CN107183046A - A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide - Google Patents
A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide Download PDFInfo
- Publication number
- CN107183046A CN107183046A CN201610144272.8A CN201610144272A CN107183046A CN 107183046 A CN107183046 A CN 107183046A CN 201610144272 A CN201610144272 A CN 201610144272A CN 107183046 A CN107183046 A CN 107183046A
- Authority
- CN
- China
- Prior art keywords
- phosphorus
- insect amide
- worm
- cyanogen insect
- chlorine fluorine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/44—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing at least one carboxylic group or a thio analogue, or a derivative thereof, and a nitrogen atom attached to the same carbon skeleton by a single or double bond, this nitrogen atom not being a member of a derivative or of a thio analogue of a carboxylic group, e.g. amino-carboxylic acids
- A01N37/46—N-acyl derivatives
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N37/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
- A01N37/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof
- A01N37/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group —CO—N<, e.g. carboxylic acid amides or imides; Thio analogues thereof containing the group; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/06—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings
- A01N43/12—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom five-membered rings condensed with a carbocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/34—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom
- A01N43/40—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one nitrogen atom as the only ring hetero atom six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/48—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
- A01N43/56—1,2-Diazoles; Hydrogenated 1,2-diazoles
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/90—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/24—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing the groups, or; Thio analogues thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N51/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds having the sequences of atoms O—N—S, X—O—S, N—N—S, O—N—N or O-halogen, regardless of the number of bonds each atom has and with no atom of these sequences forming part of a heterocyclic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N53/00—Biocides, pest repellants or attractants, or plant growth regulators containing cyclopropane carboxylic acids or derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/16—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing heterocyclic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N63/00—Biocides, pest repellants or attractants, or plant growth regulators containing microorganisms, viruses, microbial fungi, animals or substances produced by, or obtained from, microorganisms, viruses, microbial fungi or animals, e.g. enzymes or fermentates
- A01N63/30—Microbial fungi; Substances produced thereby or obtained therefrom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Zoology (AREA)
- General Health & Medical Sciences (AREA)
- Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Environmental Sciences (AREA)
- Microbiology (AREA)
- Mycology (AREA)
- Biotechnology (AREA)
- Virology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide.The invention discloses a kind of Pesticidal combination containing two kinds of active components, the first described active component is chlorine fluorine cyanogen insect amide, and second active ingredient is selected from compounds such as nicotinic insecticide, organophosphorus insecticides, carbamate insecticides, urea insecticide, biological source insecticide, biological insecticides, pyrethroid insecticides and tebufenpyrads.The Pesticidal combination that the present invention is provided is suitable for preventing and treating striped rice borer, planthopper, cabbage caterpillar and red spider.
Description
Technical field
The invention belongs to pesticide field, it is related to a kind of composition pesticide of containing chlorine fluorine cyanogen insect amide.
Background technology
The resistance problem of agricultural pests is a global problem.With the continuity of Chemical Control of Harmful Insects, the increasing of Pesticide use amount
Plus with unscientific use agricultural chemicals, pest resistance is increasingly serious, and the pest species for producing resistance are on the increase.Particularly to agricultural
The mite class for causing harm serious and Lepidoptera class pest are produced, resistance level is higher, and resistance development speed is relatively fast.Meanwhile, it is high-strength
The use agricultural chemicals of degree, causes that Residual Pesticides in Farm Produce is exceeded, environmental pollution serious and peasant's drug cost increase etc., is unfavorable for
Agricultural sustainable development.In addition, the use of single agricultural chemicals is easier to cause the resistance to the action of a drug.By by different pesticide species mixtures, sieving
Rational formula is selected, actual prevention effect can be effectively improved, dosage is reduced, reduces cost, delay the production of pest resistance to insecticide
It is raw, extend the service life of medicament, be also a kind of important means of integrated pest management.Therefore, research and develop efficiently, low toxicity,
The pesticide and Recompounded pesticide of environmental protection have positive effect to agricultural sustainable development.
Chlorine fluorine cyanogen insect amide, chemical name：The chloro- N of 3-1- (2- methyl -4- sevoflurane isopropyls base)-N2- (1- first
Base -1- cyano ethyls) phthalic amide (test code number：ZJ4042), be Zhejiang Provincial Chemical Engineering Research Inst voluntarily develop it is new
Type insecticide, shown in structural formula following (I)：
The insecticide belongs to new phthalic amide insecticides, by activating calcium release channel in blue Buddhist nun's alkali recipient cell, causes storage
The runaway release of calcium ion, is the compounds for acting on blue Buddhist nun alkali (Ryanodine) acceptor of insect cell few in number at present.
There is wide spectrum preventive effect to lepidoptera pest, produced with existing insecticide no interactions resistance, be extremely suitable for existing insecticide and produce resistance
Insect preventing and treating.
Drug cost is higher when chlorine fluorine cyanogen insect amide is used alone, and its popularization and application is limited to a certain extent, and long-term independent
It is continuously increased using pest resistance degree is easily caused.By the way that chlorine fluorine cyanogen insect amide and other insecticides are compounded, Neng Gouyou
Effect reduces cost and slows down pest resistance to insecticide, has positive effect for the exploitation of efficient, low toxicity, environment-protection pesticide.
The content of the invention
It is an object of the invention to provide a kind of Pesticidal combination, with efficient, low toxicity, lasting period length, farming can be effectively prevented and treated
The characteristics of thing insect.
The present invention provides following technical scheme：
A kind of Pesticidal combination, the composition includes two kinds of active components, and the first active component is chlorine fluorine cyanogen insect amide, the
Two kinds of active components are selected from least one of following compound：
Nicotinic insecticide, organophosphorus insecticides, carbamate insecticides, urea insecticide, biological source insecticide,
Biological insecticides, pyrethroid insecticides, tebufenpyrad, Tifatol, CGA 183893, flufenzine, ethiprole, ethiprole,
Phonetic worm amine, butene-fipronil, pyridine MTI-446, pyridine pyrazoles worm amine, triprene, acetyl worm nitrile, acrylonitrile, pyridine mutter the third worm of ring ester,
Fluacrypyrim, furan tebufenozide, pyridalyl, sulfime ether, mite killing thioether, thiophene worm aldehyde, fluorine worm carbonic ester, Citrazon, bromine mite
Ester, tebufenpyrad, fenpyroximate, hydramethylnon, sulfluramid, chlorfenizon, fluoraracide, sufluoxime and Fluenyl.
As preferred mode, above-mentioned nicotinic insecticide is preferably imidaclothiz and/or sends worm pyridine.
As preferred mode, above-mentioned organophosphorus insecticides is selected from isofenphos, isocarbophos, Isofenphos methyl, methyl paddy sulphur
Phosphorus, triazotion, methylpyridine phosphorus, chlorine pyrazoxon, chlorophoxim, Actellic, methidathion, cadusafos, chlorethoxyfos,
It is sub- that chlormephos, sulfur-phosphor, chlorpyrifos-methyl, demeton, demeton-methyl, demeton-methyl sulfone, methyl sulphur inhale phosphorus, chlorine
Amine sulphur phosphorus, BFPO, Carbicron, Ethodan, Entex, lythidathion, cyanogen imidazoles sulphur phosphorus, Afos, Menite, imines
Sulphur phosphorus, zolone, propetamphos, pyraclofos, desinsection bisgallic acid, terbufos, oxazole worm phosphorus, vamidothion, mecarphon,
Menazon, fosmethilan, chloramine phos, Citram, chlorothion, cyanthoate, Toyodan, quinalphos, Fudithion, dioxathion,
S-seven, Fonofos, formothion, fosmethilan, fosthietan, hexamethylene sulphur phosphorus, isazofos, aphidan, fensulfothion,
Ethoate methyl, propylamine phosphorus, isothioate, iodfenphos, S-seven, chlorazol worm phosphorus, teptophos, pyridine worm phosphorus, butenylamine phosphorus, ethyl
Phosfolan, nichlorfos, Cytrolane, 2-dichloroethylk dimethyl phosphate, the first and second sulfone phosphorus, Kayaphos, prothoate, thiophene chlorine phosphorus, sulfotep, eight first
Phosphorus, sophamide, sulprofos, Pyrimicarb sulphur phosphorus, Jia Ji quinalphoses, methyl trithion, Synergistic Phosphorus, Di-captan, fruit mite phosphorus,
Naphthylamines phosphorus, special Pyrimitate, worm phosphorus in heptan.
As preferred mode, above-mentioned carbamate insecticides be selected from Aldicarb, aldoxycarb, fenothiocarb, allyxycarb,
Dimethyl phenyl carbamate, alanycarb, fenoxycarb, dimetan, nitrilacarb, Evil worms prestige, poisonous insect prestige, ethiofencarb, furathiocarb, methiocarb,
Aphox, triaguron, thiodicarb, Meobal, sok, allyxycarb, metalkamate, Talcord, tetrachlorvinphos, Toxamate,
Ethylbenzene prestige, amine first prestige, quinoline prestige, furadan, first sulphur benzene prestige, MTMC, prothiocarb, thiofanox, trifluoro methoxy prestige, go out
Evil prestige, methyl poisonous insect prestige, malicious mite prestige, Cosban.
As preferred mode, above-mentioned urea insecticide be selected from suppression food hydrazine, bistrifluron, flucycloxuron, penfluron, chloromethiuron,
Chlorourea is killed, noviflumuron, novaluron.
As preferred mode, above-mentioned biological source insecticide is selected from rotenone, nimbin, matrine, Osthole.
As preferred mode, it is many that above-mentioned biological insecticides are selected from Dipel, beauveria bassiana, bacillus, noctuid core
Hand over precursor virus.
As preferred mode, above-mentioned pyrethroid insecticides is selected from Permethrin, tetramethrin, valerate, high suitable chlorine cyanogen chrysanthemum
Ester, dichloro alkyne valerate, thiophene furan chrysanthemum ester, silafluofene, resmethrin, phenothrin, allethrin, Tefluthrin, second
Cyano chrysanthemate, cyfloxylate, chlorofluorobenzene chrysanthemum ester, chlorine fenvalerate, trifluoro lambda-cyhalothrin, dimefluthrin, tetrafluoro benzyl
Ethofenprox, the third Flumethrin, bromine fluorine ethofenprox, fluorine chlorine ether chrysanthemum ester, tralomethrin, transfluthrin, Chinese and Western chrysanthemum ester, furethrin,
Speed chrysanthemum ester, chlorine decis, anti-Permethrin, anti-Chryson, trifluoro ethofenprox.
Can exist in any proportion between the Pesticidal combination that the present invention is provided, two kinds of active components.Preferably, described
A kind of weight proportion of active component and second active ingredient is 10~50:0.5~5.It may further be preferable that described first
The weight proportion for planting active component and second active ingredient is 10~20:1~2.
The Pesticidal combination that the present invention is provided can also further contain mineral oil and/or insect growth regulator, IGR.Preferably,
The insect growth regulator, IGR is selected from chlorine tebufenozide, hydroprene, kinoprene, methoprene.
Present invention also offers a kind of insecticide for agricultural pests, the insecticide is by weight containing 5~90% desinsection group
Compound, remaining is agriculturally acceptable carrier and auxiliary agent.Preferably, the insecticide is killed containing 5~40% by weight
Worm composition.
Carrier of the present invention can be solid or liquid, and being generally used for preparing any carrier of pesticide agent composition can use.
Suitable solid carrier includes：Mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance includes silicic acid
Salt, carbonate, Sulfates and oxide-based.Silicates such as kaolin, sepiolite, nacrite, montmorillonite,
Mica, vermiculite, pyrophyllite, talcum.Carbonate is for example：Calcium carbonate, dolomite.Sulfates such as ammonium sulfate, sodium sulphate,
Calcium sulfate.Oxide-based such as quick lime, magnesium lime, diatomite.Plant is for example：Citrus pulp, corncob cellulose, rice husk powder,
Rice husk, big soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class such as winnofil hydrate, winnofil,
White carbon.Inorganic salts such as potassium chloride, sodium chloride.
Liquid-carrier includes water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilising and antifreeze effect.
Suitable organic solvent includes aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons；Chloro fat
Hydrocarbon, such as vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and many chloroethanes；Aliphatic hydrocarbon, such as oil evaporate
Point, hexamethylene, light mineral oil and paraffin.Alcohols such as methanol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol,
Propane diols, glycerine, fatty alcohol etc.；Ethers such as Propylene Glycol ether, ethohexadiol ether, petroleum ether.Ketone such as third
Ketone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and isophorone, N- methyl-pyrrolidons；Special solvent also has dimethyl
Formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile；Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be independent
Use, can also be used in mixed way, can also be mixed together with water.
Auxiliary agent of the present invention can include in surfactant, defoamer, thickener, suspending agent and antifreezing agent as needed
One or more, other auxiliary agents that the industry is commonly used can also be included as needed.
Surfactant can be emulsifying agent, dispersant, stabilizer or wetting agent；It can be ionic or non-ionic.
Suitable surfactant includes：The sodium salt and calcium salt of polyacrylic acid and lignin sulfonic acid；Contain at least 12 carbon atoms in molecule
Aliphatic acid or fatty amine and oxirane and/expoxy propane polycondensation product；Glycerine, dodecanol -1, tetradecanol -1, mountain
The fatty acid ester of pears alcohol, sucrose or pentaerythrite；And they with oxirane and/or expoxy propane polycondensation product；Their contracting
The sulfate or sulfonate of poly- product；At least alkali metal or alkaline-earth metal of the sulfuric acid containing 10 carbon atoms or sulfonic acid in the molecule
Salt, preferably sodium salt, such as lauryl sodium sulfate, Teepol, the sodium salt of sulfonated castor oil, alkylaryl sodium sulfonate
And neopelex；The copolymer of the polymer of oxirane, oxirane and expoxy propane.
Emulsifying agent includes nonionic emulsifier and anionic emulsifier.The preferred NPE of nonionic emulsifier,
AEO, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, terminal hydroxy group polyoxy second
Alkene polyethenoxy ether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic
Emulsifying agent mainly includes calcium dodecyl benzene sulfonate, three phenethyl phenol polyoxy ether phosphate amine salts, NPE phosphorus
Acid esters amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention includes：Acrylate homopolymer sodium salt, Malaysia acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product sodium salt,
Rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, three phenethyls
One or more in phenol polyethenoxy ether phosphate, AEO phosphoric acid, p-hydroxyphenyl lignin sulfonic acid sodium salt.
Wetting agent of the present invention includes：AEO, naphthalene sulfonate, lauryl sodium sulfate, alkyl phenol tree
One or both of fat polyoxyethylene ether sulfate combination of the above.
Thickener of the present invention include xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, Arabic gum,
One or more in gelatin, polyvinyl alcohol.Defoamer of the present invention is preferably：Bubble enemy, silicone, C8~10Fatty alcohol,
C10~20Saturated fat acids and acid amides etc..
It is outstanding that Pesticidal combination of the present invention can be configured to suspending agent, wettable powder, oil according to method generally in the art
Agent, missible oil or water dispersible granules.
Pesticidal combination of the present invention is suitable at least one of preventing and treating striped rice borer, planthopper, cabbage caterpillar and red spider.
It is particularly suitable for preventing and treating paddy rice and striped rice borer, planthopper, cabbage caterpillar and red spider in vegetables.
Pesticidal combination of the present invention has following advantage compared with prior art：
(1) two kinds of pesticide compositionals show excellent synergistic effect, mixed combination in certain ratio range in composition
The insecticidal effect of thing is significantly improved compared with its single dose, and with quick-acting is good and the characteristics of long lasting effect；
(2) dosage is reduced, peasant's drug cost is reduced；
(3) reasonably mixture is carried out using two kinds of agricultural chemicals mode of action different to insect, the different mechanism of action, both extended
In the Pesticide use life-span, delay the generation of pest resistance to insecticide again.
Embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these specific implementations
Mode.One skilled in the art would recognize that all alternative present invention encompasses what is potentially included in Claims scope
Scheme, improvement project and equivalents.
In following examples, unless otherwise indicated, all percentages are weight percentage.
Embodiment 1 (20% imidaclothiz chlorine fluorine cyanogen insect amide suspending agent)
By imidaclothiz 18%, chlorine fluorine cyanogen insect amide 2%, emulsifying agent 1601# (styrylphenol polyoxyethylene poly-oxygen propylene aether)
10%th, dispersant SOPA-270 4%, bentonite 2%, xanthans 0.1%, organic silicon defoamer 0.4%, the and of glycerine 5%
Surplus is the formula of deionized water, and each component is crushed in advance, adds in sand mill and grinds, and is adjusted after high shear mixing
With obtained 20% imidaclothiz chlorine fluorine cyanogen insect amide suspending agent.
Obtained 20% imidaclothiz chlorine fluorine cyanogen insect amide suspending agent is prevented and treated for rice hoppers.20% imidaclothiz chlorine fluorine
Cyanogen insect amide suspending agent is watered even spraying by 10 grams/acre in rice hoppers nymph occurance peak, gets well heat 7 days within 3 days after medicine
Preventive effect be respectively 91.5% good heat 94.7%.Dispenser in the same way, compares the imidaclothiz suspending agent (formulation rate of single dose 20%
For 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), the preventive effect of 3 days point after medicine
Not Wei 85.7% and 22.4%, the preventive effect of 7 days is respectively 87.5% and 23.7% after medicine.Imidaclothiz and chlorine fluorine cyanogen insect amide are mixed
With rear synergistic effect substantially, preventive effect is better than single dose.
Embodiment 2 (40% chlorpyrifos-methyl chlorine fluorine cyanogen insect amide water-dispersible granules)
By chlorpyrifos-methyl 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%,
Polyethylene glycol 3% and surplus are kaolinic formula, and 40% is made after each component is carried out into dry pulverization process, granulation, drying, screening
Chlorpyrifos-methyl chlorine fluorine cyanogen insect amide water-dispersible granules.
Obtained 40% chlorpyrifos-methyl chlorine fluorine cyanogen insect amide water-dispersible granules are prevented and treated for cabbage pieris.40% first
Base chlopyrifos chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 10 grams/acre in larva occurrence in peak period, in medicine
The preventive effect of 3 days and 7 days is respectively 92.2% and 93.7% afterwards.Dispenser in the same way, compares the chlorpyrifos-methyl of single dose 20%
Suspending agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), after medicine
The preventive effect of 3 days is respectively 71.4% and 82.4%, and the preventive effect of 7 days is respectively 72.9% and 83.4% after medicine.Chlorpyrifos-methyl
With synergistic effect after chlorine fluorine cyanogen insect amide mixture substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and medication
Amount is than single dose reduction.
Embodiment 3 (70% thiodicarb chlorine fluorine cyanogen insect amide water-dispersible granules)
By thiodicarb 55%, chlorine fluorine cyanogen insect amide 15%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, poly- second
Glycol 3% and surplus are kaolinic formula, and 70% sulphur pair is made after each component is carried out into dry pulverization process, granulation, drying, screening
Prestige chlorine fluorine cyanogen insect amide water-dispersible granules.
Obtained 70% thiodicarb chlorine fluorine cyanogen insect amide water-dispersible granules are prevented and treated for paddy rice rice leaf roller.70% sulphur
Double prestige chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 10 grams/acre in rice leaf roller low instar larvae full incidence period,
The preventive effect of 7 days and 14 days is respectively 87.6% and 91.5% after medicine.Dispenser in the same way, compares the thiodicarb of single dose 20%
Suspending agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), after medicine
The preventive effect of 7 days is respectively 71.3% and 84.9%, and the preventive effect of 14 days is respectively 73.6% and 86.7% after medicine.Thiodicarb and chlorine
Substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose for synergistic effect after fluorine cyanogen insect amide mixture.
Embodiment 4 (10% beauveria bassiana chlorine fluorine cyanogen insect amide wettable powder)
By beauveria bassiana 5%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, poly-
Ethylene glycol 3% and surplus are kaolinic formula, and 10% ball is made after each component is carried out into dry pulverization process, granulation, drying, screening
Beauveria bassiana chlorine fluorine cyanogen insect amide wettable powder.
Obtained 10% beauveria bassiana chlorine fluorine cyanogen insect amide wettable powder is prevented and treated for cabbage pieris.10% ball spore
Muscardine chlorine fluorine cyanogen insect amide wettable powder is watered even spraying by 10 grams/acre in low instar larvae occurrence in peak period, in medicine
The preventive effect of 7 days and 14 days is respectively 91.3% and 94.2% afterwards.Dispenser in the same way, the control ball spore of single dose 10% is stiff in vain
Bacterium wettable powder (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre),
The preventive effect of 7 days is respectively 52.9% and 85.1% after medicine, and the preventive effect of 14 days is respectively 53.4% and 86.7% after medicine.
Embodiment 5 (20% suppression food hydrazine chlorine fluorine cyanogen insect amide oil suspending agent)
By suppression food hydrazine 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether
Phosphate 3%, organobentonite 1% and methyl oleate are mended to 100% formula, and each component is well mixed, and are sanded to certain grain
20% suppression food hydrazine chlorine fluorine cyanogen insect amide oil suspending agent is obtained behind footpath.
Obtained 20% suppression food hydrazine chlorine fluorine cyanogen insect amide oil suspending agent is prevented and treated for apple skin worm.20% suppression food hydrazine chlorine fluorine cyanogen
Insect amide oil suspending agent is watered even spraying by 10 mg/kgs in larva occurance peak, the preventive effect of 3 days and 7 days point after medicine
Wei 92.5% and 95.7%.Dispenser in the same way, the control suppression food of single dose 20% hydrazine suspending agent (formulation rate is 15 milligrams/
Kilogram) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 mg/kgs), the preventive effect of 3 days is respectively after medicine
72.4% and 85.6%, the preventive effect of 7 days is 74.3% and 88.7% after medicine.Synergy after suppression food hydrazine and chlorine fluorine cyanogen insect amide mixture
Effect is obvious, and preventive effect is better than single dose.
Embodiment 6 (20% tetramethrin chlorine fluorine cyanogen insect amide missible oil)
By tetramethrin 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, three phenethyl phenol polyethenoxy ethers 6%,
NMP 8% and the formula that surplus is dimethylbenzene, obtain 20% tetramethrin chlorine fluorine cyanogen insect amide breast after each component is mixed evenly
Oil.
Obtained 20% tetramethrin chlorine fluorine cyanogen insect amide missible oil is prevented and treated for Laphygma exigua Hubner.20% tetramethrin chlorine fluorine cyanogen
Insect amide missible oil is watered even spraying by 10 grams/acre in larva occurance peak, and 3 days and 7 days preventive effects are respectively 94.5% after medicine
With 96.0%.Dispenser in the same way, control single dose 20% tetramethrin suspending agent (formulation rate is 15 grams/acre) and 20% chlorine
Fluorine cyanogen insect amide suspending agent (formulation rate be 10 grams/acre), the preventive effect of 3 days is respectively 71.9% and 80.6% after medicine,
The preventive effect of 7 days is 73.7% and 86.7% after medicine.Substantially, preventive effect is better than for synergistic effect after tetramethrin and chlorine fluorine cyanogen insect amide mixture
Single dose.
Embodiment 7 (20% fenpyroximate chlorine fluorine cyanogen insect amide oil suspending agent)
By fenpyroximate 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether
Phosphate 3%, machine bentonite 1% and methyl oleate are mended to 100% formula, and each component is well mixed, and are sanded to certain particle diameter
After obtain 20% fenpyroximate chlorine fluorine cyanogen insect amide oil suspending agent.
Obtained 20% fenpyroximate chlorine fluorine cyanogen insect amide oil suspending agent is prevented and treated for citrus red mite.20% fenpyroximate chlorine fluorine cyanogen
Insect amide oil suspending agent is watered even spraying by 10 grams/acre in citrus red mite occurance peak, 3 days and 7 days preventive effects point after medicine
Wei 90.9% and 90.8%.Dispenser in the same way, control single dose 15% Enpyfoximate dispersant (formulation rate is 15 grams/acre)
With 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate be 10 grams/acre), the preventive effect of 3 days is respectively 73.8% and 11.7% after medicine,
The preventive effect of 7 days is 72.8% and 9.8% after medicine.Agricultural insecticide spectrum can substantially be increased after fenpyroximate and chlorine fluorine cyanogen insect amide mixture,
Preventive effect is better than single dose.
Embodiment 8 (40% nimbin chlorine fluorine cyanogen insect amide wettable powder)
By nimbin 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, poly- second
Glycol 3% and surplus are kaolinic formula, each component are carried out 40% print chinaberry is made after dry pulverization process, granulation, drying, screening
Plain chlorine fluorine cyanogen insect amide wettable powder.
Obtained 40% nimbin chlorine fluorine cyanogen insect amide wettable powder is prevented and treated for wild cabbage diamondback moth.40% nimbin chlorine
Fluorine cyanogen insect amide wettable powder is watered even spraying by 10 grams/acre in low instar larvae occurrence in peak period, 7 days and 14 after medicine
It preventive effect is respectively 91.3% and 94.2%.Dispenser in the same way, (formulation rate is control single dose 20% nimbin emulsion
15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), the preventive effect of 7 days is respectively after medicine
72.9% and 85.1%, the preventive effect of 14 days is respectively 73.4% and 86.7% after medicine.After nimbin and chlorine fluorine cyanogen insect amide mixture
Substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose for synergistic effect.
Embodiment 9 (20% suppression food hydrazine chlorine fluorine cyanogen insect amide suspending agent)
By suppression food hydrazine 18%, chlorine fluorine cyanogen insect amide 2%, emulsifying agent 1601# (styrylphenol polyoxyethylene poly-oxygen propylene aether)
10%th, dispersant SOPA-270 4%, bentonite 2%, xanthans 0.1%, organic silicon defoamer 0.4%, glycerine 5% and remaining
The formula for deionized water is measured, each component is crushed in advance, adds in sand mill and grinds, is allocated after high shear mixing
20% suppression food hydrazine chlorine fluorine cyanogen insect amide suspending agent is made afterwards.
Obtained 20% suppression food hydrazine chlorine fluorine cyanogen insect amide suspending agent is prevented and treated for apple skin worm.20% suppression food hydrazine chlorine fluorine
Cyanogen insect amide suspending agent is watered even spraying by 10 mg/kgs in apple skin worm larva occurance peak, 3 days and 7 after medicine
It preventive effect is respectively 91.6% and 93.7%.Dispenser in the same way, 50 g/l of suppression food hydrazine dispersible agents of control single dose (are applied
Dose is 75 mg/kgs) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 mg/kgs), 3 after medicine
It preventive effect is respectively 70.4% and 84.8%, and the preventive effect of 7 days is respectively 72.1% and 85.4% after medicine.Suppression food hydrazine and chlorine fluorine
Substantially, preventive effect is better than single dose for synergistic effect after cyanogen insect amide mixture.
Embodiment 10 (40% thiodicarb chlorine fluorine cyanogen insect amide water-dispersible granules)
By thiodicarb 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%, poly- second
Glycol 3% and surplus are kaolinic formula, and 40% sulphur pair is made after each component is carried out into dry pulverization process, granulation, drying, screening
Prestige chlorine fluorine cyanogen insect amide water-dispersible granules.
Obtained 40% thiodicarb chlorine fluorine cyanogen insect amide water-dispersible granules are prevented and treated for apple skin worm.40% sulphur is double
Prestige chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 20 mg/kgs in larva occurrence in peak period, after medicine
3 days and 7 days preventive effects are respectively 90.6% and 93.2%.Dispenser in the same way, control 50 g/l of thiodicarbs of single dose are dispersible
Liquor (formulation rate is 75 mg/kgs) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 mg/kgs),
The preventive effect of 3 days is respectively 76.3% and 46.8% after medicine, and the preventive effect of 7 days is respectively 78.8% and 59.2% after medicine.Sulphur is double
Substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose, and use for synergistic effect after prestige and chlorine fluorine cyanogen insect amide mixture
Dose is than single dose reduction.
Embodiment 11 (70% pyridine MTI-446 chlorine fluorine cyanogen insect amide water-dispersible granules)
By pyridine MTI-446 55%, chlorine fluorine cyanogen insect amide 15%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%,
Polyethylene glycol 3% and surplus are kaolinic formula, and 70% is made after each component is carried out into dry pulverization process, granulation, drying, screening
Pyridine MTI-446 chlorine fluorine cyanogen insect amide water-dispersible granules.
Obtained 70% pyridine MTI-446 chlorine fluorine cyanogen insect amide water-dispersible granules are prevented and treated for cabbage pieris.70% pyrrole
Pyridine MTI-446 chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 10 grams/acre in cabbage caterpillar low instar larvae full incidence period,
7 days and 14 days preventive effects are respectively 91.1% and 95.0% after medicine.Dispenser in the same way, compares 50 g/l of pyridines of single dose
MTI-446 dispersible agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre),
The preventive effect of 7 days is respectively 81.1% and 84.3% after medicine, and the preventive effect of 14 days is respectively 82.2% and 86.6% after medicine.Pyrrole
Substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose for synergistic effect after pyridine MTI-446 and chlorine fluorine cyanogen insect amide mixture.
Embodiment 12 (40% beauveria bassiana chlorine fluorine cyanogen insect amide wettable powder)
By beauveria bassiana 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride 8%,
Polyethylene glycol 3% and surplus are kaolinic formula, and 40% is made after each component is carried out into dry pulverization process, granulation, drying, screening
Beauveria bassiana chlorine fluorine cyanogen insect amide wettable powder.
Obtained 40% beauveria bassiana chlorine fluorine cyanogen insect amide wettable powder is prevented and treated for cabbage pieris.40% ball spore
Muscardine chlorine fluorine cyanogen insect amide wettable powder is watered even spraying by 10 grams/acre in cabbage caterpillar low instar larvae occurrence in peak period,
The preventive effect of 7 days and 14 days is respectively 92.6% and 94.0% after medicine.Dispenser in the same way, compares 50 g/l of balls of single dose
Beauveria bassiana dispersible agent (formulation rate is 15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/
Mu), the preventive effect of 7 days is respectively 72.3% and 81.3% after medicine, and the preventive effect of 14 days is respectively 73.2% and 83.4% after medicine.
Substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than list for synergistic effect after beauveria bassiana and chlorine fluorine cyanogen insect amide mixture
Agent.
Embodiment 13 (20% ethiprole chlorine fluorine cyanogen insect amide oil suspending agent)
By ethiprole 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, tristyrylphenol polyoxyethylene ether
Phosphate 3%, organobentonite 1% and methyl oleate are mended to 100% formula, and each component is well mixed, and are sanded to certain grain
20% ethiprole chlorine fluorine cyanogen insect amide oil suspending agent is obtained behind footpath.
Obtained 20% ethiprole chlorine fluorine cyanogen insect amide oil suspending agent is prevented and treated for cotton boll worm.20% ethiprole chlorine fluorine cyanogen
Insect amide oil suspending agent is watered even spraying by 10 grams/acre in egg hatching peak period, and 3 days and 7 days preventive effects are respectively 86.2% after medicine
With 88.8%.Dispenser in the same way, 50 g/l of ethiprole dispersible agents of control single dose (formulation rate is 15 grams/acre)
With 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate be 10 grams/acre), the preventive effect of 3 days is respectively 73.2% and 59.6% after medicine,
The preventive effect of 7 days is 78.3% and 68.5% after medicine.Substantially, preventive effect is excellent for synergistic effect after ethiprole and chlorine fluorine cyanogen insect amide mixture
In single dose.
Embodiment 14 (20% pyridalyl chlorine fluorine cyanogen insect amide missible oil)
By pyridalyl 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, three phenethyl phenol polyethenoxy ethers 6%,
NMP 8% and the formula that surplus is dimethylbenzene, obtain 20% pyridalyl chlorine fluorine cyanogen worm acyl after each component is mixed evenly
Amine missible oil.
Obtained 20% pyridalyl chlorine fluorine cyanogen insect amide missible oil is prevented and treated for cotton boll worm.20% pyridalyl chlorine fluorine
Cyanogen insect amide oil suspending agent is watered even spraying by 10 grams/acre in larva occurance peak, the preventive effect difference of 3 days and 7 days after medicine
For 95.8% and 96.7%.Dispenser in the same way, (formulation rate is control single dose 50 g/l of pyridalyl dispersible agents
15 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), the preventive effect of 3 days is respectively after medicine
75.5% and 81.7%, the preventive effect of 7 days is 79.3% and 85.6% after medicine.Increase after pyridalyl and chlorine fluorine cyanogen insect amide mixture
Effect effect is obvious, and preventive effect is better than single dose.
Embodiment 15 (20% furan tebufenozide chlorine fluorine cyanogen insect amide missible oil)
By furan tebufenozide 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, three phenethyl phenol polyethenoxy ethers 6%,
NMP 8% and the formula that surplus is dimethylbenzene, obtain 20% furan tebufenozide chlorine fluorine cyanogen worm acyl after each component is mixed evenly
Amine missible oil.
Obtained 20% furan tebufenozide chlorine fluorine cyanogen insect amide missible oil is prevented and treated for rice-stem borer.20% furans worm acyl
Hydrazine chlorine fluorine cyanogen insect amide oil suspending agent is watered even spraying by 10 grams/acre in larva occurance peak, 3 days and 7 days anti-after medicine
Effect is respectively 91.9% and 94.8%.Dispenser in the same way, (formulation rate is 100 to control single dose 30% furan tebufenozide missible oil
Gram/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), the preventive effect of 3 days is respectively 69.5% after medicine
With 83.7%, the preventive effect of 7 days is 70.8% and 88.4% after medicine.Synergy is made after furan tebufenozide and chlorine fluorine cyanogen insect amide mixture
With obvious, preventive effect is better than single dose.
Claims (10)
1. a kind of Pesticidal combination, it is characterised in that the composition includes two kinds of active components, the first active component is chlorine fluorine cyanogen worm
Acid amides, second active ingredient is selected from least one of following compound：
Nicotinic insecticide, organophosphorus insecticides, carbamate insecticides, urea insecticide, biological source insecticide,
Biological insecticides, pyrethroid insecticides, tebufenpyrad, Tifatol, CGA 183893, flufenzine, ethiprole, ethiprole,
Phonetic worm amine, butene-fipronil, pyridine MTI-446, pyridine pyrazoles worm amine, triprene, acetyl worm nitrile, acrylonitrile, pyridine mutter the third worm of ring ester,
Fluacrypyrim, furan tebufenozide, pyridalyl, sulfime ether, mite killing thioether, thiophene worm aldehyde, fluorine worm carbonic ester, Citrazon, bromine mite
Ester, tebufenpyrad, fenpyroximate, hydramethylnon, sulfluramid, chlorfenizon, fluoraracide, sufluoxime and Fluenyl.
2. according to the Pesticidal combination described in claim 1, it is characterised in that：
The nicotinic insecticide is imidaclothiz and/or sends worm pyridine；
The organophosphorus insecticides be selected from isofenphos, isocarbophos, Isofenphos methyl, methyl azinphos-methyl, triazotion,
Methylpyridine phosphorus, chlorine pyrazoxon, chlorophoxim, Actellic, methidathion, cadusafos, chlorethoxyfos, chlormephos, sulfur-phosphor,
Chlorpyrifos-methyl, demeton, demeton-methyl, demeton-methyl sulfone, methyl sulphur inhale phosphorus, dialifos, BFPO, hundred
Control phosphorus, Ethodan, Entex, lythidathion, cyanogen imidazoles sulphur phosphorus, Afos, Menite, phosmet, zolone, alkene worm
Phosphorus, pyraclofos, desinsection bisgallic acid, terbufos, oxazole worm phosphorus, vamidothion, mecarphon, menazon, fosmethilan,
Chloramine phos, Citram, chlorothion, cyanthoate, Toyodan, quinalphos, Fudithion, dioxathion, S-seven, Fonofos,
It is formothion, fosmethilan, fosthietan, hexamethylene sulphur phosphorus, isazofos, aphidan, fensulfothion, ethoate methyl, propylamine phosphorus, different
Mix phosphorus, iodfenphos, S-seven, chlorazol worm phosphorus, teptophos, pyridine worm phosphorus, butenylamine phosphorus, ethyl phosfolan, nichlorfos,
Cytrolane, 2-dichloroethylk dimethyl phosphate, the first and second sulfone phosphorus, Kayaphos, prothoate, thiophene chlorine phosphorus, sulfotep, schradane, sophamide, sulprofos,
Pyrimicarb sulphur phosphorus, Jia Ji quinalphoses, methyl trithion, Synergistic Phosphorus, Di-captan, fruit mite phosphorus, naphthylamines phosphorus, special Pyrimitate,
Heptan worm phosphorus；
The carbamate insecticides be selected from Aldicarb, aldoxycarb, fenothiocarb, allyxycarb, dimethyl phenyl carbamate, alanycarb,
Fenoxycarb, dimetan, nitrilacarb, Evil worms prestige, poisonous insect prestige, ethiofencarb, furathiocarb, methiocarb, Aphox, triaguron,
Thiodicarb, Meobal, sok, allyxycarb, metalkamate, Talcord, tetrachlorvinphos, Toxamate, ethylbenzene prestige, amine first prestige,
Quinoline prestige, furadan, first sulphur benzene prestige, MTMC, prothiocarb, thiofanox, trifluoro methoxy prestige, aminocarb, methyl poisonous insect prestige,
Malicious mite prestige, Cosban；
The urea insecticide be selected from suppression food hydrazine, bistrifluron, flucycloxuron, penfluron, chloromethiuron, chlorourea kill, noviflumuron,
Novaluron；
The biological source insecticide is selected from rotenone, nimbin, matrine, Osthole；
The biological insecticides are selected from Dipel, beauveria bassiana, bacillus, hand over precursor virus noctuid core more；
The pyrethroid insecticides be selected from Permethrin, tetramethrin, valerate, alphacypermethrin, dichloro alkyne valerate,
Thiophene furan chrysanthemum ester, silafluofene, resmethrin, phenothrin, allethrin, Tefluthrin, cycloprothrin, cyfloxylate,
Chlorofluorobenzene chrysanthemum ester, chlorine fenvalerate, trifluoro lambda-cyhalothrin, dimefluthrin, tetrafluoro benzyl ethofenprox, the third Flumethrin, bromine
Fluorine ethofenprox, fluorine chlorine ether chrysanthemum ester, tralomethrin, transfluthrin, Chinese and Western chrysanthemum ester, furethrin, speed chrysanthemum ester, chlorine bromine cyanogen chrysanthemum
Ester, anti-Permethrin, anti-Chryson, trifluoro ethofenprox.
3. according to the Pesticidal combination described in claim 2, it is characterised in that described the first active component and second active ingredient
Weight proportion is 10~50:0.5~5.
4. according to the Pesticidal combination described in claim 3, it is characterised in that described the first active component and second active ingredient
Weight proportion is 10~20:1~2.
5. according to the Pesticidal combination described in claim 1, it is characterised in that the composition further contains mineral oil and/or elder brother
Worm growth regulator, the insect growth regulator, IGR is selected from chlorine tebufenozide, hydroprene, kinoprene, methoprene.
6. a kind of insecticide for agricultural pests, it is characterised in that the insecticide by weight containing 5~90% Pesticidal combination,
Remaining is agriculturally acceptable carrier and auxiliary agent.
7. according to the insecticide described in claim 6, it is characterised in that the insecticide is by weight containing 5~40% Pesticidal combination.
8. according to the insecticide described in claim 6, it is characterised in that the insecticide can be configured to suspending agent, wettable powder, oil
Suspension, missible oil or water dispersible granules.
9. according to the Pesticidal combination described in claim 1, it is characterised in that the Pesticidal combination be used to preventing and treating striped rice borer, planthopper,
At least one of cabbage caterpillar and red spider.
10. according to the Pesticidal combination described in claim 1, it is characterised in that the Pesticidal combination is used to prevent and treat in paddy rice and vegetables
Striped rice borer, planthopper, cabbage caterpillar and red spider.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610144272.8A CN107183046A (en) | 2016-03-14 | 2016-03-14 | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201610144272.8A CN107183046A (en) | 2016-03-14 | 2016-03-14 | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107183046A true CN107183046A (en) | 2017-09-22 |
Family
ID=59871536
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201610144272.8A Pending CN107183046A (en) | 2016-03-14 | 2016-03-14 | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107183046A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106538554A (en) * | 2016-09-29 | 2017-03-29 | 天峨县全盛蜂业科技有限公司 | A kind of miticide composition containing paichongding and chlorine fluorine cyanogen insect amide |
| CN106577665A (en) * | 2016-11-15 | 2017-04-26 | 佛山市盈辉作物科学有限公司 | Composition containing afidopyropen and cyhalodiamide |
| CN106879617A (en) * | 2017-04-17 | 2017-06-23 | 深圳诺普信农化股份有限公司 | A kind of Synergistic insecticidal compositions containing bistrifluron and its application |
| CN109221126A (en) * | 2018-09-26 | 2019-01-18 | 广西壮族自治区化工研究院 | A kind of insecticide composition and its preparation method and application |
| CN109265348A (en) * | 2018-10-31 | 2019-01-25 | 长乐巧通工业设计有限公司 | The compound gel pyrethrins and its manufacturing method of desert afforestation plantation |
| CN109293603A (en) * | 2018-10-31 | 2019-02-01 | 长乐巧通工业设计有限公司 | Field fish and water rice mixed breeding compounding mosquito-killing chrysanthemum ester and its manufacturing method |
| CN110024792A (en) * | 2019-05-21 | 2019-07-19 | 青岛东生药业有限公司 | Agricultural double-crossed Pesticidal combination and its application |
Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060166830A1 (en) * | 2002-05-02 | 2006-07-27 | Yoshihiro Matsuzaki | Phthalamide derivative, agricultural or horticultural insecticide, and method of use thereof |
| CN103250720A (en) * | 2013-05-02 | 2013-08-21 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorfluazuron and ZJ4042 |
| CN104054741A (en) * | 2014-06-24 | 2014-09-24 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104322502A (en) * | 2014-10-16 | 2015-02-04 | 浙江省化工研究院有限公司 | Pesticide composition containing cyhalodiamide |
| CN104430406A (en) * | 2014-12-02 | 2015-03-25 | 广西安泰化工有限责任公司 | Insecticidal composition containing cyhalodiamide and application of insecticidal composition |
| CN104472489A (en) * | 2014-11-26 | 2015-04-01 | 广东中迅农科股份有限公司 | Insecticidal composition containing pyridalyl and cyhalodiamide |
| CN105163582A (en) * | 2013-04-19 | 2015-12-16 | 拜耳作物科学股份公司 | Insecticidal synergistic combinations of phthaldiamide derivatives and fipronil or ethiprole |
| CN105263323A (en) * | 2013-04-19 | 2016-01-20 | 拜耳作物科学股份公司 | Insecticidal synergistic combinations of phthaldiamide derivatives and abamectin, emamectin, lepimectin or milbemectin |
| CN105307491A (en) * | 2013-04-19 | 2016-02-03 | 拜耳作物科学股份公司 | Active compound combinations having insecticidal properties |
-
2016
- 2016-03-14 CN CN201610144272.8A patent/CN107183046A/en active Pending
Patent Citations (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20060166830A1 (en) * | 2002-05-02 | 2006-07-27 | Yoshihiro Matsuzaki | Phthalamide derivative, agricultural or horticultural insecticide, and method of use thereof |
| CN105163582A (en) * | 2013-04-19 | 2015-12-16 | 拜耳作物科学股份公司 | Insecticidal synergistic combinations of phthaldiamide derivatives and fipronil or ethiprole |
| CN105263323A (en) * | 2013-04-19 | 2016-01-20 | 拜耳作物科学股份公司 | Insecticidal synergistic combinations of phthaldiamide derivatives and abamectin, emamectin, lepimectin or milbemectin |
| CN105307491A (en) * | 2013-04-19 | 2016-02-03 | 拜耳作物科学股份公司 | Active compound combinations having insecticidal properties |
| CN103250720A (en) * | 2013-05-02 | 2013-08-21 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorfluazuron and ZJ4042 |
| CN104054741A (en) * | 2014-06-24 | 2014-09-24 | 北京燕化永乐生物科技股份有限公司 | Insecticidal composition |
| CN104322502A (en) * | 2014-10-16 | 2015-02-04 | 浙江省化工研究院有限公司 | Pesticide composition containing cyhalodiamide |
| CN104472489A (en) * | 2014-11-26 | 2015-04-01 | 广东中迅农科股份有限公司 | Insecticidal composition containing pyridalyl and cyhalodiamide |
| CN104430406A (en) * | 2014-12-02 | 2015-03-25 | 广西安泰化工有限责任公司 | Insecticidal composition containing cyhalodiamide and application of insecticidal composition |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106538554A (en) * | 2016-09-29 | 2017-03-29 | 天峨县全盛蜂业科技有限公司 | A kind of miticide composition containing paichongding and chlorine fluorine cyanogen insect amide |
| CN106577665A (en) * | 2016-11-15 | 2017-04-26 | 佛山市盈辉作物科学有限公司 | Composition containing afidopyropen and cyhalodiamide |
| CN106879617A (en) * | 2017-04-17 | 2017-06-23 | 深圳诺普信农化股份有限公司 | A kind of Synergistic insecticidal compositions containing bistrifluron and its application |
| CN109221126A (en) * | 2018-09-26 | 2019-01-18 | 广西壮族自治区化工研究院 | A kind of insecticide composition and its preparation method and application |
| CN109265348A (en) * | 2018-10-31 | 2019-01-25 | 长乐巧通工业设计有限公司 | The compound gel pyrethrins and its manufacturing method of desert afforestation plantation |
| CN109293603A (en) * | 2018-10-31 | 2019-02-01 | 长乐巧通工业设计有限公司 | Field fish and water rice mixed breeding compounding mosquito-killing chrysanthemum ester and its manufacturing method |
| CN109265348B (en) * | 2018-10-31 | 2021-07-13 | 长乐巧通工业设计有限公司 | Compound gelled pyrethrin for desert greening planting and manufacturing method thereof |
| CN110024792A (en) * | 2019-05-21 | 2019-07-19 | 青岛东生药业有限公司 | Agricultural double-crossed Pesticidal combination and its application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107183046A (en) | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide | |
| CN104322502A (en) | Pesticide composition containing cyhalodiamide | |
| CN104663702B (en) | A kind of insecticide acaricide composition containing chrysanthemum ester insecticide | |
| CN103039450B (en) | Agricultural insecticidal composition containing spinosad and ZJ4042 | |
| CN104026143B (en) | Binary pesticide composition and uses thereof | |
| CN104738079A (en) | Binary insecticide composition and application thereof | |
| CN103250727B (en) | Agricultural insecticidal composition containing indoxacarb and ZJ4042 | |
| CN103250720B (en) | A kind of containing chlorfluazuron and ZJ4042 agricultural pesticide composition | |
| CN103039501B (en) | Agricultural insecticidal composition containing beta cypermethrin and ZJ4042 | |
| CN103314988A (en) | Insecticidal composition containing pyridalyl and synthetic pyrethroids | |
| CN104938511B (en) | A kind of Pesticidal combination containing Teflubenzuron and chlorine fluorine cyanogen insect amide | |
| CN107148973B (en) | A kind of Pesticidal combination containing Bifenazate and chlorine fluorine cyanogen insect amide | |
| CN104920412B (en) | A kind of Pesticidal combination containing flufenoxuron and chlorine fluorine cyanogen insect amide | |
| CN104145963B (en) | A kind of Pesticidal combination containing ether chrysanthemum ester and ZJ4042 | |
| CN104351238A (en) | Pesticide composition containing picoxystrobin and pyrethroids, preparation and application thereof | |
| CN105010365B (en) | Rice insecticidal and bactericidal composition | |
| CN102613236B (en) | Farm chemical composition containing chlorpyrifos and ZJ3265 | |
| CN110115268A (en) | A kind of composition pesticide containing Tolfenpyrad and fluopyram | |
| CN103250701B (en) | Agricultural insecticidal composition containing chlorfenapyr and ZJ4042 | |
| CN105028421B (en) | A kind of composition pesticide for rice pesticide-germicide | |
| CN104026146A (en) | Binary pesticide composition and its use | |
| CN102907438A (en) | Insecticidal composite containing ZJ3757 and pymetrozine | |
| CN103053545B (en) | Agricultural pesticide combination containing pymetrozine | |
| CN105660646A (en) | Agricultural insecticide composition and application thereof | |
| CN104957160B (en) | A kind of Pesticidal combination containing carbosulfan and chlorine fluorine cyanogen insect amide |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170922 |
|
| WD01 | Invention patent application deemed withdrawn after publication |