CN107216709A - One kind printing environmentally friendly UV curable ink and preparation method thereof - Google Patents
One kind printing environmentally friendly UV curable ink and preparation method thereof Download PDFInfo
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- CN107216709A CN107216709A CN201710521187.3A CN201710521187A CN107216709A CN 107216709 A CN107216709 A CN 107216709A CN 201710521187 A CN201710521187 A CN 201710521187A CN 107216709 A CN107216709 A CN 107216709A
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- curable ink
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- environmental protection
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides a kind of printing environmentally friendly UV curable ink and preparation method thereof, and the UV curable ink includes the composition of following parts by weight：Ultraviolet powder：15 ~ 25 parts, acrylic resin：20 ~ 30 parts, propylene glycol diacrylate：25 ~ 35 parts, light trigger：5 ~ 10 parts, difunctional photoactive：10 ~ 15 parts, sensitising agent：1 ~ 5 part, organic solvent：40 ~ 50 parts, filler：10 ~ 15 parts.The UV curable ink composition composition is reasonable in design, and preparation method is simply saved, environmentally friendly, and rate of drying is fast, and water-fast, solvent resistant, anti-wear performance is good.
Description
Technical field
The invention belongs to printing-ink technical field, in particular it relates to a kind of printing with environmentally friendly UV curable ink and
Its preparation method.
Background technology
Ink is by chromoplast（Such as pigment, dyestuff）, link stuff, fill out（Fill）The material compositions such as material, additional material it is uniform
Mixture；It can be printed, and be dried in printed body；It is to have color, the pulpous state adherent with certain fluidity.Cause
This, color（Form and aspect）, body bone（The rheological properties such as dilute thick, fluidity）It is three most important performances of ink with drying property.
Their species is a lot, and physical property is also different, and what is had is very thick, very viscous；And have it is quite dilute.What is had is connected with vegetable oil work
Ramming material；What is had makees link stuff with resin and solvent or water etc..These be all according to the object i.e. stock of printing, printing process,
Type and drying means of printing plate etc. are determined.
Ink is the material for being used in printing process form graph text information, therefore ink in press acts on not insignificant,
It directly determines contrast, color, definition of printed matter epigraph etc..In press we are it should be understood that the composition and oil of ink
The classification of ink.
Ink should have chromatic colour, good printing adaptability, suitable rate of drying.In addition, should also have one
Application index in terms of fixed solvent resistant, acid, alkali, water, light, heat.With printing, paper and other requirements etc. increasingly
Height, the technical conditions to ink requirements also increase.Such as the high speed multicolour press and assorted rotary press in modern age, it is desirable to
Ink with several seconds, even dry faster by speed.Glass lament and gold, silver lament, art paper requirement have the ink of light.Print plastics
Film, it is desirable to be well combined with plastic foil；Or the ink being attached together to greatest extent with plastic foil bonding.Print specialty printing
Product, it is desirable to use photosensitive ink etc..
Wherein, ultraviolet light solidifies（UV）Ink refers in the case where ultraviolet irradiates, and utilizes different wave length and the ultraviolet light of energy
Make ink film forming and the ink dried.Using different ultraviolet spectras, different-energy can be produced, by the list in different ink vehicles
Body aggregates into polymer, so the color film of UV ink has good mechanically and chemically performance.The major advantage of UV ink has：
(1) without solvent；(2) rate of drying is fast, and power consumption is few；(3) good luster, it is bright in luster；(4) water-fast, solvent resistant, anti-wear performance
It is good.Light trigger is a kind of easily by light activated compound in UV ink, and free radical, energy transfer are excited into after illumination is absorbed
To photonasty molecule or photocrosslinking agent, UV ink are made to occur photocuring reaction.Current UV ink turn into a kind of more ripe ink skill
Art, its pollutant emission is almost nil.Except without solvent, UV ink are also just like scumming is difficult, and site is clear, the bright-coloured light of mass colour
Bright, chemical-resistance is excellent, the advantages of low-consuming.
For UV curable ink, the current country is primarily present following patent document：
China Patent Publication No.：CN105733351A, discloses a kind of UV curable ink.Described in the UV curable ink
Component presses following weight score：Aliphatic modified 15~27 parts of epoxy acrylic resin；Propylene glycol diacrylate 23~30
Part；2~11 parts of dyestuff；5~10 parts of light trigger；2~12 parts of accelerator；10~19 parts of epoxy acrylic resin；1.6- oneself two
8~17 parts of alcohol diacrylate；2~10 parts of trimethylolpropane trimethacrylate；3~10 parts of defoamer.The purpose of the present invention
It is to provide the UV curable ink that a kind of curing rate is fast, adhesiveness is strong.However, the UV curable that the patent is provided
Ink, production cost is high, using raw material not environmentally.
The content of the invention
To solve above-mentioned problem, it is an object of the invention to provide one kind printing environmental protection UV curable ink
And preparation method thereof, the UV curable ink composition composition is reasonable in design, and preparation method is simply saved, environmentally friendly,
Rate of drying is fast, and water-fast, solvent resistant, anti-wear performance is good.
To reach above-mentioned purpose, the technical scheme is that：
One kind printing includes the composition of following parts by weight with environmentally friendly UV curable ink, the UV curable ink：It is ultraviolet
Powder：15 ~ 25 parts, acrylic resin：20 ~ 30 parts, propylene glycol diacrylate：25 ~ 35 parts, light trigger：5 ~ 10 parts, double officials
Photoactive can be rolled into a ball：10 ~ 15 parts, sensitising agent：1 ~ 5 part, organic solvent：40 ~ 50 parts, filler：10 ~ 15 parts.
Further, the UV curable ink includes the composition of following parts by weight：Ultraviolet powder：15 ~ 20 parts, acrylic acid tree
Fat：25 ~ 30 parts, propylene glycol diacrylate：30 ~ 35 parts, light trigger：5 ~ 8 parts, difunctional photoactive：13~15
Part, sensitising agent：2 ~ 5 parts, organic solvent：45 ~ 50 parts, filler：10 ~ 13 parts.
Preferably, the UV curable ink includes the composition of following parts by weight：Ultraviolet powder：20 parts, acrylic resin：
25 parts, propylene glycol diacrylate：30 parts, light trigger：8 parts, difunctional photoactive：14 parts, sensitising agent：2 parts, have
Machine solvent：45 parts, filler：12 parts.
Preferably, the organic solvent is butyl.
Preferably, the difunctional photoactive is tri (propylene glycol) diacrylate or neopentyl glycol diacrylate
Ester.
Preferably, the light trigger is a- hydroxy cyclohexyl phenylketones or a- hydroxyisopropyl Benzophenones.
Preferably, the sensitising agent is triethanolamine or N methyldiethanol amine.
Preferably, the filler is in barium sulfate, talcum powder, silica, calcium hydroxide, magnesium hydroxide and calcium carbonate
One or more.
Meanwhile, the present invention also provides a kind of preparation method of the environmentally friendly UV curable ink of printing, the preparation method
Comprise the following steps：1) at 20 ~ 25 DEG C, by ultraviolet powder, acrylic resin, propylene glycol diacrylate send into dispersion machine with
1200 ~ 1500 revs/min of Rate Dispersion is uniform；2) by light trigger, difunctional photoactive, sensitising agent, organic solvent and
Filler is well mixed with 800 ~ 1000 revs/min of rotating speed, and with step 1) after gained mixed liquor mixes, with 1200 ~ 1500 revs/min
Rate Dispersion it is uniform, obtain dispersion liquid；3) gained dispersion liquid is placed on three-roller and is ground to fineness less than 20 μm, be filtered to remove
Impurity, that is, obtain the environmentally friendly UV curable ink finished product of the printing.
The beneficial effects of the present invention are：
The UV curable ink composition composition is reasonable in design, and preparation method is simply saved, environmentally friendly, rate of drying
It hurry up, water-fast, solvent resistant, anti-wear performance is good.
Embodiment
Below by specific embodiment, the present invention is described further, but embodiment is not intended to limit the protection of the present invention
Scope.
A kind of printing of the present invention includes following weight with environmentally friendly UV curable ink, the UV curable ink
Measure the composition of part：Ultraviolet powder：15 ~ 25 parts, acrylic resin：20 ~ 30 parts, propylene glycol diacrylate：25 ~ 35 parts, light draws
Send out agent：5 ~ 10 parts, difunctional photoactive：10 ~ 15 parts, sensitising agent：1 ~ 5 part, organic solvent：40 ~ 50 parts, filler：10~15
Part.
Further, the UV curable ink includes the composition of following parts by weight：Ultraviolet powder：15 ~ 20 parts, acrylic acid tree
Fat：25 ~ 30 parts, propylene glycol diacrylate：30 ~ 35 parts, light trigger：5 ~ 8 parts, difunctional photoactive：13~15
Part, sensitising agent：2 ~ 5 parts, organic solvent：45 ~ 50 parts, filler：10 ~ 13 parts.
Preferably, the UV curable ink includes the composition of following parts by weight：Ultraviolet powder：20 parts, acrylic resin：
25 parts, propylene glycol diacrylate：30 parts, light trigger：8 parts, difunctional photoactive：14 parts, sensitising agent：2 parts, have
Machine solvent：45 parts, filler：12 parts.
Preferably, the organic solvent is butyl.
Preferably, the difunctional photoactive is tri (propylene glycol) diacrylate or neopentyl glycol diacrylate
Ester.
Preferably, the light trigger is a- hydroxy cyclohexyl phenylketones or a- hydroxyisopropyl Benzophenones.
Preferably, the sensitising agent is triethanolamine or N methyldiethanol amine.
Preferably, the filler is in barium sulfate, talcum powder, silica, calcium hydroxide, magnesium hydroxide and calcium carbonate
One or more.
Meanwhile, the present invention also provides a kind of preparation method of the environmentally friendly UV curable ink of printing, the preparation method
Comprise the following steps：1) at 20 ~ 25 DEG C, by ultraviolet powder, acrylic resin, propylene glycol diacrylate send into dispersion machine with
1200 ~ 1500 revs/min of Rate Dispersion is uniform；2) by light trigger, difunctional photoactive, sensitising agent, organic solvent and
Filler is well mixed with 800 ~ 1000 revs/min of rotating speed, and with step 1) after gained mixed liquor mixes, with 1200 ~ 1500 revs/min
Rate Dispersion it is uniform, obtain dispersion liquid；3) gained dispersion liquid is placed on three-roller and is ground to fineness less than 20 μm, be filtered to remove
Impurity, that is, obtain the environmentally friendly UV curable ink finished product of the printing.
It should be noted that the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted.Although with reference to compared with
The present invention is described in detail good embodiment, it will be understood by those within the art that, can be to the technology of invention
Scheme is modified or equivalent substitution, and without departing from the scope of technical solution of the present invention, it all should cover the power in the present invention
In sharp claimed range.
Claims (9)
1. one kind printing environmental protection UV curable ink, it is characterised in that the UV curable ink includes following weight
The composition of part：Ultraviolet powder：15 ~ 25 parts, acrylic resin：20 ~ 30 parts, propylene glycol diacrylate：It is 25 ~ 35 parts, light-initiated
Agent：5 ~ 10 parts, difunctional photoactive：10 ~ 15 parts, sensitising agent：1 ~ 5 part, organic solvent：40 ~ 50 parts, filler：10~15
Part.
2. a kind of printing environmental protection UV curable ink according to claim 1, it is characterised in that the UV-curing
Carburetion ink includes the composition of following parts by weight：Ultraviolet powder：15 ~ 20 parts, acrylic resin：25 ~ 30 parts, DPG diacrylate
Ester：30 ~ 35 parts, light trigger：5 ~ 8 parts, difunctional photoactive：13 ~ 15 parts, sensitising agent：2 ~ 5 parts, organic solvent：45~
50 parts, filler：10 ~ 13 parts.
3. a kind of printing environmental protection UV curable ink according to claim 1, it is characterised in that the UV-curing
Carburetion ink includes the composition of following parts by weight：Ultraviolet powder：20 parts, acrylic resin：25 parts, propylene glycol diacrylate：30
Part, light trigger：8 parts, difunctional photoactive：14 parts, sensitising agent：2 parts, organic solvent：45 parts, filler：12 parts.
4. a kind of printing environmental protection UV curable ink according to claim 1, it is characterised in that the organic solvent
For butyl.
5. a kind of printing environmental protection UV curable ink according to claim 1, it is characterised in that the difunctional
Photoactive is tri (propylene glycol) diacrylate or neopentylglycol diacrylate.
6. a kind of printing environmental protection UV curable ink according to claim 1, it is characterised in that the light trigger
For a- hydroxy cyclohexyl phenylketones or a- hydroxyisopropyl Benzophenones.
7. a kind of printing according to claim 1 is with environmentally friendly UV curable ink, it is characterised in that the sensitising agent is
Triethanolamine or N methyldiethanol amine.
8. a kind of printing environmental protection UV curable ink according to claim 1, it is characterised in that the filler is selected from
One or more in barium sulfate, talcum powder, silica, calcium hydroxide, magnesium hydroxide and calcium carbonate.
9. a kind of printing as any one of claim 1 ~ 8 preparation method of environmentally friendly UV curable ink, it is special
Levy and be, the preparation method comprises the following steps：1) at 20 ~ 25 DEG C, by ultraviolet powder, acrylic resin, DPG two
Acrylate feeding dispersion machine is uniform with 1200 ~ 1500 revs/min of Rate Dispersion；2) by light trigger, the photosensitive list of difunctional
Body, sensitising agent, organic solvent and filler are well mixed with 800 ~ 1000 revs/min of rotating speed, and with step 1) gained mixed liquor mixes
It is uniform with 1200 ~ 1500 revs/min of Rate Dispersion after conjunction, obtain dispersion liquid；3) gained dispersion liquid is placed on three-roller and be ground to
Fineness is less than 20 μm, is filtered to remove impurity, that is, obtains the environmentally friendly UV curable ink finished product of the printing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710521187.3A CN107216709A (en) | 2017-06-30 | 2017-06-30 | One kind printing environmentally friendly UV curable ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710521187.3A CN107216709A (en) | 2017-06-30 | 2017-06-30 | One kind printing environmentally friendly UV curable ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107216709A true CN107216709A (en) | 2017-09-29 |
Family
ID=59950651
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710521187.3A Pending CN107216709A (en) | 2017-06-30 | 2017-06-30 | One kind printing environmentally friendly UV curable ink and preparation method thereof |
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| Country | Link |
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| CN (1) | CN107216709A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110201585A (en) * | 2019-06-27 | 2019-09-06 | 唐雅君 | A kind of light-curable ink and its preparation system and preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1657575A (en) * | 2005-03-22 | 2005-08-24 | 中国乐凯胶片集团公司 | UV light solidified luminous printing ink |
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
| CN103666080A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | UV-curable offset brown luminous red printing ink |
| CN105086607A (en) * | 2015-07-30 | 2015-11-25 | 安徽省中彩印务有限公司 | Ultraviolet ray cured type printing ink |
-
2017
- 2017-06-30 CN CN201710521187.3A patent/CN107216709A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1657575A (en) * | 2005-03-22 | 2005-08-24 | 中国乐凯胶片集团公司 | UV light solidified luminous printing ink |
| CN102786839A (en) * | 2012-07-31 | 2012-11-21 | 佛山市三求电子材料有限公司 | Glass protecting ink and preparation method thereof |
| CN103666080A (en) * | 2013-12-06 | 2014-03-26 | 上海德粼水性油墨有限公司 | UV-curable offset brown luminous red printing ink |
| CN105086607A (en) * | 2015-07-30 | 2015-11-25 | 安徽省中彩印务有限公司 | Ultraviolet ray cured type printing ink |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110201585A (en) * | 2019-06-27 | 2019-09-06 | 唐雅君 | A kind of light-curable ink and its preparation system and preparation method |
| CN110201585B (en) * | 2019-06-27 | 2021-09-10 | 湖北中北博睿科技有限公司 | Photo-curing ink and preparation system and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170929 |
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| RJ01 | Rejection of invention patent application after publication |