CN107188385A - A kind of greasy filth is pyrolyzed continuous feeding device - Google Patents

A kind of greasy filth is pyrolyzed continuous feeding device Download PDF

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Publication number
CN107188385A
CN107188385A CN201710428661.8A CN201710428661A CN107188385A CN 107188385 A CN107188385 A CN 107188385A CN 201710428661 A CN201710428661 A CN 201710428661A CN 107188385 A CN107188385 A CN 107188385A
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CN
China
Prior art keywords
greasy filth
outlet
discharge nozzle
pyrolyzed
feed pipe
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Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710428661.8A
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Chinese (zh)
Inventor
房凯
巴玉鑫
吴小飞
王惠惠
牛明杰
王鑫
刘春亚
吴道洪
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Beijing Shenyuan Environmental Protection Co Ltd
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Beijing Shenyuan Environmental Protection Co Ltd
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Publication date
Application filed by Beijing Shenyuan Environmental Protection Co Ltd filed Critical Beijing Shenyuan Environmental Protection Co Ltd
Priority to CN201710428661.8A priority Critical patent/CN107188385A/en
Publication of CN107188385A publication Critical patent/CN107188385A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/10Treatment of sludge; Devices therefor by pyrolysis
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B47/00Destructive distillation of solid carbonaceous materials with indirect heating, e.g. by external combustion
    • C10B47/28Other processes
    • C10B47/32Other processes in ovens with mechanical conveying means
    • C10B47/44Other processes in ovens with mechanical conveying means with conveyor-screws
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10BDESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
    • C10B53/00Destructive distillation, specially adapted for particular solid raw materials or solid raw materials in special form
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/10Nature of the water, waste water, sewage or sludge to be treated from quarries or from mining activities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/34Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32
    • C02F2103/36Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds
    • C02F2103/365Nature of the water, waste water, sewage or sludge to be treated from industrial activities not provided for in groups C02F2103/12 - C02F2103/32 from the manufacture of organic compounds from petrochemical industry (e.g. refineries)
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/40Valorisation of by-products of wastewater, sewage or sludge processing

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Combustion & Propulsion (AREA)
  • Mixers Of The Rotary Stirring Type (AREA)

Abstract

Continuous feeding device is pyrolyzed the invention discloses a kind of greasy filth, it has:Storage bin with inlet and outlet;Preload screw with entrance and outlet, the entrance of preload screw and the outlet of feed bin, preload screw side set motor;With first entrance, second entrance and first outlet, the bidirectional ram pump of second outlet, its first entrance, second entrance is connected to the first feed pipe and the second feed pipe, first outlet, second outlet is connected to the first discharge nozzle and the second discharge nozzle, first feed pipe and the second feed pipe are by feeding the outlet of house steward and preload screw, first feed pipe, the first reversal valve is set between second feed pipe and charging house steward, first discharge nozzle is connected discharge header pipe with the second discharge nozzle, first discharge nozzle, second reversal valve is set between the second discharge nozzle and discharge header pipe.This device can realize continuous feed of the highly viscous oily sludge in pyrolytic process, reliable, efficient, controllable, be adapted to large-scale promotion.

Description

A kind of greasy filth is pyrolyzed continuous feeding device
Technical field
The present invention relates to environmental energy environmental technology field, more particularly to a kind of greasy filth pyrolysis continuous feeding device.
Background technology
China's oily sludge annual production is huge, and the way of production mainly has three kinds:Produced during crude oil production, crude oil Produce and produced in sewage from oil refinery treatment plant in production and course of conveying.Wherein during oil extraction, greasy filth yield is The 0.5%~1% of crude output, State Statistics Bureau's numerical monitor, crude oil in China exploitation total amount is 2.1 × 10 within 20148Ton, oil Mud yield is about 2,000,000 tons or so, and many oil fields of China come into exploitation latter stage, and greasy filth produces ratio will be bigger. Oily sludge oil content is general between 20%~50%, moisture content typically between 10%~90%, if without processing with Meaning discharge, a large amount of arable lands is not only taken up, and great harm can be produced to soil, water and air.Because greasy filth contains largely Crude oil, not recovered random discharge is also a kind of waste to the energy.Therefore, no matter consider from environmental angle, or from resource Considered using angle, be required for a kind of advanced technology to carry out innoxious and recycling processing to it.
The pyrolysis of oily sludge anoxybiotic, which produces oil, gas, the technique of charcoal, has it advanced so that the organic matter in greasy filth is whole Processing, reclaims oil product, realizes innoxious and recycling final disposal, but in actual production process, because greasy filth viscosity is big, Poor fluidity, common rubbish or the feed system of municipal sludge can not be conveyed to greasy filth.Therefore, one kind can the company of realization Continuous charging, it is ensured that the induction system of the closed anoxybiotic of fill process is urgently developed.
The content of the invention
In order to solve the above-mentioned problems in the prior art, the present invention proposes a kind of greasy filth pyrolysis continuous feed dress Put, this device can realize continuous feed of the highly viscous oily sludge in pyrolytic process, and realize high-pressure delivery, measure defeated Send and anoxybiotic closed conveying so that oily sludge can be delivered at the top of revolving bed, and control by measuring the processing of revolving bed Amount, while realizing the zero-emission of the hypertoxic gas such as bioxin in pyrolytic process, this equipment is environmentally friendly, reliable, efficient, controllable, fits Close large-scale promotion.
A kind of greasy filth pyrolysis continuous feeding device disclosed by the invention has:
Storage bin, storage bin has inlet and outlet;
Preload screw, preload screw has entrance and outlet, the entrance of preload screw and the outlet of feed bin, precompressed spiral shell Revolve side and motor is set;
Bidirectional ram pump, bidirectional ram pump has first entrance, second entrance and first outlet, second outlet, two-way column The two entrances of plug pump are connected to the first feed pipe and the second feed pipe, and two outlets of bidirectional ram pump are connected to The outlet of first discharge nozzle and the second discharge nozzle, the first feed pipe and the second feed pipe by feeding house steward and preload screw connects It is logical, the first reversal valve is set between the first feed pipe, the second feed pipe and charging house steward, and the first discharge nozzle and the second discharge nozzle connect Discharge header pipe is connect, the second reversal valve is set between the first discharge nozzle, the second discharge nozzle and discharge header pipe.
Further, arch breaking apparatus is provided with storage bin, prevents greasy filth from forming cavity before preload screw is entered.
Further, storage bin bottom, which is set, has the gradient so that greasy filth enters preload screw one end.
Further, irreversibly delivered on the direction of preload screw from the inlet to the outlet, power is provided by motor, by turning Speed realizes the once metering to greasy filth, and greasy filth carries out primary compression in preload screw, discharges air, it is ensured that greasy filth is in anoxybiotic Conveyed under state.
Further, piston is connected by bidirectional ram pump by connecting rod with hydraulic cylinder, and bidirectional ram pump power resources are in liquid Cylinder pressure, is realized by connecting rod and moved back and forth, the unidirectional of greasy filth, high pressure, closed conveying are realized in reciprocatory movement, and complete Secondary measurement, to reduce once metering and the error of secondary measurement, in specific implementation process, preload screw rotating speed and two-way column The piston reciprocating frequency for filling in pump is corresponding, while the pyrolysis rate of correspondence pyrolysis furnace apparatus, and then realize up to production.
Further, the first reversal valve selectively communicates with charging house steward and the first feed pipe or the second feed pipe.
Further, the second reversal valve selectively communicates with discharge header pipe and the first discharge nozzle or the second discharge nozzle.
Further, discharge header pipe is connected with pyrolysis installation.
Further, the first reversal valve is changed with the second reversal valve when the piston of bidirectional ram pump changes the direction of motion To.
Said apparatus is comprised the steps of during operation:
Greasy filth enters preload screw in storage bin after arch breaking apparatus broken arch, and greasy filth realizes compacting in preload screw, Greasy filth charging house steward is drained into certain pressure.
First reversal valve coordinates the direction of motion of bidirectional ram pump with the second reversal valve and commutated, in the first feed tube When, plunger is moved right, while the second discharge nozzle outwards discharges;Conversely, when plunger is to left movement, the first reversal valve and second Reversal valve commutates simultaneously, and greasy filth is on the right side of second charging aperture suction bidirectional ram pump, and simultaneously bi-directionally greasy filth passes through on the left of plunger pump First discharge nozzle discharges;So go round and begin again, realize that greasy filth is unidirectional, high pressure, closed conveying.
Except meet the first reversal valve, the commutation of the second reversal valve with addition to bidirectional ram pump matching back and forth, preload screw rotating speed Bidirectional ram pump reciprocating frequence is met simultaneously, preload screw should carry out speed change rotation if necessary;Preload screw conveying capacity Q can basis Pyrolytic process actual treatment amount is designed, by determining pitch S, helical blade diameter D, speed of screw shaft N and material Fill factor ψ, according to formula Q=47D2SN ψ are calculated.For example, heap density big situation big in greasy filth viscosity Under, ψ values can take 0.1.Plunger pump discharge can be calculated according to the volume of bidirectional ram pump with reciprocal time, in detail below Cold test is substantially carried out in the embodiment of embodiment coordinates preload screw to provide empirical value.
By using above-mentioned technical proposal, following many beneficial effects are achieved:
(1) technique is simple, cost is low, simple to operate, stable and reliable operation;
(2) unidirectional, the continuous conveying of high viscosity greasy filth can be achieved, is greasy filth while ensureing anoxybiotic, high pressure long distance delivery Follow-up pyrolysis processing provide ensure;
(3) greasy filth metering is realized, error of the greasy filth caused by viscosity is bonded on metering device greatly is eliminated.
Brief description of the drawings
The above-mentioned and/or additional aspect and advantage of the present invention will more in the description carried out to embodiment is combined with accompanying drawing Plus substantially and be readily appreciated that, wherein:
Fig. 1 shows the schematic diagram of greasy filth pyrolysis continuous feeding device according to an embodiment of the invention.
Reference:1st, storage bin;2nd, motor;3rd, preload screw;4th, house steward is fed;5th, the first reversal valve;6th, first enters Expects pipe;7th, the second feed pipe;8th, the first discharge nozzle;9th, the second discharge nozzle;10th, the second reversal valve;11st, bidirectional ram pump;12nd, liquid Cylinder pressure;13rd, connecting rod;14th, discharge header pipe.
Embodiment
It should be appreciated that shown embodiments of the invention are merely illustrative in the exemplary embodiment.Although in this hair Only a small number of embodiments are described in detail in bright, but those skilled in the art are readily appreciated that and depart from the present invention in not essence In the case of the teaching of theme, a variety of modifications are feasible.Correspondingly, all such modifications should all be included in the present invention's In the range of.Without departing from the spirit of the invention, design, operating condition and ginseng that can be to following exemplary embodiment Number etc. makes others and replaces, changes, changes and delete.
Greasy filth pyrolysis continuous feeding device as shown in Figure 1, with storage bin 1, storage bin 1 has inlet and outlet, storage Arch breaking apparatus (not shown) is provided with feed bin 1, to prevent greasy filth from forming cavity before preload screw 3 is entered.Precompressed Spiral 2 equally has entrance and outlet, the entrance of preload screw 3 and the outlet of storage bin 1, and the side of preload screw 3 is set Put motor 2.Bidirectional ram pump 11 has first entrance, second entrance and first outlet, second outlet, the of bidirectional ram pump 11 One entrance and second entrance are connected to the first feed pipe 6 and the second feed pipe 7, the first outlet of bidirectional ram pump 11 and Two outlets are connected to the first discharge nozzle 8 and the second discharge nozzle 9, and the first feed pipe 6 and the second feed pipe 7 are by feeding house steward 4 with the outlet of preload screw 3.First reversal valve 5 is set between first feed pipe 6, the second feed pipe 7 and charging house steward 4, First discharge nozzle 8 is connected discharge header pipe 14 with the second discharge nozzle 9.First discharge nozzle 8, the second discharge nozzle 9 and discharge header pipe 14 it Between the second reversal valve 10 is set.
In operation, greasy filth is poured onto storage bin 1 by greasy filth tank car.In fill process, because part greasy filth is viscous Degree is larger, and easily putting up a bridge forms cavity, ensures that greasy filth smoothly enters preload screw 3 by arch breaking apparatus in the present embodiment, in advance Press spiral 3 to control rotating speed by motor 2, change the conveying capacity of greasy filth by adjusting rotating speed.Greasy filth reaches one in preload screw 3 Fixed pressure, while the air in space is driven out of, it is ensured that greasy filth anoxybiotic enters pyrolysis furnace apparatus, by the greasy filth of precompressed pre- Press the end of spiral 3 to enter greasy filth and feed house steward 4.Greasy filth charging house steward 4 is connected with the first reversal valve 5.The process passed through in greasy filth In, the first reversal valve 5 first is in right side so that greasy filth charging house steward 4 connects with the first feed pipe 6, at the second reversal valve 10 In right side so that the second discharge nozzle 9 is connected with greasy filth discharge header pipe 14, and simultaneously bi-directionally plunger pump 11 is moved from left to right, now Air is discharged by the second discharge nozzle 9 and greasy filth discharge header pipe 14 on the right side of the piston of bidirectional ram pump 11, greasy filth passes through greasy filth Feed on the left of the feed pipe 6 of the house steward 4 and first suction piston of bidirectional ram pump 11, when the piston of bidirectional ram pump 11 reaches low order end When, the first reversal valve 5 and the second reversal valve 10 commutate simultaneously, and bidirectional ram pump 11 starts to move from right to left, now two-way column The greasy filth sucked before is discharged by the first discharge nozzle 8 and greasy filth discharge header pipe 14 on the left of the plug piston of pump 11, greasy filth is by oil On the right side of the mud charging house steward 4 and second suction piston of bidirectional ram pump 11 of feed pipe 7, thus go round and begin again, realize that greasy filth is unidirectional, high Pressure, metering, anoxybiotic conveying.
Except meet the first reversal valve, the commutation of the second reversal valve with addition to bidirectional ram pump matching back and forth, preload screw rotating speed Bidirectional ram pump reciprocating frequence is met simultaneously, preload screw should carry out speed change rotation if necessary;Preload screw conveying capacity can basis Pyrolytic process actual treatment amount is designed, by determining pitch S, helical blade diameter D, speed of screw shaft N and material Fill factor ψ, is calculated according to formula Q=47D2SN ψ, in embodiment, because greasy filth viscosity is big, heap density Greatly, ψ values take 0.1;Plunger pump discharge can be calculated according to the volume of bidirectional ram pump with reciprocal time, mainly be entered in embodiment Row cold test coordinates preload screw to provide empirical value.Tested below by taking the greasy filth of the Liaohe River as an example, Liaohe River greasy filth feedstock analysis It is as follows:
The elementary analysis of the raw material of table 1 and Industrial Analysis table
In the present embodiment, Liaohe River greasy filth heap density is 1102.18kg/m3, therefore when spiral is fed material filling Coefficient ψ takes 0.1.Storage bin 1 carries out the greasy filth of pyrolysis processing can store up 7 days simultaneously the need for.The wherein helical-blade of preload screw 3 The a diameter of 500mm of piece, pitch is 300mm, by changing the rotating speed of helical axis, can be achieved to convey 5.28 tons of greasy filth per hour Conveying capacity.The volume of bidirectional ram pump 11 is 0.4m3, drawn by cold conditions pilot scale study, bidirectional ram pump 11 per hour reciprocal 2 ~15 times, the anoxybiotic of achievable greasy filth, high pressure, unidirectional, metering conveying.
In the present embodiment, the volume of bidirectional ram pump 11 is 0.4m3, long 2m, internal diameter 0.71m, external diameter 0.75m, conveying Pipe external diameter is 80mm.
In the present embodiment, to ensure oil-sludge treatment amount and greasy filth pyrolysis effect, using fabric thickness 80mm, revolving bed week Phase 60min, plunger pump comes and goes 6 times per hour.
Pyrolysis installation is revolving bed, its radius be 9m, revolving bed stone or metal plate for standing a stove on as a precaution against fire width be 2m, the revolving bed cycle can 30min~ Adjusted in 180min, the revolving bed cycle is 60min in the present embodiment.Fabric thickness can be adjusted in 50mm~200mm, in reality In the production of border, to ensure the treating capacity of greasy filth and the pyrolysis effect of greasy filth, cloth is generally carried out using material thickness 80mm and 100mm. By live cold test, greasy filth is arranged on revolving bed stone or metal plate for standing a stove on as a precaution against fire with different material thickness be pyrolyzed at normal temperatures, it is ensured that oil Mud is covered with stone or metal plate for standing a stove on as a precaution against fire, draws plunger pump reciprocal time interior per hour and revolving bed cycle following corresponding relation.
The plunger pump of table 2 reciprocal time and revolving bed cycle and preload screw rotating speed mapping table per hour
Or, in other embodiments, bidirectional ram pump 11 can be not isometrical bidirectional ram pump, including two work of size Plug sleeve, is correspondingly located in two piston sleeves, two pistons are connected by bar respectively with two pistons of different sizes And be connected by connecting rod with hydraulic cylinder and by Driven by Hydraulic Cylinder, two pistons can realize motion in the same direction, of different sizes by two Piston cylinder, first entrance that bidirectional ram pump has, second entrance be located at two piston cylinders respectively, what bidirectional ram pump had First outlet, second outlet distinguish two piston cylinders, are respectively the inner disc of revolving bed stone or metal plate for standing a stove on as a precaution against fire by not isometrical bidirectional ram pump Face and the outside card cloth of revolving bed stone or metal plate for standing a stove on as a precaution against fire, large diameter portion are fed for the outside card of revolving bed stone or metal plate for standing a stove on as a precaution against fire, and minor diameter part is divided into rotation The inner side card feed of rotated bed stone or metal plate for standing a stove on as a precaution against fire.
The foregoing is only presently preferred embodiments of the present invention, not for limit the present invention practical range;If do not taken off From the spirit and scope of the present invention, the present invention is modified or equivalent substitution, all should covered in the claims in the present invention Among protection domain.

Claims (10)

1. a kind of greasy filth is pyrolyzed continuous feeding device, it is characterised in that the feed arrangement has:
Storage bin, the storage bin has inlet and outlet;
Preload screw, the preload screw has entrance and outlet, and the outlet of the entrance of the preload screw and the feed bin connects Logical, the preload screw side sets motor;
Bidirectional ram pump, the bidirectional ram pump has first entrance, second entrance and first outlet, second outlet, described double The first feed pipe and the second feed pipe, two outlets point of the bidirectional ram pump are connected to the two entrances of plunger pump The first discharge nozzle and the second discharge nozzle are not connected with, and first feed pipe is with second feed pipe by feeding house steward and institute The outlet of preload screw is stated, sets first to commutate between first feed pipe, the second feed pipe and the charging house steward Valve, first discharge nozzle is connected discharge header pipe with second discharge nozzle, first discharge nozzle, the second discharge nozzle with it is described Second reversal valve is set between discharge header pipe.
2. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that be provided with brokenly in the storage bin Encircle device.
3. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the storage bin bottom has slope Degree.
4. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the preload screw from entrance to Irreversibly delivered on the direction of outlet.
5. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the bidirectional ram pump passes through even Piston is connected by bar with hydraulic cylinder.
6. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the preload screw rotating speed and institute The piston reciprocating frequency for stating bidirectional ram pump is corresponding.
7. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the first reversal valve selectivity The ground connection charging house steward and first feed pipe or second feed pipe.
8. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the second reversal valve selectivity Ground connects the discharge header pipe and first discharge nozzle or second discharge nozzle.
9. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that the discharge header pipe is filled with pyrolysis Put connection.
10. greasy filth according to claim 1 is pyrolyzed continuous feeding device, it is characterised in that first reversal valve and institute The second reversal valve is stated to be commutated when the piston of the bidirectional ram pump changes the direction of motion.
CN201710428661.8A 2017-06-08 2017-06-08 A kind of greasy filth is pyrolyzed continuous feeding device Pending CN107188385A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710428661.8A CN107188385A (en) 2017-06-08 2017-06-08 A kind of greasy filth is pyrolyzed continuous feeding device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710428661.8A CN107188385A (en) 2017-06-08 2017-06-08 A kind of greasy filth is pyrolyzed continuous feeding device

Publications (1)

Publication Number Publication Date
CN107188385A true CN107188385A (en) 2017-09-22

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110550840A (en) * 2019-09-26 2019-12-10 徐州矿源环保科技有限公司 Sludge wall breaking device and wall breaking method for deeply squeezing sludge

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110550840A (en) * 2019-09-26 2019-12-10 徐州矿源环保科技有限公司 Sludge wall breaking device and wall breaking method for deeply squeezing sludge
CN110550840B (en) * 2019-09-26 2024-03-01 江苏矿源环保科技有限公司 Sludge wall breaking device and wall breaking method for deep squeezing of sludge

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