The content of the invention
It is a primary object of the present invention to overcoming the deficiencies in the prior art there is provided a kind of metal powder injection molding feeding and
Its preparation method.
To achieve the above object, the present invention uses following technical scheme:
A kind of metal powder injection molding feeding, including binder and 316L stainless steel feeding powder, the binder and
The mass ratio of the 316L stainless steels feeding powder is 96: 4~90: 10;
The 316L stainless steels feeding powder includes the component of following mass percent:
316L powder of stainless steel:90%~99%
Chromium carbide powder:1%~10%
The binder includes the component of following mass percent:
Further:
The 316L powder of stainless steel is SUS316L powder of stainless steel.
The 316L powder of stainless steel and the chromium carbide powder meet following specification:
The mesh of 316L powder of stainless steel -500
The mesh of chromium carbide powder -800.
A kind of preparation method of described metal powder injection molding feeding, comprises the following steps:
S1. the stainless steel feeding powder is added in kneading machine and preheated;
S2. the binder added according to proportioning, is kneaded;
S3. extruding pelletization.
Further:
In step S1, the stainless steel feeding powder is preheating to predetermined temperature to exclude the aqueous vapor in powder, preferably added
Heat is to 200 DEG C.
In step S2, the binder is added at a temperature of more than 170 DEG C and is kneaded.
In step S2,185 DEG C of keeping temperature, rotating speed 20r/min is kneaded and is stopped heating after 30min, is further continued for mixing
30min。
A kind of method that product is made using described metal powder injection molding feeding, is comprised the following steps:
S1. the stainless steel feeding powder is added in kneading machine and preheated;
S2. the binder added according to proportioning, is kneaded;
S3. extruding pelletization;
S4. the product is obtained using the feeding progress injection moulding, degreasing, sintering MIM PROCESS FOR TREATMENTs of granulation.
Further:
In step S4, to injection molding member degreasing, make to carry out vacuum-sintering after total mass loss rate >=7.5%, sintering temperature
1360 DEG C of degree, soaking time 3 hours.
A kind of product, is the product being made by described metal powder injection molding feeding by MIM techniques.
Preferably, the product is 3C Electronic Equipment Structural Members.
Beneficial effects of the present invention:
The metal powder injection molding feeding that the present invention is provided is using specific formula, wherein binder and 316L stainless steels
The mass ratio of feeding powder is 96: 4~90: 10, and the 316L stainless steel feedings powder includes mass percent 90%~99%
316L powder of stainless steel and 1%~10% chromium carbide powder, the binder include the full refining of mass percent 5%~10%
Paraffin, 5%~10% ethene, 5%~10% polyethylene, 5%~10% polyethylene glycol, 75%~80% poly- first
Aldehyde, MIM techniques are used in by the metal powder injection molding feeding, as MIM feedings, can go out to meet various 3C electricity with processing and fabricating
Structural member product needed for sub- equipment, and the properties of product with high rigidity high-quality.Experiments verify that, using inventive formulation
SUS316L feedings, the hardness of MIM products strengthens up to more than 40% than the MIM products of common SUS316L feedings, effectively solves
The problem of SUS316L material parts big part thin pieces is easily deformed, model is applied in the market for expanding the part of SUS316L materials
Enclose.Due to product hardness lifting, it is unlikely to deform, meets the intensity requirement of the big part products of 316L, particularly lifts SUS316L products
Application on consumer electronics product.
Embodiment
Embodiments of the present invention are elaborated below.It is emphasized that what the description below was merely exemplary,
The scope being not intended to be limiting of the invention and its application.
In one embodiment, a kind of metal powder injection molding feeding, including binder and 316L stainless steel feeding powder
The mass ratio of end, the binder and the 316L stainless steels feeding powder is 96: 4~90: 10;
The 316L stainless steels feeding powder includes the component of following mass percent:
316L powder of stainless steel:90%~99%
Chromium carbide powder:1%~10%
The binder includes the component of following mass percent:
In a preferred embodiment, the 316L powder of stainless steel is SUS316L powder of stainless steel.
In a preferred embodiment, the 316L powder of stainless steel and the chromium carbide powder meet following specification:
The mesh of 316L powder of stainless steel -500
The mesh of chromium carbide powder -800.
In one embodiment, a kind of preparation method of described metal powder injection molding feeding, comprises the following steps:
S1. the stainless steel feeding powder is added in kneading machine and preheated;
S2. the binder added according to proportioning, is kneaded;
S3. extruding pelletization.
In a preferred embodiment, in step S1, the stainless steel feeding powder is preheating to predetermined temperature to exclude powder
In aqueous vapor, it is further preferred that being heated to 200 DEG C of predetermined temperatures.
In a preferred embodiment, in step S2, the binder is added at a temperature of more than 170 DEG C and is kneaded.
In a preferred embodiment, in step S2,185 DEG C of keeping temperature, rotating speed 20r/min is kneaded and is stopped adding after 30min
Heat, is further continued for kneading 30min.
In one embodiment, a kind of method that product is made using described metal powder injection molding feeding, including
Following steps:
S1. the stainless steel feeding powder is added in kneading machine and preheated;
S2. the binder added according to proportioning, is kneaded;
S3. extruding pelletization;
S4. the product is obtained using the feeding progress injection moulding, degreasing, sintering MIM PROCESS FOR TREATMENTs of granulation.
In a preferred embodiment, in step S4, to injection molding member degreasing, make to carry out after total mass loss rate >=7.5%
Vacuum-sintering, 1360 DEG C of sintering temperature, soaking time 3 hours.
A kind of specific preferred sintering control program is as shown in table 1.
Table 1
|
1 |
2 |
3 |
4 |
5 |
6 |
7 |
8 |
9 |
10 |
11 |
12 |
13 |
T, min |
0 |
180 |
240 |
300 |
330 |
390 |
420 |
520 |
570 |
630 |
810 |
870 |
960 |
Ts, DEG C |
0 |
600 |
600 |
800 |
800 |
1050 |
1050 |
1300 |
1300 |
1360 |
1360 |
900 |
0 |
N2, L/min |
0 |
900 |
900 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
1500 |
Ar, Pa |
0 |
0 |
0 |
0 |
0 |
0 |
0 |
500 |
500 |
500 |
500 |
500 |
0 |
Wherein 1~13 is expressed as program segment, starts to warm up (1 section) from starting device, is come out of the stove to the cooling that program has been run
(13 sections);T, min are represented from starting device to the cumulative time for having run the program, are run altogether how many minutes and are terminated this section of journey
Sequence;Numerical value in Ts, DEG C expression present segment program setting temperature, temperature rise period, even number section needs to rise after for this program segment terminating
The temperature that numerical value in the temperature that temperature is arrived, odd number section needs to keep for this program segment, temperature-fall period, numerical value is that this program segment terminates
When need the temperature that drops to;N2, L/min represent that pure nitrogen gas (purity more than 99%) is per minute and how many liter are passed through;Ar, pa represent logical
Cross and be passed through argon gas to control the sintering pressure handkerchief in vacuum sintering furnace.
In one embodiment, a kind of product, is to be made by described metal powder injection molding feeding by MIM techniques
Product.
In a preferred embodiment, the product can be 3C Electronic Equipment Structural Members.
In certain embodiments, a kind of metal powder injection molding feeding preparation method, comprises the following steps:
S1, startup kneader, Stirring main frame (5r/1min), adds SUS316L powder of stainless steel and chromium carbide at a slow speed
Proportioning material, is preheating to 200 DEG C of exclusion powder aqueous vapors;
S2, after 1 hour, with laser infrared line temperature measurer, powder temperature is detected, when detection temperature is more than 170 DEG C, by powder
The percentage of weight adds the forming agent prepared, and reduction temperature is to 185 DEG C, and adjustment rotating speed to 20r/1min continues kneading mixing
Feeding;
S3, mixing rotating speed temperature are kept after 30min, close melting temperature, continue to knead after 30min, and extrusion granulator is obtained
SUS316L injection moulding feedings after hardening.
Exemplary embodiments
The SUS316L powder of stainless steel injection moulding feedings of the embodiment of the present invention are prepared, and MIM productions are prepared with the feeding
Product.
1. taking SUS316L powder 4300g, chromium carbide powder 200g, it is put into kneading machine heating and is preheated to 200 DEG C, startup
Rotary machine is mediated after stirring system (5r/1min), 30min at a slow speed for regulation, is detected powder temperature, is added fully refined paraffin wax 25g,
Ethene 50g, polyethylene 40g, polyethylene glycol 45g, polyformaldehyde 375g, reduction design temperature heighten rotating speed to (20r/ to 185 DEG C
1min), continue to mediate stirring mixing 30min, turn off device temperature, then keep kneading 30min, extrusion granulator is made after hardening
SUS316L injection moulding feedings;
2. by using injector, the feeding high pressure after hardening is injected standard strip sample molds (product size:100*
Standard strip sample blank 10*3) is obtained, as shown in Figure 1;
3. sample blank is carried out into catalysis degreasing, measure after degreasing sample total mass loss rate >=7.5%, product is carried out
Vacuum-sintering, 1360 DEG C of sintering temperature, soaking time 3 hours, the product after being sintered, as shown in Figure 2;
4. taking the sample products sintered, detected firmly, measure vickers hardness hv 250-280;
Typical comparison's example:
Traditional SUS316L injection moulding feedings are prepared, and MIM products are prepared with the feeding.
1. taking the common SUS316L feedings of 5KG, by using injector, feeding high pressure is injected standard strip sample molds
(product size:Sample 100*10*3) is obtained, molded blank sample rate is 5.45g/cm3;
2. blank sample is carried out into catalysis degreasing, measure after degreasing sample total mass loss rate >=7.5%, product is carried out
Vacuum-sintering, 1360 DEG C of sintering temperature, soaking time 2.5 hours;
Rear outturn sample is sintered 3. taking, is detected firmly, sample vickers hardness hv 120-180 is measured.
The parameter comparison such as table 2 below and table 3 for the outturn sample that multiple embodiments are sintered with comparative example.
The 316L standard batten parameters of the conventional formulation of table 2
The 316L standard batten parameters of the embodiment of the present invention of table 3
By detection, obtained SUS316L feeding products, its hardness (Vickers HV) ratio are made by using the method for the present invention
Product prepared by conventional method can improve more than 40%.
Above content is to combine specific/preferred embodiment made for the present invention be further described, it is impossible to recognized
The specific implementation of the fixed present invention is confined to these explanations.For general technical staff of the technical field of the invention,
Without departing from the inventive concept of the premise, it can also make some replacements or modification to the embodiment that these have been described,
And these are substituted or variant should all be considered as belonging to protection scope of the present invention.