CN103250720A - Agricultural insecticidal composition containing chlorfluazuron and ZJ4042 - Google Patents
Agricultural insecticidal composition containing chlorfluazuron and ZJ4042 Download PDFInfo
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- CN103250720A CN103250720A CN2013101597532A CN201310159753A CN103250720A CN 103250720 A CN103250720 A CN 103250720A CN 2013101597532 A CN2013101597532 A CN 2013101597532A CN 201310159753 A CN201310159753 A CN 201310159753A CN 103250720 A CN103250720 A CN 103250720A
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Abstract
The invention discloses an agricultural insecticidal composition containing two active ingredients, namely chlorfluazuron and 3-chloro-N1-(2-methyl-4-heptafluoroisopropyl phenyl)-N2-(1-methyl-1-cyanoethyl)phthalimide which are in the weight ratio of (1-20): (30-1). The insecticidal composition disclosed by the invention is suitable for preventing and treating destructive insects, such as spodoptera litura, beet armyworm, cabbage caterpillar, diamondback moth and cotton bollworm, of crops. According to the agricultural insecticidal composition, the quick acting performance and effect lasting performance are better than those of single agents, and the dosage and medicating cost of insecticide are reduced, so that the environmental protection and comprehensive treatment on agricultural insects are facilitated.
Description
Technical field
The invention belongs to pesticide field, be specifically related to a kind of by fluorine pyridine urea and 3-chloro-N
1-(2-methyl-4-sevoflurane isopropyl base)-N
2Composite higher effective and lower toxic pesticide composition and the insecticide thereof that forms of-(1-methyl isophthalic acid-cyano ethyl) phthalic amide.
Background technology
The resistance problem of pest is a global problem.Along with the continuity of insect chemical control, increase and the non-science of agricultural chemicals usage amount are used agricultural chemicals, pest resistance is serious day by day, and the pest species that produces resistance is on the increase.The Lepidoptera class pest of causing harm serious to agricultural production particularly, the resistance level height, resistance development speed is fast.Simultaneously, high-intensity use agricultural chemicals causes that the agricultural product residue of pesticide exceed standard, environmental pollution and the increase of peasant's drug cost etc., is unfavorable for agricultural sustainable development.Therefore need that research and development are efficient, the pesticide of low toxicity, environmental protection.
Fluorine pyridine urea chlorfluazuron belongs to insect growth regulator, IGR, and it is synthetic to suppress chitin, hinders insect and normally peels, and is hatching, larva decortication and the pupa development deformity of ovum, and adult eclosion is obstructed.Effect characteristics such as fluorine pyridine urea has stomach toxicity, tag, the drug effect height, but speed of action is slower, and active high to insects such as Lepidopteras.
3-chloro-N
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide (test code number: ZJ4042), be the novel pesticide that develop voluntarily the Zhejiang Provincial Chemical Engineering Research Inst, shown in the structural formula following (I):
The insecticidal activity of ZJ4042 and the fipronil bisamide of recent development suitable substantially has the wide spectrum preventive effect to lepidoptera pest, do not have cross resistance with existing insecticide and produces, and is suitable for very much the control that existing insecticide produces the insect of resistance.
Drug cost was higher when fluorine pyridine urea and ZJ4042 used separately, limited it to a certain extent and applied, and long-term use separately causes the pest resistance degree constantly to increase easily.Being mixed of different pesticide species is the common methods of the agriculture resistant insect of control.By the formulation of pesticide screening, filter out rational prescription, can effectively improve actual control efficiency, reduce dosage, reduce cost, delay the generation of pest resistance to insecticide, prolong the service life of medicament, be the important means of the insect comprehensive regulation.
The Lepidoptera class pests such as control prodenia litura, beet armyworm, cabbage caterpillar, diamond-back moth, cotton bollworm that are mixed of fluorine pyridine urea and ZJ4042 still do not have report at present and use.
Summary of the invention
The object of the present invention is to provide a kind of efficient, low toxicity, lasting period long, can effectively prevent and treat crops Lepidoptera class pest and low composition pesticide and the insecticide thereof of drug cost.
For reaching goal of the invention the technical solution used in the present invention be:
A kind of Pesticidal combination for pest contains two kinds of active components, and first kind of active component is fluorine pyridine urea, and second kind of active component is 3-chloro-N
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that described first kind of active component and second kind of activity become is 1～20:30～1.
The weight ratio that above-mentioned a kind of active component and second kind of activity become is preferably 1～10:10～1, more preferably 1～5:5～1.
The present invention also provides a kind of insecticide for pest, contains 5～90% above-mentioned Pesticidal combinations by weight, and all the other are that agricultural goes up acceptable carrier and auxiliary agent.As preferred embodiment, preferably contain 5～40% above-mentioned Pesticidal combination in the insecticide.
Carrier of the present invention can be solid or liquid, and any carrier that is generally used for preparing insecticides all can use.
Suitable solid carrier comprises: mineral substance, plant class, synthetic filling class and inorganic salts.Wherein mineral substance comprises silicates, carbonate, Sulfates and oxide-based.Silicates is kaolin for example, sepiolite, nacrite, imvite, mica, vermiculite, pyrophyllite, talcum.Carbonate is for example: calcium carbonate, dolomite.Sulfates such as ammonium sulfate, sodium sulphate, calcium sulphate.Oxide-based as quicklime, magnesium lime, diatomite.The plant class is for example: oranges and tangerines slag, corncob cellulose, rice husk powder, rice husk, big soya bean stem meal, tobacco powder, walnut shell, sawdust.Synthetic filling class such as winnofil hydrate, winnofil, white carbon.Inorganic salts is potassium chloride for example, sodium chloride.
Liquid-carrier comprises water and organic solvent.When effective composition was suspension emulsion, organic solvent played solubilising and antifreeze effect.Appropriate organic solvent comprises aromatic hydrocarbons, for example benzene, dimethylbenzene, toluene, alkylbenzene, Fluhyzon and chlorinated aromatic hydrocarbons; Chlorinated aliphatic hydrocarbon, for example vinyl chloride, chloroform, carrene, chloroform, carbon tetrachloride and many chloroethanes; Aliphatic hydrocarbon, for example petroleum distillate, cyclohexane, light mineral oil and paraffin.Alcohols is methyl alcohol for example, ethanol, isopropyl alcohol, butanols, isobutanol, ethylene glycol, propane diols, glycerine, fatty alcohol etc.; Ethers is Propylene Glycol ether for example, ethohexadiol ether, benzinum.Ketone is acetone, MEK, methyl iso-butyl ketone (MIBK), cyclohexanone and different fluorine that ketone, N-methyl-pyrrolidones for example; Special solvent also has dimethyl formamide, dimethyl sulfoxide (DMSO), polyethylene glycol, nitrile; Vegetable oil and the vegetable oil that methylates.Above-mentioned organic solvent both can be used alone, but also also mix together, and can also be mixed together use with water.
Auxiliary agent of the present invention can comprise one or more in surfactant, defoamer, thickener, suspending agent and the antifreezing agent as required, can also comprise other auxiliary agents that the industry is commonly used as required.
Surfactant can be emulsifier, dispersant, stabilizing agent or wetting agent; Can be ionic or nonionic.Suitable surfactant comprises: the sodium salt of polyacrylic acid and lignin sulfonic acid and calcium salt; Contain in the molecule fatty acid of at least 12 carbon atoms or fatty amine and oxirane and/polycondensation product of expoxy propane; The fatty acid ester of glycerine, dodecanol-1, tetradecanol-1, sorbierite, sucrose or pentaerythrite; And the polycondensation product of they and oxirane and/or expoxy propane; The sulphate of their polycondensation product or sulfonate; At least contain the sulfuric acid of 10 carbon atoms or alkali metal or the alkali salt of sulfonic acid in molecule, preferable is sodium salt, as sodium salt, alkylaryl sodium sulfonate and the neopelex of lauryl sodium sulfate, Teepol, sulfonated castor oil; The copolymer of polymers of ethylene oxide, oxirane and expoxy propane.
Emulsifier comprises nonionic emulsifier and anionic emulsifier.The preferred polyoxyethylene nonylphenol ether of nonionic emulsifier, fatty alcohol-polyoxyethylene ether, styryl phenyl APEO, alkyl phenol formaldehyde resin polyoxyethylene ether, the terminal hydroxy group polyoxyethylene poly-oxygen propylene aether, styryl phenol formaldehyde resin polyoxyethylene poly-oxygen propylene aether, castor oil polyoxyethylene ether.Anionic emulsifier mainly comprises calcium dodecyl benzene sulfonate, triphen ethyl phenol polyoxy ether phosphate amine salt, polyoxyethylene nonylphenol ether phosphate amine salt, castor oil polyoxyethylene ether phosphate amine salt.
Dispersant of the present invention comprises: the acrylate homopolymer sodium salt, the maleic acid disodium salt, the naphthalene sulfonic acid-formaldehyde condensation product sodium salt, rosin segmented APEO polyoxypropylene ether sulfonate, terminal hydroxy group polyoxyethylene poly-oxygen propylene aether block copolymer, triphen ethyl phenol polyoxyethylene ether phosphate, fatty alcohol-polyoxyethylene ether phosphoric acid is in the hydroxyphenyl lignin sulfonic acid sodium salt one or more.
Wetting agent of the present invention comprises: fatty alcohol-polyoxyethylene ether, naphthalene sulfonate, lauryl sodium sulfate, one or more combinations in the alkyl phenol resin polyoxyethylene ether sulfate.。
Thickener of the present invention comprises xanthans, aluminium-magnesium silicate, sodium alginate, sodium carboxymethylcellulose, gum Arabic, gelatin, one or more in the polyvinyl alcohol.Defoamer of the present invention is preferably: bubble enemy, silicone, C
8～10Fatty alcohol, C
10～20Saturated fat acids and acid amides etc.
Pesticidal combination of the present invention can be configured to missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules according to this area method in common.
Pesticidal combination of the present invention is specially adapted to prevent and treat the Lepidoptera class pest in the plants such as fruit tree, vegetables, paddy rice or cotton, comprises prodenia litura, beet armyworm, cabbage caterpillar, diamond-back moth and cotton bollworm etc.
Pesticidal combination of the present invention has following advantage compared to existing technology:
(1) two kinds of pesticide compositionals show good synergistic effect in the composition in certain ratio range, and the insecticidal effect of mixed composition is significantly improved than its single agent, and have the advantages that quick-acting is good and lasting effect is long;
(2) reduce using dosage, reduced peasant's drug cost;
(3) utilize two kinds of agricultural chemicals that the different mode of action of insect, the different mechanism of action reasonably are mixed, both prolonged agricultural chemicals service life, delay the generation of pest resistance to insecticide again.
Embodiment
Come the present invention is further specified below in conjunction with specific embodiment, but do not limit the invention to these embodiments.One skilled in the art would recognize that the present invention contained in claims scope all alternatives, improvement project and the equivalents that may comprise.
Material prescription is selected and can be suited measures to local conditions among the following embodiment, and the result is not had substantial influence.In these embodiments, unless otherwise indicated, all percentages all are weight percentage.
The inventor is mixed to fluorine pyridine urea and ZJ4042 and has carried out the Toxicity Determination test.
Test is estimated SOP(insecticide volume with reference to pesticide indoor bioassay test rule (agricultural industry criteria NY/T1154.7-2006) and initiative pesticide bioactivity), adopt infusion process.
Synergy adopts following method to calculate:
Theory is used the content (%) of toxicity index * A in using with of toxicity index (TTI)=A with
The content (%) of toxicity index * B of+B in using with
If co-toxicity coefficient is greater than 120, and showing has synergistic effect; If less than 80, be indicated as antagonism; If greater than 80 less than 120, be indicated as summation action.
Embodiment 1:ZJ4042 and the fluorine pyridine urea embodiment that is mixed
Table 1 ZJ4042 and fluorine pyridine urea are to the effect of wild cabbage diamond-back moth Plutella xylostella synergy
| Handle | Proportioning | LC 50(mg/L) | The actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Fluorine pyridine urea | - | 0.32 | 115.63 | ? | ? |
| ZJ4042 | - | 0.37 | 100.00 | ? | ? |
| Fluorine pyridine urea: ZJ4042 | 20:30 | 0.25 | 148.00 | 106.25 | 139.29 |
| Fluorine pyridine urea: ZJ4042 | 20:1 | 0.22 | 168.18 | 114.88 | 146.40 |
| Fluorine pyridine urea: ZJ4042 | 10:1 | 0.23 | 160.87 | 114.20 | 140.86 |
| Fluorine pyridine urea: ZJ4042 | 5:1 | 0.25 | 148.00 | 113.02 | 130.95 |
| Fluorine pyridine urea: ZJ4042 | 1:1 | 0.22 | 168.18 | 107.81 | 155.99 |
| Fluorine pyridine urea: ZJ4042 | 1:5 | 0.23 | 160.87 | 102.60 | 156.79 |
| Fluorine pyridine urea: ZJ4042 | 1:10 | 0.25 | 148.00 | 101.42 | 145.93 |
| Fluorine pyridine urea: ZJ4042 | 1:30 | 0.26 | 142.31 | 100.50 | 141.59 |
Table 2 ZJ4042 and fluorine pyridine urea are to the effect of wild cabbage beet armyworm Spodoptera exigua synergy
| Handle | Proportioning | LC 50(mg/L) | The actual measurement toxicity index | Theoretical toxicity index | Co-toxicity coefficient |
| Fluorine pyridine urea | - | 0.59 | 54.24 | ? | ? |
| ZJ4042 | - | 0.32 | 100.00 | ? | ? |
| Fluorine pyridine urea: ZJ4042 | 20:30 | 0.28 | 114.29 | 81.69 | 139.89 |
| Fluorine pyridine urea: ZJ4042 | 20:1 | 0.41 | 78.05 | 56.42 | 138.34 |
| Fluorine pyridine urea: ZJ4042 | 10:1 | 0.38 | 84.21 | 58.40 | 144.20 |
| Fluorine pyridine urea: ZJ4042 | 5:1 | 0.38 | 84.21 | 61.86 | 136.12 |
| Fluorine pyridine urea: ZJ4042 | 1:1 | 0.31 | 103.23 | 77.12 | 133.85 |
| Fluorine pyridine urea: ZJ4042 | 1:5 | 0.23 | 139.13 | 92.37 | 150.62 |
| Fluorine pyridine urea: ZJ4042 | 1:10 | 0.25 | 128.00 | 95.84 | 133.56 |
| Fluorine pyridine urea: ZJ4042 | 1:30 | 0.23 | 139.13 | 98.52 | 141.22 |
From result of the test table 1,2 as can be seen, fluorine pyridine urea and ZJ4042, in) the scope, co-toxicity coefficient all shows as synergistic effect all greater than 120 to wild cabbage diamond-back moth and beet armyworm at 1～20:30～1(by weight.Fluorine pyridine urea and ZJ4042 are mixed and have reasonability and feasibility.
Embodiment 2 (20% fluorine pyridine urea ZJ4042 suspending agent)
Press fluorine pyridine urea 18%, ZJ40422%, emulsifier 1601#(styryl phenol polyoxyethylene poly-oxygen propylene aether) 10%, dispersant SOPA one 27044%, bentonite 2%, xanthans 0.1%, silicone defoaming agent 0.4%, glycerine 5%, surplus is deionized water.Above-mentioned prescription is pulverized in proportion in advance, added in the sand mill and grind, allotment makes 20% fluorine pyridine urea ZJ4042 suspending agent after high shear mixing.
This embodiment is applied to prevent and treat the wild cabbage diamond-back moth.20% fluorine pyridine urea ZJ4042 suspending agent is converted the water even spraying by 10 grams/mu in wild cabbage diamondback moth larvae occurance peak, and 3 days, 7 days preventive effect is respectively 94.3%, 96.1% behind the medicine.Contrast single agent 5% 5 percent of hexaflumuron emulsifiable concentrate (formulation rate is 30 grams/mu), 20%ZJ4042 suspending agent (formulation rate is 10 grams/mu) by with the quadrat method dispenser, 3 days preventive effect is respectively 77.3%, 85.3% behind the medicine, and 7 days preventive effect is respectively 79.2%, 86.5% behind the medicine.Fluorine pyridine urea and ZJ4042 be mixed the back synergistic effect obvious, preventive effect is better than single agent.
Embodiment 3 (40% fluorine pyridine urea ZJ4042 water-dispersible granules)
Press fluorine pyridine urea 35%, ZJ40425%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.Dry pulverization process, granulation, drying, screening make 40% fluorine pyridine urea ZJ4042 water-dispersible granules in proportion with above-mentioned prescription.
This embodiment is applied to prevent and treat the wild cabbage prodenia litura.40% fluorine pyridine urea ZJ4042 water-dispersible granules is converted the water even spraying by 10 grams/mu in wild cabbage Spodoptera litura larvae occurrence in peak period, and 3 days, 7 days preventive effects are respectively 93.5%, 97.2% behind the medicine.Contrast single agent 5% 5 percent of hexaflumuron emulsifiable concentrate (formulation rate is 30 grams/mu), 20%ZJ4042 suspending agent (formulation rate is 10 grams/mu) by with the quadrat method dispenser, 3 days preventive effect is respectively 78.3%, 85.9% behind the medicine, and 7 days preventive effect is respectively 78.9%, 89.2% behind the medicine.Fluorine pyridine urea and ZJ4042 be mixed the back synergistic effect obvious, preventive effect is better than single agent, quick-acting and lasting effect also are better than single agent, and dosage reduces than single agent.
Embodiment 4 (70% fluorine pyridine urea ZJ4042 water-dispersible granules)
Press fluorine pyridine urea 55%, ZJ404215%, lauryl sodium sulfate 6%, poly-shuttle hydrochlorate 4%, sodium chloride 8%, polyethylene glycol 3%, surplus is kaolin.Dry pulverization process, granulation, drying, screening make 70% fluorine pyridine urea ZJ4042 water-dispersible granules in proportion with above-mentioned prescription.
This embodiment is applied to prevent and treat the wild cabbage beet armyworm.70% fluorine pyridine urea ZJ4042 water-dispersible granules is converted the water even spraying by 5 grams/mu in wild cabbage beet exigua larvae occurrence in peak period, and 3 days, 7 days preventive effects are respectively 90.2%, 92.4% behind the medicine.Contrast single agent 5% 5 percent of hexaflumuron emulsifiable concentrate (formulation rate is 30 grams/mu), 20%ZJ4042 suspending agent (formulation rate is 10 grams/mu) by with the quadrat method dispenser, 3 days preventive effect is respectively 73.7%, 77.8% behind the medicine, and 7 days preventive effect is respectively 76.3%, 82.1% behind the medicine.Fluorine pyridine urea and ZJ4042 be mixed the back synergistic effect obvious, preventive effect is better than single agent, quick-acting and lasting effect also are better than single agent.
Embodiment 5 (20% fluorine pyridine urea ZJ4042 oil suspending agent)
Fluorine pyridine urea 15%, ZJ40425%, castor oil polyoxyethylene ether 13%, triphenyl vinyl phenol polyoxyethylene ether phosphate 3%, organobentonite 1%, methyl oleate is mended to 100%.After above-mentioned prescription mixed, sand milling to certain particle diameter got final product.
This embodiment is applied to prevent and treat cotton bollworm.20% fluorine pyridine urea ZJ4042 oil suspending agent is converted the water even spraying by 10 grams/mu in the cotton bollworm larvae occurance peak, and 3 days, 7 days preventive effects are respectively 93.7%, 95.7% behind the medicine.Contrast single agent 5% 5 percent of hexaflumuron emulsifiable concentrate (formulation rate is 30 grams/mu), by with the quadrat method dispenser, 3 days preventive effect is respectively 71.3%, 83.2% to 20%ZJ4042 suspending agent (formulation rate is 10 grams/mu) behind the medicine, 7 days preventive effect is 78.0%, 88.7% behind the medicine.Fluorine pyridine urea and ZJ4042 be mixed the back synergistic effect obvious, preventive effect is better than single agent.
Embodiment 6 (20% fluorine pyridine urea ZJ4042 missible oil)
Press fluorine pyridine urea 15%, ZJ40425%, calcium dodecyl benzene sulfonate 6%, triphen ethyl phenol APEO 6%, NMP8%, surplus is dimethylbenzene.With above-mentioned prescription in proportion mixing and stirring get final product.
This embodiment is applied to prevent and treat cabbage pieris.20% fluorine pyridine urea ZJ4042 missible oil is converted the water even spraying by 10 grams/mu in cabbage pieris larva occurance peak, and 3 days, 7 days preventive effect is respectively 94.8%, 96.9% behind the medicine.Contrast single agent 5% 5 percent of hexaflumuron emulsifiable concentrate (formulation rate is 30 grams/mu), 20%ZJ4042 suspending agent (formulation rate is 10 grams/mu) by with the quadrat method dispenser, 3 days preventive effect is respectively 75.6%, 84.6% behind the medicine, and 7 days preventive effect is respectively 80.2%, 85.4% behind the medicine.Fluorine pyridine urea and ZJ4042 be mixed the back synergistic effect obvious, preventive effect is better than single agent.
Claims (8)
1. a Pesticidal combination that is used for pest is characterized in that containing two kinds of active components, and first kind of active component is fluorine pyridine urea, and second kind of active component is 3-chloro-N
1-(2-methyl-4-sevoflurane isopropyl base)-N
2-(1-methyl isophthalic acid-cyano ethyl) phthalic amide, the weight ratio that described first kind of active component and second kind of activity become is 1～20:30～1.
2. according to the described Pesticidal combination for pest of claim 1, it is characterized in that the weight ratio that described first kind of active component and second kind of activity become is 1～10:10～1.
3. according to the described Pesticidal combination for pest of claim 2, it is characterized in that the weight ratio that described first kind of active component and second kind of activity become is 1～5:5～1.
4. an insecticide that is used for pest is characterized in that containing by weight the described Pesticidal combination of 5～90% claims 1, and all the other are that agricultural goes up acceptable carrier and auxiliary agent.
5. according to the described insecticide for pest of claim 4, it is characterized in that containing by weight the described Pesticidal combination of 5～40% claims 1.
6. according to the described insecticide for pest of claim 4, it is characterized in that described insecticide can be configured to missible oil, oil suspending agent, suspending agent, wetting powder or water dispersible granules.
7. according to the described Pesticidal combination of one of claim 1-6, it is characterized in that described Pesticidal combination is used for control Lepidoptera class pest prodenia litura, beet armyworm, cabbage caterpillar, diamond-back moth and cotton bollworm.
8. according to the described Pesticidal combination of claim 7, it is characterized in that described Pesticidal combination is used for the Lepidoptera class pest of control fruit tree, vegetables, paddy rice or cotton.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104488932A (en) * | 2014-11-27 | 2015-04-08 | 浙江省化工研究院有限公司 | Insecticidal composition containing diafenthiuron and cyhalodiamide |
| CN106259343A (en) * | 2015-05-25 | 2017-01-04 | 浙江省化工研究院有限公司 | A kind of pyriproxyfen-containing and the Pesticidal combination of chlorine fluorine cyanogen insect amide |
| CN106577665A (en) * | 2016-11-15 | 2017-04-26 | 佛山市盈辉作物科学有限公司 | Composition containing afidopyropen and cyhalodiamide |
| CN106577709A (en) * | 2015-10-20 | 2017-04-26 | 浙江省化工研究院有限公司 | Pesticide compound containing cyhalodiamide and hexaflumuron |
| CN107183046A (en) * | 2016-03-14 | 2017-09-22 | 浙江省化工研究院有限公司 | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN101755794A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing ehlorfluazuron and flubendiamide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
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2013
- 2013-05-02 CN CN201310159753.2A patent/CN103250720B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101755794A (en) * | 2009-11-17 | 2010-06-30 | 陕西汤普森生物科技有限公司 | Pesticidal composition containing ehlorfluazuron and flubendiamide |
| CN102613183A (en) * | 2012-03-07 | 2012-08-01 | 中化蓝天集团有限公司 | Insecticide |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104488932A (en) * | 2014-11-27 | 2015-04-08 | 浙江省化工研究院有限公司 | Insecticidal composition containing diafenthiuron and cyhalodiamide |
| CN106259343A (en) * | 2015-05-25 | 2017-01-04 | 浙江省化工研究院有限公司 | A kind of pyriproxyfen-containing and the Pesticidal combination of chlorine fluorine cyanogen insect amide |
| CN106577709A (en) * | 2015-10-20 | 2017-04-26 | 浙江省化工研究院有限公司 | Pesticide compound containing cyhalodiamide and hexaflumuron |
| CN107183046A (en) * | 2016-03-14 | 2017-09-22 | 浙江省化工研究院有限公司 | A kind of Pesticidal combination of containing chlorine fluorine cyanogen insect amide |
| CN106577665A (en) * | 2016-11-15 | 2017-04-26 | 佛山市盈辉作物科学有限公司 | Composition containing afidopyropen and cyhalodiamide |
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| CN103250720B (en) | 2015-10-21 |
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