retardant coating and preparation method thereof - Google Patents
A kind of air compressor wear resistant fire-retardant coating and preparation method thereof Download PDFInfo
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- CN107227099A CN107227099A CN201710609861.3A CN201710609861A CN107227099A CN 107227099 A CN107227099 A CN 107227099A CN 201710609861 A CN201710609861 A CN 201710609861A CN 107227099 A CN107227099 A CN 107227099A
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- parts
- resistant
- coupling agent
- fire
- air compressor
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- 238000000576 coating method Methods 0.000 title claims abstract description 48
- 239000011248 coating agent Substances 0.000 title claims abstract description 46
- 238000002360 preparation method Methods 0.000 title abstract description 11
- 239000003063 flame retardant Substances 0.000 title abstract description 6
- 239000007822 coupling agent Substances 0.000 claims abstract description 37
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 34
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims abstract description 33
- 239000000843 powder Substances 0.000 claims abstract description 33
- 235000019353 potassium silicate Nutrition 0.000 claims abstract description 17
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000011787 zinc oxide Substances 0.000 claims abstract description 17
- 239000002994 raw material Substances 0.000 claims abstract description 14
- 239000003822 epoxy resin Substances 0.000 claims abstract description 13
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 13
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims abstract description 12
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001768 carboxy methyl cellulose Substances 0.000 claims abstract description 12
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims abstract description 12
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims abstract description 12
- XFZRQAZGUOTJCS-UHFFFAOYSA-N phosphoric acid;1,3,5-triazine-2,4,6-triamine Chemical compound OP(O)(O)=O.NC1=NC(N)=NC(N)=N1 XFZRQAZGUOTJCS-UHFFFAOYSA-N 0.000 claims abstract description 12
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 12
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 12
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 12
- 239000010451 perlite Substances 0.000 claims abstract description 11
- 235000019362 perlite Nutrition 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- -1 alcohol fatty acid ester compound Chemical class 0.000 claims description 61
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 25
- 238000003756 stirring Methods 0.000 claims description 25
- 230000009970 fire resistant effect Effects 0.000 claims description 23
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 20
- 239000000194 fatty acid Substances 0.000 claims description 20
- 229930195729 fatty acid Natural products 0.000 claims description 20
- YKTSYUJCYHOUJP-UHFFFAOYSA-N [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] Chemical compound [O--].[Al+3].[Al+3].[O-][Si]([O-])([O-])[O-] YKTSYUJCYHOUJP-UHFFFAOYSA-N 0.000 claims description 16
- 239000002518 antifoaming agent Substances 0.000 claims description 16
- 239000002216 antistatic agent Substances 0.000 claims description 16
- 229910052593 corundum Inorganic materials 0.000 claims description 16
- 239000010431 corundum Substances 0.000 claims description 16
- 239000004575 stone Substances 0.000 claims description 16
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 15
- 239000002033 PVDF binder Substances 0.000 claims description 12
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 12
- OWICEWMBIBPFAH-UHFFFAOYSA-N (3-diphenoxyphosphoryloxyphenyl) diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=C(OP(=O)(OC=2C=CC=CC=2)OC=2C=CC=CC=2)C=CC=1)(=O)OC1=CC=CC=C1 OWICEWMBIBPFAH-UHFFFAOYSA-N 0.000 claims description 11
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 10
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 10
- RBNPOMFGQQGHHO-UHFFFAOYSA-N glyceric acid Chemical compound OCC(O)C(O)=O RBNPOMFGQQGHHO-UHFFFAOYSA-N 0.000 claims description 10
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 claims description 10
- 229910052726 zirconium Inorganic materials 0.000 claims description 10
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 5
- 239000002202 Polyethylene glycol Substances 0.000 claims description 5
- 150000003973 alkyl amines Chemical class 0.000 claims description 5
- 150000001412 amines Chemical class 0.000 claims description 5
- 239000004205 dimethyl polysiloxane Substances 0.000 claims description 5
- 150000002195 fatty ethers Chemical class 0.000 claims description 5
- 235000011187 glycerol Nutrition 0.000 claims description 5
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims description 5
- 229920001223 polyethylene glycol Polymers 0.000 claims description 5
- 229920001451 polypropylene glycol Polymers 0.000 claims description 5
- 229910001414 potassium ion Chemical group 0.000 claims description 5
- 239000011734 sodium Substances 0.000 claims description 5
- 229910001415 sodium ion Inorganic materials 0.000 claims description 5
- 238000005303 weighing Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims 3
- 229920002545 silicone oil Polymers 0.000 claims 1
- 230000007797 corrosion Effects 0.000 abstract description 6
- 238000005260 corrosion Methods 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 3
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 abstract 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 abstract 1
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract 1
- 235000010290 biphenyl Nutrition 0.000 abstract 1
- 239000004305 biphenyl Substances 0.000 abstract 1
- 125000006267 biphenyl group Chemical group 0.000 abstract 1
- 239000013530 defoamer Substances 0.000 abstract 1
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N phenylbenzene Natural products C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 229920001296 polysiloxane Polymers 0.000 description 4
- YNQLUTRBYVCPMQ-UHFFFAOYSA-N Ethylbenzene Chemical compound CCC1=CC=CC=C1 YNQLUTRBYVCPMQ-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 230000003111 delayed effect Effects 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- IVSZLXZYQVIEFR-UHFFFAOYSA-N m-xylene Chemical group CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 239000000758 substrate Substances 0.000 description 2
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- MQJKPEGWNLWLTK-UHFFFAOYSA-N Dapsone Chemical compound C1=CC(N)=CC=C1S(=O)(=O)C1=CC=C(N)C=C1 MQJKPEGWNLWLTK-UHFFFAOYSA-N 0.000 description 1
- GHKOFFNLGXMVNJ-UHFFFAOYSA-N Didodecyl thiobispropanoate Chemical compound CCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCC GHKOFFNLGXMVNJ-UHFFFAOYSA-N 0.000 description 1
- 239000003508 Dilauryl thiodipropionate Substances 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- DHKHKXVYLBGOIT-UHFFFAOYSA-N acetaldehyde Diethyl Acetal Natural products CCOC(C)OCC DHKHKXVYLBGOIT-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 235000019304 dilauryl thiodipropionate Nutrition 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- JBVCEGLZIMVTFE-UHFFFAOYSA-N formaldehyde;phenoxybenzene Chemical compound O=C.C=1C=CC=CC=1OC1=CC=CC=C1 JBVCEGLZIMVTFE-UHFFFAOYSA-N 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011261 inert gas Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 230000008719 thickening Effects 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/24—Electrically-conducting paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Fireproofing Substances (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of air compressor wear resistant fire-retardant coating, belong to technical field of coatings, include the raw material of following parts by weight:36 40 parts of brominated epoxy resin, 18 24 parts of Kynoar, 10 12 parts of alumina silicate, 57 parts of schmigel, 35 parts of glass-cermic powder, 67 parts of zinc oxide, 25 parts of expanded perlite, resorcinol are double(Diphenyl phosphoester)68 parts, 57 parts of melamine phosphate, 9 11 parts of triethyl citrate, 35 parts of waterglass, 0.5 1 parts of carboxymethyl cellulose, 13 parts of defoamer, 0.2 0.8 parts of antistatic additive, 46 parts of coupling agent, 14 18 parts of methanol, 17 20 parts of water;The invention also discloses a kind of preparation method of air compressor wear resistant fire-retardant coating;The present invention has preferably abrasive resistance and flameproof effect, and corrosion-resistant, service life is long.
Description
Technical Field
The invention relates to the technical field of coatings, and particularly relates to a wear-resistant and fire-resistant coating for an air compressor and a preparation method thereof.
Background
The fire-proof paint is a special paint which is used on the surface of flammable base material, can reduce the flammability of the surface of the material to be painted, can retard the rapid spread of fire and is used for improving the fire endurance of the material to be painted.
The fire-retardant mechanism of the fire-retardant coating can be roughly summarized as the following five points: 1. The fireproof coating has flame retardancy or incombustibility, so that the protected substrate is not directly contacted with air, the ignition of an object is delayed, and the combustion speed is reduced; 2. The fireproof coating has low heat conductivity coefficient besides flame retardancy or incombustibility, and can delay the transmission of flame temperature to a protected substrate; 3. the fire-proof coating is heated to decompose non-combustible inert gas, and dilute combustible gas decomposed by the protected object when heated, so that the protected object is not easy to burn or the burning speed is reduced; 4. The nitrogenous fireproof coating is heated to decompose groups such as NO, NH3 and the like, and the groups are combined with organic free radicals, so that the chain reaction is interrupted, and the temperature is reduced; 5. The expansion type fireproof coating expands and foams by heating to form a carbonaceous foam heat insulation layer to seal a protected object, so that the transfer of heat and a base material is delayed, and the object is prevented from catching fire and burning or the strength is prevented from being reduced due to the rise of temperature.
However, the existing fireproof coating for the air compressor is insufficient in wear resistance, acid and alkali resistance and fire resistance, short in service time and needs to be further enhanced.
In a reference document with publication number CN103740227A, a fire-resistant coating is disclosed, which comprises the following raw materials in parts by weight: 25-40 parts of diphenyl ether formaldehyde resin, 12-20 parts of polyvinyl acetal modified phenolic resin, 10-15 parts of m-benzene type unsaturated polyester resin, 6-10 parts of m-xylene, 10-14 parts of ethylbenzene, 3-7 parts of dilauryl thiodipropionate, 2-4 parts of carbon black, 6-9 parts of aluminium dihydrogen tripolyphosphate and 2-6 parts of diaminodiphenyl sulfone; wherein the oil absorption value of the aluminum dihydrogen tripolyphosphate is 25-30%. In the invention, the fireproof coating has good fireproof performance, excellent corrosion resistance, long service life and lower cost; but the performance of the fire resistant coating can still be further enhanced.
Disclosure of Invention
The invention aims to overcome the defects of the prior art and provides the wear-resistant and fire-resistant coating for the air compressor and the preparation method thereof, wherein the wear-resistant and fire-resistant coating is simple to prepare, has better wear resistance and fire-proof effect, is corrosion-resistant and has long service life.
The invention provides a wear-resistant and fire-resistant coating for an air compressor, which comprises the following raw materials in parts by weight:
36-40 parts of brominated epoxy resin, 18-24 parts of polyvinylidene fluoride, 10-12 parts of aluminum silicate, 5-7 parts of corundum powder, 3-5 parts of cast stone powder, 6-7 parts of zinc oxide, 2-5 parts of expanded perlite, 6-8 parts of resorcinol bis (diphenyl phosphate), 5-7 parts of melamine phosphate, 9-11 parts of triethyl citrate, 3-5 parts of water glass, 0.5-1 part of carboxymethyl cellulose, 1-3 parts of defoaming agent, 0.2-0.8 part of antistatic agent, 4-6 parts of coupling agent, 14-18 parts of methanol and 17-20 parts of water.
Preferably, the corundum powder and the cast stone powder have 270 meshes, and the aluminum silicate and the zinc oxide have 325 meshes.
Preferably, the water glass has a SiO in the range of 2.2 to 2.62/M2O modulus, wherein M represents sodium and/or potassium ions.
Preferably, the defoaming agent is one or a mixture of two or more of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
Preferably, the antistatic agent is one or a mixture of more than two of polyoxyethylene alkylamine, glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene fatty ether, polyoxyethylene alkylphenyl ether and polyethylene glycol ester fatty acid ester.
Preferably, the coupling agent is a mixture of a silane coupling agent, a titanate coupling agent and a zirconium coupling agent, and the weight ratio of the silane coupling agent to the titanate coupling agent to the zirconium coupling agent is 4:2: 1.
The invention also provides a preparation method of the wear-resistant and fire-resistant coating for the air compressor, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding aluminum silicate, corundum powder, cast stone powder, zinc oxide and expanded perlite into a stirrer, controlling the temperature to be 50-70 ℃, stirring for 10min, and standing for 3 min;
(3) adding brominated epoxy resin, polyvinylidene fluoride, resorcinol bis (diphenyl phosphate), melamine phosphate, triethyl citrate, water glass, a coupling agent, methanol and water into a stirrer, raising the temperature to 75-80 ℃, stirring for 20min, adding carboxymethyl cellulose, a defoaming agent and an antistatic agent, reducing the temperature to 30-40 ℃, uniformly stirring, and adjusting the pH to 7-8.
Wherein,
the stirring speed in the step (2) is 100-150r/min, and the stirring speed in the step (3) is 420-450 r/min.
The wear-resistant and fire-resistant coating for the air compressor and the preparation method thereof are simple to prepare, have better wear resistance and fire-proof effect, are corrosion-resistant and have long service life, and have the following specific beneficial effects:
(1) the brominated epoxy resin has good self-extinguishing property, heat resistance, electrical insulation property and cohesiveness, and can effectively protect the coating surface on the air compressor; the polyvinylidene fluoride has excellent chemical corrosion resistance, high-temperature color change resistance, oxidation resistance, wear resistance, flexibility, high expansion strength, impact strength, ultraviolet ray resistance and high-energy radiation resistance, and the combination of the brominated epoxy resin and the polyvinylidene fluoride can effectively ensure the wear resistance, high-temperature resistance and fire resistance of the coating and longer service life;
(2) the corundum powder, the cast stone powder, the aluminum silicate and the zinc oxide are used as fillers, so that the wear resistance and the high-temperature resistance and fire resistance of the coating can be effectively improved; the resorcinol bis (diphenyl phosphate) and the melamine phosphate can further improve the flame retardant property of the coating, thereby improving the fire resistance of the coating; the triethyl citrate has the function of plasticization, so that the toughness of the coating is improved;
(3) the water glass enables a dispersant to have the function of dissolving aid and can also improve the bonding capability of the coating; the carboxymethyl cellulose aqueous solution has the functions of thickening, film forming, adhesion, water retention, colloid protection, emulsification, suspension and the like, and can effectively improve the quality of the coating;
(4) the defoaming agent can prevent the generation of bubbles in the coating; the antistatic agent can reduce the generation of static electricity; the coupling agent can improve the performance of the coating;
(5) the raw materials are mixed according to the corresponding proportion, so that the mechanical strength, corrosion resistance, adhesive capacity, wear resistance and fire resistance of the coating can be effectively ensured, and the service life is long; the preparation method is simple and stable, and can effectively and fully mix the raw materials, thereby ensuring the quality of the coating.
Detailed Description
The present invention will be described in further detail with reference to specific examples.
Example 1
The wear-resistant and fire-resistant coating for the air compressor comprises the following raw materials in parts by weight:
36 parts of brominated epoxy resin, 18 parts of polyvinylidene fluoride, 10 parts of aluminum silicate, 5 parts of corundum powder, 3 parts of cast stone powder, 6 parts of zinc oxide, 2 parts of expanded perlite, 6 parts of resorcinol bis (diphenyl phosphate), 5 parts of melamine phosphate, 9 parts of triethyl citrate, 3 parts of water glass, 0.5 part of carboxymethyl cellulose, 1 part of defoaming agent, 0.2 part of antistatic agent, 4 parts of coupling agent, 14 parts of methanol and 17 parts of water.
In this example, the corundum powder and the cast stone powder had 270 mesh, and the aluminum silicate and the zinc oxide had 325 mesh.
In the present example, the water glass has SiO in the range of 2.2 to 2.62/M2O modulus, wherein M represents sodium and/or potassium ions.
In this embodiment, the defoaming agent is a mixture of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
In this example, the antistatic agent is a mixture of polyoxyethylene alkylamine, glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene fatty ether, polyoxyethylene alkylphenyl ether, and polyethylene glycol ester fatty acid ester.
In this embodiment, the coupling agent is a mixture of a silane coupling agent, a titanate coupling agent, and a zirconium coupling agent, and the weight ratio of the silane coupling agent, the titanate coupling agent, and the zirconium coupling agent is 4:2: 1.
The embodiment also provides a preparation method of the wear-resistant and fire-resistant coating for the air compressor, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding aluminum silicate, corundum powder, cast stone powder, zinc oxide and expanded perlite into a stirrer, controlling the temperature at 50 ℃, stirring for 10min, and standing for 3 min;
(3) adding brominated epoxy resin, polyvinylidene fluoride, resorcinol bis (diphenyl phosphate), melamine phosphate, triethyl citrate, water glass, a coupling agent, methanol and water into a stirrer, raising the temperature to 75 ℃, stirring for 20min, adding carboxymethyl cellulose, a defoaming agent and an antistatic agent, reducing the temperature to 30 ℃, stirring uniformly, and adjusting the pH to 7.
Wherein,
the stirring speed in the step (2) is 100r/min, and the stirring speed in the step (3) is 420 r/min.
Example 2
The wear-resistant and fire-resistant coating for the air compressor comprises the following raw materials in parts by weight:
38 parts of brominated epoxy resin, 21 parts of polyvinylidene fluoride, 11 parts of aluminum silicate, 6 parts of corundum powder, 4 parts of cast stone powder, 6.5 parts of zinc oxide, 4 parts of expanded perlite, 7 parts of resorcinol bis (diphenyl phosphate), 6 parts of melamine phosphate, 10 parts of triethyl citrate, 4 parts of water glass, 0.8 part of carboxymethyl cellulose, 2 parts of defoaming agent, 0.5 part of antistatic agent, 5 parts of coupling agent, 16 parts of methanol and 19 parts of water.
In this example, the corundum powder and the cast stone powder had 270 mesh, and the aluminum silicate and the zinc oxide had 325 mesh.
In the present example, the water glass has SiO in the range of 2.2 to 2.62/M2O modulus, wherein M represents sodium and/or potassium ions.
In this embodiment, the defoaming agent is a mixture of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
In this example, the antistatic agent is a mixture of polyoxyethylene alkylamine, glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene fatty ether, polyoxyethylene alkylphenyl ether, and polyethylene glycol ester fatty acid ester.
In this embodiment, the coupling agent is a mixture of a silane coupling agent, a titanate coupling agent, and a zirconium coupling agent, and the weight ratio of the silane coupling agent, the titanate coupling agent, and the zirconium coupling agent is 4:2: 1.
The embodiment also provides a preparation method of the wear-resistant and fire-resistant coating for the air compressor, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding aluminum silicate, corundum powder, cast stone powder, zinc oxide and expanded perlite into a stirrer, controlling the temperature at 60 ℃, stirring for 10min, and standing for 3 min;
(3) adding brominated epoxy resin, polyvinylidene fluoride, resorcinol bis (diphenyl phosphate), melamine phosphate, triethyl citrate, water glass, a coupling agent, methanol and water into a stirrer, raising the temperature to 78 ℃, stirring for 20min, adding carboxymethyl cellulose, a defoaming agent and an antistatic agent, reducing the temperature to 35 ℃, uniformly stirring, and adjusting the pH to 7.5.
Wherein,
the stirring speed in the step (2) is 130r/min, and the stirring speed in the step (3) is 435 r/min.
Example 3
The wear-resistant and fire-resistant coating for the air compressor comprises the following raw materials in parts by weight:
40 parts of brominated epoxy resin, 24 parts of polyvinylidene fluoride, 12 parts of aluminum silicate, 7 parts of corundum powder, 5 parts of cast stone powder, 7 parts of zinc oxide, 5 parts of expanded perlite, 8 parts of resorcinol bis (diphenyl phosphate), 7 parts of melamine phosphate, 11 parts of triethyl citrate, 5 parts of water glass, 1 part of carboxymethyl cellulose, 3 parts of defoaming agent, 0.8 part of antistatic agent, 6 parts of coupling agent, 18 parts of methanol and 20 parts of water.
In this example, the corundum powder and the cast stone powder had 270 mesh, and the aluminum silicate and the zinc oxide had 325 mesh.
In the present example, the water glass has SiO in the range of 2.2 to 2.62/M2O modulus, wherein M represents sodium and/or potassium ions.
In this embodiment, the defoaming agent is a mixture of silicone emulsion, a higher alcohol fatty acid ester complex, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether, and polydimethylsiloxane.
In this example, the antistatic agent is a mixture of polyoxyethylene alkylamine, glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene fatty ether, polyoxyethylene alkylphenyl ether, and polyethylene glycol ester fatty acid ester.
In this embodiment, the coupling agent is a mixture of a silane coupling agent, a titanate coupling agent, and a zirconium coupling agent, and the weight ratio of the silane coupling agent, the titanate coupling agent, and the zirconium coupling agent is 4:2: 1.
The embodiment also provides a preparation method of the wear-resistant and fire-resistant coating for the air compressor, which comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding aluminum silicate, corundum powder, cast stone powder, zinc oxide and expanded perlite into a stirrer, controlling the temperature to be 50-70 ℃, stirring for 10min, and standing for 3 min;
(3) adding brominated epoxy resin, polyvinylidene fluoride, resorcinol bis (diphenyl phosphate), melamine phosphate, triethyl citrate, water glass, a coupling agent, methanol and water into a stirrer, raising the temperature to 80 ℃, stirring for 20min, adding carboxymethyl cellulose, a defoaming agent and an antistatic agent, reducing the temperature to 40 ℃, uniformly stirring, and adjusting the pH to 8.
Wherein,
the stirring speed in the step (2) is 150r/min, and the stirring speed in the step (3) is 450 r/min.
The above description is only a preferred embodiment of the present invention, and the protection scope of the present invention is not limited to the above embodiments, and all technical solutions belonging to the idea of the present invention belong to the protection scope of the present invention. It should be noted that modifications and embellishments within the scope of the invention may occur to those skilled in the art without departing from the principle of the invention, and are considered to be within the scope of the invention.
Claims (8)
1. The wear-resistant and fire-resistant coating for the air compressor is characterized by comprising the following components in parts by weight: the feed comprises the following raw materials in parts by weight:
36-40 parts of brominated epoxy resin, 18-24 parts of polyvinylidene fluoride, 10-12 parts of aluminum silicate, 5-7 parts of corundum powder, 3-5 parts of cast stone powder, 6-7 parts of zinc oxide, 2-5 parts of expanded perlite, 6-8 parts of resorcinol bis (diphenyl phosphate), 5-7 parts of melamine phosphate, 9-11 parts of triethyl citrate, 3-5 parts of water glass, 0.5-1 part of carboxymethyl cellulose, 1-3 parts of defoaming agent, 0.2-0.8 part of antistatic agent, 4-6 parts of coupling agent, 14-18 parts of methanol and 17-20 parts of water.
2. The wear-resistant and fire-resistant coating for the air compressor, according to claim 1, is characterized in that: the meshes of the corundum powder and the cast stone powder are 270 meshes, and the meshes of the aluminum silicate and the zinc oxide are 325 meshes.
3. The wear-resistant and fire-resistant coating for the air compressor, according to claim 1, is characterized in that: the water glass has SiO in the range of 2.2 to 2.62/M2O modulus, wherein M represents sodium and/or potassium ions.
4. The wear-resistant and fire-resistant coating for the air compressor, according to claim 1, is characterized in that: the defoaming agent is one or a mixture of more than two of emulsified silicone oil, a higher alcohol fatty acid ester compound, polyoxyethylene polyoxypropylene pentaerythritol ether, polyoxyethylene polyoxypropylene amine ether, polyoxypropylene glycerol ether, polyoxypropylene polyoxyethylene glycerol ether and polydimethylsiloxane.
5. The wear-resistant and fire-resistant coating for the air compressor, according to claim 1, is characterized in that: the antistatic agent is one or more of polyoxyethylene alkylamine, glycerin fatty acid ester, sorbitan fatty acid ester, polyoxyethylene fatty ether, polyoxyethylene alkylphenyl ether and polyethylene glycol ester fatty acid ester.
6. The wear-resistant and fire-resistant coating for the air compressor, according to claim 1, is characterized in that: the coupling agent is a mixture of a silane coupling agent, a titanate coupling agent and a zirconium coupling agent, and the weight ratio of the silane coupling agent to the titanate coupling agent to the zirconium coupling agent is 4:2: 1.
7. The method for preparing the wear-resistant and fire-resistant coating for the air compressor, according to any one of claims 1 to 6, is characterized in that: the method comprises the following steps:
(1) weighing the raw materials in parts by weight;
(2) adding aluminum silicate, corundum powder, cast stone powder, zinc oxide and expanded perlite into a stirrer, controlling the temperature to be 50-70 ℃, stirring for 10min, and standing for 3 min;
(3) adding brominated epoxy resin, polyvinylidene fluoride, resorcinol bis (diphenyl phosphate), melamine phosphate, triethyl citrate, water glass, a coupling agent, methanol and water into a stirrer, raising the temperature to 75-80 ℃, stirring for 20min, adding carboxymethyl cellulose, a defoaming agent and an antistatic agent, reducing the temperature to 30-40 ℃, uniformly stirring, and adjusting the pH to 7-8.
8. The method for preparing the wear-resistant and fire-resistant coating for the air compressor, according to claim 7, is characterized in that: the stirring speed in the step (2) is 100-150r/min, and the stirring speed in the step (3) is 420-450 r/min.
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CN108485492A (en) * | 2018-04-25 | 2018-09-04 | 青岛中能集团有限公司 | A kind of effective automobile specified external paint coating of exhaust |
CN108976628A (en) * | 2018-06-29 | 2018-12-11 | 芜湖市新京桥包装科技有限公司 | A kind of EPS pressure-resisting plate produced using supercritical carbon dioxide process |
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