CN105603287A - Oxide-based high-entropy alloy ceramic binding agent special for PCBN - Google Patents
Oxide-based high-entropy alloy ceramic binding agent special for PCBN Download PDFInfo
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- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 54
- 239000000956 alloy Substances 0.000 title claims abstract description 54
- GJNGXPDXRVXSEH-UHFFFAOYSA-N 4-chlorobenzonitrile Chemical compound ClC1=CC=C(C#N)C=C1 GJNGXPDXRVXSEH-UHFFFAOYSA-N 0.000 title claims abstract description 20
- 239000000919 ceramic Substances 0.000 title claims abstract description 18
- 239000011230 binding agent Substances 0.000 title claims description 27
- 239000002994 raw material Substances 0.000 claims abstract description 24
- 229910052574 oxide ceramic Inorganic materials 0.000 claims abstract description 16
- 239000011224 oxide ceramic Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims description 37
- 239000002245 particle Substances 0.000 claims description 20
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 10
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 7
- 229910052782 aluminium Inorganic materials 0.000 claims description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 7
- 229910052721 tungsten Inorganic materials 0.000 claims description 7
- 239000010937 tungsten Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 6
- 229910052790 beryllium Inorganic materials 0.000 claims description 6
- ATBAMAFKBVZNFJ-UHFFFAOYSA-N beryllium atom Chemical compound [Be] ATBAMAFKBVZNFJ-UHFFFAOYSA-N 0.000 claims description 6
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 10
- 238000002156 mixing Methods 0.000 abstract description 8
- 238000005275 alloying Methods 0.000 abstract description 5
- 239000007767 bonding agent Substances 0.000 abstract description 3
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 238000000265 homogenisation Methods 0.000 abstract description 2
- 238000002844 melting Methods 0.000 abstract description 2
- 230000008018 melting Effects 0.000 abstract description 2
- 239000006104 solid solution Substances 0.000 abstract description 2
- 230000002195 synergetic effect Effects 0.000 abstract description 2
- 238000000034 method Methods 0.000 description 40
- 238000002360 preparation method Methods 0.000 description 15
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 9
- 238000005245 sintering Methods 0.000 description 9
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000498 ball milling Methods 0.000 description 6
- 239000004615 ingredient Substances 0.000 description 6
- 238000007873 sieving Methods 0.000 description 6
- 229910052582 BN Inorganic materials 0.000 description 3
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 3
- 238000003723 Smelting Methods 0.000 description 3
- 238000000889 atomisation Methods 0.000 description 3
- 239000011812 mixed powder Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 229910000851 Alloy steel Inorganic materials 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 229910001018 Cast iron Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229910018098 Ni-Si Inorganic materials 0.000 description 1
- 229910018529 Ni—Si Inorganic materials 0.000 description 1
- 229910004349 Ti-Al Inorganic materials 0.000 description 1
- 229910004692 Ti—Al Inorganic materials 0.000 description 1
- 229910002056 binary alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 229910003460 diamond Inorganic materials 0.000 description 1
- 239000010432 diamond Substances 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 229910002058 ternary alloy Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C29/00—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides
- C22C29/12—Alloys based on carbides, oxides, nitrides, borides, or silicides, e.g. cermets, or other metal compounds, e.g. oxynitrides, sulfides based on oxides
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C30/00—Alloys containing less than 50% by weight of each constituent
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- Chemical & Material Sciences (AREA)
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- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Powder Metallurgy (AREA)
Abstract
本发明公开一种PCBN专用氧化物基高熵合金陶瓷结合剂。该结合剂是由下述质量百分比的原料组成，其中：高熵合金30%～65%、氧化物陶瓷35%～70%。本发明的高熵合金可以形成高混合熵稳定的固溶体，产生多种特殊效应，例如热力学上的高熵效应，结构上的晶格畸变效应、多组元之间的协同效应以及性能上的“鸡尾酒”效应等。因此，与传统合金相比，高熵合金更容易实现均质化和合金化，合金熔点更低，具有一些传统合金所无法比拟的优异性能，例如高强度、高硬度、高耐磨、高电阻、高热阻、耐腐蚀性等。The invention discloses an oxide-based high-entropy alloy ceramic bond special for PCBN. The bonding agent is composed of the following raw materials in mass percentage, including: 30%-65% of high-entropy alloy and 35%-70% of oxide ceramics. The high-entropy alloy of the present invention can form a stable solid solution with high mixing entropy, and produce a variety of special effects, such as high-entropy effects in thermodynamics, lattice distortion effects in structure, synergistic effects between multiple components, and " Cocktail" effect, etc. Therefore, compared with traditional alloys, high-entropy alloys are easier to achieve homogenization and alloying, have lower melting points, and have excellent properties that cannot be compared with traditional alloys, such as high strength, high hardness, high wear resistance, and high electrical resistance. , high thermal resistance, corrosion resistance, etc.
Description
技术领域technical field
本发明属于立方氮化硼聚晶（下称PCBN）超硬材料制造技术领域，具体说是涉及一种PCBN专用氧化物基高熵合金陶瓷结合剂。The invention belongs to the technical field of manufacturing cubic boron nitride polycrystalline (hereinafter referred to as PCBN) superhard materials, and specifically relates to a special oxide-based high-entropy alloy ceramic binder for PCBN.
背景技术Background technique
现在制造立方氮化硼聚晶使用的结合剂，有三类：1．金属结合剂，由金属或合金组成；2．陶瓷结合剂，仅陶瓷组成。3．金属陶瓷结合剂，由陶瓷和金属或合金组成。通常用一种金属和一种陶瓷组成，例如Ni-Si3N4。使用的合金，常用二元合金，例如Ti-Al，至多用到三元合金，例如Ti-Al-Mo。There are three types of binders used in the manufacture of cubic boron nitride polycrystals: 1. Metal binder, composed of metal or alloy; 2. A vitrified bond consisting of ceramics only. 3. Metal-ceramic bond, composed of ceramic and metal or alloy. It is usually composed of a metal and a ceramic, such as Ni-Si 3 N 4 . The alloys used are usually binary alloys, such as Ti-Al, and at most ternary alloys, such as Ti-Al-Mo.
现有PCBN结合剂存在的问题是：1.聚晶烧结温度和压力很高；2.聚晶产品硬度和强度不够高；3.聚晶组织和性能均匀性差，产品质量不够稳定。The problems existing in the existing PCBN binder are: 1. The polycrystalline sintering temperature and pressure are very high; 2. The hardness and strength of the polycrystalline product are not high enough; 3. The uniformity of the polycrystalline structure and performance is poor, and the product quality is not stable enough.
由于存在这些问题，PCBN聚晶产品的应用受到限制，特别是作为刀具用的聚晶还不过关，对一些硬韧合金钢材料加工效果差，还有一些高硬度金属材料难以加工。例如，加工铸铁，现在无论是金刚石聚晶或是PCBN聚晶，加工效果都不够理想。Due to these problems, the application of PCBN polycrystalline products is limited, especially the polycrystalline used as cutting tools is not good enough, the processing effect on some hard and tough alloy steel materials is poor, and some high-hardness metal materials are difficult to process. For example, when processing cast iron, whether it is diamond polycrystalline or PCBN polycrystalline, the processing effect is not ideal.
发明内容Contents of the invention
本发明的目的正是针对上述现有技术中所存在的不足之处而提供一种PCBN专用氧化物基高熵合金陶瓷结合剂。The object of the present invention is to provide a special oxide-based high-entropy alloy ceramic bond for PCBN in view of the deficiencies in the above-mentioned prior art.
本发明的目的可通过下述技术措施来实现：The purpose of the present invention can be achieved through the following technical measures:
本发明的PCBN专用氧化物基高熵合金陶瓷结合剂是由下述质量百分比的原料组成，其中：高熵合金30%～65%、氧化物陶瓷35%～70%。优选方案是由高熵合金40%，氧化物陶瓷60%组成。The special oxide-based high-entropy alloy ceramic binder for PCBN of the present invention is composed of the following raw materials in mass percentage, wherein: high-entropy alloy 30%-65%, oxide ceramic 35%-70%. The preferred solution is composed of 40% high-entropy alloy and 60% oxide ceramics.
本发明中所述高熵合金包括下述质量百分比的原料组成，其中：铬15%～25%、钨15%～25%、锆15%～25%、钴10%～20%、铝10%～20%，以及0%～5%的铍；且所述高熵合金为粒径5～40μm的粉末颗粒。The high-entropy alloy described in the present invention includes the following raw material composition in mass percentage, wherein: 15%-25% of chromium, 15%-25% of tungsten, 15%-25% of zirconium, 10%-20% of cobalt, and 10% of aluminum ~20%, and 0%~5% beryllium; and the high-entropy alloy is a powder particle with a particle size of 5-40 μm.
本发明中所述高熵合金优选方案是由铬25%、钨20%、锆20%、钴15%、铝15%、铍5%组成。The preferred solution of the high entropy alloy in the present invention is composed of 25% chromium, 20% tungsten, 20% zirconium, 15% cobalt, 15% aluminum and 5% beryllium.
本发明中所述氧化物陶瓷是由下述质量百分比的原料组成，其中：氧化铝55%～95%、氧化锆5%～45%；且所述氧化物陶瓷为粒径5～40μm的粉末颗粒。The oxide ceramics in the present invention are composed of the following raw materials in mass percentage, wherein: 55% to 95% of alumina and 5% to 45% of zirconia; and the oxide ceramics are powders with a particle size of 5 to 40 μm particles.
本发明中所述氧化物陶瓷优选方案是由氧化铝70%，氧化锆30%组成。The preferred solution of the oxide ceramics in the present invention is composed of 70% alumina and 30% zirconia.
本发明的结合剂用量如下：在高压高温合成PCBN的制造工艺中，氧化物基高熵合金陶瓷结合剂与立方氮化硼（CBN）配料的质量比为：The dosage of the bonding agent of the present invention is as follows: in the manufacturing process of high-pressure high-temperature synthesis of PCBN, the mass ratio of oxide-based high-entropy alloy ceramic bonding agent to cubic boron nitride (CBN) ingredients is:
结合剂：CBN=15%～40%：60%～85%。Binder: CBN=15%～40%: 60%～85%.
优选：结合剂20%，CBN80%。Preferable: binder 20%, CBN 80%.
本发明的高熵合金可以形成高混合熵稳定的固溶体，产生多种特殊效应，例如热力学上的高熵效应，结构上的晶格畸变效应、多组元之间的协同效应以及性能上的“鸡尾酒”效应等。因此，与传统合金相比，高熵合金更容易实现均质化和合金化，合金熔点更低，具有一些传统合金所无法比拟的优异性能，例如高强度、高硬度、高耐磨、高电阻、高热阻、耐腐蚀性等。The high-entropy alloy of the present invention can form a stable solid solution with high mixing entropy, and produce a variety of special effects, such as high-entropy effects in thermodynamics, lattice distortion effects in structure, synergistic effects between multiple components, and " Cocktail" effect, etc. Therefore, compared with traditional alloys, high-entropy alloys are easier to achieve homogenization and alloying, have lower melting points, and have excellent properties that cannot be compared with traditional alloys, such as high strength, high hardness, high wear resistance, and high electrical resistance. , high thermal resistance, corrosion resistance, etc.
因此，高熵合金作为结合剂应用于PCBN高压高温烧结，有利于实现烧结过程，降低烧结条件（烧结压力、烧结温度和烧结时间），提高和稳定聚晶产品质量。Therefore, high-entropy alloys are used as binders in PCBN high-pressure and high-temperature sintering, which is beneficial to realize the sintering process, reduce sintering conditions (sintering pressure, sintering temperature and sintering time), and improve and stabilize the quality of polycrystalline products.
本发明的有益效果如下：The beneficial effects of the present invention are as follows:
1.降低CBN聚晶烧结压力和温度。传统工艺常用压力为4.5～6.5GPa，加热至1450～1650℃。与原有工艺相比，表观压力（100MPa）降低1～5ＭPa（相当于压力降低1%～5%）,温度下降10～50℃。1. Reduce the sintering pressure and temperature of CBN polycrystalline. The commonly used pressure in the traditional process is 4.5-6.5GPa, and it is heated to 1450-1650°C. Compared with the original process, the apparent pressure (100MPa) is reduced by 1-5MPa (equivalent to a pressure reduction of 1%-5%), and the temperature is reduced by 10-50°C.
2.有效地提高PCBN聚晶质量。生产的聚晶具有高硬度（维氏硬度38～50GPa）、高强度、高耐磨、耐腐蚀性等特点。这种聚晶成功用于制造切削刀具，可以加工既硬又韧的耐高温难加工合金钢等黑色金属材料。2. Effectively improve the quality of PCBN polycrystalline. The polycrystalline produced has the characteristics of high hardness (Vickers hardness 38-50GPa), high strength, high wear resistance and corrosion resistance. This kind of polycrystal is successfully used in the manufacture of cutting tools, which can process ferrous materials such as hard and tough high-temperature-resistant and difficult-to-machine alloy steel.
3.提高了高压高温烧结工艺过程和聚晶质量的稳定性。产品优等品率可提高5%～10%，优等品率达到90%以上。3. Improve the stability of high-pressure high-temperature sintering process and polycrystalline quality. The rate of high-quality products can be increased by 5% to 10%, and the rate of high-quality products can reach more than 90%.
具体实施方式detailed description
本发明以下将结合实施例作进一步描述：The present invention will be further described below in conjunction with embodiment:
实施例1Example 1
1、高熵合金粉的制备：1. Preparation of high entropy alloy powder:
⑴按质量百分比取：铬25%、钨20%、锆20%、钴15%、铝15%、铍5%。⑴According to mass percentage: 25% chromium, 20% tungsten, 20% zirconium, 15% cobalt, 15% aluminum, 5% beryllium.
⑵通过粉碎、筛分工序将上述原料制备成为粒径20μm的粉末颗粒。(2) The above-mentioned raw materials are prepared into powder particles with a particle size of 20 μm through crushing and sieving processes.
⑶高熵合金粉的配制方法可采用下述两种方法之一来进行：(3) The preparation method of high-entropy alloy powder can be carried out by one of the following two methods:
方法之一：使用单质金属混合粉。此法操作简便，照发明要求的成分和配比，进行配料和混料。在三维混料机中进行球磨混料。混合好的金属粉料，可以作为结合剂的原料备用。One of the methods: use elemental metal mixed powder. This method is easy to operate, according to the ingredients and proportioning required by the invention, batching and mixing are carried out. Ball milling was carried out in a three-dimensional mixer. The mixed metal powder can be used as the raw material of the binder for standby.
方法之二：使用预合金粉末。此法需要预先合金化，然后制成粉末以备使用。预先制成高熵合金粉末以备使用。实施步骤如下：①按照上述方法之一给出的高熵合金的配方要求进行配料；②采用真空熔炼的方法，将配好的物料置于高温炉内，熔炼成高熵合金；③然后采用雾化法，将熔炼好的合金通过雾化过程制成粉末，作为结合剂原料以备使用。Method 2: Use pre-alloyed powder. This method requires pre-alloying and then powdered for use. Pre-made high-entropy alloy powder ready for use. The implementation steps are as follows: ① According to the formula requirements of the high-entropy alloy given by one of the above methods, the ingredients are prepared; ②Using the method of vacuum smelting, the prepared materials are placed in a high-temperature furnace to be smelted into a high-entropy alloy; ③Then use fog In the chemical method, the smelted alloy is made into powder through the atomization process, which is used as the raw material of the binder for use.
2、制备氧化物陶瓷粉2. Preparation of oxide ceramic powder
⑴按质量百分比取：氧化铝70%，氧化锆30%。⑴According to mass percentage: alumina 70%, zirconia 30%.
⑵通过粉碎、筛分工序将上述原料制备成为粒径20μm的粉末颗粒。(2) The above-mentioned raw materials are prepared into powder particles with a particle size of 20 μm through crushing and sieving processes.
⑶配制方法：按照本发明要求的成分和配比，进行配料和混料。在三维混料机中进行球磨混料。混合好的陶瓷粉料，可以作为结合剂的原料以备使用。(3) Preparation method: according to the composition and proportioning required by the present invention, batching and mixing are carried out. Ball milling was carried out in a three-dimensional mixer. The mixed ceramic powder can be used as the raw material of the binder for use.
3、结合剂粉末的配制3. Preparation of binder powder
将准备好的上述两种材料，按照高熵合金40%和氧化物陶瓷60%的配比进行配料，然后在三维混料机中进行球磨混料。混合料妥善保存，作为制造PCBN的结合剂使用。The above two prepared materials are mixed according to the ratio of 40% high-entropy alloy and 60% oxide ceramics, and then ball milled and mixed in a three-dimensional mixer. The mixture is properly preserved and used as a binder for the manufacture of PCBN.
实施例2Example 2
1、高熵合金粉的制备：1. Preparation of high entropy alloy powder:
⑴按质量百分比取：铬25%、钨24%、锆20%、钴14%、铝14%、铍3%。⑴According to mass percentage: chromium 25%, tungsten 24%, zirconium 20%, cobalt 14%, aluminum 14%, beryllium 3%.
⑵通过粉碎、筛分工序将上述原料制备成为粒径20μm的粉末颗粒。(2) The above-mentioned raw materials are prepared into powder particles with a particle size of 20 μm through crushing and sieving processes.
⑶高熵合金粉的配制方法可采用下述两种方法之一来进行：(3) The preparation method of high-entropy alloy powder can be carried out by one of the following two methods:
方法之一：使用单质金属混合粉。此法操作简便，照发明要求的成分和配比，进行配料和混料。在三维混料机中进行球磨混料。混合好的金属粉料，可以作为结合剂的原料备用。One of the methods: use elemental metal mixed powder. This method is easy to operate, according to the ingredients and proportioning required by the invention, batching and mixing are carried out. Ball milling was carried out in a three-dimensional mixer. The mixed metal powder can be used as the raw material of the binder for standby.
方法之二：使用预合金粉末。此法需要预先合金化，然后制成粉末以备使用。预先制成高熵合金粉末以备使用。实施步骤如下：①按照上述方法之一给出的高熵合金的配方要求进行配料；②采用真空熔炼的方法，将配好的物料置于高温炉内，熔炼成高熵合金；③然后采用雾化法，将熔炼好的合金通过雾化过程制成粉末，作为结合剂原料以备使用。Method 2: Use pre-alloyed powder. This method requires pre-alloying and then powdered for use. Pre-made high-entropy alloy powder ready for use. The implementation steps are as follows: ① According to the formula requirements of the high-entropy alloy given by one of the above methods, the ingredients are prepared; ②Using the method of vacuum smelting, the prepared materials are placed in a high-temperature furnace to be smelted into a high-entropy alloy; ③Then use fog In the chemical method, the smelted alloy is made into powder through the atomization process, which is used as the raw material of the binder for use.
2、制备氧化物陶瓷粉2. Preparation of oxide ceramic powder
⑴按质量百分比取：氧化铝80%，氧化锆20%。⑴According to mass percentage: alumina 80%, zirconia 20%.
⑵通过粉碎、筛分工序将上述原料制备成为粒径20μm的粉末颗粒。(2) The above-mentioned raw materials are prepared into powder particles with a particle size of 20 μm through crushing and sieving processes.
⑶配制方法：按照本发明要求的成分和配比，进行配料和混料。在三维混料机中进行球磨混料。混合好的陶瓷粉料，可以作为结合剂的原料以备使用。(3) Preparation method: according to the composition and proportioning required by the present invention, batching and mixing are carried out. Ball milling was carried out in a three-dimensional mixer. The mixed ceramic powder can be used as the raw material of the binder for use.
3、结合剂粉末的配制3. Preparation of binder powder
将准备好的上述两种材料，按照高熵合金35%和氧化物陶瓷65%的配比进行配料，然后在三维混料机中进行球磨混料。混合料妥善保存，作为制造PCBN的结合剂使用。The prepared above two materials are mixed according to the ratio of 35% of high-entropy alloy and 65% of oxide ceramics, and then ball milled and mixed in a three-dimensional mixer. The mixture is properly preserved and used as a binder for the manufacture of PCBN.
实施例3Example 3
1、高熵合金粉的制备：1. Preparation of high entropy alloy powder:
⑴按质量百分比取：铬25%、钨23%、锆22%、钴15%、铝15%。⑴According to mass percentage: chromium 25%, tungsten 23%, zirconium 22%, cobalt 15%, aluminum 15%.
⑵通过粉碎、筛分工序将上述原料制备成为粒径20μm的粉末颗粒。(2) The above-mentioned raw materials are prepared into powder particles with a particle size of 20 μm through crushing and sieving processes.
⑶高熵合金粉的配制方法可采用下述两种方法之一来进行：(3) The preparation method of high-entropy alloy powder can be carried out by one of the following two methods:
方法之一：使用单质金属混合粉。此法操作简便，照发明要求的成分和配One of the methods: use elemental metal mixed powder. This method is simple and easy to operate, according to the composition and the composition of the invention requirement
比，进行配料和混料。在三维混料机中进行球磨混料。混合好的金属粉料，可以作为结合剂的原料备用。Ratio, batching and mixing. Ball milling was carried out in a three-dimensional mixer. The mixed metal powder can be used as the raw material of the binder for standby.
方法之二：使用预合金粉末。此法需要预先合金化，然后制成粉末以备使用。预先制成高熵合金粉末以备使用。实施步骤如下：①按照上述方法之一给出的高熵合金的配方要求进行配料；②采用真空熔炼的方法，将配好的物料置于高温炉内，熔炼成高熵合金；③然后采用雾化法，将熔炼好的合金通过雾化过程制成粉末，作为结合剂原料以备使用。Method 2: Use pre-alloyed powder. This method requires pre-alloying and then powdered for use. Pre-made high-entropy alloy powder ready for use. The implementation steps are as follows: ① According to the formula requirements of the high-entropy alloy given by one of the above methods, the ingredients are prepared; ②Using the method of vacuum smelting, the prepared materials are placed in a high-temperature furnace to be smelted into a high-entropy alloy; ③Then use fog In the chemical method, the smelted alloy is made into powder through the atomization process, which is used as the raw material of the binder for use.
2、制备氧化物陶瓷粉2. Preparation of oxide ceramic powder
⑴按质量百分比取：氧化铝85%，氧化锆15%。⑴According to mass percentage: alumina 85%, zirconia 15%.
⑵通过粉碎、筛分工序将上述原料制备成为粒径20μm的粉末颗粒。(2) The above-mentioned raw materials are prepared into powder particles with a particle size of 20 μm through crushing and sieving processes.
⑶配制方法：按照本发明要求的成分和配比，进行配料和混料。在三维混料机中进行球磨混料。混合好的陶瓷粉料，可以作为结合剂的原料以备使用。(3) Preparation method: according to the composition and proportioning required by the present invention, batching and mixing are carried out. Ball milling was carried out in a three-dimensional mixer. The mixed ceramic powder can be used as the raw material of the binder for use.
3、结合剂粉末的配制3. Preparation of binder powder
将准备好的上述两种材料，按照高熵合金40%和氧化物陶瓷60%的配比进行配料，然后在三维混料机中进行球磨混料。混合料妥善保存，作为制造PCBN的结合剂使用。The above two prepared materials are mixed according to the ratio of 40% high-entropy alloy and 60% oxide ceramics, and then ball milled and mixed in a three-dimensional mixer. The mixture is properly preserved and used as a binder for the manufacture of PCBN.
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