CN107221617B - 一种防酸油 - Google Patents
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Abstract
本发明涉及一种防酸油,由以下重量百分比的各组分组成:硅烷偶联剂,10%‑20%;去离子水,20%‑30%;加氢精制矿物油,10%‑20%;烷基磺酸盐,10%‑25%;石油磺酸钡,15%‑20%;十二烯基丁二酸,5%‑10%。本发明弥补了铅酸蓄电池行业金属部件在酸雾浓度大的环境下防酸防腐,使用方便不含有毒成分,环保性好。
Description
技术领域
本发明涉及一种防酸油,具体涉及一种用于蓄电池金属部件的防酸油。
背景技术
蓄电池(Storage Battery)是将化学能直接转化成电能的一种装置,是按可再充电设计的电池,通过可逆的化学反应实现再充电,通常是指铅酸蓄电池,它是电池中的一种,属于二次电池。它的工作原理:充电时利用外部的电能使内部活性物质再生,把电能储存为化学能,需要放电时再次把化学能转换为电能输出,比如生活中常用的手机电池等。
蓄电池内部结构需要大量金属进行支撑,又由于其内部具有大量的酸性液体,内部酸雾浓度过高,会对金属进行腐蚀,因此需要在金属外侧涂膜一层防酸油,以防止内部金属被酸雾腐蚀。
发明内容
为解决上述技术问题,本发明的目的是提供一种防酸油以防止蓄电池内部的金属件被内部的酸雾腐蚀。
本发明的技术方案如下:
一种防酸油,其特征在于,包括以下原料:硅烷偶联剂、去离子水、加氢精制矿物油、烷基磺酸盐、石油磺酸钡、十二烯基丁二酸。
进一步的,各原料的重量百分比如下:
硅烷偶联剂, 10%-20%;
去离子水, 20%-30%;
加氢精制矿物油, 10%-20%;
烷基磺酸盐, 10%-25%;
石油磺酸钡, 15%-20%;
十二烯基丁二酸 , 5%-10%。
进一步的,所述防酸油的制备方法如下,
S1、将加氢精制矿物油注入到容器中,将该容器的内部压力调整为标准大气压的两倍,温度为25℃~30℃;
S2、将烷基磺酸盐通过注射装置注入到容器中,并放置2~4小时;
S3、将容器中的压力恢复至常压,将石油磺酸钡和十二烯基丁二酸加入到到该容器中,打开该容器,通过电磁搅拌棒对改容器内的物料进行搅拌,搅拌时间为1~2小时,得到A溶液;
S4、取去离子水于另一容器中,放入用去离子水清洗干净的磁力搅拌棒,开始搅拌,搅拌速度控制在使去离子水形成漩涡,但是不溅出容器 ;向容器中加入硅烷偶联剂搅拌均匀,放置2小时后得到B溶液;
S5、将步骤S3得到的A溶液和步骤S4得到的B溶液混合,并通过去离子水清洗干净的磁力搅拌棒搅拌30分钟,即得到防酸油。
进一步的,所述硅烷偶联剂的制备方法为:
a、将氨基硅与邻苯二甲酸混合,加入溶剂,混合搅拌后形成混合溶液;
b、在向该混合液中加入浓度80%以上的硫酸,反应后静止两小时;
c、在氮气保护下,向步骤b得到的溶液中加入阻燃型环氧树脂,搅拌1-2小时后得到硅烷偶联剂。
进一步的,所述溶剂为甲苯和无水乙醇的混合物,其中所述甲苯和无水乙醇的体积比为1:1。
进一步的,所述阻燃型环氧树脂为四氯双酚A环氧树脂、四嗅双酚A环氧树脂、只聚磷睛系环氧树脂中的任一种。
借由上述方案,本发明至少具有以下优点:
(1)本发明加入了烷基磺酸盐,其具有良好的润湿性,并具有良好的生物降解性能,不陈胜度代谢物,对人体皮肤刺激性小;
(2)本发明加入了石油磺酸钡,具有优良的抗潮湿、抗盐雾、抗盐水和水置换性能,对多种金属具有优良的防锈性能。
(3)本发明加入了十二烯基丁二酸,其加入后可在金属表面形成牢固的油膜从而保护金属表面不被锈蚀和腐蚀。
(4)本发明制备方法中,先通过高压将加氢精制矿物油和烷基磺酸盐混合,相比较于普通压力下的混合,混合更加充分。
(5)本发明制备方法中加入了硅烷偶联剂,该硅烷偶联剂主链引入了杂芳环,可以在不降低其耐热性的前提下改善防酸性能。
(6)该硅烷偶联剂中加入了阻燃型环氧树脂,为防酸油提供了阻燃特性。
具体实施方式
下面结合实施例,对本发明的具体实施方式作进一步详细描述。以下实施例用于说明本发明,但不用来限制本发明的范围。
防酸油的制备方法如下,
S1、将加氢精制矿物油注入到容器中,将该容器的内部压力调整为标准大气压的两倍,温度为25℃~30℃;
S2、将烷基磺酸盐通过注射装置注入到容器中,并放置2~4小时;
S3、将容器中的压力恢复至常压,将石油磺酸钡和十二烯基丁二酸加入到到该容器中,打开该容器,通过电磁搅拌棒对改容器内的物料进行搅拌,搅拌时间为1~2小时,得到A溶液;
S4、取去离子水于另一容器中,放入用去离子水清洗干净的磁力搅拌棒,开始搅拌,搅拌速度控制在使去离子水形成漩涡,但是不溅出容器 ;向容器中加入硅烷偶联剂搅拌均匀,放置2小时后得到B溶液;
S5、将步骤S3得到的A溶液和步骤S4得到的B溶液混合,并通过去离子水清洗干净的磁力搅拌棒搅拌30分钟,即得到防酸油。
其中硅烷偶联剂的制备方法为:
a、将氨基硅与邻苯二甲酸混合,加入溶剂,混合搅拌后形成混合溶液;
b、在向该混合液中加入浓度80%以上的硫酸,反应后静止两小时;
c、在氮气保护下,向步骤b得到的溶液中加入阻燃型环氧树脂,搅拌1-2小时后得到硅烷偶联剂。
其中溶剂为甲苯和无水乙醇的混合物,其中所述甲苯和无水乙醇的体积比为1:1;阻燃型环氧树脂为四氯双酚A环氧树脂、四嗅双酚A环氧树脂、只聚磷睛系环氧树脂中的任一种。
实施例1
硅烷偶联剂, 10%;
去离子水, 20%;
加氢精制矿物油, 20%;
烷基磺酸盐, 20%
石油磺酸钡, 25%
十二烯基丁二酸 , 5%。
实施例2
硅烷偶联剂, 15%;
去离子水, 25%;
加氢精制矿物油, 10%
烷基磺酸盐, 25%;
石油磺酸钡, 20%;
十二烯基丁二酸 , 5%。
实施例3
硅烷偶联剂, 15%;
去离子水, 22%;
加氢精制矿物油, 18%;
烷基磺酸盐, 18%;
石油磺酸钡, 20%;
十二烯基丁二酸 , 7%。
实施例4
硅烷偶联剂, 20%;
去离子水, 30%;
加氢精制矿物油, 10%;
烷基磺酸盐, 15%;
石油磺酸钡, 15%;
十二烯基丁二酸 , 10%。
本发明至少具有以下优点:
(1)本发明加入了烷基磺酸盐,其具有良好的润湿性,并具有良好的生物降解性能,不陈胜度代谢物,对人体皮肤刺激性小;
(2)本发明加入了石油磺酸钡,具有优良的抗潮湿、抗盐雾、抗盐水和水置换性能,对多种金属具有优良的防锈性能。
(3)本发明加入了十二烯基丁二酸,其加入后可在金属表面形成牢固的油膜从而保护金属表面不被锈蚀和腐蚀。
(4)本发明制备方法中,先通过高压将加氢精制矿物油和烷基磺酸盐混合,相比较于普通压力下的混合,混合更加充分。
(5)本发明制备方法中加入了硅烷偶联剂,该硅烷偶联剂主链引入了杂芳环,可以在不降低其耐热性的前提下改善防酸性能。
(6)该硅烷偶联剂中加入了阻燃型环氧树脂,为防酸油提供了阻燃特性。
本发明弥补了铅酸蓄电池行业金属部件在酸雾浓度大的环境下防酸防腐,使用方便不含有毒成分,环保性好。
以上所述仅是本发明的优选实施方式,并不用于限制本发明,应当指出,对于本技术领域的普通技术人员来说,在不脱离本发明技术原理的前提下,还可以做出若干改进和变型,这些改进和变型也应视为本发明的保护范围。
Claims (3)
1.一种防酸油的制备方法,包括以下原料:硅烷偶联剂、去离子水、加氢精制矿物油、烷基磺酸盐、石油磺酸钡、十二烯基丁二酸,各原料的重量百分比如下:
硅烷偶联剂, 10%-20%;
去离子水, 20%-30%;
加氢精制矿物油, 10%-20%;
烷基磺酸盐, 10%-25%;
石油磺酸钡, 15%-20%;
十二烯基丁二酸, 5%-10%
特征在于:防酸油的制备方法如下:
S1、将加氢精制矿物油注入到容器中,将该容器的内部压力调整为标准大气压的两倍,温度为25℃~30℃;
S2、将烷基磺酸盐通过注射装置注入到容器中,并放置2~4小时;
S3、将容器中的压力恢复至常压,将石油磺酸钡和十二烯基丁二酸加入到该容器中,打开该容器,通过电磁搅拌棒对改容器内的物料进行搅拌,搅拌时间为1~2小时,得到A溶液;
S4、取去离子水于另一容器中,放入用去离子水清洗干净的磁力搅拌棒,开始搅拌,搅拌速度控制在使去离子水形成漩涡,但是不溅出容器;向容器中加入硅烷偶联剂搅拌均匀,放置2小时后得到B溶液,其中所述硅烷偶联剂的制备方法为:a、将氨基硅与邻苯二甲酸混合,加入溶剂,混合搅拌后形成混合溶液;b、在向该混合液中加入浓度80%以上的硫酸,反应后静止两小时;c、在氮气保护下,向步骤b得到的溶液中加入阻燃型环氧树脂,搅拌1-2小时后得到硅烷偶联剂;
S5、将步骤S3得到的A溶液和步骤S4得到的B溶液混合,并通过去离子水清洗干净的磁力搅拌棒搅拌30分钟,即得到防酸油。
2.根据权利要求1所述的一种防酸油制备方法,其特征在于:所述溶剂为甲苯和无水乙醇的混合物,其中所述甲苯和无水乙醇的体积比为1:1。
3.根据权利要求2所述的一种防酸油制备方法,其特征在于:所述阻燃型环氧树脂为四氯双酚A环氧树脂、四溴双酚A环氧树脂任一种。
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CN103409221A (zh) * | 2013-07-02 | 2013-11-27 | 昌利锻造有限公司 | 一种金属切削液及其制备方法 |
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CN103361649A (zh) * | 2012-04-09 | 2013-10-23 | 殷邗清 | 一种豆蔻酸油溶性缓蚀剂的配制方法 |
CN103409221A (zh) * | 2013-07-02 | 2013-11-27 | 昌利锻造有限公司 | 一种金属切削液及其制备方法 |
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