CN107214637A - Hard emery wheel and preparation method thereof - Google Patents
Hard emery wheel and preparation method thereof Download PDFInfo
- Publication number
- CN107214637A CN107214637A CN201710415888.9A CN201710415888A CN107214637A CN 107214637 A CN107214637 A CN 107214637A CN 201710415888 A CN201710415888 A CN 201710415888A CN 107214637 A CN107214637 A CN 107214637A
- Authority
- CN
- China
- Prior art keywords
- abrasive material
- emery wheel
- hard
- bottoming
- working lining
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D7/00—Bonded abrasive wheels, or wheels with inserted abrasive blocks, designed for acting otherwise than only by their periphery, e.g. by the front face; Bushings or mountings therefor
- B24D7/02—Wheels in one piece
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/0009—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for using moulds or presses
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D18/00—Manufacture of grinding tools or other grinding devices, e.g. wheels, not otherwise provided for
- B24D18/009—Tools not otherwise provided for
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B24—GRINDING; POLISHING
- B24D—TOOLS FOR GRINDING, BUFFING OR SHARPENING
- B24D3/00—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents
- B24D3/02—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent
- B24D3/04—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic
- B24D3/06—Physical features of abrasive bodies, or sheets, e.g. abrasive surfaces of special nature; Abrasive bodies or sheets characterised by their constituents the constituent being used as bonding agent and being essentially inorganic metallic or mixture of metals with ceramic materials, e.g. hard metals, "cermets", cements
Abstract
The present invention relates to a kind of hard emery wheel and preparation method thereof, belong to the technical field of diamond tool.The hard emery wheel of the present invention includes being formed with bottoming abrasive material, the prime coat by cold spraying on annular base, the annular base forms abrasive material working lining by hot pressed sintering.The bottoming abrasive material is made up of metallic bond, and abrasive material working lining is made up of metallic bond and hard abrasive material.The hard emery wheel of the present invention ensure that matrix is combined the bond strength of suitable even more high with abrasive material working lining with soldering by introducing cold spray process, so that the hard emery wheel of the present invention can be applied to the environment of high-speed grinding.And the abrasive material prime coat that cold spraying is formed can equally play ablation, reduce the waste of metallic bond.
Description
Technical field
The present invention relates to the technical field of diamond tool, it is more particularly related to a kind of hard emery wheel and its
Preparation method.
Background technology
Diamond-impregnated wheel is mainly used in the flat surface grinding working process of the materials such as marble, granite, cement concrete, main
Play grinding corner and surface action.Diamond-impregnated wheel generally uses structure of mounting hole, it is easy to load and unload, with processing flatness
Well, the features such as grinding efficiency is high, and a variety of equipment for grinding can be applied to.
Diamond-impregnated wheel is generally by integral heat pressure sinter molding, and its process characteristic is by metallic bond and Buddha's warrior attendant stone mill
Grain direct sintering is in steel matrix.Due to the linear expansion coefficient of steel matrix and metallic bond and diamond abrasive grain exist it is larger
Thermal stress can be produced after difference, sintering, so that the bond strength between diamond segment and steel matrix is relatively low, is easily caused
Shearing separation causes cutter head to occur improper destruction.Therefore, in the prior art by between diamond segment and matrix
One layer is set not include the basalis of diamond abrasive grain to improve bond strength therebetween, basalis is generally also by metal knot
Mixture is constituted, but its bond strength is still relatively low.In addition, prior art can also by soldering processes by diamond segment with
Matrix is combined, but for the preparation of the diamond-impregnated wheel of multi-knife-head, brazing operation technique is complicated, takes longer.
The content of the invention
In order to overcome the drawbacks described above that prior art is present, combined by force with steel matrix it is an object of the invention to provide one kind
High hard emery wheel of degree and preparation method thereof.
In order to realize foregoing invention purpose, the first aspect of the present invention employs following technical scheme:
A kind of hard emery wheel, it includes annular base, is characterised by the annular base being formed with by cold spraying and beats
Pass through hot pressed sintering formation abrasive material working lining on bottom abrasive material, the prime coat.
Wherein, the thickness of the bottoming abrasive material is 20 μm~200 μm, preferably 20~100 μm.
Wherein, the bottoming abrasive material is made up of metallic bond.
Wherein, the abrasive material working lining is made up of metallic bond and hard abrasive material.
Wherein, the bottoming abrasive material is identical with the metallic bond used in abrasive material working lining.
Wherein, the bottoming abrasive material is different with the metallic bond used in abrasive material working lining.
The second aspect of the present invention, further relates to a kind of preparation method of hard emery wheel, it includes annular base, and feature exists
In:Bottoming abrasive material is formed with by cold spraying on the annular base first, then passed through on the bottoming abrasive material
Hot pressed sintering formation abrasive material working lining.
Wherein, the bottoming abrasive material is made up of metallic bond.
Wherein, the abrasive material working lining is made up of metallic bond and hard abrasive material.
Wherein, the bottoming abrasive material is identical with the metallic bond used in abrasive material working lining.
Compared with immediate prior art, the hard emery wheel of the present invention for preparing has the advantages that:
The hard emery wheel of the present invention ensure that matrix is combined with abrasive material working lining with soldering by introducing cold spray process
The bond strength of suitable even more high, so that the hard emery wheel of the present invention can be applied to the environment of high-speed grinding.And
The abrasive material prime coat that cold spraying is formed can equally play ablation, reduce the waste of metallic bond.
Embodiment
Hard emery wheel of the present invention and preparation method thereof is further elaborated below with reference to specific embodiment,
To make more complete and clear explanation to technical scheme.
The present invention relates to a kind of hard emery wheel, it includes being formed with by cold spraying on annular base, the annular base
By hot pressed sintering formation abrasive material working lining on bottoming abrasive material, bottoming abrasive material, the thickness of the bottoming abrasive material for 100~
2000 μm, preferably 200~1000 μm.The bottoming abrasive material is made up of metallic bond, and abrasive material working lining is combined by metal
Agent and hard abrasive material composition.In the present invention, the bottoming abrasive material is different with the metallic bond used in abrasive material working lining,
For example bottoming abrasive material can be using having the metallic bond of more preferable bond strength with substrate, and the metal knot of abrasive material working lining
Mixture mainly considers the matching with hard abrasive material, for example, can have good hold to hard abrasive material and with described hard
The loss of matter abrasive material is suitable.Certainly, because cold spray process can accelerate metallic bond to critical speed by compressed air
So that metallic is attacked directly to after matrix surface physical deformation occurs for (supersonic speed), and metallic hits flat in matrix surface and firm
Attachment, and then eliminating distortional stress in abrasive material working lining hot pressed sintering further increases adhesiveness, so as to
Greatly improve the bond strength between abrasive material working lining and matrix.Therefore, in the present invention, the metal knot that bottoming abrasive material is used
Mixture is identical with the composition of the metallic bond of abrasive material working lining, also can guarantee that abrasive material working lining has with matrix and is combined with soldering
The bond strength of suitable even more high.The metallic bond be copper base metal bonding agent or ferrous metals bonding agent, and its
In can be added with Co, Ni, Sn, Zn, Si, B, Ti or Re (rare earth).As exemplarily, the metallic bond can for example be selected
FAM1021 alloyed powders (such as Ni containing 18.2wt%, 2.0wt% Co and the Fe of surplus electrolysis alloyed powder), LFP is selected to close
Bronze (such as Cu containing 15.0wt%, 3.8wt% Sn, 12.0wt% Ni, 1.8wt% Co and the Fe of surplus electrolysis
Powder), copper base metal bonding agent etc..The hard abrasive material includes diamond, carbide, boride, nitride, carbonitride or oxygen
Nitride, for example preferably, can select diamond, boron nitride, carborundum, silicon nitride, silica, titanium carbide, nitrogen
Change titanium, titanium dioxide etc..Wherein, most preferably diamond and/or boron nitride, and their particle diameter is generally 100~500
μm scope.
Embodiment 1
The present embodiment is related to a kind of preparation of hard emery wheel.Manufacture includes following process:Matrix processing-dispensing-batch mixing-is cold
Spraying-dress powder cold pressing-hot pressed sintering-emery wheel blasting treatment-dynamic balancing of survey emery wheel-paints-puts the first edge on a knife or a pair of scissors-and mark, printing package enter
Storehouse.
1) dispensing, batch mixing:In terms of weight percentage, 82% FAM1021 alloyed powders, 8% glass putty, and 10% copper powder;
Molding mass is blended into, using three-dimensional material mixer, batch mixing obtains compound 1 in 30 minutes.In terms of weight percentage, 82%
FAM1021 alloyed powders, 8% glass putty, and 10% copper powder, by diamond concentration 0.7ct/cm3, diamond grit 35/40#-35%,
40/50#-30%, 50/60#-35% requirement, are blended into molding mass, using three-dimensional material mixer, and batch mixing is mixed for 120 minutes
Material 2.
2) cold spraying:Matrix is No. 45 steel, using N2As working gas, dusty spray is compound 1, and gas temperature is
120 DEG C, gas pressure is 2.5MPa, powder feeding rate 50g/min, and spray is away from 20mm, and initial velocity 1500m/s, thickness is 50 μm.
3) it is cold-pressed:Moulds of industrial equipment are adjusted, steel matrix-dispensing compound 2- is first delivered and powder is scraped into uniformly-cold moudling
It is press-formed in punching block.
4) hot pressed sintering:The blank of cold pressing is assembled in graphite jig, adds thickness 15cm iron block, in protection gas
It is sintered in the environment of body, hot pressing pressure is 20MPa, sintering temperature is 840 DEG C.
5) sandblasting of corrugated abrasive wheel matrix surface, survey dynamic balancing, paint, put the first edge on a knife or a pair of scissors, be processed into required size by technological requirement.
6) the good corrugated abrasive wheel of post-processing, carries out mark, lettering, on request packaging and storage.
Embodiment 2
The present embodiment is related to a kind of preparation of hard emery wheel.Manufacture includes following process:Matrix processing-dispensing-batch mixing-is cold
Spraying-dress powder cold pressing-hot pressed sintering-emery wheel blasting treatment-dynamic balancing of survey emery wheel-paints-puts the first edge on a knife or a pair of scissors-and mark, printing package enter
Storehouse.
1) dispensing, batch mixing:In terms of weight percentage, 82% LFP alloyed powders, 8% glass putty, and 10% copper powder;It is blended
Into molding mass, using three-dimensional material mixer, batch mixing obtains compound 1 in 30 minutes.In terms of weight percentage, 82% LFP alloys
Powder, 8% glass putty, and 10% copper powder, by diamond concentration 0.7ct/cm3, diamond grit 35/40#-35%, 40/50#-
30%th, 50/60#-35% requirement, is blended into molding mass, using three-dimensional material mixer, and batch mixing obtains compound 2 in 120 minutes.
2) cold spraying:Matrix is No. 45 steel, using N2As working gas, dusty spray is compound 1, and gas temperature is
120 DEG C, gas pressure is 2.5MPa, powder feeding rate 50g/min, and spray is away from 20mm, and initial velocity 1500m/s, thickness is 50 μm.
3) it is cold-pressed:Moulds of industrial equipment are adjusted, steel matrix-dispensing compound 2- is first delivered and powder is scraped into uniformly-cold moudling
It is press-formed in punching block.
4) hot pressed sintering:The blank of cold pressing is assembled in graphite jig, adds thickness 15cm iron block, in protection gas
It is sintered in the environment of body, hot pressing pressure is 20MPa, sintering temperature is 840 DEG C.
5) sandblasting of corrugated abrasive wheel matrix surface, survey dynamic balancing, paint, put the first edge on a knife or a pair of scissors, be processed into required size by technological requirement.
6) the good corrugated abrasive wheel of post-processing, carries out mark, lettering, on request packaging and storage.
Embodiment 3
The present embodiment is related to a kind of preparation of hard emery wheel.Manufacture includes following process:Matrix processing-dispensing-batch mixing-is cold
Spraying-dress powder cold pressing-hot pressed sintering-emery wheel blasting treatment-dynamic balancing of survey emery wheel-paints-puts the first edge on a knife or a pair of scissors-and mark, printing package enter
Storehouse.
1) dispensing, batch mixing:In terms of weight percentage, 32wt% iron powder, 5wt% nickel powder, 8wt% glass putty, and
55wt% copper powder is blended into molding mass, using three-dimensional material mixer, and batch mixing obtains compound 1 in 30 minutes.With percentage by weight table
Show, 32wt% iron powder, 5wt% nickel powder, 8wt% glass putty, and 55wt% copper powder, by diamond concentration 0.7ct/cm3,
Diamond grit 35/40#-35%, 40/50#-30%, 50/60#-35% requirement, are blended into molding mass, using three-dimensional blender
Machine, batch mixing obtains compound 2 in 120 minutes.
2) cold spraying:Matrix is No. 45 steel, using N2As working gas, dusty spray is compound 1, and gas temperature is
120 DEG C, gas pressure is 2.5MPa, powder feeding rate 50g/min, and spray is away from 20mm, and initial velocity 1500m/s, thickness is 50 μm.
3) it is cold-pressed:Moulds of industrial equipment are adjusted, steel matrix-dispensing compound 2- is first delivered and powder is scraped into uniformly-cold moudling
It is press-formed in punching block.
4) hot pressed sintering:The blank of cold pressing is assembled in graphite jig, adds thickness 15cm iron block, in protection gas
It is sintered in the environment of body, hot pressing pressure is 20MPa, sintering temperature is 840 DEG C.
5) sandblasting of corrugated abrasive wheel matrix surface, survey dynamic balancing, paint, put the first edge on a knife or a pair of scissors, be processed into required size by technological requirement.
6) the good corrugated abrasive wheel of post-processing, carries out mark, lettering, on request packaging and storage.
Comparative example 1
This comparative example is related to a kind of preparation of hard emery wheel.Manufacture includes following process:Matrix processing-diamond and metal
Dispensing-batch mixing of powder-secondary dress powder cold pressing-sintering-emery wheel blasting treatment-dynamic balancing of survey emery wheel-paints-puts the first edge on a knife or a pair of scissors-mark,
Printing package is put in storage.
1) dispensing, batch mixing:In terms of weight percentage, 82% FAM1021 alloyed powders, 8% glass putty, and 10% copper powder;
Molding mass is blended into, using three-dimensional material mixer, batch mixing obtains compound 1 in 30 minutes.In terms of weight percentage, 82%
FAM1021 alloyed powders, 8% glass putty, and 10% copper powder, by diamond concentration 0.7ct/cm3, diamond grit 35/40#-35%,
40/50#-30%, 50/60#-35% requirement, are blended into molding mass, using three-dimensional material mixer, and batch mixing is mixed for 120 minutes
Material 2.
2) moulds of industrial equipment are adjusted, first deliver steel matrix-dispensing compound 1- by powder scrape uniformly-go up press it is half-formed-
Unload seaming chuck-deliver compound 2 again to be press-formed into cold moudling punching block, matrix is No. 45 steel.
3) hot pressed sintering:The blank of cold pressing is assembled in graphite jig, adds thickness 15cm iron block, in protection gas
It is sintered in the environment of body, hot pressing pressure is 20MPa, sintering temperature is 840 DEG C.
4) sandblasting of corrugated abrasive wheel matrix surface, survey dynamic balancing, paint, put the first edge on a knife or a pair of scissors, be processed into required size by technological requirement.
5) the good corrugated abrasive wheel of post-processing, carries out mark, lettering, on request packaging and storage.
Comparative example 2
This comparative example is related to a kind of preparation of hard emery wheel.Manufacture includes following process:Matrix processing-diamond and metal
Dispensing-batch mixing of powder-secondary dress powder cold pressing-sintering-emery wheel blasting treatment-dynamic balancing of survey emery wheel-paints-puts the first edge on a knife or a pair of scissors-mark,
Printing package is put in storage.
1) dispensing, batch mixing:In terms of weight percentage, 82% LFP alloyed powders, 8% glass putty, and 10% copper powder;It is blended
Into molding mass, using three-dimensional material mixer, batch mixing obtains compound 1 in 30 minutes.In terms of weight percentage, 82% LFP alloys
Powder, 8% glass putty, and 10% copper powder, by diamond concentration 0.7ct/cm3, diamond grit 35/40#-35%, 40/50#-
30%th, 50/60#-35% requirement, is blended into molding mass, using three-dimensional material mixer, and batch mixing obtains compound 2 in 120 minutes.
2) moulds of industrial equipment are adjusted, first deliver steel matrix-dispensing compound 1- by powder scrape uniformly-go up press it is half-formed-
Unload seaming chuck-deliver compound 2 again to be press-formed into cold moudling punching block, matrix is No. 45 steel.
3) hot pressed sintering:The blank of cold pressing is assembled in graphite jig, adds thickness 15cm iron block, in protection gas
It is sintered in the environment of body, hot pressing pressure is 20MPa, sintering temperature is 840 DEG C.
4) sandblasting of corrugated abrasive wheel matrix surface, survey dynamic balancing, paint, put the first edge on a knife or a pair of scissors, be processed into required size by technological requirement.
5) the good corrugated abrasive wheel of post-processing, carries out mark, lettering, on request packaging and storage.
Comparative example 3
This comparative example is related to a kind of preparation of hard emery wheel.Manufacture includes following process:Matrix processing-diamond and metal
Dispensing-batch mixing of powder-secondary dress powder cold pressing-sintering-emery wheel blasting treatment-dynamic balancing of survey emery wheel-paints-puts the first edge on a knife or a pair of scissors-mark,
Printing package is put in storage.
1) dispensing, batch mixing:In terms of weight percentage, 32wt% iron powder, 5wt% nickel powder, 8wt% glass putty, and
55wt% copper powder is blended into molding mass, using three-dimensional material mixer, and batch mixing obtains compound 1 in 30 minutes.With percentage by weight table
Show, 32wt% iron powder, 5wt% nickel powder, 8wt% glass putty, and 55wt% copper powder, by diamond concentration 0.7ct/cm3,
Diamond grit 35/40#-35%, 40/50#-30%, 50/60#-35% requirement, are blended into molding mass, using three-dimensional blender
Machine, batch mixing obtains compound 2 in 120 minutes.
2) moulds of industrial equipment are adjusted, first deliver steel matrix-dispensing compound 1- by powder scrape uniformly-go up press it is half-formed-
Unload seaming chuck-deliver compound 2 again to be press-formed into cold moudling punching block, matrix is No. 45 steel.
3) hot pressed sintering:The blank of cold pressing is assembled in graphite jig, adds thickness 15cm iron block, in protection gas
It is sintered in the environment of body, hot pressing pressure is 20MPa, sintering temperature is 840 DEG C.
4) sandblasting of corrugated abrasive wheel matrix surface, survey dynamic balancing, paint, put the first edge on a knife or a pair of scissors, be processed into required size by technological requirement.
5) the good corrugated abrasive wheel of post-processing, carries out mark, lettering, on request packaging and storage.
To the tensile strength (10 between embodiment 1~3 and the test abrasive material working lining of comparative example 1~3 and No. 45 steel matrix
Individual sample is averaged), as a result as shown in table 1.
Table 1
Tensile strength (MPa) | |
Embodiment 1 | 293 |
Embodiment 2 | 285 |
Embodiment 3 | 296 |
Comparative example 1 | 164 |
Comparative example 2 | 158 |
Comparative example 3 | 189 |
The tensile strength values of embodiment 1~3 are higher than the tensile strength scope using common 230~260MPa of brazing piece.
For the ordinary skill in the art, simply the present invention is exemplarily described for specific embodiment,
The obvious present invention, which is implemented, to be not subject to the restrictions described above, and is entered as long as employing the inventive concept and technical scheme of the present invention
The improvement of capable various unsubstantialities, or it is not improved by the present invention design and technical scheme directly apply to other occasions
, within protection scope of the present invention.
Claims (10)
1. a kind of hard emery wheel, it includes annular base, is characterised by being formed with bottoming by cold spraying on the annular base
Pass through hot pressed sintering formation abrasive material working lining on abrasive material, the prime coat.
2. hard emery wheel according to claim 1, it is characterised in that:The thickness of the bottoming abrasive material is 20 μm~200 μ
m。
3. hard emery wheel according to claim 1, it is characterised in that:The bottoming abrasive material is made up of metallic bond.
4. hard emery wheel according to claim 1, it is characterised in that:The abrasive material working lining is by metallic bond and hard
Abrasive material is constituted.
5. hard emery wheel according to claim 4, it is characterised in that:Used in the bottoming abrasive material and abrasive material working lining
Metallic bond it is identical.
6. hard emery wheel according to claim 4, it is characterised in that:Used in the bottoming abrasive material and abrasive material working lining
Metallic bond it is different.
7. a kind of preparation method of hard emery wheel, it includes annular base, is characterised by:Pass through first on the annular base
Cold spraying is formed with bottoming abrasive material, then passes through hot pressed sintering formation abrasive material working lining on the bottoming abrasive material.
8. preparation method according to claim 7, is characterised by:The bottoming abrasive material is made up of metallic bond.
9. preparation method according to claim 8, is characterised by:The abrasive material working lining is ground by metallic bond and hard
Material composition.
10. preparation method according to claim 9, is characterised by:Used in the bottoming abrasive material and abrasive material working lining
Metallic bond it is identical.
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CN201710415888.9A CN107214637A (en) | 2017-06-05 | 2017-06-05 | Hard emery wheel and preparation method thereof |
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CN201710415888.9A CN107214637A (en) | 2017-06-05 | 2017-06-05 | Hard emery wheel and preparation method thereof |
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Family
ID=59947157
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109822465A (en) * | 2019-03-14 | 2019-05-31 | 泉州众志金刚石工具有限公司 | A kind of tile edge Metal Substrate emery wheel material |
CN111136591A (en) * | 2018-11-06 | 2020-05-12 | 丹阳华昌钻石工具制造有限公司 | Grinding wheel for ceramic tile processing |
CN113319751A (en) * | 2021-05-18 | 2021-08-31 | 珠海市巨海科技有限公司 | Method for manufacturing metal bond diamond grinding wheel and equipment for manufacturing metal bond diamond grinding wheel |
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EP2735404A2 (en) * | 2007-12-28 | 2014-05-28 | Shin-Etsu Chemical Co., Ltd. | Cutting wheels, their manufacture and use |
CN104162848A (en) * | 2014-08-07 | 2014-11-26 | 王强 | Metallic bond grinding wheel for grinding ceramic tile arc chamfers and manufacturing process of metallic bond grinding wheel |
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CN1880019A (en) * | 2005-06-17 | 2006-12-20 | 吴诺顿株式会社 | Metal binding agent grinding wheel for discharge finishing |
EP2735404A2 (en) * | 2007-12-28 | 2014-05-28 | Shin-Etsu Chemical Co., Ltd. | Cutting wheels, their manufacture and use |
CN102814746A (en) * | 2012-07-09 | 2012-12-12 | 南京航空航天大学 | Grinding material optimizing and distributing sintered diamond tool and manufacture method thereof |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN111136591A (en) * | 2018-11-06 | 2020-05-12 | 丹阳华昌钻石工具制造有限公司 | Grinding wheel for ceramic tile processing |
CN111136591B (en) * | 2018-11-06 | 2021-12-14 | 丹阳华昌钻石工具制造有限公司 | Grinding wheel for ceramic tile processing |
CN109822465A (en) * | 2019-03-14 | 2019-05-31 | 泉州众志金刚石工具有限公司 | A kind of tile edge Metal Substrate emery wheel material |
CN113319751A (en) * | 2021-05-18 | 2021-08-31 | 珠海市巨海科技有限公司 | Method for manufacturing metal bond diamond grinding wheel and equipment for manufacturing metal bond diamond grinding wheel |
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Application publication date: 20170929 |