CN107207981A - The manufacture method of lubricant solution and article with lubricant film - Google Patents
The manufacture method of lubricant solution and article with lubricant film Download PDFInfo
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- CN107207981A CN107207981A CN201680007358.4A CN201680007358A CN107207981A CN 107207981 A CN107207981 A CN 107207981A CN 201680007358 A CN201680007358 A CN 201680007358A CN 107207981 A CN107207981 A CN 107207981A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M107/00—Lubricating compositions characterised by the base-material being a macromolecular compound
- C10M107/50—Lubricating compositions characterised by the base-material being a macromolecular compound containing silicon
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
- C09D183/04—Polysiloxanes
- C09D183/08—Polysiloxanes containing silicon bound to organic groups containing atoms other than carbon, hydrogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/20—Diluents or solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/02—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen and halogen only
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2211/00—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions
- C10M2211/04—Organic non-macromolecular compounds containing halogen as ingredients in lubricant compositions containing carbon, hydrogen, halogen, and oxygen
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/041—Siloxanes with specific structure containing aliphatic substituents
- C10M2229/0415—Siloxanes with specific structure containing aliphatic substituents used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/047—Siloxanes with specific structure containing alkylene oxide groups
- C10M2229/0475—Siloxanes with specific structure containing alkylene oxide groups used as base material
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
- C10M2229/04—Siloxanes with specific structure
- C10M2229/05—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon
- C10M2229/052—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen
- C10M2229/0525—Siloxanes with specific structure containing atoms other than silicon, hydrogen, oxygen or carbon containing nitrogen used as base material
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/70—Soluble oils
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/50—Medical uses
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/015—Dispersions of solid lubricants
- C10N2050/02—Dispersions of solid lubricants dissolved or suspended in a carrier which subsequently evaporates to leave a lubricant coating
Abstract
The present invention relates to lubricant solution, it contains the lubricant (A) of the modification organic silicon oil containing diamines and containing trans 1,2 dichloroethylene (tDCE) and 1,1,2,2 tetrafluoros 1 (2,2,2 trifluoro ethoxies) ethane (HFE 347pc f) solvent (B), tDCE and HFE 347pc f add up to tDCE, tDCE and HFE the 347pc f containing 40~70 mass % in 100 mass % to add up to the HFE 347pc f containing 30~60 mass % in 100 mass %.
Description
Technical field
The present invention relates to lubricant solution and the article with lubricant film manufacture method.
Background technology
Article with the film (being also denoted as lubricant film below) containing lubricant for example can be by being applied thing
Surface, which is coated with, to be dissolved in lubricant after lubricant solution obtained by solvent, solvent is evaporated and is being applied the surface shape of thing
Manufactured into lubricant film.
As solvent, from the point of view of with noninflammability and chemical stability and good heat stability, CFC is used
Class (being designated as CFC classes below), HCFC class (being designated as HCFC classes below).But, because CFC classes and HCFC classes have to ozone layer
There is negative effect, developed country is predefined in the production that the year two thousand twenty abrogates CFC classes and HCFC classes comprehensively.
It is used as the solvent not had a negative impact to ozone layer, it is known to perfluoroalkanes (being designated as PFC classes below), HFC
Class (being designated as HFC classes below), hydrofluoroether class (being designated as HFE classes below) etc..But, the greenhouse effects coefficient of PFC classes and HFC classes
Greatly, thus be the Kyoto Protocol limitation object material.In addition, PFC classes, HFC classes and HFE classes are low to the dissolubility of lubricant,
It is used as the narrow application range of the solvent of lubricant.
As not had a negative impact to earth environment and the excellent solvent of the dissolubility to lubricant, it is known to trans-
1,2-dichloroethene (trans-CHCl=CHCl, tDCE is also denoted as below).But, tDCE is due to being difficult to list with ignition point
Solely use.
As without ignition point and the excellent solvent of the dissolubility to lubricant, it is proposed that tDCE is mixed with fluorine solvent
Various solvents obtained by conjunction.For example, Patent Document 1 discloses by tDCE and methyl perfluorobutyl ether (CH3OCF2CF2CF2CF3,
Be also denoted as HFE-449s1 below) constitute solvent.Solvent disclosed in patent document 1 can be used as the molten of organic silicon lubricant
Agent.In addition, Patent Document 2 discloses the solvent containing tDCE Yu methyl perfluoro heptene ether (being also denoted as MPHE below).Patent
Solvent disclosed in document 2 is effective as the solvent of the silicone fluid for removing substrate surface.
Be formed with lubricant film be applied thing for the metal such as injection needle in the case of, as lubricant, from gold
From the point of view of the adaptation of category is excellent, modification organic silicon oil, particularly diamines modification organic silicon oil can be used.Patent document 1
Although the solvent with 2 can dissolve diamines modification organic silicon oil, the stability for preserving solution after a couple of days (is designated as preserving stable below
Property) insufficient.Therefore, the lubricant solution containing diamines modification organic silicon oil and the solvent of patent document 1 or 2, which has, to be preserved
In the problem of there is white opacity or lubricant separation.Then, white opacity or lubricant separation lubricant is being used
In the case of solution, uniform lubricant film can not be formed sometimes by being applied the surface of thing.
In addition, diamines modification organic silicon oil as the alkoxy silane containing diaminourea of crosslinking agent sometimes with being applied in combination.
In addition, the solvent being obtained by mixing as tDCE and fluorine solvent, Patent Document 3 discloses by tDCE and 1,1,2,
2- tetra- fluoro- 1- (2,2,2- trifluoro ethoxies) ethane (CF3CH2OCF2CF2H, is also denoted as HFE-347pc-f below) constitute it is molten
Agent, Patent Document 4 discloses the solvent containing tDCE, HFE-347pc-f and methanol.But, do not have in patent document 3 and 4
On the record for being used the solvent of these disclosed solvent as lubricants.Moreover, on the molten of patent document 3 and 4
Whether agent has dissolubility also and indefinite diamines modification organic silicon oil.
Prior art literature
Patent document
Patent document 1：No. 2908033 publications of Japanese Patent No.
Patent document 2：Japanese Patent Laid 2014-511428 publications
Patent document 3：No. 2879847 publications of Japanese Patent No.
Patent document 4：No. 4556669 publications of Japanese Patent No.
The content of the invention
The technical problems to be solved by the invention
It is an object of the invention to provide being had no adverse effect to earth environment, storage stability is excellent without catching fire
The lubricant solution of point, and the manufacture method with the article using lubricant film obtained by the lubricant solution.
Solve the technical scheme that technical problem is used
The present invention provides the lubricant solution with following composition and the article with lubricant film.
[1] lubricant solution, it contains the lubricant (A) of the modification organic silicon oil containing diamines and containing tDCE and HFE-347pc-
F solvent (B), tDCE and HFE-347pc-f add up to tDCE, tDCE and HFE- containing 40~70 mass % in 100 mass %
347pc-f adds up to the HFE-347pc-f containing 30~60 mass % in 100 mass %.
[2] lubricant solution as described in [1], wherein, 0.01~50 matter is contained in the mass % of lubricant solution 100
Measure the % lubricant (A).
[3] lubricant solution as described in [1] or [2], wherein, in the mass % of lubricant solution 100 containing 50~
The 99.99 mass % solvent (B).
[4] lubricant solution as any one of [1]~[3], wherein, the solvent (B), which is also contained, to be dissolved in
TDCE organic solvent (B1).
[5] lubricant solution as described in [4], wherein, the organic solvent (B1) is the alcohol of carbon number 1~3.
[6] lubricant solution as described in [4] or [5], wherein, 0.1~50 is contained in the mass % of solvent (B) 100
The quality % organic solvent (B1).
[7] lubricant solution as any one of [1]~[6], wherein, the solvent (B) is by anti-form-1,2- dichloros
The alcohol of ethene, the fluoro- 1- of 1,1,2,2- tetra- (2,2,2- trifluoro ethoxies) ethane and carbon number 1~3 is constituted.
[8] lubricant solution as any one of [1]~[7], wherein, also containing the alkoxy silane containing diaminourea
Any of and its partial condensate.
[9] manufacture method of the article with lubricant film, including：Be applied thing surface be coated with [1]~
[8] process of the lubricant solution any one of, and make to be coated on the lubricant on the surface for being applied thing
The solvent (B) evaporation in solution, the process in the film of the surface formation containing the lubricant (A) for being applied thing.
[10] manufacture method of the article with lubricant film as described in [9], wherein, the thing that is applied is injection
Pin.
Invention effect
Can then be provided by the present invention earth environment is not had a negative impact, storage stability is excellent does not have
The lubricant solution of fire point.Further, it is possible to provide can safely manufacture having of not had a negative impact to earth environment equal
The manufacture method of the article with lubricant film of the article of even lubricant film.
Embodiment
Below, embodiments of the present invention are illustrated.The invention is not restricted to implementation below.This can not departed from
Various changes and replacement are carried out to implementation below in the case of the scope of invention.
The definition of following term is applied to present specification and claims." lubricant " refers to, in 2 components
Face with contact with each other state motion when mitigate contact surface friction, prevent heat and abrasion damage reagent." fluorine class lubricates
Agent " refers to the lubricant containing fluorine atom in molecule." organic silicon lubricant " refers to the lubricant containing organosilicon.It is " organic
Silicone oil " refers to, is to be combined with organosilicon obtained by the organic groups such as methyl on main chain and silicon atom with siloxanes key (Si-O-Si)
In the polymer of class compound, i.e. in organosilicon the degree of polymerization it is relatively low be under normal temperature (25 DEG C) oily material." diamines is modified
Organic silicone oil " refers to, contains diaminourea (- RNHR ' NH2, wherein, R and R ' they are divalent organic group respectively) as organic silicone oil
Organic group a part silicone oil." solvent " refer to individually to dissolve diamines modification organic silicon oil or with addition
Solvent combination come dissolve diamines modification organic silicon oil, formed lubricant film at the temperature at which can evaporate and not with lubrication
Agent or the compound under normal temperature (25 DEG C) for liquid of additive reaction." organic solvent for dissolving in tDCE " refers to, with institute
Two layers of separation and muddy do not occur when solvent is mixed in tDCE, stirred under normal temperature (25 DEG C) for the concentration needed can be equably
The organic solvent of dissolving." not having ignition point " refers to do not have ignition point between 23 DEG C~boiling point." the alkane containing diaminourea
TMOS " refers to, the compound of the alkoxy combined with diaminourea and with silicon atom.
<Lubricant solution>
The lubricant solution of the present invention contains lubricant (A) and solvent (B).In the scope for the effect for not destroying the present invention
Interior, lubricant solution can also contain additive (C) as needed in addition to lubricant (A) and solvent (B).
(lubricant (A))
Lubricant (A) contains diamines modification organic silicon oil.In the range of the effect of the present invention is not destroyed, lubricant (A)
In addition to diamines modification organic silicon oil, other lubricants can be also contained as needed.
(diamines modification organic silicon oil)
The concrete example of diamines modification organic silicon oil or lubricant (A) containing diamines modification organic silicon oil can enumerate it is following into
Point.Described in Japan Patent examined patent publication 46-3627 publications with the alkylsiloxane containing diaminourea and dimethyl siloxane
Copolymer is the composition of principal component.Japan Patent examined patent publication 61-35870 publications or Japan Patent examined patent publication 62-52796 public affairs
The reaction product and two organic poly- silicon of siliceous alcohol radical with the silane containing diaminourea and the silane containing epoxy radicals described in report
The reaction product of oxygen alkane is the composition of principal component.Described in Japanese Patent Laid-Open 7-178159 publications side chain and/
Or end has the organosilicon of diaminourea and the mixture of diorganopolysiloxanecompositions.Japanese Patent Laid-Open 10-309316 public affairs
The alkoxy silane containing diaminourea described in report, the alkoxy silane containing epoxy radicals and there is having for silanol base in two ends
The mixture of organosilicon and non-reactive organic silicone obtained by machine pasc reaction.
As diamines modification organic silicon oil, the difficulty from acquisition, adsorptivity and lubricity in metal surface are excellent
From the point of view of, preferably a part for the side chain of dimethyl polysiloxane or the methyl of end by diaminourea replace obtained by formula
(1) compound shown in.
[changing 1]
In formula (1), A is separately methyl, hydroxyl, epoxy radicals, alkoxy (- OR ") or diaminourea (- RNHR '
NH2).Wherein, at least one in A is diaminourea.R and R ' are the organic group of divalent respectively, and R " is the organic group of 1 valency.m
Be respectively with n more than 1 integer.As R, preferably alkylidene, more preferably carbon number 1~5 alkylidene, particularly preferred carbon number 3
Alkylidene.R ', preferably alkylidene, more preferably carbon number 1~5 alkylidene are used as, particularly preferred carbon number is 2 alkylidene.As
R ", preferably alkyl, more preferably carbon number 1~3 alkyl, particularly preferred methyl.
The commercially available product of lubricant (A) as diamines modification organic silicon oil or containing diamines modification organic silicon oil, can be enumerated
Following commodity.Step Japanese contract commercial firm (the モ メ Application テ ィ Block パ フ ォ ー マ Application ス マ テ リ ア Le ズ of figure new high-tech material
ジ ャ パ Application society) system " TSF4702 ", " TSF4703 ", " TSF4704 ", " TSF4705 ", " TSF4706 ", " TSF4707 ",
“TSF4708”." SF8417 ", " BY16- of Dong Li DOW CORNINGs Co., Ltd. (East レ ダ ウ U ー ニ Application グ societies) system
849”、“BY16-205”、“FZ-3760”、“BY16-892”、“FZ-3785”、“BY16-872”、“BY16-893”、“FZ-
3789”、“MDX4-4159”.Wa Ke organosilicons Co., Ltd. of Asahi Chemical Industry (ワ ッ カ ー シ リ U ー Application society of Asahi Chemical Industry) system
“L653”、“L655”、“L656”、“L662”、“WR210”、“WR301”、“WR1100”、“WR1200”、“WR1300”、
“WR1250”、“WT1650”、“65000VP”." KF-859 " of Shin-Etsu Chemial Co., Ltd (chemical industry society of SHIN-ETSU HANTOTAI) system,
“KF-393”、“KF-860”、“KF-880”、“KF-8004”、“KF-8002”、“KF-8005”、“KF-867”、“KF-8021”、
“KF-896”、“KF-861”.Diamines modification organic silicon oil can be used alone a kind, can also two or more be applied in combination.
(other lubricants)
As other lubricants, from the point of view of dissolubility from tDCE is excellent, preferred diamines modification organic silicon oil
Organic silicon lubricant or fluorine class lubricant in addition.According to required greasy property, other lubricants can be suitably selected.Other
Lubricant can be liquid (oil), semi-solid any of (grease) and solid form.
As organic silicone oil, preferably as the dimethyl organic silicone oil or modification organic silicon oil (its of unmodified organic silicone oil
In, except diamines modification organic silicon oil).As modification organic silicon oil, preferably hydrogen modification organic silicon oil, tolyl organic silicone oil,
Ring-type dimethyl organic silicone oil.As the commercially available product of organic silicone oil, for example following commodity can be enumerated.SHIN-ETSU HANTOTAI's chemical industry strain formula meeting
" KF-96 ", " KF-965 ", " KF-968 ", " KF-99 ", " KF-50 ", " KF-54 ", " HIVAC F-4 ", " the HIVAC F- of society
5”、“KF-56A”、“KF-995”." SH200 " of the beautiful DOW CORNING Co. Ltd. system in east.
As organosilicon grease, preferably by base oil of organic silicone oil, incorporation metallic soap etc. thickener and various additives and
The grease obtained.As the commercially available product of organosilicon grease, for example following commodity can be enumerated.Shin-Etsu Chemial Co., Ltd
" G-30 series ", " G-40 series ", " FG-720 series ", " G-411 ", " G-501 ", " G-6500 ", " G-330 ", " G-340 ",
“G-350”、“G-630”.The beautiful DOW CORNING Co. Ltd. system in east " モ リ コ ー ト (Molykote) (registration mark) SH33L ",
" Molykote (registration mark) 41 ", " Molykote (registration mark) 44 ", " Molykote (registration mark) 822M ",
" Molykote (registration mark) 111 ", " Molykote (registration mark) high vacuum grease ", " Molykote (registration mark)
Radiation compound ".
As fluorine class lubricant, fluorocarbon oil, fluorocarbon oil fat, fluorine class kollag (powder of polytetrafluoroethylene (PTFE) etc.) can be enumerated.
As organic silicon lubricant, organic silicone oil, organosilicon grease can be enumerated.As while being that fluorine class lubricant and organic silicon are moistened
The lubricant of lubrication prescription, can enumerate as end or side chain by fluoro-alkyl replace obtained by modification organic silicon oil fluoro organosilicon
Oil.
It is used as fluorocarbon oil, preferably PFPE, the oligomer of a chlorotrifluoroethylene., can example citing as the commercially available product of fluorocarbon oil
Such as following commodity." Network ラ イ ト ッ Network ス (Krytox) (registration mark) GPL102 " of E.I.Du Pont Company (デ ュ ポン societies) system.Greatly
Golden Industrial Co., Ltd (ダ イ キ Application industry society) system " ダ イ Off ロ イ Le (Daifloil) (registration mark) #1 ",
" Daifloil (registration mark) #3 ", " Daifloil (registration mark) #10 ", " Daifloil (registration mark) #20 ",
" Daifloil (registration mark) #50 ", " Daifloil (registration mark) #100 ", " デ system Na system (Demnum) (registration mark)
S-65”." the Off ォ Application Block リ Application of Sol dimension particular polymer company (ソ Le ベ イ ス ペ シ ャ リ テ ィ ー Port リ マ ー ズ societies) system
(FOMBLIN) (registration mark) M03 ", " FOMBLIN (registration mark) M15 ", " FOMBLIN (registration mark) M30 ",
" FOMBLIN (registration mark) M60 ", " FOMBLIN (registration mark) M100 ", " FOMBLIN (registration mark) Y04 ",
" FOMBLIN (registration mark) Y06 ", " FOMBLIN (registration mark) Y25 ", " FOMBLIN (registration mark) Y45 ", " FOMBLIN
(registration mark) YR ", " FOMBLIN (registration mark) YPL1500 ", " FOMBLIN (registration mark) YPL1800 ", " FOMBLIN
(registration mark) YLVAC06/6 ", " FOMBLIN (registration mark) YLVAC14/6 ", " FOMBLIN (registration mark) YLVAC16/
6 ", " FOMBLIN (registration mark) YLVAC25/6 ", " FOMBLIN (registration mark) YHVAC18/8 ", " FOMBLIN (registrars
Mark) YHVAC25/9 ", " FOMBLIN (registration mark) YHVAC40/11 ", " FOMBLIN (registration mark) YHVAC140/13 ",
" FOMBLIN (registration mark) W150 ", " FOMBLIN (registration mark) W500 ", " FOMBLIN (registration mark) W800 ",
" FOMBLIN (registration mark) Z03 ", " FOMBLIN (registration mark) Z15 ", " FOMBLIN (registration mark) Z25 ", " FOMBLIN
(registration mark) Z60 ".
As fluorocarbon oil fat, preferably by base oil of fluorocarbon oil, fluorine obtained by the powder and other thickeners of polytetrafluoroethylene (PTFE) is mixed
Grease.As the commercially available product of fluorocarbon oil fat, for example following commodity can be enumerated." the Network ラ イ ト ッ Network ス (Krytox) of E.I.Du Pont Company
(registration mark) grease 240AC "." Daifloil (registration mark) greases DG-203 ", " the デ system of Daikin Ind Ltd
Na system (Demnum) (registration mark) L65 ", " Demnum (registration mark) L100 ", " Demnum (registration mark) L200 ".Firmly ore deposit
" ス ミ テ ッ Network (SUMITEC) F936 " of lubricant Co., Ltd. (living Mining Run HuaAGENT societies) system.Dong Li DOW CORNINGs Co., Ltd.
" モ リ コ ー ト (Molykote) (registration mark) HP-300 ", " Molykote (registration mark) HP-500 ", " Molykote of system
(registration mark) HP-870 ", " Molykote (registration mark) 6169 ".Sol ties up " the Off ォ Application Block リ of particular polymer company system
Application (FOMBLIN) (registration mark) OT-20 ", " FOMBLIN (registration mark) RT-15 ", " FOMBLIN (registration mark)
YVAC2 ", " FOMBLIN (registration mark) YVAC3 ".
As the commercially available product of fluoro organosilicon oil, for example following commodity can be enumerated." the ユ ニ of Daikin Ind Ltd
ダ イ Application (registration mark) TG-5601 ".The beautiful DOW CORNING Co. Ltd. system in east " Molykote (registration mark) 3451 ",
" Molykote (registration mark) 3452 "." FL-5 ", " X-22-821 ", " X-22- of Shin-Etsu Chemial Co., Ltd
822”、“FL-100”。
Other lubricants that lubricant (A) is included can be a kind of or two or more.Organic silicon lubricant and
Fluorine class lubricant can be used individually, can also be applied in combination.
(solvent (B))
Solvent (B) contains tDCE and HFE-347pc-f.Do not destroy the present invention effect in the range of, solvent (B) except
, can also be as needed containing the organic solvent (B1) for dissolving in tDCE outside tDCE and HFE-347pc-f.Additionally, it is preferred that solvent
(B) other solvents in addition to tDCE, HFE-347pc-f and organic solvent (B1) are not contained.
〔tDCE〕
TDCE is the alkene between carbon atom-carbon atom with double bond, therefore short life in an atmosphere, over the ground ball
Border is without negative effect.TDCE boiling point is about 49 DEG C, therefore drying property is excellent.Even if in addition, boiling forms steam, boiling point is also about
For 49 DEG C, therefore tDCE is not easy to have a negative impact for the part of the easily heated influence such as resin component.TDCE surface
Tension force and viscosity are low, at room temperature also easily evaporation.TDCE is excellent to the dissolubility of other lubricants.As described above, tDCE is removed
Have outside ignition point, with enough as the performance of the solvent in lubricant solution.
As tDCE commercially available product, for example following commodity can be enumerated.Air products Electronics Co., Ltd of Datong District (Datong District エ
ア プ ロ ダ Network Star エ レ Network ト ロ ニ Network ス societies) system " Trans-LC (registration mark) ".PPG Industries Inc. (PPG
INDUSTRIES INC) system " anti-form-1,2- dichloroethylene ".
〔HFE-347pc-f〕
HFE-347pc-f ozone destruction coefficient is 0, and greenhouse effects coefficient is small.HFE-347pc-f boiling point is about 56
DEG C, therefore drying property is excellent.In addition, even if boiling forms steam, boiling point is also about 56 DEG C, therefore HFE-347pc-f is for tree
The part that fat part etc. is easily influenced by heat is not easy to have a negative impact.HFE-347pc-f does not have ignition point.HFE-347pc-
F surface tension and viscosity is low, at room temperature also easily evaporation.As described above, HFE-347pc-f is organic except being modified to diamines
Outside the dissolubility of silicone oil is low, with enough as the performance of the solvent in lubricant solution.
HFE-347pc-f can be for example, by molten in aprotic polar described in International Publication No. 2004/108644
2,2,2 tfifluoroethyl alcohol is set to be reacted with tetrafluoroethene in the presence of agent and catalyst (alkali metal alcoholates or alkali metal hydroxide)
Method manufacture.
As HFE-347pc-f commercially available product, for example following commodity can be enumerated.Asahi Glass Co., Ltd (Asahi Glass society) makes
" ア サ ヒ Network リ Application (ASAHIKLIN) (registration mark) AE-3000 ".
(organic solvent (B1))
Organic solvent (B1) is soluble in tDCE organic solvent.For improving, dissolubility, regulation evaporation rate etc. are various
Purpose, can suitably select organic solvent (B1).
As organic solvent (B1), the hydro carbons for dissolving in tDCE, alcohols, ketone, ethers, esters, chlorinated hydrocarbon can be enumerated
(except tDCE), HFC classes, HFE classes (except HFE-347pc-f), hydrofluoroolefin (being also denoted as HFO classes below), chlorine fluoroolefins
Class (being also denoted as CFO classes below), hydrochlorofluoroolefins (HCFO classes) etc..
It is used as the hydro carbons for dissolving in tDCE, preferably hydro carbons of the carbon number more than 5.Hydro carbons can be chain hydro carbons, cyclic hydrocarbon
Class, saturated hydrocarbons or unsaturated hydro carbons.It is used as the hydro carbons for dissolving in tDCE, including pentane, 2- methybutanes, n-hexane, 2-
Methylpentane, 2,2- dimethylbutanes, 2,3- dimethylbutanes, normal heptane, 2- methyl hexanes, 3- methyl hexanes, 2,4- diformazans
Base pentane, normal octane, 2- methyl heptanes, 3- methyl heptanes, 4- methyl heptanes, 2,2- methyl hexanes, 2,5- dimethylhexanes, 3,
3- dimethylhexanes, 2- methyl -3- ethylpentanes, 3- methyl -3- ethylpentanes, 2,3,3- trimethylpentanes, 2,3,4- front threes
Base pentane, 2,2,3- trimethylpentanes, 2- methylpentanes, 2,2,4- trimethylpentanes, n -nonane, 2,2,5- trimethyl cyclohexanes,
N-decane, n-dodecane, 2- methyl-2-butenes, 1- amylenes, 2- amylenes, 1- hexenes, 1- octenes, 1- nonenes, 1- decene, ring penta
Alkane, methyl cyclopentane, hexamethylene, hexahydrotoluene, ethyl cyclohexane, bicyclohexane, cyclohexene, australene (Japanese：α-ピネ
Application), cinene, decahydronaphthalenes, tetrahydronaphthalene, amyl naphthalene etc..Wherein preferred pentane, pentamethylene, n-hexane, hexamethylene, just
Heptane.
As the alcohols of the alcohols for dissolving in tDCE, preferably carbon number 1~16, from being total to tDCE and HFE-347pc-f
Boil from the point of view of constituting, more preferably the alcohols of carbon number 1~3.Alcohols can be the alcohols of chain, the alcohols of ring-type, saturated alcohols
Class or unsaturated alcohols.It is used as the alcohols for dissolving in tDCE, including methanol, ethanol, normal propyl alcohol, isopropanol, n-butanol, Zhong Ding
Alcohol, isobutanol, the tert-butyl alcohol, 1- amylalcohols, 2- amylalcohols, 1- ethyl -1- propyl alcohol, 2-methyl-1-butene alcohol, 3- methyl-1-butanols, 3- first
Base -2- butanol, neopentyl alcohol, 1- hexanols, 2- methyl-1-pentenes alcohol, 4- methyl -2- amylalcohols, 2- ethyls-n-butyl alcohol, 1-heptanol, 2- heptan
Alcohol, 3- enanthol, 1- octanols, sec-n-octyl alcohol, 2- ethyl -1- hexanols, 1 nonyl alcohol, 3,5,5- trimethyl -1- hexanols, 1- decyl alcohol, 1- ten
One alcohol, 1- lauryl alcohols, allyl alcohol, propargyl alcohol (Japanese：プ ロ パ Le ギ Le ア ル コ ー Le), benzylalcohol, cyclohexanol, 1- methyl rings
Hexanol, 2 methyl cyclohexanol, 3 methyl cyclohexanol, 4 methyl cyclohexanol, α-terpineol, 2,6- 2,6-dimethyl-4-heptanols, nonyl alcohol,
Tetradecyl alchohol etc..Wherein preferred methanol, ethanol, isopropanol.
It is used as the ketone of the ketone for dissolving in tDCE, preferably carbon number 3~9.Ketone can be the ketone of chain, the ketone of ring-type
Class, saturated ketone or unsaturated ketone.It is used as the ketone for dissolving in tDCE, including acetone, MEK, 2 pentanone, propione, 2-
Hexanone, methylisobutylketone, 2-HEPTANONE, 3- heptanone, 4- heptanone, diisobutyl ketone, isopropylidene acetone (Japanese：メシチルオキシ
De), phorone, methyln-hexyl ketone, cyclohexanone, methyl cyclohexanone, isophorone, 2,4- pentanediones, 2,5- acetyl butyryls, DAA,
Acetophenone etc..Wherein preferred acetone and MEK.
It is used as the ethers of the ethers for dissolving in tDCE, preferably carbon number 2~8.Ethers can be the ethers of chain, the ether of ring-type
Class, saturation ethers or unsaturated ether.It is used as the ethers for dissolving in tDCE, including diethyl ether, dipropyl ether, diisopropyl ether, two fourths
Ether, ethyl vinyl ether, butyl vinyl ether, methyl phenyl ethers anisole, phenetole, methylanisole, furans, methylfuran, tetrahydrofuran
Deng.Wherein preferred diethyl ether, diisopropyl ether and tetrahydrofuran.
It is used as the esters of the esters for dissolving in tDCE, preferably carbon number 2~19.Esters can be the esters of chain, ring-type
Esters, saturation esters or unsaturated esters.It is used as the esters for dissolving in tDCE, including methyl formate, Ethyl formate, formic acid third
Ester, butyl formate, iso-butyl formate, amyl formate, methyl acetate, ethyl acetate, propyl acetate, isopropyl acetate, acetic acid fourth
Ester, isobutyl acetate, sec-butyl acetate, pentyl acetate, methoxy butyl acetate, sec-hexyl acetate, acetic acid 2- ethyls butyl ester, second
Sour 2- ethylhexyls, cyclohexyl acetate, benzyl acetate, methyl propionate, ethyl propionate, butyl propionate, methyl butyrate, butyric acid second
Ester, butyl butyrate, isobutyl isobutyrate, 2- hydroxy-2-methyls ethyl propionate, methyl benzoate, ethyl benzoate, benzoic acid third
Ester, butyl benzoate, Ergol, gamma-butyrolacton, diethy-aceto oxalate, dibutyl oxalate, diamyl oxalate, malonic acid two
Ethyl ester, dimethyl maleate, diethyl maleate, dibutyl maleate, dibutyl tartrate, ATBC, decanedioic acid
Dibutyl ester, repefral, diethyl phthalate, dibutyl phthalate etc..Wherein preferred methyl acetate
And ethyl acetate.
It is used as the chlorinated hydrocarbon of the chlorinated hydrocarbon for dissolving in tDCE, preferably carbon number 1~3.Chlorinated hydrocarbon can be chain
Chlorinated hydrocarbon, the chlorinated hydrocarbon of ring-type, saturation chlorinated hydrocarbon or unsaturated chlorinated hydrocarbon.It is used as the chlorohydrocarbon for dissolving in tDCE
Class, including dichloromethane, 1,1- dichloroethanes, 1,2- dichloroethanes, 1,1,2- trichloroethanes, 1,1,1,2- tetrachloroethanes, 1,
1,2,2- tetrachloroethanes, pentachloroethane, 1,1- dichloroethylene, cis -1,2- dichloroethylene, trichloro ethylene, tetrachloro-ethylene, 1,2-
Dichloropropane etc..Wherein preferred dichloromethane.
As the HFC classes of the HFC classes for dissolving in tDCE, the preferably chain of carbon number 4~8 or ring-type, in more preferably 1 molecule
HFC class of the number of fluorine atoms more than number of hydrogen atoms.As the HFC classes for dissolving in tDCE, including 1,1,1,3,3- 3-pentafluorobutane, 1,
1,1,2,2,3,4,5,5,5- Decafluoropentanes, the fluorine pentamethylene of 1,1,2,2,3,3,4- seven, the fluorine of 1,1,1,2,2,3,3,4,4- nine oneself
Alkane, the trifluorohexanes of 1,1,1,2,2,3,3,4,4,5,5,6,6- ten, the fluoro-octanes of 1,1,1,2,2,3,3,4,4,5,5,6,6- 13
Deng.Wherein, preferably 1,1,1,2,2,3,4,5,5,5- Decafluoropentane, 1,1,1,2,2,3,3,4,4- nine fluorine hexane, 1,1,1,2,
The trifluorohexanes of 2,3,3,4,4,5,5,6,6- ten.
As the HFE classes for dissolving in tDCE, including HFE-449s1, ethyl perfluorobutyl ether etc..Wherein preferred HFE-
449s1.As the HFO classes for dissolving in tDCE, including MPHE, 1,1, Isosorbide-5-Nitrae, 4,4- hexafluoro -2- butylene etc..As dissolving in tDCE
CFO classes, including 1,1- bis- chloro- 2,3,3,3- tetrafluoro-1-propenes (CFO-1214ya) etc..It is used as the HCFO for dissolving in tDCE
Class, includes cis and trans isomers, 1, the 1- bis- chloro- 3,3,3- trifluoro propenes etc. of 1- chloro-3,3,3 ,-trifluoropropenes.
Organic solvent (B1) contained by solvent (B) can be a kind of or two or more.In addition, solvent (B) contains
In the case of two or more organic solvents (B1), the combination of organic solvent (B1) can be the combination of the solvent of identical category,
The combination of the solvent of different categories can also be made.For example, organic solvent (B1) can be two kinds of hydrocarbon combination or a kind
The combination of hydrocarbon and a kind of alcohol.
Organic solvent (B1) is more preferably the solvent without ignition point.It is used as the organic solvent without ignition point
(B1) 1,1,1,2,2,3,4,5,5,5- Decafluoropentane, 1,1,1,2,2,3,3,4,4- nine fluorine hexane, 1, can be enumerated, 1,1,2,2,
HFE classes such as HFC classes and HFE-449s1 such as trifluorohexanes of 3,3,4,4,5,5,6,6- ten etc..Made using the solvent with ignition point
In the case of for organic solvent (B1), as solvent (B) it is also preferred that in the range of without ignition point with tDCE and HFE-
347pc-f mixing is used.In addition, in the case that tDCE and HFE-347pc-f is constituted with organic solvent (B1) formation azeotropic,
These compositions can also azeotropic composition mode used.
(additive (C))
Additive (C) is the composition in addition to lubricant (A) and solvent (B) in lubricant solution.As additive (C),
It can enumerate crosslinking agent and other solvents in addition to tDCE, HFE-347pc-f and organic solvent (B1), and in addition its
His additive.
As crosslinking agent, alkoxyl silicone alkanes or part thereof condensation product (oligomer) can be enumerated.As alkoxyl silicone alkanes,
Including tetraalkoxysilane, monoalkoxysilane, dialkoxy silicane or trialkoxy silane with alkyl or aryl have
The so-called silane coupler such as monoalkoxysilane, dialkoxy silicane or the trialkoxy silane of reactive functional groups.As
Alkoxyl silicone alkanes, from the adsorptivity of metal it is excellent from the point of view of, the preferred alkoxy silane containing diaminourea.
As the alkoxy silane containing diaminourea, 3- (2- aminoethylaminos) propyl trimethoxy silicane, 3- can be enumerated
(2- aminoethylaminos) hydroxypropyl methyl dimethoxysilane etc.., can example as the commercially available product of the alkoxy silane containing diaminourea
Citing such as following commodity." KBM-602 ", " KBM-603 " of Shin-Etsu Chemial Co., Ltd.Figure new high-tech material Japan is stepped to close
With " TSL8340 ", " TSL8345 " of commercial firm.
As other solvents in addition to tDCE, HFE-347pc-f and organic solvent (B1) or in addition other add
Plus agent, nitromethane, nitroethane, nitropropane, nitrobenzene, diethylamine, triethylamine, isopropylamine, diisopropylamine, fourth can be enumerated
Amine, isobutyl amine, tert-butylamine, α-methylpyridine, N- methylbenzylamines, diallylamine, N-methylmorpholine, phenol, orthoresol, a first
Phenol, paracresol, thymol (Japanese：チ モ ー Le), p-tert-butylphenol, tert-butyl catechol, catechol, isobutyl it is fragrant
Phenol (Japanese：イ ソ オ イ ゲ ノ ー Le), o- metoxyphenol, 4,4 '-dihydroxy phenyl -2,2- propane, salicylic acid isoamyl
Ester, benzyl salicylate, gaultherolin, 2,6- di-t-butyls-paracresol, 2- (2 '-hydroxyl -5 '-aminomethyl phenyl) BTA,
2- (2 '-hydroxyl -3 '-the tert-butyl group -5 '-aminomethyl phenyl) -5- chlorinated benzotriazoles, l, 2,3 triazole, the 1- [(double -2- of N, N-
Ethylhexyl) amino methyl] BTA, 1,2 epoxy prapane, 1,2- epoxy butanes, 1,4- dioxanes, butyl glycidyl
Ether, phenyl glycidyl ether etc..
(ratio of each composition)
Ratio of the lubricant (A) in the mass % of lubricant solution 100 is preferably 0.01~50 mass %, more preferably
0.05~30 mass %, more preferably 0.1~20 mass %.Lubricant (A) if ratio in the scope, apply
The thickness of film and the thickness of dried lubricant film during cloth lubricant solution are readily adjusted to appropriate scope.
Lubricant (A) only can be made up of diamines modification organic silicon oil, can also contain other lubricants.Removed in lubricant (A)
In the case of also containing other lubricants outside diamines modification organic silicon oil, diamines modification organic silicon oil is in lubricant (A) 100
Ratio in quality % is preferably 1~99 mass %, more preferably 10~95 mass %, more preferably 20~90 matter
Measure %.Ratio of other lubricants in the mass % of lubricant (A) 100 is preferably 1~99 mass %, more preferably 5~90 matter
Measure %, more preferably 10~80 mass %.
Ratio of the solvent (B) in the mass % of lubricant solution 100 is preferably 50~99.99 mass %, more preferably 70
~99.95 mass %, more preferably 80~99.9 mass %.Solvent (B) if ratio in the scope, be coated with
The thickness of film and the thickness of dried lubricant film during lubricant solution are readily adjusted to appropriate scope.
Ratios of the tDCE in tDCE and HFE-347pc-f adds up to 100 mass % is 40~70 mass %, preferably 45~60
Quality %, more preferably 50~55 mass %.Ratios of the HFE-347pc-f in tDCE and HFE-347pc-f adds up to 100 mass %
For 30~60 mass %, more preferably preferably 40~55 mass %, 45~50 mass %.TDCE ratio and HFE-347pc-f
If ratio in the scope, the dissolubility to diamines modification organic silicon oil is excellent and lubricant solution is without catching fire
Point.
The ratio that tDCE and HFE-347pc-f are aggregated in the mass % of solvent (B) 100 is preferably 50~100 mass %, more
Preferably 75~100 mass %, more preferably 80~100 mass %.Contain the situation of organic solvent (B1) in solvent (B)
Under, preferably contain organic solvent (B1) in the range of solvent (B) does not have ignition point.Solvent (B) contains organic solvent (B1)
In the case of, the ratio that tDCE and HFE-347pc-f are aggregated in the mass % of solvent (B) 100 is preferably 50~99.9 mass %,
More preferably 75~99.9 mass %, more preferably 80~99.9 mass %.Must catching fire according to organic solvent (B1)
Characteristic, the ratio to organic solvent (B1) in the range of solvent (B) does not have ignition point is suitably adjusted, organic solvent
(B1) ratio in the mass % of solvent (B) 100 is preferably 0.1~50 mass %, more preferably 0.1~25 mass %, enters one
Step is preferably 0.1~20 mass %.TDCE and HFE-347pc-f total ratio and organic solvent (B1) if ratio exist
In the scope, then the effect of the present invention is given full play to.
Ratio of the additive (C) in the mass % of lubricant solution 100 is preferably in below 5 mass %, more preferably in 3 matter
Below % is measured, further preferably in below 1 mass %.Additive (C) if ratio in the scope, give full play to this
The effect of invention.
In the case where lubricant solution contains the alkoxy silane containing two amidos, the alkoxy silane containing two amidos is in profit
Ratio in the mass % of lubrication prescription solution 100 is preferably 0.01~5 mass %, more preferably 0.05~3 mass %, further preferably
For 0.1~1 mass %.If the ratio of the alkoxy silane containing two amidos gives full play to conduct more than the lower limit
The effect of crosslinking agent.If the ratio of the alkoxy silane containing two amidos gives full play to the present invention below the higher limit
Effect.
The lubricant solution of the present invention has used ozone destruction coefficient and greenhouse effects coefficient small tDCE and HFE-
347pc-f does not have a negative impact as solvent to earth environment.Moreover, as solvent, by being made with specific ratio
It is low but do not have with the dissolubility of the excellent tDCE of the dissolubility to diamines modification organic silicon oil and diamines modification organic silicon oil
The HFE-347pc-f of ignition point so that lubricant solution is excellent, lubricant solution to the dissolubility of diamines modification organic silicon oil
Do not separated without white opacity or lubricant in preservation, and lubricant solution does not have ignition point.
<The manufacture method of article with lubricant film>
The manufacture method of the article with lubricant film of the present invention includes following processes (a) and (b).Process (a)
The middle lubricant solution by the present invention is coated on the surface for being applied thing.Make to be coated on the surface for being applied thing in process (b)
Solvent (B) evaporation in lubricant solution, forms the film containing lubricant (A) on the surface for being applied thing and is applied as lubricant
Film.
(process (a))
As thing is applied, the various materials such as metal, plastics, elastomer, glass, ceramics, preferably metal can be enumerated.As
The concrete example of thing is applied, the injection needle and syringe of syringe, medical pipe part, metal blade, conduit etc. can be enumerated, preferably
Injection needle.
As the coating method of lubricant solution, it can enumerate and be for example coated with by hairbrush, by spraying coating, by will be by
Coating material is impregnated in lubricant solution to be coated with.
(process (b))
As the method for making to be coated on solvent (B) evaporation being applied in the lubricant solution on thing surface, it can enumerate known
Drying means.As drying means, it can enumerate such as air-dried, heat drying.Preferably 20~100 DEG C of drying temperature.Pass through
Make to be coated on solvent (B) evaporation in the lubricant solution for being applied thing, lubricant film is formed on the surface for being applied thing.According to
This manufactures the article with lubricant film on the surface for being applied thing with lubricant film.
The manufacture method of the article with lubricant film of the present invention has been used imitates containing ozone destruction coefficient and greenhouse
TDCE that coefficient is small and HFE-347pc-f lubricant solution of the invention are answered, therefore earth environment is not had a negative impact.
In addition, used it is excellent to the dissolubility of diamines modification organic silicon oil, do not occur in preservation white opacity or lubricant regardless of
From lubricant solution of the invention, therefore, it is possible to form uniform lubricant film.In addition, having used without ignition point
The lubricant solution of the present invention, therefore, it is possible to safely manufacture the article with lubricant film.
Embodiment
Hereinafter, the present invention is described in detail by embodiment, but the present invention is not limited to this.Example 1~5,7~11 is reference
Example, example 6,12,13,16~21,23~27,30,31,34,35 is embodiment, and example 14,15,22,28,29,32,33 is to compare
Example.
(dissolubility test)
Following adjusted solvent (B) 100g is added in Pyrex bulb, in addition regulation at 23 DEG C in solvent (B)
Following organic silicone oils of amount are used as subjects thing.Observe the lubricant solution obtained by with the addition of at 23 DEG C after subjects thing
State at once and the state of the lubricant solution after 5 days is saved at 23 DEG C, have rated dissolubility by following standards.
A：It is excellent, the separation of white opacity or lubricant is not observed.
B：Well, it was observed that slightly white opacity, but without practical sex chromosome mosaicism.
C：It is bad, it was observed that the separation of obvious white opacity or lubricant.
(ignition point)
For the solvent before addition organic silicone oil, using the open fire test device in Cleveland, (Jitian makes institute
Co., Ltd. (Ji Tiansystemzuosuoshe) makes, model 828) confirm whether there is ignition point untill boiling point from 23 DEG C.
(example 1~13)
(dissolubilities of various organic silicone oils in solvent (B))
TDCE (PPG Industries Inc.'s system, anti-form-1,2- dichloroethylene), HFE-347pc- are being contained with the ratio shown in table 1
Added in f (Asahi Glass Co., Ltd, ア サ ヒ Network リ Application (registration mark) AE-3000) and the solvent (B) of ethanol under ormal weight
Organic silicone oil is stated, lubricant solution has been prepared, dissolubility is have rated.As a result it is shown in table 1.Example 1,2,7,8 has used dimethyl-silicon
Oily (Shin-Etsu Chemial Co., Ltd's system, KF-96).Example 3,9 has used epoxy modified silicone oil (SHIN-ETSU HANTOTAI's chemical industry strain formula
Commercial firm's system, KF-101).Example 4,10 has used monoamine modification organic silicon oil (Shin-Etsu Chemial Co., Ltd's system, KF-868).Example
5th, 11 hydrogen modification organic silicon oil (Shin-Etsu Chemial Co., Ltd's system, KF-99) has been used.Example 6,12 and 13 has used diamines to change
Property organic silicone oil (Shin-Etsu Chemial Co., Ltd's system, KF-859).
[table 1]
As shown in table 1, solvent (B) is high to the dissolubility of each silicone oil.
(example 14~25)
(ignition point of the dissolubility of diamines modification organic silicon oil and solvent in solvent)
Prepare and tDCE (PPG Industries Inc.'s system, anti-form-1,2- dichloroethylene), HFE- are contained with the ratio shown in table 2
347pc-f (Asahi Glass Co., Ltd, ア サ ヒ Network リ Application (registration mark) AE-3000) and ethanol solvent.Add in a solvent
The diamines modification organic silicon oil (Shin-Etsu Chemial Co., Ltd's system, KF-859) of ormal weight, has prepared lubricant solution, evaluates
Dissolubility and ignition point.As a result it is shown in table 2.
[table 2]
TDCE ratio is high in example 14,15, therefore solvent has ignition point.In example 16~21,23~25, tDCE and HFE-
347pc-f ratio within the scope of the invention, therefore diamines modification organic silicon oil dissolving and solvent (B) do not have ignition point.
In example 22, HFE-347pc-f ratio is high, therefore diamines modification organic silicon oil is undissolved, after the addition of diamines modification organic silicon oil
Lubricant solution is immediately disconnected as two layers.
(example 26~33)
(dissolubility of diamines modification organic silicon oil in various solvents)
Prepare and various solvents and (the SHIN-ETSU HANTOTAI's chemical industry strain formula meeting of diamines modification organic silicon oil are contained with the ratio shown in table 3
Society's system, KF-859) or diamines modification organic silicon oil containing 50 mass % organic silicone oil product (Dong Li DOW CORNINGs Co., Ltd.
System, MDX4-4159) lubricant solution, have rated dissolubility.As a result it is shown in table 3.Example 28,32 has used Novec (registrars
Mark) HFE-71DE ((ス リ ー エ system ジ ャ パ Application society of 3M Japanese firms) systems, tDCE/HFE-449s1=50/50 (mass ratio)).
Example 29,33 has used Vertrel (registration mark) Sion (E.I.Du Pont Company's system, tDCE and the mixture of HFO classes).
[table 3]
In example 26,27,30,31, within the scope of the invention, therefore lubricant is molten for tDCE and HFE-347pc-f ratio
The separation of white opacity or lubricant is not observed in liquid.Example 28,29,32,33 is containing fluorine-containing molten in addition to HFE-347pc-f
The separation of white opacity or lubricant is observed in lubricant solution after agent, therefore five days, storage stability is poor.
(example 34)
(the coating experiment of lubricant solution)
The solvent (B) being made up of 50.3 mass % tDCE and 49.7 mass % HFE-347pc-f is prepared.In solvent
(B) addition diamines modification organic silicon oil (Shin-Etsu Chemial Co., Ltd's system, KF-859) causes the oily concentration in solution in
For 3 mass %, lubricant solution has been prepared.By aluminium-vapour deposition in obtained by iron plate on the surface of aluminium-vapour deposition plate with average thickness
The mode application of lubricating solution for being about 0.4mm, air-dries under conditions of 19~21 DEG C, is thereby formed on the surface of aluminium-vapour deposition plate
Lubricant film.White opacity is not observed in lubricant solution, solvent (B) steams rapidly from the lubricant solution after coating
Hair, the state of lubricant film is also good.
(example 35)
(the coating experiment of lubricant solution)
Prepare what is be made up of 50.5 mass % tDCE, 47.5 mass % HFE-347pc-f and 2 mass % ethanol
Solvent (B).Then, in addition to using the solvent (B), lubricant solution has been prepared in the same manner as example 34, in aluminium-vapour deposition plate
Surface forms lubricant film.White opacity is not observed in lubricant solution, solvent (B) is from the lubricant solution after coating
In evaporate rapidly, the state of lubricant film is also good.
The possibility utilized in industry
The lubricant solution of the present invention can be used as the lubrication in the metallic surfaces such as injection needle formation lubricant film
Agent solution.
Claims (10)
1. lubricant solution, it is characterised in that contain：
The lubricant (A) of the modification organic silicon oil containing diamines and
Containing anti-form-1, the solvent (B) of 2- dichloroethylene and 1,1,2,2- tetra- fluoro- 1- (2,2,2- trifluoro ethoxies) ethane；
Anti-form-1,2- dichloroethylene and 1,1,2,2- tetra- fluoro- 1- (2,2,2- trifluoro ethoxies) ethane add up to be contained in 100 mass %
There is 40~70 mass % anti-form-1,2- dichloroethylene,
Anti-form-1,2- dichloroethylene and 1,1,2,2- tetra- fluoro- 1- (2,2,2- trifluoro ethoxies) ethane add up to be contained in 100 mass %
There is 30~60 mass % 1,1,2,2- tetra- fluoro- 1- (2,2,2- trifluoro ethoxies) ethane.
2. lubricant solution as claimed in claim 1, it is characterised in that contain in the mass % of lubricant solution 100
0.01~50 mass % lubricant (A).
3. lubricant solution as claimed in claim 1 or 2, it is characterised in that contain in the mass % of lubricant solution 100
50~99.99 mass % solvent (B).
4. such as lubricant solution according to any one of claims 1 to 3, it is characterised in that the solvent (B) is also containing solvable
In anti-form-1, the organic solvent (B1) of 2- dichloroethylene.
5. lubricant solution as claimed in claim 4, it is characterised in that the organic solvent (B1) is the alcohol of carbon number 1~3.
6. the lubricant solution as described in claim 4 or 5, it is characterised in that contain 0.1 in the mass % of solvent (B) 100
~50 mass % organic solvent (B1).
7. such as lubricant solution according to any one of claims 1 to 6, it is characterised in that the solvent (B) by anti-form-1,
The alcohol of 2- dichloroethylene, the fluoro- 1- of 1,1,2,2- tetra- (2,2,2- trifluoro ethoxies) ethane and carbon number 1~3 is constituted.
8. such as lubricant solution according to any one of claims 1 to 7, it is characterised in that also containing the alcoxyl containing diaminourea
Any of base silane and its partial condensate.
9. the manufacture method of the article with lubricant film, it is characterised in that be included in the surface coating right for being applied thing
It is required that the process of lubricant solution any one of 1~8 and
Make to be coated on the solvent (B) evaporation being applied in the lubricant solution on the surface of thing, applied described
The process that the surface of cloth thing forms the film containing the lubricant (A).
10. there is the manufacture method of the article of lubricant film as claimed in claim 9, it is characterised in that described to be applied
Thing is injection needle.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2015-013155 | 2015-01-27 | ||
| JP2015013155 | 2015-01-27 | ||
| PCT/JP2016/052278 WO2016121795A1 (en) | 2015-01-27 | 2016-01-27 | Lubricant solution and method for manufacturing article with lubricant coating film |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN107207981A true CN107207981A (en) | 2017-09-26 |
| CN107207981B CN107207981B (en) | 2021-01-12 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680007358.4A Active CN107207981B (en) | 2015-01-27 | 2016-01-27 | Lubricant solution and method for producing article having lubricant coating film |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6686911B2 (en) |
| CN (1) | CN107207981B (en) |
| WO (1) | WO2016121795A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112074591A (en) * | 2018-05-03 | 2020-12-11 | 科慕埃弗西有限公司 | Ternary and quaternary azeotrope and azeotrope-like compositions comprising perfluoroheptenes |
| CN113454140A (en) * | 2019-02-26 | 2021-09-28 | 富士胶片株式会社 | Adhesive for endoscope, cured product thereof, endoscope, and method for producing endoscope |
| CN114651048A (en) * | 2019-09-13 | 2022-06-21 | 永净先进材料公司 | Formulation and method for forming a protective surface |
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- 2016-01-27 WO PCT/JP2016/052278 patent/WO2016121795A1/en active Application Filing
- 2016-01-27 CN CN201680007358.4A patent/CN107207981B/en active Active
- 2016-01-27 JP JP2016572087A patent/JP6686911B2/en active Active
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN112074591A (en) * | 2018-05-03 | 2020-12-11 | 科慕埃弗西有限公司 | Ternary and quaternary azeotrope and azeotrope-like compositions comprising perfluoroheptenes |
| CN113454140A (en) * | 2019-02-26 | 2021-09-28 | 富士胶片株式会社 | Adhesive for endoscope, cured product thereof, endoscope, and method for producing endoscope |
| CN113454140B (en) * | 2019-02-26 | 2023-12-08 | 富士胶片株式会社 | Adhesive for endoscope, cured product thereof, endoscope, and method for producing same |
| CN114651048A (en) * | 2019-09-13 | 2022-06-21 | 永净先进材料公司 | Formulation and method for forming a protective surface |
| US11883558B2 (en) | 2019-09-13 | 2024-01-30 | Spotless Materials Inc. | Formulations and processes to generate repellent surfaces on medical devices |
Also Published As
| Publication number | Publication date |
|---|---|
| JP6686911B2 (en) | 2020-04-22 |
| CN107207981B (en) | 2021-01-12 |
| JPWO2016121795A1 (en) | 2017-11-02 |
| WO2016121795A1 (en) | 2016-08-04 |
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