CN107184497A

CN107184497A - Alkalescence myrobalan's pigment hair dye and hair colouring methods

Info

Publication number: CN107184497A
Application number: CN201710640621.XA
Authority: CN
Inventors: 宋慧君; 贾佩; 张宁; 长孙龙飞; 曹珂珂; 刘玉琦
Original assignee: Henan Institute of Engineering
Current assignee: Henan Institute of Engineering
Priority date: 2017-07-31
Filing date: 2017-07-31
Publication date: 2017-09-22

Abstract

The invention discloses a kind of alkalescence myrobalan pigment hair dye, including agent A, agent B, agent C and agent D；Agent A includes hydrogen peroxide 6% ~ 10%, and surplus is deionized water；Agent B include Activation of Hydrogen Peroxide Solution agent 1% ~ 2%, thickener 6% ~ 10%, swelling agent 5% ~ 10%, surplus is water；Agent B pH value is adjusted to 9 ~ 10 using one or both of sodium acid carbonate and sodium carbonate；Agent C include myrobalan's pigment 4% ~ 10%, accelerant 3% ~ 5%, thickener 3% ~ 5%, surplus is water；Agent D include water-soluble metal salt 1% ~ 4%, swelling agent 2% ~ 5%, thickener 4% ~ 6%, surplus is water；Agent A, agent B, agent C and agent D component unit are mass percent.The invention also discloses the hair colouring methods using above-mentioned alkalescence myrobalan pigment hair dye.The shortcoming for poor performance of being had hair dyed instant invention overcomes conventional natural pigment hair dye, make the scale layer of hair effectively expanded under alkalescence condition and the synergy of swelling agent, natural pigment member is passed through scale layer and reach cortical layer, realize lasting hair dyeing effect.

Description

Alkalescence myrobalan's pigment hair dye and hair colouring methods

Technical field

The present invention relates to hair color technology field, more particularly to a kind of myrobalan's pigment hair dye and hair colouring methods.

Background technology

With the continuous improvement of quality of life, appearance is increasingly valued by the people, walk on streets and lanes it is seen that, The hair dyeing particularly color hair of dye dark hair, dye has become a kind of consumption fashion.

Hair dye can be divided into metal salt form hair dye by composition（Inorganic hair dye）, oxidative hair dyes（Synthetic dyes） And natural hair dye.

Metal salt form hair dye is the relatively early hair dye used, mainly there is the hair dyes such as silver salt, lead salt.The silver salt dye of early stage Hair agent is that silver nitrate solution is first smeared on hair, then smears sodium sulfide solution, and the two reaction generation black silver sulfide is attached to Make hair coloring on hair.The lead ion that the hair dyeing mechanism of lead salt hair dye is mainly in hair dye is penetrated into hair, with Sulphur effect in hair cysteine, generates black vulcanized lead, makes hair coloring.It can not see immediately during this kind of hair dye hair dyeing Effect, just will can be such that hair coloring progressively deepens, after the color for reaching needs, tone can be kept for the long period through being used for multiple times. The heavy metal ion contained in metal salt form hair dye, easily causes and accumulates poisoning, and the injury to human body is very big, it is also possible to cause Some diseases difficult to treat, China's cosmetics health specification（Version in 2007）The content of middle limitation lead is 40mg/kg, silver nitrate Maximum concentration be 4%.

At present, hair dyeing product the most popular on international and domestic market is oxidative hair dyes.

Oxidative hair dyes are typically formulated as two formulations, and dyestuff matrix is constituted by dyestuff intermediate, coupling agent and matrix（The It is one）, the composition oxidized form matrix such as oxidized color developing agent（Second dose）.Conventional dyeing intermediate have p-phenylenediamine, o-phenylenediamine, M-phenylene diamine (MPD), para-aminophenol and its derivative, conventional coupling agent have resorcinol, 2- methylresorcinols etc..Oxidant Hydrogen peroxide typically is used, is also had using sodium perborate, urea peroxide etc..During hair dyeing, in the common of alkaline matter and peroxide Under effect, original melanin in hair fades, and dyestuff intermediate and coupling agent penetrate into hair cortical layer, under oxidant effect Generation oxidation, coupling and condensation reaction, formation, which is locked in inside hair, stablizes coloured macromolecular, hair is shown color, Because macromolecular pigment is formed in the cortical layer of hair, it is not easy to be washed with water out, so that lasting hair dyeing effect is played, Hair color can be kept 1 to 3 months.

The advantage of oxidative hair dyes is that dyeing time is short, chromatogram is wide, fastness good, and price is low.It has the disadvantage：Conventional dye Expect that intermediate is noxious material, can be absorbed through skin, cause fash and hinder liver damage, suction dust can cause allergy, nose The different illness such as inflammation, bronchitis, fever.Modern science research shows that Huppert's disease, the generation of cutaneum carcinoma are with containing benzene The long-term use of the hair dye of diamines, Exposed are relevant.Based on the dyestuff intermediates such as phenylenediamine, para-aminophenol and isophthalic two The toxicity and carcinogenicity of the coupling agents such as phenol, China's cosmetics health specification（Version in 2007）Regulation disabling m-phenylene diamine (MPD) and its salt Class, the maximum allowable concentration for limiting p-phenylenediamine is that the maximum allowable concentration of 6%, para-aminophenol is 1%, isophthalic The maximum allowable concentration of diphenol is 5%.Oxidant hydrogen peroxide in second dose of oxidative hair dyes has two effects, i.e., Bleached hair and dye oxidation.

The colouring agent of natural hair dye is the natural pigment obtained from the Nature.Natural pigment comprising vegetable colour, Animality pigment and mineral pigment, wherein with the most commonly used of vegetable colour, and available material category is also most rich It is rich.Natural pigment has good biological degradability, nontoxic, harmless, to skin without allergy, the advantages of not carcinogenic, while also having There are a variety of functions such as medicine, spices, some natural pigments are rare Chinese medicinal herbses.The color that natural pigment is dyed is not only pure Gorgeous, color and luster is soft, and skin friendly, there is health protection effect to human body, deeply welcomed by the people.

There is the shortcomings of dyeability is poor in natural pigment dyeing hair, mainly by the structure and natural pigment hair dye of hair Constitute what is caused.Hair is made up of hair shaft and hair follicle, and hair shaft part can be divided into three layers of hair cuticle, cortex and medullary substance from outside to inside. Wherein, hair cuticle layer is made up of 3 to 7 layers of thin, transparent keratinocyte, also known as cuticula, can be divided into epicuticle, exocuticle and Contain substantial amounts of High-sulphur protein in three layers of endepidermis, epicuticle and exocuticle, close structure can resist mechanical stretching, friction, day The effect of the various extraneous factors such as solarization, washing, has protective effect, also known as scale layer to hair.Cortical layer is the master of hair Body, accounts for the 75% ~ 90% of hair gross weight, is the pith for determining hair performance, and the pigment granule of hair is present in skin In matter layer, the color of hair by pigment granule number determined with species.Medullary substance layer is in hollow cavernous structure.Due to hair squama Lamellar structure is close, causes dyestuff macromolecular during dyeing from the beginning to deliver difficult towards diffusion inside.

Hair belongs to protein, in terms of intensity and feel, and the acid resistance of hair is better than alkali resistance therefore existing Natural pigment hair dye is acidic hair coloring preparation.

Existing synthesis basic hair dye, colourant molecule is small, and readily permeable scale layer reaches cortical layer, therefore existing synthesis Basic hair dye is generally not present the problem of dyeability is poor.By contrast, the organic molecule of natural pigment is big, it is difficult to permeate scale Layer reaches cortical layer, therefore existing natural pigment hair dye has the shortcomings of dyeability is poor, and this is largely supported Disappeared its various advantage（It is degradable, it is nontoxic, harmless, it is not carcinogenic etc. to skin without allergy）, limit natural pigment hair dye Application.

The content of the invention

It is an object of the invention to provide a kind of preferable alkalescence myrobalan pigment hair dye of dyeability.

To achieve the above object, alkalescence myrobalan's pigment hair dye of the invention includes agent A, agent B, agent C and agent D；

Agent A includes hydrogen peroxide 6% ~ 10%, and surplus is deionized water；

Agent B include Activation of Hydrogen Peroxide Solution agent 1% ~ 2%, thickener 6% ~ 10%, swelling agent 5% ~ 10%, surplus is water；Use sodium acid carbonate Agent B pH value is adjusted to 9 ~ 10 with one or both of sodium carbonate；

Agent C include myrobalan's pigment 4% ~ 10%, accelerant 3% ~ 5%, thickener 3% ~ 5%, surplus is water；

Agent D include water-soluble metal salt 1% ~ 4%, swelling agent 2% ~ 5%, thickener 4% ~ 6%, surplus is water；

Agent A, agent B, agent C and agent D component unit are mass percent.

During thickener in agent B, agent C and agent D is dextrin, methylcellulose, hydroxyethyl cellulose, imperial glue and guar gum One or more.

Swelling agent in agent B and agent D is the one or more in propane diols, glycerine and polyethylene glycol 200.

Agent C accelerant is sodium chloride or sodium sulphate.

Water-soluble metal salt in agent D be one kind in ferrous sulfate, zinc sulfate, aluminum sulfate, lanthanum chloride and cerium chloride or It is several.

The present invention also aims to provide a kind of hair colouring methods using above-mentioned alkalescence myrobalan pigment hair dye, the party Method is carried out as follows successively：

First agent A is well mixed with agent B, is equably applied on hair, 20 ~ 30min is kept under the conditions of 40 ~ 45 DEG C；Now head The scale layer of hair is expanded；

Agent C is uniformly applied on hair again, 10min is kept at room temperature, 40 ~ 50 DEG C are warming up to, 30 ~ 50min is kept, uses clear water Rinse hair；

Then, agent D is uniformly applied on hair, 20 ~ 30min is kept under the conditions of 40 ~ 50 DEG C；

Finally, Hair grooming clear water is cleaned up, completes hair dye.

In hair dye, agent A, agent B, agent C and agent D use volume ratio are：3-5：4-6：4-6：4-6.

In hair dye, agent A, agent B, agent C and agent D use volume ratio are：4：5：5：5.

The present invention has the advantage that：

The shortcoming for poor performance of being had hair dyed instant invention overcomes conventional natural pigment hair dye, in the collaboration of alkalescence condition and swelling agent Make the scale layer of hair effectively expanded under effect, so that the organic molecule of the much bigger natural pigment of relative synthetic dyestuff molecule Scale layer can be passed through（And endepidermis）Cortical layer is reached, lasting hair dyeing effect is realized.

Although existing synthetic dyes also have basic hair dye, its effective dyeing composition is synthetic dyestuff rather than day Right pigment（Molecule is larger）, the problem of it is difficult to the scale layer by hair in the absence of pigment.Existing hair dye neutral and alkali environment Purpose be to make hydrogen peroxide enemy initiate to arrive blanching effect, the lighter of hair is easily synthesized the color of pigment and cover, Rather than with swelling agent synergy so that scale layer is effectively expanded and then enable suitable as the natural pigment of organic macromolecule Profit reaches cortical layer by scale layer and endepidermis.

The hair colouring methods of the present invention are simple and convenient, equilibrium uses agent A, agent B, agent C and agent D, it is to avoid agent A, agent B, agent C and A certain or some dose of consumption excessively causes to waste in agent D.

Agent A, agent B, agent C and agent D just occur mixing and contacted in hair dye, effectively prevent hydrogen peroxide in storage Decompose, the problems such as the natural pigment in agent C and agent D metal ion are complexed in storage process, extend this hair The quality guarantee period of bright alkalescence myrobalan's pigment hair dye.

Myrobalan's pigment is the natural dye extracted from myrobalan fruit, nontoxic, harmless with good biological degradability, right Skin is without allergy, while also having medicinal health-care function, myrobalan's pigment also has effects that black hair in itself.The present invention can be by myrobalan Pigment is directly used in various hairs（Dark hair, grey hair, white hair）Dyeing, bleached hair, softening, desquamation etc. need not be carried out before dyeing Processing.Myrobalan's pigment is used for hair-dyeing, can not only change the color of hair, trend is adapted to, personalized demand is met, Hair quality can also be improved by being used for a long time simultaneously, and play a part of black hair.Myrobalan's pigment is good to oxidant, acid, alkali equistability, Be conducive to opening the disulfide bond of hair scale layer under the conditions of alkalescence, make hair occur significantly to be swelled, be conducive to myrobalan's pigment The scale layer for diffusing through hair enters cortical layer, improves in the color fastness of institute's dyeing hair, agent D and adds different water-soluble metals Addition ferrous sulfate in different colors, agent D is can obtain after salt, hair dyeing can dye white hair in pitch-black hair.

Embodiment

Alkalescence myrobalan's pigment hair dye of the present invention includes agent A, agent B, agent C and agent D；

Agent A includes hydrogen peroxide 6% ~ 10%, and surplus is deionized water；

Agent A, agent B, agent C and agent D component unit are mass percent.

Agent C accelerant is sodium chloride or sodium sulphate.

Water-soluble metal salt in agent D is the metallic salt for allowing in cosmetics to use, and is ferrous sulfate, zinc sulfate, sulphur One or more in sour aluminium, lanthanum chloride and cerium chloride.

Wherein, agent C can not long term storage in the basic conditions because agent C stability can decline under alkalescence condition, in Property under the conditions of agent C it is most stable, therefore agent B and agent C are separately able to ensure that the hair dye of the present invention can carry out long period storage Deposit, extend the shelf life.If agent A and agent B are mixed, the hydrogen peroxide in agent A is easily decomposed, therefore by agent A Composition and agent B in composition separate, be prevented from merge storage tape come adverse effect, extend the shelf life.If agent C Mixed with agent D, in storage process, with the metal ion in agent D complex reaction can occur for the natural pigment in agent C, Natural pigment member becomes big, during dyeing, and the scale layer that natural pigment member is more difficult to diffuse through hair enters cortical layer, therefore will The composition in composition and agent D in agent C is separated, and equally be also prevent and is merged the adverse effect that storage tape is come, extends the shelf life.

The invention also discloses the hair colouring methods using above-mentioned alkalescence myrobalan pigment hair dye, enter according to the following steps successively OK：

During hair dyeing, agent A, agent B, agent C and agent D use volume ratio are：3-5：4-6：4-6：4-6, volume ratio preferably is 4：5：5：5.

Finally, Hair grooming clear water is cleaned up, completes hair dye.

Embodiment 1

Agent A

Hydrogen peroxide 6%；

Surplus is deionized water.

Agent B

Activation of Hydrogen Peroxide Solution agent 1%；

Hydroxyethyl cellulose 10%；

Polyethylene glycol 200 7%；

Glycerine 3%；

Surplus is water；

It is 10 with sodium carbonate regulation pH value.

Agent C

Myrobalan's pigment 10%；

Accelerant sodium sulphate 5%；

Hydroxyethyl cellulose 5%；

Surplus is water.

Agent D

Ferrous sulfate 4%；

Polyethylene glycol 200 5%；

Hydroxyethyl cellulose 5%；

Surplus is water.

Agent A, agent B, agent C and agent D component unit are mass percent.

In hair dye, agent A, agent B, agent C and agent D use volume ratio are：4：5：5：5

First agent A is well mixed with agent B, is equably applied on hair, 30min is kept under the conditions of 45 DEG C；Agent C is uniformly applied again Smear on hair, 10min is kept at room temperature, be warming up to 45 DEG C, keep 40min, hair is rinsed with clear water；Then, it is agent D is uniform It is applied on hair, 25min is kept under the conditions of 45 DEG C；Finally, by Hair grooming clear water wash clean, the present embodiment contaminates pitch-black Hair.

Wherein, the effect of Activation of Hydrogen Peroxide Solution agent is reduction Activation of Hydrogen Peroxide Solution energy, promotes decomposing hydrogen dioxide solution, and hair strength is damaged Wound is small, it is preferred to use the DM-1430 type Activation of Hydrogen Peroxide Solution agent of Guangdong Demei Fine Chemical Co., Ltd.'s production.

Embodiment two

Agent A

Hydrogen peroxide 10%；

Surplus is deionized water；

Agent B

Activation of Hydrogen Peroxide Solution agent 2%；

Imperial glue 6%；

Propane diols 5%；

Surplus is water；

It is 9.5 with sodium carbonate regulation pH value；

Agent C

Myrobalan's pigment 4%；

Accelerant sodium chloride 3%；

Imperial glue 3%；

Surplus is water；

Agent D

Zinc sulfate 1%；

Glycerine 2%；

Imperial glue 4%；

Surplus is water；

Agent A, agent B, agent C and agent D component unit are mass percent.

In hair dye, agent A, agent B, agent C and agent D use quality ratio are：3：4：4：4.

First agent A is well mixed with agent B, is equably applied on hair, 20min is kept under the conditions of 40 DEG C；It is again that agent C is equal It is even to be applied on hair, 10min is kept at room temperature, 40 DEG C are warming up to, 50min is kept, and hair is rinsed with clear water；Then, by agent D Uniformly it is applied on hair, 30min is kept under the conditions of 40 DEG C；Finally, by hair wash clean.The present embodiment contaminates to obtain yellowish-brown Hair.

Embodiment three

Agent A

Hydrogen peroxide 8%；

Surplus is deionized water；

Agent B；

Activation of Hydrogen Peroxide Solution agent 1.5%；

Methylcellulose 8%；

Propane diols 3%；

Polyethylene glycol 200 3%；

Surplus is water；

It is 9 with sodium acid carbonate regulation pH value；

Agent C

Myrobalan's pigment 6%；

Accelerant sodium sulphate 4%；

Methylcellulose 4%；

Surplus is water；

Agent D；

Aluminum sulfate 2%；

Propane diols 3%；

Methylcellulose 4%；

Dextrin 2%；

Surplus is water；

Agent A, agent B, agent C and agent D component unit are mass percent.

In hair dye, agent A, agent B, agent C and agent D use quality ratio are：5：6：6：4.

First agent A is well mixed with agent B, is equably applied on hair, 25min is kept under the conditions of 43 DEG C；It is again that agent C is equal It is even to be applied on hair, 10min is kept at room temperature, 50 DEG C are warming up to, 30min is kept, and hair is rinsed with clear water；Then, by agent D Uniformly it is applied on hair, 20min is kept under the conditions of 50 DEG C；Finally, by hair wash clean.The present embodiment contaminates isabelline Hair.Isabelline mass-tone tuningout yellow, filemot mass-tone tuningout brown.

Example IV

Agent A

Hydrogen peroxide 7%；

Surplus is deionized water；

Agent B

Activation of Hydrogen Peroxide Solution agent 1%；

Guar gum 9%；

Polyethylene glycol 200 9%；

Surplus is water；

It is 9.5 with sodium carbonate regulation pH value；

Agent C

Myrobalan's pigment 8%；

Accelerant sodium chloride 4%；

Guar gum 4%；

Surplus is water；

Agent D

Lanthanum chloride 3%；

Polyethylene glycol 200 4%；

Guar gum 5%；

Surplus is water；

Agent A, agent B, agent C and agent D component unit are mass percent.

In hair dye, agent A, agent B, agent C and agent D use quality ratio are：5：5：5：5.

First agent A is well mixed with agent B, is equably applied on hair, 23min is kept under the conditions of 45 DEG C；It is again that agent C is equal It is even to be applied on hair, 10min is kept at room temperature, 47 DEG C are warming up to, 35min is kept, and hair is rinsed with clear water；Then, by agent D Uniformly it is applied on hair, 23min is kept under the conditions of 47 DEG C；Finally, by hair wash clean.The present embodiment contaminates to obtain yellowish-brown Hair, compared with Example 2, contaminate the gold-tinted of hair becomes apparent from.

Embodiment five

Agent A

Hydrogen peroxide 9%；

Surplus is deionized water；

Agent B

Activation of Hydrogen Peroxide Solution agent 2%；

Dextrin 3%；

Imperial glue 4%；

Glycerine 7%；

Surplus is water；

It is 9 with sodium acid carbonate and sodium carbonate regulation pH value；

Agent C

Myrobalan's pigment 7%；

Accelerant sodium sulphate 3%；

Dextrin 5%；

Surplus is water；

Agent D

Cerium chloride 2%；

Ferrous sulfate 2%；

Glycerine 3%；

Dextrin 3%；

Imperial glue 3%；

Surplus is water；

Agent A, agent B, agent C and agent D component unit are mass percent.

In hair dye, agent A, agent B, agent C and agent D use quality ratio are：5：5：6：6.

First agent A is well mixed with agent B, is equably applied on hair, 27min is kept under the conditions of 42 DEG C；It is again that agent C is equal It is even to be applied on hair, 10min is kept at room temperature, 43 DEG C are warming up to, 45min is kept, and hair is rinsed with clear water；Then, by agent D Uniformly it is applied on hair, 28min is kept under the conditions of 43 DEG C；Finally, by hair wash clean.The present embodiment contaminates to obtain brown Hair.

Above example is only used to illustrative and not limiting technical scheme, although with reference to above-described embodiment to this hair It is bright to be described in detail, it will be understood by those within the art that：Still the present invention can be modified or be waited With replacement, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should cover the power in the present invention Among sharp claimed range.

Claims

1. alkalescence myrobalan's pigment hair dye, it is characterised in that：Including agent A, agent B, agent C and agent D；

Agent A includes hydrogen peroxide 6% ~ 10%, and surplus is deionized water；

Agent A, agent B, agent C and agent D component unit are mass percent.

2. alkalescence myrobalan pigment hair dye according to claim 1, it is characterised in that：Thickening in agent B, agent C and agent D Agent is the one or more in dextrin, methylcellulose, hydroxyethyl cellulose, imperial glue and guar gum.

3. alkalescence myrobalan pigment hair dye according to claim 1, it is characterised in that：Swelling agent in agent B and agent D is One or more in propane diols, glycerine and polyethylene glycol 200.

4. alkalescence myrobalan pigment hair dye according to claim 1, it is characterised in that：Agent C accelerant is sodium chloride Or sodium sulphate.

5. alkalescence myrobalan pigment hair dye according to claim 1, it is characterised in that：Water-soluble metal salt in agent D For the one or more in ferrous sulfate, zinc sulfate, aluminum sulfate, lanthanum chloride and cerium chloride.

6. the hair colouring methods of alkalescence myrobalan's pigment hair dye any one of usage right requirement 1 to 5, it is characterised in that according to It is secondary to carry out according to the following steps：

Finally, Hair grooming clear water is cleaned up, completes hair dye.

7. hair colouring methods according to claim 6, it is characterised in that：In hair dye, agent A, agent B, agent C and agent D make It is with volume ratio：3-5：4-6：4-6：4-6.

8. hair colouring methods according to claim 6, it is characterised in that：In hair dye, agent A, agent B, agent C and agent D make It is with volume ratio：4：5：5：5.