CN107191289A - Pure oxygen oxygen-enriched combusting mover device and the vehicles and system using the device - Google Patents
Pure oxygen oxygen-enriched combusting mover device and the vehicles and system using the device Download PDFInfo
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- CN107191289A CN107191289A CN201610910900.9A CN201610910900A CN107191289A CN 107191289 A CN107191289 A CN 107191289A CN 201610910900 A CN201610910900 A CN 201610910900A CN 107191289 A CN107191289 A CN 107191289A
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
- F02G1/00—Hot gas positive-displacement engine plants
- F02G1/04—Hot gas positive-displacement engine plants of closed-cycle type
- F02G1/043—Hot gas positive-displacement engine plants of closed-cycle type the engine being operated by expansion and contraction of a mass of working gas which is heated and cooled in one of a plurality of constantly communicating expansible chambers, e.g. Stirling cycle type engines
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
- B01D53/04—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography with stationary adsorbents
- B01D53/0462—Temperature swing adsorption
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B13/00—Oxygen; Ozone; Oxides or hydroxides in general
- C01B13/02—Preparation of oxygen
- C01B13/0229—Purification or separation processes
- C01B13/0248—Physical processing only
- C01B13/0259—Physical processing only by adsorption on solids
- C01B13/0277—Temperature swing adsorption
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
- C25B1/00—Electrolytic production of inorganic compounds or non-metals
- C25B1/01—Products
- C25B1/02—Hydrogen or oxygen
- C25B1/04—Hydrogen or oxygen by electrolysis of water
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F01—MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
- F01K—STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES
- F01K11/00—Plants characterised by the engines being structurally combined with boilers or condensers
- F01K11/02—Plants characterised by the engines being structurally combined with boilers or condensers the engines being turbines
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
- F02G5/00—Profiting from waste heat of combustion engines, not otherwise provided for
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
- F02G5/00—Profiting from waste heat of combustion engines, not otherwise provided for
- F02G5/02—Profiting from waste heat of exhaust gases
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0913—Carbonaceous raw material
- C10J2300/0916—Biomass
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
- C10J2300/00—Details of gasification processes
- C10J2300/09—Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
- C10J2300/0953—Gasifying agents
- C10J2300/0959—Oxygen
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- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02G—HOT GAS OR COMBUSTION-PRODUCT POSITIVE-DISPLACEMENT ENGINE PLANTS; USE OF WASTE HEAT OF COMBUSTION ENGINES; NOT OTHERWISE PROVIDED FOR
- F02G2254/00—Heat inputs
- F02G2254/10—Heat inputs by burners
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E20/00—Combustion technologies with mitigation potential
- Y02E20/14—Combined heat and power generation [CHP]
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/129—Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
- Y02T10/00—Road transport of goods or passengers
- Y02T10/10—Internal combustion engine [ICE] based vehicles
- Y02T10/12—Improving ICE efficiencies
Abstract
The present invention provide a kind of use pure oxygen, oxygen-enriched combusting, gasification technology directly using the various wide material sources such as biomass energy, the solid energy material and be converted into the primemover system device of the electricity that can directly utilize, hydrogen or other motive power that can directly utilize, especially lighting, miniaturization can be used for the power source system of the vehicles such as new-energy automobile, novel high speed dirigible.
Description
Technical field
The present invention relates to directly utilize the various sources such as biomass energy, the solid energy using pure oxygen, oxygen-enriched combustion technology
Extensive material and the primemover system device for being translated into the electricity that can directly utilize, hydrogen energy source or motive power, particularly for
The power source system of the traffic system instruments such as new-energy automobile, high speed dirigible.
Background technology
Low-carbon technology, regenerative resource, Biomass Energy Utilization, hydrogen energy source development are all current hot research technologies,
The conversion that biomass energy trans-utilization technology is broadly divided into biomass can be divided into physical method, and thermochemical study method is biological
Method for transformation；Physical method is shape, the consistency for changing biomass, in order to apply and store；Thermochemical study method is
Biomass conversion is prepared by the materials such as carbon monoxide, hydrogen, small molecule hydrocarbon or bio-oil by heat chemistry；And biological turn
Change is the process for biomass being carried out by microorganism or enzyme biochemical reaction, advantage and disadvantage, the technology development bottleneck of these technologies etc.
There are a large amount of descriptions in all kinds of treatises.
The noticeable several background technologies for having certain correlation with the present invention have：
First, Stirling engine.External-combustion engine is a kind of closed cycle reciprocating-piston Thermal Motor of external combustion, new outer
Combustion engine uses hydrogen as working medium (media material of transmission energy is working medium), filled with a constant volume in the cylinder of four closings
Working medium.Cylinder one end is hot chamber, and the other end is cold chamber.Working medium is compressed in low temperature cold chamber, then flows to fast in high warm chamber
Speed heating, expansion work.Fuel continuous burning in the combustion chamber outside cylinder, is transmitted to working medium, working medium is not direct by heater
Burning is participated in, is also changed without.Due to the quick-fried acting problem of shake that external-combustion engine avoids traditional combustion engine, it is achieved thereby that low noise,
Low stain and low operating cost.External-combustion engine can burn various fuel gas, such as：Natural gas, biogas, oil gas, hydrogen, coal gas
Deng the also liquid fuel such as incendivity diesel oil, liquefied petroleum gas can be with burn wood, and utilizes solar energy etc..As long as hot chamber
Reach 700 DEG C, equipment can do work operation, environment temperature is lower, and generating efficiency is higher.Compare typically U.S. STM companies
25kW grades of units of STM4-120 types of offer, its generating efficiency is 29.6%, and cogeneration of heat and power gross efficiency reaches more than 80%；But
It is that Stirling engine also has many problems to solve, the moment of torsion that for example then seems for automobile engine is small, power output is smaller
Deng the substance combustion condition such as timber is also easy to produce pollution when bad, still have many burning conditions to be restricted and be especially difficult in atmosphere
The biological material of burning can not do fuel and use, and section components processed complex, expensive, therefore can not still answer on a large scale
With.And Submarine AIP technology then mainly carries oxygen by submarine and engine combustion is eliminated the reliance on air, it is also possible to there is pure oxygen
The Stirling engine technology of burning, but that is in the case of be with air exclusion.Have grinding for Stirling-electric hybrid hybrid vehicle
Study carefully, for example nineteen sixty-eight AM General automobile was once released Stirling-electric hybrid hybrid vehicle and sold, and was generated electricity with Stirling-electric hybrid, institute
Electric power access motor is obtained as the power of start.
2nd, portable steam engine (locomobile)：The power machine that boiler and steam engine connect together, what is had is filled with wheel, can
With movement.Portable steam engine can drive waterwheel, generator or other various machineries, do fuel with coal, firewood, heavy oil etc., be suitable to
Rural area is used.Portable steam engine can carry out irrigation and drainage with water pump, waterwheel matching；Can being generated electricity with generator matching, there is provided electric power；And can
Directly drive the various work mechanisms in threshing, husk rice, oil expression, sawmilling, food processing and machine-building.Steam engine is placed in
Above boiler or side, and with a compact integral power unit of the subsidiary engine such as water pump, valve composition.The steam come from boiler
Into steam engine, expansion working, makes main axis and exports mechanical work in the cylinder.Portable steam engine is mainly used in the rural area without electricity.
It can carry out irrigation and drainage with water pump, waterwheel matching；Can being generated electricity with generator matching, there is provided electric power；And can directly drive threshing,
Various work mechanisms in husk rice, oil expression, sawmilling, food processing and machine-building.In addition, the exhaust steam of large-scale portable steam engine can also be made
For thermal source, it is used for heating, evaporation, dry and heating etc..The power of portable steam engine is generally 10~20 horsepowers (1 horsepower=735.5
Watt), rarely exceed 100 horsepowers.Its type is more, but basic pattern is nothing more than vertical and horizontal, fixed and movable type.Pot
The advantage of hunchbacked machine is：Burning various endemic inferior fuels and combustible waste, operation, installation and maintenance are easy, and work can
Lean on, be simple to manufacture, cost is relatively low.Have the disadvantage：It is longer to fire the preparation time, and boiler must be kept in heat in temporary transient parking
Stand-by state, the thermal efficiency is relatively low, and device is heavier.With a large amount of appearance, the popularization of power network and various energy of small diesel engine
The comprehensive utilization in source, has substantially been eliminated as the portable steam engine of isolated power source.In the case where oil supply is nervous, burning
The portable steam engine of various miscellaneous material passes through technological transformation, it is possible to be applied in subrange.
3rd, burn timber engine technology, occurred during the Second World War it is substantial amounts of using firewood, coal, charcoal as fuel
The biological materials such as timber, are mainly pyrolyzed, are cracked, being gasified by automobile, motorcycle, tank engine, generate wood gas
Etc gas, then cool down, purify, compress after send into special engine combustion, this technology is because power output is unstable, tail gas pollution
Greatly, the startup time is long, is phased out after development of oil industry gets up, and as rise of the oil price and petroleum resources are exhausted, now
There is part inventor again in this technology of Improvement.There is oxygen-rich gasification skill notably as biomass gasification technology
Art, the pure oxygen of optimal use about 90%, the calorific value of material gas produced by can making bring up to calorific value level in town gas identical,
But need to add the oxygen generating plant of costliness, usually omnibus control system, high energy consumption, equipment weight, it is difficult to bring up to car, that is, minimize
Until vehicle-mounted.Also there is the oxygen-enriched continuous gasification technology of coal, product is semiwater gas, it also requires adding expensive, high energy
The oxygen generating plant of consumption, now to use THE PRESSURE SWING ADSORPTION OXYGEN GENERATING DEVICE to be many, also uses Deep Cooling Method making oxygen by air separation and with hyperbaric oxygen
Gas cylinder, Dewar bottle store the technology of oxygen supply.
4th, vehicle-mounted hydrogen and oxygen generator technology, it is combustion-supporting using vehicle power electrolysis water oxygen producing, but be mainly used in solution
Combustion engine fuel combustion is insufficient and the problems such as more tail gas pollution, such as automobile engine carbon remover；Also similar is all kinds of
Vehicular oxygen-making machine technology, such as low discharge oxygen generator of membrane separation, pressure swing adsorption oxygen, but it is mainly used in occupant's oxygen uptake；
All kinds of monographs have more description.
5th, current new-energy automobile research is more, mainly there is three technology paths：One is the pure of electrokinetic cell plus charging pile
Electric vehicle engineering, but electrokinetic cell is expensive, weight is big, dangerous, and the charging interval is long, and course continuation mileage is short, and charging pile is built
Rhetoric question topic is complicated；Two be hydrogen energy source automobile, wherein most strikingly fuel cell car technology, including efficient high temperature
Electrolytic cell；But what current all Hydrogen Energy source technologies were directed to hydrogen multiple links such as produces, converts, storing, transporting, hydrogenation stations
All there is many technical bottlenecks in the links such as construction；Three be biomass substitute fuel automobile, but conversion of biomass material ring
Section is more, and yield is few, and presence and grain ration land conflict problem, and uneconomical, some wood-based composites, diesel oil are even more expensive than gasoline；It is all kinds of
All there are many problems in Technology Ways, the preferable solution of neither one, development and popularization are very limited.
The content of the invention
Can be with pure oxygen burning or oxygen-enriched combusting, pure oxygen oxygen-rich gasification technology combination hydrogen-oxygen the purpose of the present invention is to propose to one kind
The technology change burning such as generator utilizes condition, so as to utilize firewood, stalk, vegetable and animals oils and different kind organism material or coal
Charcoal, heavy oil etc. are apparently difficult to directly utilize at present including some and extremely extensive fuel of originating is direct by pure oxygen oxygen-enriched combusting
Be converted into electric power, hydrogen energy source or be further converted to it is other can directly utilize the energy prime mover (engine) system, especially
Miniaturization, lighting so as to vehicle-mounted, the airborne biomass fermentation motivation that is used in vehicles such as automobile, steamer, dirigibles or
Dynamical system, makes biomass energy turn into primary energy and be no longer pass through multiple transformation.
To reach above-mentioned purpose, the present invention is main using such technical scheme：Topmost corrective measure is to pass through
Light oxygen supply is installed additional in engine system (with external-combustion engines such as Stirling engines than more typical) after selection and improvement to fill
Put, so as to use pure oxygen oxygen-enriched combustion technology；For example using stirling generator, thermal generator direct combustion power generation, with gained
Driven by power electric automobile.Or installing hydrogen-oxygen generating device, electrolysis water hydrogen making and pure oxygen additional, gained pure oxygen access combustion chamber is helped
Combustion, (pure oxygen not enough then sets supplemental oxygen system, oxygen needed for supplement)；Gained hydrogen then separately accesses fuel cell with air
Generate electricity or other hydrogen provide power using equipment, so move in circles, equivalent to the primary energy such as timber material endlessly
It is converted into the energy that can directly utilize；Engine system first choice Stirling engine is that external-combustion engine is improved, certainly
Be not limited to Stirling-electric hybrid, for example steam engine (steam turbine), thermal generator (piece), pressure electricity-generating material gji so it is some in
Combustion engine, can convert heat energy into electric energy, each advantageous under respective applicable elements after improvement.
The system and device of the present application is according to use occasion difference respectively by defeated including fuel Pretreater apparatus, fuel
Send device, pure oxygen (oxygen-enriched) combustion system, engine system, generator system, cooling system, exhaust pipe, vent gas treatment
System, output cable, oxyhydrogen generator system (including the SOEC high-temperature electrolysis pond of foresight technology), oxygen generation system, oxygen
Delivery pipe, hydrogen delivery tube, hydrogen utilization equipment (hydrogen fuel cell, hydrogen engine, hydrogen gas combustor etc.), gasification furnace, steam
The equipment such as generation steam generator system, steam conveying pipe, turbine generating system, combustion of hydrogen room, air inlet duct, superheater exist
Interior system in combination is formed.
The operation principle or workflow of the present application system are anticipated as shown in Figure 3, selection fuel cell car
Vehicle-mounted Stirling engine (generating) system is explained, using other engine system technologies can also this analogize.
As schematically shown in Figure 1, fuel first passes around fuel Pretreater apparatus 1 and handled, mainly shredded, be bonded into be easy to combustion
The shape of burning, incorporation portion of reagent just mix quick lime or limewash for example with desulphurizer technology and remove denitrification
Urea, moisture it is more add preheating and drying program, waste heat from tail gas can be used in heat source gas；This technique can also be in advance special
Door factory completes, if the putrefactive biological material of timber etc first passes through limewash, urea liquid immersion not only profit in advance
Preserved in anti-corrosion, also eliminate the sulfide in tail gas beneficial to desulphurizer, and it is previously extruded, supplied with finished product；Fuel is passed through
Cross after fuel Pretreater apparatus 1 and the pure oxygen burning room and pure oxygen of pure oxygen (oxygen-enriched) combustion system 3 are sent into by fuel delivery means 2
Or the mixed combining combustion of sufficient oxygen, generation hyperpyrexia, and combustion chamber and the heater (also referred to as hot chamber) 5 of Stirling engine system 4
It is connected, driving Stirling engine operation, and generated electricity with dynamotor 7, electric energy is sent out through the access hydrogen-oxygen of output cable 11
Raw device system 12, makes its electrolysis water produce hydrogen and pure oxygen, and hydrogen passes through hydrogen after the hydrogen/oxygen separator separation in system
Delivery pipe 14 separately accesses hydrogen utilization equipment 15 (hydrogen fuel cell, hydrogen engine, hydrogen gas combustor etc.)；Gained pure oxygen then leads to
The combustion chamber for crossing the access pure oxygen burning system of pure oxygen delivery pipe 13 is combustion-supporting, forms circulation；Because generating efficiency can not possibly reach
100%, often only 30% or so, also imply that oxyhydrogen generator at most only provide needed for oxygen 30%, remaining will
Supplemented by supplemental oxygen system；Waste gas, the ashes of pure oxygen burning room generation then pass through exhaust pipe 9 and send into vent gas treatment system
System 10, the calcium sulfite or calcium sulfate generated originally to prevent the high temperature produced during pure oxygen burning from making decomposes generation sulphur oxidation again
Thing, in exhaust treatment system control exhaust temperature below calcium sulfite and calcium sulfate decomposition temperature, more than synthesis temperature simultaneously
Try one's best and mix with ashes, so as to remove sulfur dioxide or sulfur trioxide, and further take other tail gas desulfuration technologies and purification
Technology, while can also carry out the design such as waste heat from tail gas utilization, dedusting, ash collecting or even packing, these are same as the prior art；
In addition the cooler 6 (cold chamber) of Stirling engine is connected with cooling system 8, can be air cooling or water circulation
Cooling, so that hot-water supply, that is, realize cogeneration of heat and power, improves efficiency of energy utilization.
The desirable part of gained hydrogen is by after purification, the Stirling entered by reserving high-pressure pump using hydrogen as working medium is sent out
In motivation, the working medium of supplement institute seepage；Then nitrogen is supplemented Stirling-electric hybrid using nitrogen as working medium as obtained by temp.-changing adsorption oxygen.
To adapt to the popularity and diversity of fuel source, fuel delivery means make corresponding adaptability design, it is existing can
The design of gasoline feed, diesel oil, also there is conveying palm oil, soya-bean oil, the design of vegetable and animals oils, can also convey sucrose for fuel,
There are conveying coal, the device of biological particles, and the processing unit design structure that should mutually have the ashes such as plant ash, flyash is repaiied
Change；Many conveying facilities for adapting to various fuel can exist simultaneously, can also do skid-mounted type, menu mode combination.
The supplemental oxygen system described above for needing to add when oxygen is inadequate, if directly installing oxygenerator additional from oxygen,
Existing oxygenerator power consumption is big, bulky, weight is big, it is impossible to directly utilize；Oxygen system can be extracted empty with air-extractor
The anoxic gas to supplement of gas；Also high-pressure oxygen cylinder, liquid oxygen Dewar bottle can be installed additional to provide oxygen；Membrane separation technique can also be used
Air is changed into oxygen rich gas to supplement, because membrane separation technique less energy consumption, cheap, lightweight, small volume, gained oxygen
Though concentration is relatively low (30%~50%), if fuel is to be sufficient for by preferred machine-shaping needed for oxygen-enriched combusting,
These are all that prior art is i.e. achievable by simply designing, and here is omitted.
The application then especially advocates that combining waste heat from tail gas, cooler waste heat and temp.-changing adsorption Technology design system constitutes to carry
For high-concentration oxygen, though temp.-changing adsorption oxygen is more rare, its research and development technology progress is also faster, such as Chinese patent
The method that CN201110021156.4 discloses a kind of oxygen nitrogen combined separation of temp.-changing adsorption, except common gas is compressed again
Being reached by pretreatment system except deoiling, after the solid impurity such as dust allows to enter the known technologies such as piece-rate system after requirement, uses
The pressure-variable adsorption of carbon molecular sieve (CMS) based on dynamics separating mechanism continuously can extract nitrogen from air, disclose oxygen suction
Attached dose be a kind of modified RE X-type zeolite, the adsorption of oxygen below≤100 DEG C, and >=300 DEG C discharge oxygen；And adsorbent
For perovskite ceramic oxides mixture, start adsorption of oxygen more than 300~600 DEG C, and start more than 400~600 DEG C
Discharge oxygen；The technology is thermal source using engine exhaust heat, and air is cooling gas, and interaction is heated and cooled down adsorbent and combines
Pressure swing adsorption is so as to obtain more than 90% pure oxygen；Actually there are many similar techniques；In view of on-board engine system
70% energy is distributed in tail gas in vain in waste heat form, therefore the application surrounds tail gas, the cooler heat of Stirling-electric hybrid
As thermal source, according to different temperatures selected adsorbent, oxygen, nitrogen temp.-changing adsorption flow scheme design are carried out respectively, and use electronics
Cooling piece, thermo-electric generation sheet etc. accelerate ramp rates and recycle portion of energy：
Raw air dries through air pretreatment system, except deoiling, the solid impurity such as dust reaches and enters after allowing requirement
Air chamber；Each air chamber arrives multiple adsorption chambers equipped with sorbing material combining structure equipped with one, and fluid switch valve and
Heating, cooling system pipeline；Heating system thermal source is motor exhaust and cooler, and cooling system is typically cooled down by air, (
It is not excluded for other types of cooling)；Sorbing material arranges around with the heat exchanging fin (fin) that pipeline is connected is heated or cooled,
The material that heat exchanging fin is easy to heat conduction by scale copper, flake aluminum etc. is made, beneficial to rapid heat absorption, cooling, sorbing material combination knot
Structure 32 is as schematically shown in Figure 4；The air chamber valve plate 30 for having activity between air chamber 29 and adsorption chamber 31 is separated, the other end of adsorption chamber
There is adsorption chamber valve plate 33 to be opened/closed；Workflow is about adsorption chamber valve plate 33 when air chamber valve plate 30 is opened and closed, air
It is stirred and is fully contacted with adsorbent, while heating system or cooling system valve are opened, a certain component is preferentially adsorbed；Up to
Air chamber valve plate 30 is closed after to saturation, while adsorption chamber valve plate 33 is opened, corresponding heating system or cooling system are also begun to
Work, and sorbing material combining structure removing residual components are purged, downstream is entered back into, it is general to set because thermal source is larger
A large amount of adsorption chambers, and multiple adsorption chambers then adsorb (desorption) to accelerate oxygen speed processed successively simultaneously by thermal desorption (absorption),
Certain pressure initiation alternating temperature pressure-variable adsorption can be increased and further speed up oxygen speed processed；So move in circles, continually convey
High-concentration oxygen.
Due to sorbing material, often specific heat capacity is larger, and ramp rates are slower, therefore except heat exchanging fin uses transcalent material
Material makes, including heating pipe, cooling pipe are made using for example thin copper of transcalent material, thin aluminum, and can added outside pipeline
The fin for accelerating rate of heat exchange further expands radiating heat-conducting area；Simultaneously electricity is accordingly covered in pipeline, fin surface
Sub- cooling piece, thermo-electric generation sheet, preferably have both refrigeration, generate electricity dual-purpose；Electric current is passed to when needing cooling operations, makes temperature
It is rapid to decline；And then it is changed into thermo-electric generation sheet function in cooling process, utilize its thermo-electric generation between cooling air-flow, gained
Electric current can be filled with battery, and heating (cooling) pipeline that directly can be made by wire or metal is connected to another part and freezed
Generating piece at be used as power supply；Structure does corresponding function adjustment, example between thermo-electric generation sheet, cooling piece and heating, cooling pipe
Such as design the switch of various circuits when thermo-electric generation sheet switches with electronic refrigerating sheet function, disconnect.
Equally, cooler one end of Stirling-electric hybrid can also make similar structures design, to accelerate cooling velocity, while recoverer
Divide electric energy.
Can also be done when the sustainers such as Stirling-electric hybrid do not work corresponding operating by these spread all over cooling tube, heating tube, this
The electronic refrigerating sheet of special woods machine colling end etc., thermo-electric generation sheet are converted to using thermo-electric generation state and undertake generating function.
Also membrane separating, omnibus control system, or multiple technologies combination can be according to circumstances used, these are according to prior art
Easily design, is repeated no more again.Also there is the new approaches i.e. compression energy of pressure-variable adsorption to be difficult to reclaim, air energy engine can be combined
Technology, and using tail gas, coolant heat energization generating recovery section energy, so as to big using pressure swing adsorption low energy consumption
Flow oxygen supply.
Constituted as engine using other primemover systems such as steam engine, the class of steam turbine technology one, then such as Fig. 2 institutes
Signal, the pure oxygen burning that fuel is sent into steam generating pot furnace system 16 after fuel Pretreater apparatus 1 by conveying device 2
System 17 mixes combining combustion with pure oxygen or sufficient oxygen, produces steam and is sent into through the heating of superheater 23 by steam conveying pipe 18
Turbine generating system 19 generates electricity, and produces electric power through the part of handling cable 11 output access electrical appliance 22；Another part electric energy is then
Accessing oxyhydrogen generator 12 is used for electrolysis water, and the oxygen that oxyhydrogen generator 12 is produced accesses pure oxygen burning by oxygen conveying pipe 13
Room 17, forms circulation, and oxygen insufficient section is supplemented by supplemental oxygen system 24；Gained hydrogen is then separately accessed in steam generator system 16
Combustion of hydrogen room 20, and the air mixed combustion introduced through air inlet duct 21, heating steam generating pot furnace system 16 constitutes
Complete process cycles, it is similar to steam engine, turbine generating system technology if the scheme of cogeneration of heat and power is carried out；Hydrogen now
Process equipment of the hydrogen by combustion of hydrogen room Jing Guo combustion heating steam generation boiler is referred to using equipment；Pure oxygen herein
Combustion system 17 includes tail gas ash treatment device.Remaining species engine can also this analogize.
Due to use occasion difference, equipment combination and work relationship are otherwise varied, and what is had even can reduce hydrogen-oxygen
The capacity of generating means or even cancel oxyhydrogen generator, with this link of hydrogen storage equipment, and direct combustion power generation：
In pure electric automobile Curve guide impeller, combination, the work relationship of workflow and component devices are：Pure oxygen is rich
Power supplement battery electric quantity, motor exhaust and cooler waste heat of oxygen combustion system combustion heat supplying, Stirling engine supplies alternating temperature
Adsorption system produces high-concentration oxygen supplemental oxygen deficiency, and remaining is basically identical with existing electric vehicle structure, make use of existing
The advantages of electric vehicle engineering efficiency is high, motor explosive force is strong, so as to form the new electronic vapour by the energy of biological material
Car, but be no longer pass through hydrogen and circulate this link.
The automobile of biomass fuel is and for example designed using biomass gasification technology, improves ancient by timber, coal in other words
Charcoal, which gasifies, does the technology of engine fuel, biomass fuel (or coal etc) feeding gasification furnace, due to using pure oxygen or highly concentrated
Degree is oxygen gasified, and gasification furnace volume weight is greatly reduced；Control oxygen concentration is so as to obtain optimal aerogenesis effect, biological material
Pure oxygen gasification generates calorific value, and compared with originally high biogas, and in supplemental oxygen system, the thermal source of temp.-changing adsorption oxygenerator is just
It is the high-temperature biomass gas come out from gasification furnace, gas is sent into specially designed biogas through supercooling, purification, compression and started
Machine, and oxygenized air combustion supporting raising power output is supplied, remaining is substantially similar with existing gas-fueled vehicles structure, so as to improve the back of the body
The automotive engineering of old burning charcoal in scape technology, overcomes that its power output is unstable, vaporization time is difficult to control to, tail gas pollution
The weakness, the gas combustion automobile as new cleaning fuel such as serious.There is no oxyhydrogen generator equipment, use in this workflow
Hydrogen storage equipment and generating equipment, it is to avoid energy multiple transformation.And this structure is particularly suitable for use in, a kind of newest high speed dirigible is set
Meter.
It using Pure Oxygen Combustion Technology ensure that burning bar relative to the portable steam engine in background technology for the application and its device
Part, makes fuel source more extensive, and machine is light, and more efficient；It improves Stirling engine system, makes it can be with
Burn some air-breathings when the relatively low and unavailable fuel of temperature, make fuel source more extensively so as to purposes it is wider；Phase
For other Hydrogen Energy source technologies, coal, timber or other biological material are directly converted into hydrogen and are used again by it, and no longer
Certain his all too many levels are needed, especially system realizes lighting, it is loaded onto the vehicles such as automobile, steamer, dirigible, again
Burning condition is ensure that, makes utilizable biological material more extensive, is that regenerative resource is progressively subtracted with wood, coal multifuel combustion
Few oil coal consumption or even the thoroughly fossil energy such as substitution oil are provided may；Relative to the electronic vapour such as fuel cell car
Car, it thoroughly solves the technical bottlenecks such as source, storage, the transport of hydrogen, also no longer needs hydrogenation stations, gas station construction；For
Continuation of the journey is solved the problems, such as pure electric automobile or hybrid electric vehicle, it is no longer necessary to the construction of charging pile etc, be not required to for a long time
Charging, it also avoid hydrogen and uses the safety problem of storage and the safety problem of electrokinetic cell；For wood gas automobile gram
Take that power output is unstable, tail gas pollution is big, the low defect of fuel gases calorific value；It is used as the independent cold alliance machine of low power thermoelectric
Group, pure oxygen combustion-supporting makes fuel range of choice significantly expand, even the branch just cut down, fresh weeds can also make fuel, with the sun
It can generate electricity, the combination of wind energy electrolysis water obtains more pure oxygens, hydrogen, so as to utilize the regenerative resource that fully belongs to of abundance
Agricultural product replaces fossil fuel, meet remote districts, distributed energy with can demand, at this stage also can direct burning coal
Part substitution oil.And the present invention is simple structure, cheap, system peace convenience in major applications occasion, beneficial to work
Industryization is promoted, and is had in each new energy field and is widely applied very much prospect.
Brief description of the drawings
Fig. 1 is the application system and device composition schematic diagram using stirling generator technology；
Fig. 2 is the application system and device composition schematic diagram using steam turbine power generation technology；
Fig. 3 is system principle and workflow relation schematic diagram；
Fig. 4 is sorbing material combining structure schematic diagram；
Fig. 5 is adsorption chamber and air chamber structure composition schematic diagram；
In accompanying drawing：1st, fuel Pretreater apparatus；2nd, fuel delivery means；3rd, pure oxygen (oxygen-enriched) combustion system；4th, Stirling
Engine system；5th, the heater (hot chamber) of Stirling engine system；6th, the cooler (cold chamber) of Stirling engine system；
7th, the dc generator of Stirling engine system；8th, cooling system；9th, exhaust pipe；10th, exhaust treatment system；11st, it is defeated
Go out cable；12nd, oxyhydrogen generator system；13rd, oxygen conveying pipe；14th, hydrogen delivery tube；15th, hydrogen utilization equipment (hydrogen fuel electricity
Pond, hydrogen engine, hydrogen gas combustor etc.)；16th, steam generating pot furnace system；17th, the pure oxygen burning in steam generating pot furnace system
System；18th, steam conveying pipe；19th, turbine generating system；20th, combustion of hydrogen room；21st, air inlet duct；22nd, electrical appliance；
23rd, superheater；24th, supplemental oxygen system；25th, sorbing material；26th, heat radiating fin structure；27th, heating system pipeline；28th, cooling system
Road under the overall leadership；29th, air chamber；30th, air chamber valve plate；31st, adsorption chamber；32nd, sorbing material combining structure；33rd, adsorption chamber valve plate；
In conjunction with drawings and examples, the invention will be further described：
Embodiment
Embodiment 1
So that tesla MOLDE S are reequiped as an example, cancellation 85KWH high capacity cells are changed to the storage compared with low capacity 10KWH
Electricity consumption when battery adjusts power output and ensures engine warm-up, climbing, acceleration etc., the Stirling hair for the 25KW or so that changes the outfit
Electric system weighs about 300 kilograms, and about 100,000 yuans of cost, about 400 liters of volume installs oxygen-enriched membrane oxygen-producing machine additional and provides 30% concentration
Oxygen, supply per hour 60 cubes weigh about two, 30 kilograms, about 40 liters of volume, cost replaces about more than 10,000 yuan
About 200,000 yuans of great-capacity power battery, weigh 600 kilograms, 500 liters of volume, remaining equipment is constant, under kerb weight
300 kilograms of costs of drop decline tens thousand of yuans, and full car length slightly increases, and performance, parameter constant are even more excellent.Fuel is
Gasoline, diesel oil can be used, it is more mixed as fuel-saving type than the advantage of internal combustion engine drive systems efficiency high more than 20% using power drive system
Close power vehicle, it is possible to use industrial palm oil, industrial soya-bean oil, cheap, also no ashes need place as vapour, diesel oil
Reason；But gas station needs to add the oil supply business such as industrial palm oil.
Embodiment 2
Certain remote forest zone supply of electric power is difficult, but the biological material such as forest enriches, therefore uses system illustrated in Figure 2 to fill
Put, trees are higher due to just cutting down moisture content, are nonflammable in atmosphere；The materials such as branch send into fuel Pretreater apparatus
Crush, drying is blown using tail gas, and the quantitative pulverized limestone of penetrating, urea are well mixed, and steam generating pot is sent into through conveying device
Pure oxygen burning room in stove, combustion heating steam generation boiler in pure oxygen, for the benefit of instantaneously producing steam, boiler is divided into multiple
Small boiler simultaneously adds fin；Steam in boiler accesses the miniature steam turbine that generated output is 10 to 20 kilowatts by heat pipes heat
Machine generating set is generated electricity, and electric energy directly output in part is used, access big flow oxyhydrogen generator after separately having part electric energy rectified,
Pure oxygen access pure oxygen burning room auxiliary combustion is produced, oxygen insufficient section produces oxygen by a membrane separating oxygenerator oxygen supply
Concentration is 30%；Fire the combustion of hydrogen room that hydrogen produced by oxyhydrogen generator separately accesses steam generating pot furnace system with air
Burn, formation process circulation；It is as good as the part hot water supply in boiler with prior art, while ammonia working medium cooling；From
And thermoelectric cold cogeneration is formed, heat energy efficiency is not less than 80%.The coal by fine purifiation can be mixed if fuel combustion conditions are still not enough
Powder multifuel combustion improves calorific value, or uses coal oxygen-enriched mixed combustion technology.
Embodiment 3
By taking the repacking of BYD F1 classes electric automobile as an example, 1.4 tons of prototype car kerb weight, 100 kilometers, hundred kilometers of speed per hour
Power consumption 10 to 12 per hour is spent；Install 300 kilograms of stirling generator after transformation additional, 270 kilograms of high-pressure oxygen cylinder 4 bottle is (public containing 32
About 24 cubes of oxygen of jin), or 300 kilograms of Dewar bottle (contain 200 kilograms of liquid oxygen), kerb weight increases to 2.3 tons, hundred kilometers of power consumptions by
10~12 degree increase to 17~22 degree, are generated electricity per hour 25 degree with 25KW engines and are enough to supplement.Stirling-electric hybrid (U.S. STM4-
120 types) cost increases by 100,000 yuan.Generated electricity per hour 25 degree with 25 kilowatts of Stirling engines and consume 15 kilograms of firewoods, hyperbaric oxygen
8 kilograms of gas (about six cubes of bottle of unification) is calculated, hundred kilometers of twenties yuan of expenses；Load 150 kilograms of timber, Dewar bottle liquid oxygen just
10 hours thousands of kilometers of stroke can be run, gas station is changed to firewood, oxygen addition station and Plant ash fertilizer collection transfer station can.
Above equipment has matured product on the market, simple assembling transformation, technically reliable；But need to separately it be set in gas station
Oxygen supply equipment.
Embodiment 4
By taking BYD F1 class electric automobile Curve guide impellers as an example, 1.4 tons of prototype car kerb weight, 100 kilometers of speed per hour, hundred
The kilometer degree of power consumption 10 to 12 per hour；Install 25 kilowatts of 400 kilograms of Stirling engines, 25 KW generator 200 after improvement additional public
Jin, increased 15 cubes of alternating temperature swing adsorption oxygen generating systems estimate about 200 kilograms, and kerb weight increases to 2.2 tons, hundred kilometers of power consumptions
15~22 degree are increased to by 10~12 degree, is generated electricity per hour 25 degree with 25KW engines and is enough to supplement.The increase of Stirling-electric hybrid cost
100000 yuan.Generated electricity per hour 25 degree with 25 kilowatts of Stirling engines and consume 10 kilograms of calculating of firewoods, hundred kilometers of more than ten yuan of expenses；
10 hours thousands of kilometers of stroke can be run by loading 150 kilograms of timber, and gas station is changed to firewood addition station and Plant ash fertilizer is received
Collecting transfer station can.
Stirling generator about increases by 100,000 yuan, about 50,000 yuan of oxygen generation system, the RMB of total cost increase about 150,000.Can be certainly
Row oxygen supply, generator system can charge a battery and (retain about 10~20kwh capacity, be full of within one hour) during parking, also
Family expenses, the emergent or stand-by generator of station-service, and hot, electric, cold alliance can be used as.
Embodiment 5
(high efficiency fluid drag reduction technology and high speed airship technology are shown in Chinese patent to certain solar high-speed dirigible
ZL200610106732.4), long 400 meters, high 8 meters, wide 40 meters, 20 tons of load-carrying arranges solar power generation using huge surface area
Plate, electrolysis water produces hydrogen and pure oxygen, and hydrogen enters safety anti-explosive hydrogen capsule (air bag is another patented technology) and produces and float
Power, as fuel reserve；Biomass fuel, gained pure oxygen access gasification furnace, due to using pure oxygen gasification so gas are used simultaneously
Change furnace volume's weight to be greatly reduced, gasification rate is greatly improved；Biomass fuel sends into gasification furnace, uses high-purity oxygen gas
Change, control oxygen concentration is so as to obtain optimal aerogenesis effect, and gained biogas combustion value is controlled in more than 1200KJ；High-temperature gas
Into air bag (while also producing buoyancy aid), cooled down by air for cooling gas through heat exchanger, and filter, purify；Because of electricity
Solution produces pure oxygen not enough, and supplemental oxygen system uses temp.-changing adsorption oxygenerator, and temperature-variable heat source is exactly the height come out from gasification furnace
Warm biogas, and using the cold air in high-altitude as cooling gas, alternately heat, adsorbent cooled down, so as to provide high concentration oxygen
Gas；Biomass gas is sent into specially designed biogas engine combustion and done work through supercooling, purification, compression, drives dirigible
Power-equipment is run.So dirigible daytime is power using solar energy, and be power using biomass fuel in the evening, thoroughly breaking away from
Stone fuel.
Embodiment 6
The pure Electric Transit bus of BYD K9A types is reequiped, the 324KWH electrokinetic cells of 2500 kilograms of weight is removed, changes
100 kilowatts of stirling generator groups (weighing 1200 kilograms) are filled, 100 cubes of temp.-changing adsorption oxygenerators (weighing about 400 kilograms) is installed additional, makes
With about 70 kilograms per hour of biomass granule fuel, kerb weight declines about 500 kilograms, though the people of cost increase about 200,000
Coin, but course continuation mileage is unlimited, it is not necessary to charge for a long time.
Embodiment 7
Certain light tank car is adapted as electronic tank, using system illustrated in Figure 1,600 tank engines are removed,
4 U.S.'s production STM4-120 stirling generators of repacking, gross output is 100KW, its hot chamber is suitably modified, in order to pure
Oxygen burns and exclusion ashes and processing tail gas, and cold chamber uses air cooling system；Fuel be it is previously extruded and through limewash,
Urea immersion the biological particles material supplied in batch, on an hourly basis 30 kilograms of speed feed intake, generate electricity can access 50KWH store
Electricity consumption when battery adjusts power output and ensures engine warm-up, climbing, acceleration etc.；Supplemental oxygen is using herein described
Temp.-changing adsorption oxygen generating plant, and a large amount of overlay electronic cooling pieces, thermo-electric generation sheet accelerate oxygen speed processed and recovery section waste heat；
Jungle area operation fuel is available anywhere, and Stirling-electric hybrid can accomplish Jing Yin generating, traveling, hidden to close with the enemy.
Claims (10)
1. it is a kind of directly by the primemover system device that conversion of biomass material is primary energy, divided according to use occasion difference
Not by including fuel Pretreater apparatus, fuel delivery means, pure oxygen (oxygen-enriched) combustion system, engine system, generator system,
(including the SOEC of foresight technology is high for cooling system, exhaust pipe, exhaust treatment system, output cable, oxyhydrogen generator system
Including warm electrolytic cell), supplemental oxygen system, oxygen conveying pipe, hydrogen delivery tube, hydrogen utilization equipment (hydrogen fuel cell, hydrogen hair
Motivation, hydrogen gas combustor etc.), gasification furnace, steam generating pot furnace system, steam conveying pipe, turbine generating system, hydrogen combustion
System in combination including the equipment such as burning room, air inlet duct, superheater is formed.It is characterized in that：Fuel pre-processes dress by fuel
1 processing is put, shredded, be bonded into the shape being readily burned, incorporation portion of reagent such as quick lime or limewash and urea, in advance
If fuel preheating drying program, heat source gas is tail gas；Fuel delivery means 2 send into the pure oxygen of pure oxygen (oxygen-enriched) combustion system 3
Combustion chamber and pure oxygen or the mixed combining combustion of sufficient oxygen, generation hyperpyrexia, and combustion chamber and the heater of Stirling engine system 4
(also referred to as hot chamber) 5 is connected, driving Stirling engine operation, and is generated electricity with dynamotor 7, and electric energy is through output cable 11
Oxyhydrogen generator system 12 is accessed, its electrolysis water is produced hydrogen and pure oxygen, the hydrogen after the hydrogen/oxygen separator separation in system
Gas separately accesses hydrogen utilization equipment 15 (hydrogen fuel cell, hydrogen engine, hydrogen gas combustor etc.) by hydrogen delivery tube 14；Institute
Obtain combustion chamber of the pure oxygen then by the access pure oxygen burning system of pure oxygen delivery pipe 13 combustion-supporting, form circulation.
2. system and device according to claim 1, it is characterized in that：The cooler 6 (cold chamber) of the Stirling engine system
It is connected with cooling system 8, water circulation cooling hot-water supply realizes cogeneration of heat and power.
3. system and device according to claim 1, it is characterized in that：Workflow and the combination of component devices, work are closed
System is to be powered to supplement battery electric quantity, motor exhaust and cooling by pure oxygen oxygen-enriched combustion system combustion heat supplying, Stirling engine
Device waste heat produces high-concentration oxygen supplemental oxygen deficiency, remainder and existing electric vehicle structure group for temperature swing adsorption system
Close, so as to form the new electric automobile using biological material as the energy.
4. system and device according to claim 1, it is characterized in that：The fuel delivery means 2, many various fuel of adaptation
Conveying facility can exist simultaneously, can also do skid-mounted type, menu mode combination.
5. system and device according to claim 1, it is characterized in that：The Stirling engine system 4 can be sent out by hydrogen-oxygen
Nitrogen is by after purification, the work of institute's seepage being supplemented through reserving high-pressure pump obtained by raw the gained hydrogen of device system 12 or temp.-changing adsorption oxygen
Matter.
6. system and device according to claim 1, it is characterized in that：Fuel passes through conveying after fuel Pretreater apparatus 1
Pure oxygen burning system 17 in the feeding steam generating pot of device 2 furnace system 16 mixes combining combustion with pure oxygen or sufficient oxygen, produces
Steam is sent into turbine generating system 19 by steam conveying pipe 18 through the heating of superheater 23 and generated electricity, and produces electric power through conveying electricity
The part of cable 11 output access electrical appliance 22；Another part electric energy, which then accesses oxyhydrogen generator 12, is used for electrolysis water, oxyhydrogen generator
12 oxygen produced access pure oxygen burning room 17 by pure oxygen delivery pipe 13, and insufficient section is supplemented by supplemental oxygen system 24, from
And form circulation；The combustion of hydrogen room 20 that gained hydrogen is then separately accessed in steam generator system 16, with being introduced through air inlet duct 21
Air mixed combustion, heating steam generating pot furnace system 16 constitutes complete process cycles.
7. system and device according to claim 1, it is characterized in that：Exhaust temperature is controlled in exhaust treatment system in sulfurous acid
It is sufficiently mixed below calcium and calcium sulfate decomposition temperature, more than synthesis temperature and with ashes, and further takes tail gas desulfuration technology
And purification techniques, while carrying out the design such as waste heat from tail gas utilization, dedusting, ash collecting or even packing.
8. system and device according to claim 1, it is characterized in that：The supplemental oxygen system is the change using engine exhaust heat
Warm adsorption oxygen-preparation equipment, each air chamber arrives multiple adsorption chambers equipped with sorbing material combining structure equipped with one, and fluid is cut
Change valve and heating, cooling system pipeline；Heating system thermal source is motor exhaust and cooler, and cooling system is typically by air
Cooling；Sorbing material is arranged around the heat exchanging fin being connected with pipeline is heated or cooled, beneficial to rapid heat absorption, cooling；Air
The air chamber valve plate 30 for having activity between room 29 and adsorption chamber 31 is separated, and the other end of adsorption chamber has adsorption chamber valve plate to be opened/closed
33；Workflow is that adsorption chamber valve plate 33 is closed when air chamber valve plate 30 is opened, and air is stirred fully to be contacted with adsorbent, together
When heating system or cooling system valve open, a certain component is preferentially adsorbed；Air chamber valve plate 30 is closed after saturation is reached,
Adsorption chamber valve plate 33 is opened simultaneously, and corresponding heating system or cooling system also begin to work, and purge sorbing material combination knot
Structure removes residual components, enters back into downstream, so moves in circles, continually conveys high-concentration oxygen.
9. temp.-changing adsorption oxygen generating plant according to claim 8, it is characterized in that：Heat exchanging fin uses transcalent material system
Make, including heating pipe, cooling pipe are made using for example thin copper of transcalent material, thin aluminum, and quickening heat is added outside pipeline and is handed over
The fin of throw-over degree further expands radiating heat-conducting area；Simultaneously pipeline, the corresponding overlay electronic cooling piece of fin surface,
Thermo-electric generation sheet, or have both refrigeration, generate electricity dual-purpose；Electric current is passed to when needing cooling operations, makes rapid drop in temperature；And in drop
Warm process is then changed into thermo-electric generation sheet function, and using its thermo-electric generation between cooling air-flow, gained electric current can be filled with electric power storage
Pond, heating (cooling) pipeline that directly can be made by wire or metal, which is connected at the generating piece that another part is freezed, is used as
Power supply；Structure design arrangement thermo-electric generation sheet and electronic refrigerating sheet function between thermo-electric generation sheet, cooling piece and heating, cooling pipe
The switch of various circuits during switching, the function adjustment such as disconnect.Sustainer can do corresponding operating by these when not working
Spread all over the electronic refrigerating sheet of cooling tube, heating tube, Stirling-electric hybrid colling end etc., thermo-electric generation sheet to be converted to and utilize thermo-electric generation
State simultaneously undertakes generating function.
10. system and device according to claim 1, it is characterized in that：Workflow and the combination of component devices, work are closed
System is to send into gasification furnace by biomass fuel, is gasified using pure oxygen or high-concentration oxygen, and control oxygen concentration is optimal so as to obtain
Aerogenesis effect, biological material pure oxygen gasification generates calorific value compared with originally high biogas；Alternating temperature is inhaled in supplemental oxygen system
The thermal source of attached oxygenerator is the high-temperature biomass gas come out from gasification furnace, and gas is especially set through supercooling, purification, compression feeding
The biogas engine of meter, is combined with existing gas combustion automobile structure, so that the gas combustion automobile as new cleaning fuel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/CN2017/076670 WO2017157287A1 (en) | 2016-03-15 | 2017-03-14 | Oxygen generation system and electric car |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610149028 | 2016-03-15 | ||
| CN2016101490280 | 2016-03-15 |
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|---|---|---|---|
| CN201610254898.4A Pending CN107191288A (en) | 2016-03-15 | 2016-04-20 | Pure oxygen oxygen-enriched combusting primemover system device |
| CN201610910900.9A Pending CN107191289A (en) | 2016-03-15 | 2016-10-14 | Pure oxygen oxygen-enriched combusting mover device and the vehicles and system using the device |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107891759A (en) * | 2017-12-05 | 2018-04-10 | 吉林大学 | A kind of energy-autarchic mobile platform |
| CN110700961A (en) * | 2019-10-11 | 2020-01-17 | 上海齐耀动力技术有限公司 | Closed Stirling engine underwater power process and system based on aluminum powder combustion |
| CN110792479A (en) * | 2019-11-07 | 2020-02-14 | 安徽伯华氢能源科技有限公司 | Hydrogen power generation system |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108865276A (en) * | 2018-06-27 | 2018-11-23 | 华电电力科学研究院有限公司 | A kind of provide multiple forms of energy to complement each other comprehensive energy supplying system and the energy supply method of combination biomass economy |
| DE102019128882B3 (en) | 2019-10-25 | 2020-12-17 | Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. | Process for the process-integrated oxygen supply of a hydrogen cycle engine with circulation of a noble gas |
-
2016
- 2016-04-20 CN CN201610254898.4A patent/CN107191288A/en active Pending
- 2016-10-14 CN CN201610910900.9A patent/CN107191289A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107891759A (en) * | 2017-12-05 | 2018-04-10 | 吉林大学 | A kind of energy-autarchic mobile platform |
| CN110700961A (en) * | 2019-10-11 | 2020-01-17 | 上海齐耀动力技术有限公司 | Closed Stirling engine underwater power process and system based on aluminum powder combustion |
| CN110700961B (en) * | 2019-10-11 | 2023-08-29 | 上海齐耀动力技术有限公司 | Closed Stirling engine underwater power process and system based on aluminum powder combustion |
| CN110792479A (en) * | 2019-11-07 | 2020-02-14 | 安徽伯华氢能源科技有限公司 | Hydrogen power generation system |
| CN110792479B (en) * | 2019-11-07 | 2020-07-28 | 安徽伯华氢能源科技有限公司 | Hydrogen power generation system |
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