CN104957160B - A kind of Pesticidal combination containing carbosulfan and chlorine fluorine cyanogen insect amide - Google Patents
A kind of Pesticidal combination containing carbosulfan and chlorine fluorine cyanogen insect amide Download PDFInfo
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- CN104957160B CN104957160B CN201510361669.8A CN201510361669A CN104957160B CN 104957160 B CN104957160 B CN 104957160B CN 201510361669 A CN201510361669 A CN 201510361669A CN 104957160 B CN104957160 B CN 104957160B
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- fluorine cyanogen
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Abstract
The invention provides a kind of Pesticidal combination containing carbosulfan and chlorine fluorine cyanogen insect amide for agricultural pests, carbosulfan is 1~50 with the weight ratio of chlorine fluorine cyanogen insect amide:20~1.The Pesticidal combination for providing of the invention is efficient, low toxicity and lasting period are long, can effectively prevent and treat crops lepidoptera pest.
Description
Technical field
The invention belongs to pesticide field, and in particular to a kind of Insecticidal combinations containing carbosulfan and chlorine fluorine cyanogen insect amide
Thing.
Background technology
The resistance problem of agricultural pests is a global problem.As the continuity of Chemical Control of Harmful Insects, agricultural chemicals make
The increase of consumption and not scientifical use agricultural chemicals, pest resistance are increasingly serious, produce the pest species of resistance to be on the increase.Especially
It is the Lepidoptera class pest for causing harm to agricultural production serious, resistance level is higher, and resistance development speed is relatively fast.Meanwhile, it is high
The use agricultural chemicals of intensity, cause exceeded Practice for Pesticide Residue in Agricultural Products, environmental pollution and peasant's drug cost to increase etc., it is unfavorable for agricultural
Sustainable development.Therefore, efficient, low toxicity is researched and developed, the pesticide of environmental protection has actively meaning to agricultural sustainable development
Justice.
Carbosulfan (carbosulfan) belongs to carbamates, and its toxicity mechanism is to suppress insect acetylcholine
The activity of enzyme (Ache) and carboxy-lesterase, causes the accumulation of acetylcholine (Ach) and carboxylate, and the normal nerve of influence insect is passed
Lead and lethal.Carbosulfan lethality is strong, and instant effect is effective to adult and larva with stomach toxicity and action of contace poison, to making
Thing is harmless, the diversified economy crop pest such as the fruit such as oranges and tangerines and vegetables, corn, cotton, paddy rice, sugarcane can be prevented and treated, to aphid
Prevention effect is particularly excellent.
Chlorine fluorine cyanogen insect amide is the novel pesticide that Zhejiang Provincial Chemical Engineering Research Inst is voluntarily developed, code name ZJ4042, chemical name
Referred to as：The chloro- N of 3-1- (2- methyl -4- sevoflurane isopropyls base)-N2- (1- methyl isophthalic acids-cyano ethyl) neighbour's benzene two
Formamide, shown in structural formula following (I)：
The insecticide belongs to new phthalic amide insecticides, is led to by activating blue Buddhist nun's alkali recipient cell Intracellular calcium release
Road, causes to store the runaway release of calcium ion, is few in number at present to act on insect cell orchid Buddhist nun's alkali (Ryanodine)
The compound of acceptor.There is wide spectrum preventive effect to lepidoptera pest.
Drug cost is higher when carbosulfan and chlorine fluorine cyanogen insect amide are used alone, and it is limited to a certain extent and is pushed away
Extensively apply, and long-term exclusive use easily causes pest resistance degree and is continuously increased.Therefore, by carbosulfan and chlorine fluorine cyanogen worm
Acid amides carries out mixture, is a kind of effective ways for preventing and treating agriculture resistant insect.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of efficient, low toxicity and the lasting period is long, can effectively prevent and treat crops
The Pesticidal combination of homoptera pest and lepidoptera pest, is conducive to the comprehensive regulation of insect.
To solve the above problems, the technical solution adopted in the present invention is：
A kind of Pesticidal combination for agricultural pests, it is characterised in that the Pesticidal combination contain carbosulfan and
Chlorine fluorine cyanogen insect amide, and carbosulfan and the weight ratio of chlorine fluorine cyanogen insect amide are 1~50:20~1.
The chlorine fluorine cyanogen insect amide that the present invention is used, the as compound shown in said structure formula (I).
Pesticidal combination of the present invention, carbosulfan and chlorine fluorine cyanogen insect amide are used as active component.Preferably, fourth
Carbosulfan is 1~10 with the weight ratio of chlorine fluorine cyanogen insect amide:10~1.It may further be preferable that carbosulfan and chlorine fluorine cyanogen
The weight ratio of insect amide is 1~5:5~1.
Present invention also offers a kind of insecticide for agricultural pests, 5~90% above-mentioned desinsection groups are contained by weight
Compound, remaining is agriculturally acceptable carrier and auxiliary agent.As preferred embodiment, in insecticide preferably comprising 5~
40% above-mentioned Pesticidal combination.
Carrier of the present invention can be solid or liquid, and any carrier for being generally used for preparing insecticides is equal
Can use.
Suitable solid carrier includes：Mineral substance, plant, synthetic filling class and inorganic salts.Wherein mineral substance includes
Silicates, carbonate, Sulfates and oxide-based.Silicates such as kaolin, sepiolite, nacrite covers de-
Soil, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example：Calcium carbonate, dolomite.Sulfates such as ammonium sulfate, sodium sulphate,
Calcium sulfate.Oxide-based such as quick lime, magnesium lime, diatomite.Plant is for example：Citrus pulp, corncob cellulose, rice husk powder, rice husk,
Big soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class such as winnofil hydrate, winnofil, white carbon.
Inorganic salts such as potassium chloride, sodium chloride.
Liquid-carrier includes water and organic solvent.When active ingredient is suspension emulsion, organic solvent plays solubilized and antifreeze
Effect.Suitable organic solvent includes aromatic hydrocarbons, such as benzene, dimethylbenzene, toluene, alkylbenzene, alkylnaphthalene and chlorinated aromatic hydrocarbons；Chloro fat
Fat hydrocarbon, such as vinyl chloride, chloroform, dichloromethane, chloroform, carbon tetrachloride and many chloroethanes；Aliphatic hydrocarbon, such as oil evaporate
Point, hexamethylene, light mineral oil and paraffin.Alcohols such as methyl alcohol, ethanol, isopropanol, butanol, isobutanol, ethylene glycol, the third two
Alcohol, glycerine, fatty alcohol etc.；Ethers such as Propylene Glycol ether, ethohexadiol ether, petroleum ether.Ketone such as acetone, first and second
Ketone, methyl iso-butyl ketone (MIBK), cyclohexanone and isophorone, N- methyl-pyrrolidons；Special solvent also has dimethylformamide,
Dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile；Vegetable oil and methylated vegetable oils.Above-mentioned organic solvent both can be used alone,
Can be used in mixed way, can also be mixed together with water.
Auxiliary agent of the present invention can as needed include surfactant, defoamer, thickener, suspending agent and antifreezing agent
In one or more, can also as needed include the industry commonly use other auxiliary agents.
Surfactant can be emulsifying agent, dispersant, stabilizer or wetting agent；Can be ionic or nonionic
's.Suitable surfactant includes：The sodium salt and calcium salt of polyacrylic acid and lignin sulfonic acid；Contain at least 12 carbon in molecule
The aliphatic acid or fatty amine of atom and oxirane and the polycondensation product of/expoxy propane；Glycerine, dodecanol -1, tetradecanol -
1st, the fatty acid ester of sorbierite, sucrose or pentaerythrite；And they with oxirane and/or expoxy propane polycondensation product；It
Polycondensation product sulfate or sulfonate；In the molecule at least the alkali metal of the sulfuric acid containing 10 carbon atoms or sulfonic acid or
Alkali salt, preferably sodium salt, such as lauryl sodium sulfate, Teepol, the sodium salt of sulfonated castor oil, alkaryl
Sodium sulfonate and neopelex；The copolymer of the polymer, oxirane and expoxy propane of oxirane.
Emulsifying agent includes nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonyl phenyl of nonionic emulsifier
Vinethene, AEO, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether holds hydroxyl
Base polyoxyethylene poly-oxygen propylene aether, styrylphenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.
Anionic emulsifier mainly includes calcium dodecyl benzene sulfonate, and three phenethyl phenol polyoxy ether phosphate amine salts, nonyl phenol gathers
Oxygen vinethene phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention includes：Acrylate homopolymer sodium salt, Malaysia acid disodium salt, naphthalene sulfonic acid-formaldehyde condensation product
Sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, three
Phenethyl phenol polyethenoxy ether phosphate, AEO phosphoric acid, the one kind in p-hydroxyphenyl lignin sulfonic acid sodium salt
Or it is several.
Wetting agent of the present invention includes：AEO, naphthalene sulfonate, lauryl sodium sulfate, alkyl
One or more combinations in phenol resin polyoxyethylene ether sulfate.
Thickener of the present invention includes xanthans, and aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose is Arabic
Glue, gelatin, one or more in polyvinyl alcohol.Defoamer of the present invention is preferably：Bubble enemy, silicone, C8~10Fat
Alcohol, C10~20Saturated fat acids and acid amides etc..
Pesticidal combination of the present invention can be configured to missible oil, oil suspending agent, suspension according to method generally in the art
Agent, wettable powder or water dispersible granules.
Pesticidal combination of the present invention is suitable for preventing and treating homoptera pest and lepidoptera pest, it is especially suitable for anti-
Control the homoptera pest and lepidoptera pest in paddy rice, vegetables and cotton.The homoptera pest is preferably aphid, planthopper.
The lepidoptera pest is preferably diamondback moth, yellow rice borer, bollworm.
Pesticidal combination of the present invention has following advantage compared to existing technology：
(1) two kinds of active components compounding shows excellent synergistic effect in certain ratio range in composition, mixes
The insecticidal effect of composition afterwards is significantly improved compared with its single dose, and with quick-acting is good and the characteristics of lasting effect long；
(2) dosage is reduced, peasant's drug cost is reduced；
(3) reasonably mixture is carried out using the two kinds of active components mode of action different to insect, the different mechanism of action,
Both the Pesticide use life-span had been extended, the generation of pest resistance to insecticide had been delayed again.
Specific embodiment
The present invention is further described with reference to specific embodiment, but does not limit the invention to these tools
Body implementation method.One skilled in the art would recognize that present invention encompasses being potentially included in Claims scope
All alternatives, improvement project and equivalents.
In following embodiments, unless otherwise indicated, all percentages are weight percentage.
The application has carried out Toxicity Determination experiment to carbosulfan and chlorine fluorine cyanogen insect amide mixture.
Experiment with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and
Initiative pesticide bioactivity evaluates SOP (insecticide volume), using infusion process.
Synergy is calculated using following methods：
Contents (%) of the toxicity index × A of mixed toxicity index (the TTI)=A of theory in mixed
Contents (%) of the toxicity index × B of+B in mixed
If co-toxicity coefficient is more than 120, show there is synergistic effect；If being less than 80, antagonism is shown to be；If being less than more than 80
120, it is shown to be summation action.
Embodiment 1：Chlorine fluorine cyanogen insect amide and carbosulfan mixture
Table 1, chlorine fluorine cyanogen insect amide and carbosulfan are acted on aphid (Aphis medicagini) synergy
| Proportioning | LC50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Carbosulfan | 0.25 | 13024.00 |
| Chlorine fluorine cyanogen insect amide | 32.56 | 100.00 | ||
| Carbosulfan:Chlorine fluorine cyanogen insect amide=50:1 | 0.15 | 21706.67 | 12770.59 | 169.97 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=20:1 | 0.16 | 20350.00 | 12408.57 | 164.00 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=1:1 | 0.27 | 12059.26 | 6562.00 | 183.77 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=1:10 | 1.45 | 2245.52 | 1274.91 | 176.13 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=1:20 | 2.57 | 1266.93 | 715.43 | 177.09 |
Table 2, chlorine fluorine cyanogen insect amide and carbosulfan are made to yellow rice borer (Tryporyza incertulas) synergy
With
| Proportioning | LC50(mg/L) | Actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Carbosulfan | 12.36 | 10.44 | ||
| Chlorine fluorine cyanogen insect amide | 1.29 | 100.00 | ||
| Carbosulfan:Chlorine fluorine cyanogen insect amide=50:1 | 6.26 | 20.61 | 12.19 | 169.01 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=20:1 | 5.21 | 24.76 | 14.70 | 168.42 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=1:1 | 1.35 | 95.56 | 55.22 | 173.05 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=1:10 | 0.75 | 172.00 | 91.86 | 187.25 |
| Carbosulfan:Chlorine fluorine cyanogen insect amide=1:20 | 0.84 | 153.57 | 95.74 | 160.41 |
From result of the test table 1,2 as can be seen that carbosulfan and chlorine fluorine cyanogen insect amide are 1~50：20~1 (by weight
Than) in the range of, co-toxicity coefficient is all higher than 120, and synergistic effect is shown as to aphid and Yellow Rice Borer.Carbosulfan and
Chlorine fluorine cyanogen insect amide mixture has reasonability and feasibility.
Embodiment 2 (20% carbosulfan chlorine fluorine cyanogen insect amide suspending agent)
By carbosulfan 18%, chlorine fluorine cyanogen insect amide 2%, emulsifying agent 1601# (styrylphenol polyoxyethylene polyoxies
Propylene ether) 10%, dispersant SOPA-2704%, bentonite 2%, xanthans 0.1%, organic silicon defoamer 0.4%, glycerine
5%th, the formula of balance of deionized water, each component is crushed in advance, grinding in sand mill is added, most afterwards through high shear
20% carbosulfan chlorine fluorine cyanogen insect amide suspending agent is obtained after being allocated after mixing.
Obtained 20% carbosulfan chlorine fluorine cyanogen insect amide suspending agent is prevented and treated for wild cabbage diamondback moth.20% fourth sulphur
Carbofuran chlorine fluorine cyanogen insect amide suspending agent is watered even spraying by 10 grams/acre of amount in wild cabbage diamondback moth larva occurance peak,
The preventive effect of 3 days and 7 days is respectively 92.9% and 96.3% after medicine.Dispenser in the same way, compares the fourth sulphur gram hundred of single dose 20%
Prestige suspending agent (formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), 3 days after medicine
Preventive effect be respectively 61.5% and 86.7%, the preventive effect of 7 days is respectively 63.4% and 86.9% after medicine.Carbosulfan and chlorine
Substantially, preventive effect is better than single dose for synergistic effect after fluorine cyanogen insect amide mixture.
Embodiment 3 (40% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules)
By carbosulfan 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride
8%th, polyethylene glycol 3%, balance of kaolinic formula, are obtained after each component is carried out into dry pulverization process, granulation, drying, screening
40% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules.
Obtained 40% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules are used for control of aphids.40% fourth sulphur
Carbofuran chlorine fluorine cyanogen insect amide water-dispersible granules are watered even spraying by 10 grams/acre of amount in aphid occurrence in peak period,
The preventive effect of 3 days and 7 days is respectively 92.9% and 95.2% after medicine.Dispenser in the same way, compares the carbosulfan of single dose 20%
Suspending agent (formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), 3 days after medicine
Preventive effect is respectively 75.1% and 59.6%, and the preventive effect of 7 days is respectively 81.7% and 61.7% after medicine.Carbosulfan and chlorine fluorine
Substantially, preventive effect is better than single dose for synergistic effect after cyanogen insect amide mixture, and quick-acting and lasting effect are also better than single dose, and dosage than single
Agent reduction.
Embodiment 4 (70% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules)
By carbosulfan 55%, chlorine fluorine cyanogen insect amide 15%, lauryl sodium sulfate 6%, polycarboxylate 4%, chlorination
Sodium 8%, polyethylene glycol 3%, balance of kaolinic formula, make after each component is carried out into dry pulverization process, granulation, drying, screening
Obtain 70% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules.
Obtained 70% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules are prevented and treated for Yellow Rice Borer.
70% carbosulfan chlorine fluorine cyanogen insect amide water-dispersible granules are contained in Yellow Rice Borer low instar larvae by 10 grams/acre of amount and sent out
Phase is watered even spraying, and the preventive effect of 7 days and 14 days is respectively 94.5% and 95.6% after medicine.Dispenser in the same way, control
(formulation rate is 10 for the carbosulfan suspending agent of single dose 20% (formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent
Gram/acre), the preventive effect of 7 days is respectively 52.3% and 86.7% after medicine, and the preventive effect of 14 days is respectively 55.8% He after medicine
88.1%.Substantially, preventive effect is better than single dose, quick-acting and holding effect for synergistic effect after carbosulfan and chlorine fluorine cyanogen insect amide mixture
Property is also better than single dose.
Embodiment 5 (40% carbosulfan chlorine fluorine cyanogen insect amide wettable powder)
By carbosulfan 35%, chlorine fluorine cyanogen insect amide 5%, lauryl sodium sulfate 6%, polycarboxylate 4%, sodium chloride
8%th, polyethylene glycol 3%, balance of kaolinic formula, are obtained after each component is carried out into dry pulverization process, granulation, drying, screening
40% carbosulfan chlorine fluorine cyanogen insect amide wettable powder.
Obtained 40% carbosulfan chlorine fluorine cyanogen insect amide wettable powder is prevented and treated for yellow rice borer.40% fourth sulphur
Carbofuran chlorine fluorine cyanogen insect amide wettable powder is watered uniformly by 10 grams/acre of amount in yellow rice borer low instar larvae occurrence in peak period
Spraying, the preventive effect of 7 days and 14 days is respectively 97.4% and 98.3% after medicine.Dispenser in the same way, compares the fourth of single dose 20%
Carbosulfan suspending agent (formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), in medicine
The preventive effect of 7 days is respectively 55.8% and 82.9% afterwards, and the preventive effect of 14 days is respectively 57.3% and 79.8% after medicine.Fourth sulphur gram hundred
Substantially, preventive effect is better than single dose, and quick-acting and lasting effect are also better than single dose for synergistic effect after prestige and chlorine fluorine cyanogen insect amide mixture.
Embodiment 6 (20% carbosulfan chlorine fluorine cyanogen insect amide oil suspending agent)
By carbosulfan 15%, chlorine fluorine cyanogen insect amide 5%, castor oil polyoxyethylene ether 13%, triphenyl vinyl phenol
Polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate are mended to 100% formula, each component are well mixed, sand
20% carbosulfan chlorine fluorine cyanogen insect amide oil suspending agent is obtained final product after being milled to certain particle diameter.
Obtained 20% carbosulfan chlorine fluorine cyanogen insect amide oil suspending agent is used for cotton bollworm control.20% fourth sulphur gram hundred
Prestige chlorine fluorine cyanogen insect amide oil suspending agent is watered even spraying by 10 grams/acre of amount in cotton bollworm larvae occurance peak, 3 days after medicine
Preventive effect with 7 days is respectively 94.6% and 95.7%.Dispenser in the same way, compares the carbosulfan suspending agent of single dose 20%
(formulation rate is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), the preventive effect of 3 days point after medicine
Not Wei 48.6% and 83.8%, after medicine the preventive effect of 7 days be 50.8% and 87.9%.Carbosulfan and chlorine fluorine cyanogen insect amide are mixed
With rear synergistic effect substantially, preventive effect is better than single dose.
Embodiment 7 (20% carbosulfan chlorine fluorine cyanogen insect amide missible oil)
By carbosulfan 15%, chlorine fluorine cyanogen insect amide 5%, calcium dodecyl benzene sulfonate 6%, three phenethyl phenol polyoxy second
Alkene ether 6%, NMP 8%, the formula of balance of dimethylbenzene, will obtain final product 20% carbosulfan after each component mixing and stirring
Chlorine fluorine cyanogen insect amide missible oil.
Obtained 20% carbosulfan chlorine fluorine cyanogen insect amide missible oil is prevented and treated for planthopper.20% fourth sulphur gram hundred
Prestige chlorine fluorine cyanogen insect amide missible oil is watered even spraying by 10 grams/acre of amount in planthopper nymph occurance peak, after medicine 3 days and
The preventive effect of 7 days is respectively 92.6% and 96.5%.Dispenser in the same way, the control carbosulfan suspending agent of single dose 20% (is applied
Dose is 30 grams/acre) and 20% chlorine fluorine cyanogen insect amide suspending agent (formulation rate is 10 grams/acre), the preventive effect of 3 days is respectively after medicine
54.3% and 86.9%, the preventive effect of 7 days is respectively 57.9% and 88.0% after medicine.Carbosulfan and chlorine fluorine cyanogen insect amide are mixed
With rear synergistic effect substantially, preventive effect is better than single dose.
Claims (10)
1. a kind of Pesticidal combination for agricultural pests, it is characterised in that the Pesticidal combination contains carbosulfan and chlorine fluorine
Cyanogen insect amide, and carbosulfan and the weight ratio of chlorine fluorine cyanogen insect amide are 1~50:20~1.
2. according to the Pesticidal combination described in claim 1, it is characterised in that the carbosulfan and chlorine fluorine cyanogen insect amide
Weight ratio is 1~10:10~1.
3. according to the Pesticidal combination described in claim 2, it is characterised in that the carbosulfan and chlorine fluorine cyanogen insect amide
Weight ratio is 1~5:5~1.
4. a kind of insecticide for agricultural pests, it is characterised in that：The insecticide contains 5~90% desinsection by weight
Composition, remaining is agriculturally acceptable carrier and auxiliary agent；The Pesticidal combination contains carbosulfan and chlorine fluorine cyanogen worm acyl
Amine, and carbosulfan and the weight ratio of chlorine fluorine cyanogen insect amide are 1~50:20~1.
5. according to the insecticide for agricultural pests described in claim 4, it is characterised in that the insecticide contains by weight
There is 5~40% Pesticidal combination.
6. according to the insecticide for agricultural pests described in claim 4, it is characterised in that the insecticide is missible oil, suspends
Agent, wettable powder or water dispersible granules.
7. according to the insecticide for agricultural pests described in claim 6, it is characterised in that the suspending agent is oil suspending agent.
8. the purposes of the Pesticidal combination described in a kind of claim 1, it is characterised in that the Pesticidal combination is used to prevent and treat same
Wing mesh insect and lepidoptera pest.
9. according to the purposes of the Pesticidal combination described in claim 8, it is characterised in that the homoptera pest is aphid, rice flies
Lice, the lepidoptera pest is diamondback moth, yellow rice borer, bollworm.
10. according to the purposes of the Pesticidal combination described in claim 8, it is characterised in that the Pesticidal combination is used for anti-harnessing the river
Homoptera pest and lepidoptera pest in rice, vegetables and cotton.
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103039512A (en) * | 2013-01-05 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 |
| CN103250727A (en) * | 2013-05-02 | 2013-08-21 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing indoxacarb and ZJ4042 |
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| US6362369B2 (en) * | 1997-11-25 | 2002-03-26 | Nihon Nohyaku Co., Ltd. | Phthalic acid diamide derivatives fluorine-containing aniline compounds as starting material, agricultural and horticultural insecticides, and a method for application of the insecticides |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103039512A (en) * | 2013-01-05 | 2013-04-17 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing chlorpyrifos and ZJ4042 |
| CN103250727A (en) * | 2013-05-02 | 2013-08-21 | 中化蓝天集团有限公司 | Agricultural insecticidal composition containing indoxacarb and ZJ4042 |
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