CN107189516A - Wear-resisting interior wall coating of one kind insulation and preparation method thereof - Google Patents
Wear-resisting interior wall coating of one kind insulation and preparation method thereof Download PDFInfo
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- CN107189516A CN107189516A CN201710575946.4A CN201710575946A CN107189516A CN 107189516 A CN107189516 A CN 107189516A CN 201710575946 A CN201710575946 A CN 201710575946A CN 107189516 A CN107189516 A CN 107189516A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
- C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/46—Polymerisation initiated by wave energy or particle radiation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F251/00—Macromolecular compounds obtained by polymerising monomers on to polysaccharides or derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/16—Antifouling paints; Underwater paints
- C09D5/1687—Use of special additives
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses wear-resisting interior wall coating of one kind insulation and preparation method thereof, belong to building coating field, the coating includes the following raw material counted by weight：25 35 parts of pure acrylate elastic emulsion, 20 30 parts of PVDC latex, 15 25 parts of polyethylene micropowder wax, 10 20 parts of methyl methacrylate, 8 12 parts of talcum powder, 5 15 parts of silicon calcium powder, 37 parts of amylum adhesive, 24 parts of EVA, 15 parts of dispersant, 13 parts of foaming agent, 13 parts of foam stabilizer, 13 parts of water reducer, 13 parts of hydrophober.Its preparation method is at a certain temperature, the part materials such as PVDC latex to be mixed into pasty state, obtains batch mixing A, the part materials such as pure acrylate elastic emulsion are mixed into pasty state, mixed material B is obtained；Batch mixing A and mixed material B are mixed, remaining additive is added and stirs.The interior wall coating preparation technology of the present invention is simple, and production cost is low, strong with heat-insulating property, and wearability is high, the characteristics of good antifouling effect.
Description
Technical field
The present invention relates to interior wall coating field, more particularly, to wear-resisting interior wall coating of one kind insulation and preparation method thereof.
Background technology
With the rapid development of the national economy, the continuous improvement of living standards of the people, the consumption to the energy is also increasing,
Energy shortage problem is become increasingly conspicuous, therefore, and energy saving and environment friendly insulation material is gradually valued by the people, and thermal insulation coatings are as new
One kind in type building materials, is widely used, and thermal insulation coatings realize heat-insulation and heat-preservation by low thermal conductivity and high thermal resistance, and the insulation is applied
Material generally adds chemical addition agent and high temperature stick slurrying by high-quality natural mineral matter and mixed, generally emulsion, grease, fill out
Charge, pigment etc., the features such as with waterproof, sound insulation, fire prevention, fire-retardant, insulation, antiacid alkali, lightweight, easy construction, so as to reach
To the effect of energy-conserving and environment-protective, although this kind of thermal insulation coatings have many performance advantages as above, still, market compared to common coating
Much be present heat-insulating property deficiency in upper existing thermal insulation coatings, wear no resistance, the problem of antifouling property is not strong has a strong impact on insulation
Coating using effect indoors.Therefore, a kind of interior wall coating that can solve the problem that above-mentioned performance issue is developed to be highly desirable to.
The content of the invention
The purpose of the present invention is that there is provided the wear-resisting interior wall coating of one kind insulation and its preparation side for problem of the prior art
Method, this kind of interior wall coating preparation technology is simple, and production cost is low, strong with heat-insulating property, and wearability is high, the spy of good antifouling effect
Point.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
The wear-resisting interior wall coating of one kind insulation, including the following raw material counted by weight：25-35 parts of pure acrylate elastic emulsion,
20-30 parts of PVDC latex, 15-25 parts of polyethylene micropowder wax, 10-20 parts of methyl methacrylate, 8-12 parts of talcum powder, silicon calcium powder
5-15 parts, 3-7 parts of amylum adhesive, 2-4 parts of EVA, 1-5 parts of dispersant, 1-3 parts of foaming agent, 1-3 parts of foam stabilizer, water reducer 1-
3 parts, 1-3 parts of hydrophober.
The amylum adhesive is made by following steps：
1) raw material of following parts by weight is prepared：20 parts of cornstarch, 350 parts of water, 15 parts of acrylic acid, 5 parts of lauryl mercaptan,
10 parts of 3 parts of sodium benzoate, 1 part of sodium tetraborate and bentonite；
2) ready cornstarch, water, acrylic acid and lauryl mercaptan are mixed, is again heated to 75-85 DEG C and is gelatinized；
3) product after gelatinization is placed in 60Co- gamma Rays and carries out radiation graft polymerization, receiving dosage is
0.5-1.5KGy；
4) sodium benzoate, sodium tetraborate and bentonite are added in the product after radiation graft polymerization and is uniformly mixed so as to obtain shallow lake
Powder adhesive.
Further, the interior wall coating includes the following raw material counted by weight：30 parts of pure acrylate elastic emulsion, PVDC
25 parts of latex, 20 parts of polyethylene micropowder wax, 15 parts of methyl methacrylate, 10 parts of talcum powder, 6 parts of silicon calcium powder, amylum adhesive 3
Part, 3 parts of EVA, 3 parts of dispersant, 2 parts of foaming agent, 2 parts of foam stabilizer, 2 parts of water reducer, 2 parts of hydrophober.
Preferably, the dispersant is one kind in lignin or Lignosite.
Preferably, the foaming agent is pressed for the one or several kinds in neopelex, rosin or benzene sulfonic acid sodium salt
The mixture arbitrarily matched.
Preferably, the foam stabilizer is a kind of or several in silicones polyethers emulsion, polyacrylamide or polyvinyl alcohol
Plant the mixture by any proportioning.
Preferably, the water reducer is one kind in Sodium Polyacrylate or sulfamic acid sodium.
Preferably, the hydrophober is organic silicon emulsion.
A kind of preparation method of the above-mentioned wear-resisting interior wall coating of insulation, is followed the steps below：
(1) under the conditions of temperature is 36-42 DEG C, PVDC latex, polyethylene micropowder wax, silicon calcium powder and amylum adhesive are mixed
Stirring is closed to pasty state, batch mixing A is obtained, pure acrylate elastic emulsion, methyl methacrylate and talcum powder is mixed into pasty state, obtain mixed
Expect B；
(2) EVA is added after above-mentioned batch mixing A and mixed material B being mixed evenly, is mixed evenly again, afterwards in temperature
Spend under the conditions of 42-46 DEG C, to stand 2-4h, obtain batch mixing C；
(3) dispersant, foaming agent, foam stabilizer, water reducer and hydrophober is sequentially added in most backward batch mixing C to be stirred
After mixing processing, wherein, speed of agitator is 400-600r/min, and mixing time is 20-30min.
The present invention has following beneficial effect：
(1) extensively, cost is low for interior wall coating raw material sources of the invention, and preparation technology is simple, in the absence of industrial wastes, gives up
The discharge of gas and waste, raw material availability is high, and the interior wall coating free from extraneous odour of finished product, and no pernicious gas is produced, heat insulation property
By force, green, the standard of energy-saving and environmental protection that country advocates are met；
(2) interior wall coating of the invention is used to wall, and strong with stain resistance, the high advantage of wearability makes wall
Top layer can keep cleaning, smooth, smooth state for a long time, the service life of coating be improved, with wide market prospects.
Embodiment
The embodiment of the present invention is further described with reference to embodiment, following examples are only used for more
Technical scheme is clearly demonstrated, and can not be limited the scope of the invention with this.
Embodiment 1
The wear-resisting interior wall coating of one kind insulation, weighs following raw material：Pure acrylate elastic emulsion 25kg, PVDC latex 20kg, poly- second
Alkene micro mist wax 15kg, methyl methacrylate 10kg, talcum powder 8kg, silicon calcium powder 5kg, amylum adhesive 3kg, EVA 2kg, point
Powder 1kg, foaming agent 1kg, foam stabilizer 1kg, water reducer 1kg, hydrophober 1kg.
The amylum adhesive is made by following steps：
1) following raw material is weighed：Cornstarch 20kg, water 350kg, acrylic acid 15kg, lauryl mercaptan 5kg, sodium benzoate
3kg, sodium tetraborate 1kg and bentonite 10kg；
2) ready cornstarch, water, acrylic acid and lauryl mercaptan are mixed, is again heated to 75 DEG C and is gelatinized；
3) product after gelatinization is placed in 60Co- gamma Rays and carries out radiation graft polymerization, receiving dosage is
0.5KGy；
4) sodium benzoate, sodium tetraborate and bentonite are added in the product after radiation graft polymerization and is uniformly mixed so as to obtain shallow lake
Powder adhesive.
Wherein, above-mentioned dispersant uses lignin；Foaming agent uses neopelex；Foam stabilizer uses silicones
Polyethers emulsion；Water reducer uses Sodium Polyacrylate；Hydrophober uses organic silicon emulsion.
A kind of preparation method of the above-mentioned wear-resisting interior wall coating of insulation, is followed the steps below：
(1) under the conditions of temperature is 36 DEG C, PVDC latex, polyethylene micropowder wax, silicon calcium powder and amylum adhesive are mixed
Stirring obtains batch mixing A, pure acrylate elastic emulsion, methyl methacrylate and talcum powder is mixed into pasty state, batch mixing is obtained to pasty state
B；
(2) EVA is added after above-mentioned batch mixing A and mixed material B being mixed evenly, is mixed evenly again, afterwards in temperature
Spend under the conditions of 42 DEG C, to stand 2h, obtain batch mixing C；
(3) dispersant, foaming agent, foam stabilizer, water reducer and hydrophober is sequentially added in most backward batch mixing C to be stirred
The wear-resisting interior wall coating of insulation of the present invention is made after mixing processing, wherein, speed of agitator is 400r/min, and mixing time is
20min。
Embodiment 2
The wear-resisting interior wall coating of one kind insulation, weighs following raw material：Pure acrylate elastic emulsion 30kg, PVDC latex 25kg, poly- second
Alkene micro mist wax 20kg, methyl methacrylate 15kg, talcum powder 10kg, silicon calcium powder 6kg, amylum adhesive 3kg, EVA 3kg, point
Powder 3kg, foaming agent 2kg, foam stabilizer 2kg, water reducer 2kg, hydrophober 2kg.
The amylum adhesive is made by following steps：
1) following raw material is weighed：Cornstarch 20kg, water 350kg, acrylic acid 15kg, lauryl mercaptan 5kg, sodium benzoate
3kg, sodium tetraborate 1kg and bentonite 10kg；
2) ready cornstarch, water, acrylic acid and lauryl mercaptan are mixed, is again heated to 80 DEG C and is gelatinized；
3) product after gelatinization is placed in 60Co- gamma Rays and carries out radiation graft polymerization, receiving dosage is
1.0KGy；
4) sodium benzoate, sodium tetraborate and bentonite are added in the product after radiation graft polymerization and is uniformly mixed so as to obtain shallow lake
Powder adhesive.
Wherein, above-mentioned dispersant uses Lignosite；Foaming agent uses two kinds of mixtures of rosin and benzene sulfonic acid sodium salt, and two
Mass ratio between person is 1:1；Foam stabilizer uses two kinds of mixtures of silicones polyethers emulsion and polyacrylamide, and between the two
Mass ratio be 1:1；Water reducer uses sulfamic acid sodium；Hydrophober uses organic silicon emulsion.
A kind of preparation method of the above-mentioned wear-resisting interior wall coating of insulation, is followed the steps below：
(1) under the conditions of temperature is 39 DEG C, PVDC latex, polyethylene micropowder wax, silicon calcium powder and amylum adhesive are mixed
Stirring obtains batch mixing A, pure acrylate elastic emulsion, methyl methacrylate and talcum powder is mixed into pasty state, batch mixing is obtained to pasty state
B；
(2) EVA is added after above-mentioned batch mixing A and mixed material B being mixed evenly, is mixed evenly again, afterwards in temperature
Spend under the conditions of 44 DEG C, to stand 3h, obtain batch mixing C；
(3) dispersant, foaming agent, foam stabilizer, water reducer and hydrophober is sequentially added in most backward batch mixing C to be stirred
The wear-resisting interior wall coating of insulation of the present invention is made after mixing processing, wherein, speed of agitator is 500r/min, and mixing time is
25min。
Embodiment 3
The wear-resisting interior wall coating of one kind insulation, weighs following raw material：Pure acrylate elastic emulsion 35kg, PVDC latex 30kg, poly- second
Alkene micro mist wax 25kg, methyl methacrylate 20kg, talcum powder 12kg, silicon calcium powder 15kg, amylum adhesive 7kg, EVA4kg, point
Powder 5kg, foaming agent 3kg, foam stabilizer 3kg, water reducer 3kg, hydrophober 3kg.
The amylum adhesive is made by following steps：
1) following raw material is weighed：Cornstarch 20kg, water 350kg, acrylic acid 15kg, lauryl mercaptan 5kg, sodium benzoate
3kg, sodium tetraborate 1kg and bentonite 10kg；
2) ready cornstarch, water, acrylic acid and lauryl mercaptan are mixed, is again heated to 85 DEG C and is gelatinized；
3) product after gelatinization is placed in 60Co- gamma Rays and carries out radiation graft polymerization, receiving dosage is
1.5KGy；
4) sodium benzoate, sodium tetraborate and bentonite are added in the product after radiation graft polymerization and is uniformly mixed so as to obtain shallow lake
Powder adhesive.
Wherein, above-mentioned dispersant uses lignin；Foaming agent uses benzene sulfonic acid sodium salt；Foam stabilizer uses polyvinyl alcohol；Diminishing
Agent uses Sodium Polyacrylate；Hydrophober uses organic silicon emulsion.
A kind of preparation method of the above-mentioned wear-resisting interior wall coating of insulation, is followed the steps below：
(1) under the conditions of temperature is 42 DEG C, PVDC latex, polyethylene micropowder wax, silicon calcium powder and amylum adhesive are mixed
Stirring obtains batch mixing A, pure acrylate elastic emulsion, methyl methacrylate and talcum powder is mixed into pasty state, batch mixing is obtained to pasty state
B；
(2) EVA is added after above-mentioned batch mixing A and mixed material B being mixed evenly, is mixed evenly again, afterwards in temperature
Spend under the conditions of 46 DEG C, to stand 4h, obtain batch mixing C；
(3) dispersant, foaming agent, foam stabilizer, water reducer and hydrophober is sequentially added in most backward batch mixing C to be stirred
The wear-resisting interior wall coating of insulation of the present invention is made after mixing processing, wherein, speed of agitator is 600r/min, and mixing time is
30min。
The preferred embodiments of the present invention are the foregoing is only, are not intended to limit the invention, although with reference to foregoing reality
Apply example the present invention is described in detail, for those skilled in the art, it still can be to foregoing each implementation
Technical scheme described in example is modified, or carries out equivalent substitution to which part technical characteristic.All essences in the present invention
God is with principle, and any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.
Claims (8)
1. the wear-resisting interior wall coating of one kind insulation, it is characterised in that including the following raw material counted by weight：Pure acrylate elastic emulsion
25-35 parts, 20-30 parts of PVDC latex, 15-25 parts of polyethylene micropowder wax, 10-20 parts of methyl methacrylate, talcum powder 8-12
Part, 5-15 parts of silicon calcium powder, 3-7 parts of amylum adhesive, 2-4 parts of EVA, 1-5 parts of dispersant, 1-3 parts of foaming agent, foam stabilizer 1-3
Part, 1-3 parts of water reducer, 1-3 parts of hydrophober；
The amylum adhesive is made by following steps：
1) raw material of following parts by weight is prepared：20 parts of cornstarch, 350 parts of water, 15 parts of acrylic acid, 5 parts of lauryl mercaptan, benzene first
10 parts of sour 3 parts of sodium, 1 part of sodium tetraborate and bentonite；
2) ready cornstarch, water, acrylic acid and lauryl mercaptan are mixed, is again heated to 75-85 DEG C and is gelatinized；
3) product after gelatinization is placed in 60Co- gamma Rays and carries out radiation graft polymerization, reception dosage is 0.5-
1.5KGy；
4) added in the product after radiation graft polymerization the sodium benzoate, sodium tetraborate and bentonite be uniformly mixed so as to obtain starch glue
Mixture.
2. a kind of wear-resisting interior wall coating of insulation according to claim 1, it is characterised in that counted by weight including following
Raw material：30 parts of pure acrylate elastic emulsion, 25 parts of PVDC latex, 20 parts of polyethylene micropowder wax, 15 parts of methyl methacrylate, talcum
10 parts of powder, 6 parts of silicon calcium powder, 3 parts of amylum adhesive, 3 parts of EVA, 3 parts of dispersant, 2 parts of foaming agent, 2 parts of foam stabilizer, water reducer 2
Part, 2 parts of hydrophober.
3. a kind of wear-resisting interior wall coating of insulation according to claim 1, it is characterised in that the dispersant be lignin or
One kind in Lignosite.
4. a kind of wear-resisting interior wall coating of insulation according to claim 1, it is characterised in that the foaming agent is dodecyl
One or several kinds in benzene sulfonic acid sodium salt, rosin or benzene sulfonic acid sodium salt press the mixture of any proportioning.
5. a kind of wear-resisting interior wall coating of insulation according to claim 1, it is characterised in that the foam stabilizer is poly- for silicones
One or several kinds in ether emulsion, polyacrylamide or polyvinyl alcohol press the mixture of any proportioning.
6. a kind of wear-resisting interior wall coating of insulation according to claim 1, it is characterised in that the water reducer is polyacrylic acid
One kind in sodium or sulfamic acid sodium.
7. a kind of wear-resisting interior wall coating of insulation according to claim 1, it is characterised in that the hydrophober is organosilicon breast
Liquid.
8. a kind of preparation method of the wear-resisting interior wall coating of insulation as described in claim 1-7 any one, it is characterised in that bag
Include following steps：
(1) under the conditions of temperature is 36-42 DEG C, PVDC latex, polyethylene micropowder wax, silicon calcium powder and amylum adhesive is mixed and stirred
Mix to pasty state, obtain batch mixing A, pure acrylate elastic emulsion, methyl methacrylate and talcum powder are mixed into pasty state, mixed material B is obtained；
(2) EVA is added after above-mentioned batch mixing A and mixed material B being mixed evenly, is mixed evenly again, is in temperature afterwards
Under the conditions of 42-46 DEG C, 2-4h is stood, batch mixing C is obtained；
(3) dispersant, foaming agent, foam stabilizer, water reducer and hydrophober are sequentially added in most backward batch mixing C and is stirred mixing
After processing, wherein, speed of agitator is 400-600r/min, and mixing time is 20-30min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710575946.4A CN107189516A (en) | 2017-07-14 | 2017-07-14 | Wear-resisting interior wall coating of one kind insulation and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710575946.4A CN107189516A (en) | 2017-07-14 | 2017-07-14 | Wear-resisting interior wall coating of one kind insulation and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107189516A true CN107189516A (en) | 2017-09-22 |
Family
ID=59882148
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| CN201710575946.4A Withdrawn CN107189516A (en) | 2017-07-14 | 2017-07-14 | Wear-resisting interior wall coating of one kind insulation and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019160681A1 (en) * | 2018-02-17 | 2019-08-22 | Benjamin Moore & Co. | Scuff resistant and chip resistant architectural compositions |
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| CN105820640A (en) * | 2016-05-09 | 2016-08-03 | 孙法峰 | Interior wall putty powder and preparation method thereof |
| CN105820638A (en) * | 2016-05-09 | 2016-08-03 | 孙法峰 | Anti-cracking exterior wall putty powder and preparation method thereof |
| CN105860641A (en) * | 2016-05-09 | 2016-08-17 | 孙法峰 | Waterproof interior wall putty powder and preparation method thereof |
| CN107083091A (en) * | 2017-06-03 | 2017-08-22 | 合肥雅克丽新型建材有限公司 | Heat-insulating wear-resistant interior wall coating and preparation method thereof |
| CN107118600A (en) * | 2017-05-27 | 2017-09-01 | 明光市泰丰新材料有限公司 | Wear-resisting interior wall coating of one kind insulation and preparation method thereof |
-
2017
- 2017-07-14 CN CN201710575946.4A patent/CN107189516A/en not_active Withdrawn
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105820640A (en) * | 2016-05-09 | 2016-08-03 | 孙法峰 | Interior wall putty powder and preparation method thereof |
| CN105820638A (en) * | 2016-05-09 | 2016-08-03 | 孙法峰 | Anti-cracking exterior wall putty powder and preparation method thereof |
| CN105860641A (en) * | 2016-05-09 | 2016-08-17 | 孙法峰 | Waterproof interior wall putty powder and preparation method thereof |
| CN107118600A (en) * | 2017-05-27 | 2017-09-01 | 明光市泰丰新材料有限公司 | Wear-resisting interior wall coating of one kind insulation and preparation method thereof |
| CN107083091A (en) * | 2017-06-03 | 2017-08-22 | 合肥雅克丽新型建材有限公司 | Heat-insulating wear-resistant interior wall coating and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2019160681A1 (en) * | 2018-02-17 | 2019-08-22 | Benjamin Moore & Co. | Scuff resistant and chip resistant architectural compositions |
| CN111918930A (en) * | 2018-02-17 | 2020-11-10 | 本杰明·摩尔公司 | Abrasion and chip resistant construction composition |
| US11898050B2 (en) | 2018-02-17 | 2024-02-13 | Columbia Insurance Company | Scuff resistant and chip resistant architectural compositions |
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Application publication date: 20170922 |