CN107177385B

CN107177385B - Environment-friendly high-hydrogen-energy biological alcohol oil fuel and preparation method thereof

Info

Publication number: CN107177385B
Application number: CN201710616449.4A
Authority: CN
Inventors: 温晓梅
Original assignee: Nanjing Xingjing Chemical Co ltd
Current assignee: NANJING XINGJING CHEMICAL Co.,Ltd.
Priority date: 2017-07-26
Filing date: 2017-07-26
Publication date: 2020-09-08
Anticipated expiration: 2037-07-26
Also published as: CN107177385A

Abstract

The invention provides an environment-friendly high-hydrogen energy biological alcohol oil fuel which is characterized by comprising the following components: preparing methanol more than or equal to 88.95 percent, hydrogen peroxide 0.05 percent, glycerol 0.5 percent, n-butanol 0.5 percent and methylal less than or equal to 10 percent; the preparation method of the environment-friendly high-hydrogen energy biological alcohol oil fuel is characterized by comprising the following steps of: adding hydrogen peroxide, glycerol, n-butanol and methylal into prepared methanol in sequence; and II, uniformly mixing to obtain the environment-friendly high-hydrogen energy biological alcohol oil fuel. The environment-friendly high-hydrogen-energy biological alcohol oil fuel and the preparation method thereof are high-cleanness fuels, methanol is prepared in advance, the environment is protected, the combustion efficiency is effectively improved, the product is smokeless and odorless in combustion, the flame temperature is 1100-1300 ℃, combustion products mainly comprise carbon dioxide and water, the heat utilization rate is high, and the safety is good.

Description

Environment-friendly high-hydrogen-energy biological alcohol oil fuel and preparation method thereof

Technical Field

The invention relates to the field of alcohol oil fuels, in particular to an environment-friendly high-hydrogen-energy biological alcohol oil fuel and a preparation method thereof.

Background

The alcohol-based fuel is a fuel mainly prepared from alcohol substances. It is in liquid or solid form. It is also a biomass energy, and is the same as nuclear energy, solar energy, wind energy and hydraulic energy, and is an environment-friendly clean energy which is widely popularized by governments in various countries at present; in the face of the exhaustion of petrochemical energy, the alcohol-based fuel is the most potential novel alternative energy and is deeply favored by enterprises and organizations of various countries.

At present, the alcohol-based fuel has the problems of unstable heating, low heat value, overhigh additive manufacturing cost and the like, and cannot be widely popularized and used.

Disclosure of Invention

The invention aims to overcome the defects of the traditional technology and provides an environment-friendly high-hydrogen-energy biological alcohol oil fuel and a preparation method thereof.

The technical scheme of the invention is as follows:

the environment-friendly high-hydrogen-energy biological alcohol oil fuel is characterized by comprising the following components:

preparing methanol more than or equal to 88.95 percent, hydrogen peroxide 0.05 percent, glycerol 0.5 percent, n-butanol 0.5 percent and methylal less than or equal to 10 percent;

the prepared methanol comprises the following components:

75 to 90 percent of methanol, 9.9 to 24.9 percent of softened water and less than or equal to 0.1 percent of salt;

the preparation method of the prepared methanol comprises the following steps:

i, according to a ratio of 10-20: 1, dissolving one of water or methanol and salt, and filtering to obtain a solution I;

ii, mixing the residues in the components according to the proportion in the step i to obtain a solution II;

and iii, mixing the solution I and the solution II to obtain the prepared methanol.

Wherein:

methanol, CH₃OH, the most simple saturated monohydric alcohol in structure, has a molecular weight of 32.04 and a boiling point of 64.7 ℃. It is also called "xylitol" or "wood essence" because it is found in dry-distilled wood for the first time. Is colorless liquid with alcohol smell and volatile smell. Methanol is composed of methyl and hydroxyl groups and has the chemical properties of alcohol. Methanol can react with gases such as fluorine gas, pure oxygen and the like, and the methanol is violently combusted in the pure oxygen to generate water vapor and carbon dioxide.

Hydrogen peroxide, chemical formula: h₂O₂Pure hydrogen peroxide is light blue viscous liquid, can be mixed and dissolved with water in any proportion, is a strong oxidant, and is a colorless transparent liquid, and the aqueous solution is commonly called hydrogen peroxide. The water solution is suitable for medical wound disinfection, environmental disinfection and food disinfection. Generally, the catalyst is slowly decomposed into water and oxygen, but the decomposition speed is extremely slow, and the reaction speed is accelerated by adding the catalyst.

Glycerol, glycerol, which is known as glycerol by the national standard, is colorless, odorless, sweet in taste, clear, viscous and liquid in appearance, and is an organic substance. Glycerol, which absorbs moisture from the air, also absorbs hydrogen sulfide, hydrogen cyanide and sulfur dioxide. Insoluble in benzene, chloroform, carbon tetrachloride, carbon disulfide, petroleum ether and oils. Glycerol is a backbone component of the triglyceride molecule. Relative density 1.26362. Melting point 17.8 ℃. Boiling point 290.0 deg.c (decomposition). Refractive index 1.4746. Flash point (open cup) 176 ℃. Acute toxicity: LD 50: 31500mg/kg (per rat).

N-butanol, CH₃CH₂CH₂CH₂OH, a colorless, alcoholic liquid with a boiling point of 117.7 ℃ and slightly water-soluble, is a solvent for many paints and a raw material for the plasticizer dibutyl phthalate, also for the production of butyl acrylate, butyl acetate, butyl glycol ether and as an organic synthesisIntermediates and biochemical extractants, and also for the manufacture of surfactants.

The methylal is colorless, clear, volatile and combustible liquid, has chloroform smell and pungent smell, and can be dissolved in water by 3 times.

In a specific optimization scheme, the salts comprise copper salts and/or iron salts and/or sodium salts and/or potassium salts.

In a specific preferred embodiment, the salts include ferrocene and/or copper sulfate pentahydrate and/or sodium chloride and/or potassium chloride.

Wherein ferrocene is an organic transition metal compound having aromatic properties. It is orange yellow powder at room temperature, and has camphor smell. The melting point is 172-174 ℃, the boiling point is 249 ℃, and the sublimation can be carried out at the temperature of more than 100 ℃; is insoluble in water and soluble in organic solvents such as benzene, ether, gasoline, diesel oil, etc. Does not react with acid, alkali and ultraviolet rays, has stable chemical properties, and does not decompose within 400 ℃. The molecules of the material are polar, and have high thermal stability, chemical stability and radiation resistance.

Copper sulfate pentahydrate, chemical formula: CuSO₄·5H₂O, also known as copper sulfate crystals, is commonly read as "copper sulfate pentahydrate" for distinction from "anhydrous copper sulfate," and has a relative molecular mass of 250. Commonly known as Chalcanthitum, Chalcanthitum or copperas.

Sodium chloride, chemical formula NaCl, colorless cubic crystal or fine crystal powder, and salty taste. The appearance is white crystal, the source of the crystal is mainly seawater, and the crystal is the main component of the salt. Is easily soluble in water and glycerol, and is slightly soluble in ethanol and liquid ammonia; insoluble in concentrated hydrochloric acid. The stability is good, the water solution is neutral, the industry generally adopts the method of electrolyzing saturated sodium chloride solution to produce hydrogen, chlorine and sodium hydroxide and other chlor-alkali industries, and can also be used for ore smelting, electrolyzing fused sodium chloride crystal to produce active metal sodium, and the medical treatment is used for preparing physiological saline, and can be used for seasoning in life.

Potassium chloride, with the chemical formula of KCl, is colorless, elongated diamond-shaped or cubic crystal, or white crystalline small granular powder, looks like common salt, and has no odor and salty taste. Is commonly used as additive for low sodium salt and mineral water. The potassium chloride is a clinically common electrolyte balance regulating medicine, has definite clinical curative effect and is widely applied to various clinical departments.

In a specific optimization scheme, the salts comprise ferrocene, copper sulfate pentahydrate and sodium chloride.

A specific optimization scheme is that the weight ratio of ferrocene, copper sulfate pentahydrate and sodium chloride is 1:1: 1.

A specific optimization scheme, a blending method for preparing methanol, comprises the following steps:

ai, according to a ratio of 10-20: 1, dissolving methanol and ferrocene, and filtering to obtain a ferrocene methanol solution;

aii, mixing the residual methanol taken from the components according to the proportion in the step ai with softened water to obtain a solution II;

and aiii, uniformly mixing the ferrocene methanol solution with the solution II to obtain the prepared methanol.

b i, according to a ratio of 10-20: 1, dissolving softened water and blue copperas in the weight ratio of the solution, and filtering to obtain a blue copperas aqueous solution;

b ii, mixing the residual softened water in the components according to the proportion in the step b i with methanol to obtain a solution II;

and b iii, uniformly mixing the copper sulfate aqueous solution with the solution II to obtain the prepared methanol.

c i, according to a ratio of 10-20: 1, dissolving softened water and sodium chloride, and filtering to obtain a sodium chloride aqueous solution;

c ii, mixing the residual softened water in the components according to the proportion in the step c i with methanol to obtain a solution II;

and c iii, uniformly mixing the sodium chloride aqueous solution with the solution II to obtain the prepared methanol.

d i, according to a ratio of 10-20: 1, dissolving softened water and potassium chloride, and filtering to obtain a potassium chloride aqueous solution;

d ii, mixing the softened water taken from the components according to the proportion in the step d i with methanol to obtain a solution II;

and d iii, uniformly mixing the potassium chloride aqueous solution with the solution II to obtain the prepared methanol.

A specific optimization scheme and a manufacturing method of an environment-friendly high-hydrogen-energy biological alcohol oil fuel are characterized by comprising the following steps:

adding hydrogen peroxide, glycerol, n-butanol and methylal into prepared methanol in sequence;

and II, uniformly mixing to obtain the environment-friendly high-hydrogen energy biological alcohol oil fuel.

The environment-friendly high-hydrogen-energy biological alcohol oil fuel and the preparation method thereof are high-cleanness fuels, methanol is prepared in advance, the environment is protected, the combustion efficiency is effectively improved, the product is smokeless and odorless in combustion, the flame temperature is 1100-1300 ℃, combustion products mainly comprise carbon dioxide and water, the heat utilization rate is high, and the safety is good.

Detailed Description

Example 1: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

prepared methanol 88.95%, hydrogen peroxide 0.05%, glycerol 0.5%, n-butanol 0.5%, and methylal 10%.

The prepared methanol comprises the following components:

75-90% of methanol, 9.9-24.9% of softened water and less than or equal to 0.1% of ferrocene.

In this example, methanol 75%, demineralized water 24.9%, and ferrocene 0.1%.

The preparation method for preparing the methanol comprises the following steps:

ai, according to a 20: 1, dissolving methanol and ferrocene, and filtering to obtain a ferrocene methanol solution; the methanol accounts for 2 percent of the total weight of the prepared methanol, and the ferrocene accounts for 0.1 percent.

aii, mixing the residual methanol taken from the components according to the proportion in the step ai with softened water to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The residual methanol accounts for 73 percent of the total weight of the prepared methanol, and the softened water accounts for 24.9 percent.

The preparation method of the environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following steps:

I. hydrogen peroxide, glycerol, n-butanol and methylal are sequentially added into the prepared methanol;

The product prepared by the formula is smokeless and tasteless in combustion, the flame temperature is 1100 ℃ and 1300 ℃, and the flame color is orange.

Example 2: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

82.5% of methanol, 17.4% of softened water and 0.1% of ferrocene.

ai, according to 15: 1, dissolving methanol and ferrocene, and filtering to obtain a ferrocene methanol solution; the methanol accounts for 1.5 percent of the total weight of the prepared methanol, and the ferrocene accounts for 0.1 percent.

aii, mixing the residual methanol taken from the components according to the proportion in the step ai with softened water to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The residual methanol accounts for 81.5 percent of the total weight of the prepared methanol, and the softened water accounts for 17.4 percent.

Example 3: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

90% of methanol, 9.9% of softened water and 0.1% of ferrocene.

ai, according to 10: 1, dissolving methanol and ferrocene, and filtering to obtain a ferrocene methanol solution; the methanol accounts for 1 percent of the total weight of the prepared methanol, and the ferrocene accounts for 0.1 percent.

aii, mixing the residual methanol taken from the components according to the proportion in the step ai with softened water to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest methanol accounts for 89 percent of the total weight of the prepared methanol, and the softened water accounts for 9.9 percent.

Example 4: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

75 to 90 percent of methanol, 9.9 to 24.9 percent of softened water and less than or equal to 0.1 percent of blue vitriol.

In this example, 75% of methanol, 24.9% of demineralized water, and 0.1% of copper sulfate pentahydrate.

b i, according to 20: 1, dissolving softened water and blue copperas in the weight ratio of the solution, and filtering to obtain a blue copperas aqueous solution; the softened water accounts for 2 percent of the total weight of the prepared methanol, and the blue copperas accounts for 0.1 percent.

b ii, mixing the residual softened water in the components according to the proportion in the step b i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 22.9 percent of the total weight of the prepared methanol, and the methanol accounts for 75 percent.

The product of the formula has no smoke and no smell during combustion, the flame temperature is 1100 ℃ and 1300 ℃, and the flame color is blue-green.

Example 5: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

82.5 percent of methanol, 17.4 percent of softened water and less than or equal to 0.1 percent of blue vitriol.

b i, according to 15: 1, dissolving softened water and blue copperas in the weight ratio of the solution, and filtering to obtain a blue copperas aqueous solution; the softened water accounts for 1.5 percent of the total weight of the prepared methanol, and the blue copperas accounts for 0.1 percent.

b ii, mixing the residual softened water in the components according to the proportion in the step b i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 15.9 percent of the total weight of the prepared methanol, and the methanol accounts for 88.95 percent.

Example 6: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

9 percent of prepared methanol, 0.05 percent of hydrogen peroxide, 0.5 percent of glycerol, 0.5 percent of n-butyl alcohol and 10 percent of methylal.

The prepared methanol comprises the following components:

90% of methanol, 9.9% of softened water and less than or equal to 0.1% of blue vitriol.

b i, according to 10: 1, dissolving softened water and blue copperas in the weight ratio of the solution, and filtering to obtain a blue copperas aqueous solution; the softened water accounts for 1 percent of the total weight of the prepared methanol, and the blue copperas accounts for 0.1 percent.

b ii, mixing the residual softened water in the components according to the proportion in the step b i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 8.9 percent of the total weight of the prepared methanol, and the methanol accounts for 90 percent.

Example 7: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

75-90% of methanol, 9.9-24.9% of softened water and less than or equal to 0.1% of sodium chloride.

In this example, 75% of methanol, 24.9% of demineralized water, and 0.1% of sodium chloride were used.

c i, according to 20: 1, dissolving softened water and sodium chloride, and filtering to obtain a sodium chloride solution; the softened water accounts for 2 percent of the total weight of the prepared methanol, and the sodium chloride accounts for 0.1 percent.

c ii, mixing the residual softened water in the components according to the proportion in the step c i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 22.9 percent of the total weight of the prepared methanol, and the methanol accounts for 75 percent.

And c iii, uniformly mixing the sodium chloride solution with the solution II to obtain the prepared methanol.

The product of the formula has no smoke and no smell during combustion, the flame temperature is 1100 ℃ and 1300 ℃, and the color of the flame is yellow.

Example 8: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

82.5 percent of methanol, 17.4 percent of softened water and less than or equal to 0.1 percent of sodium chloride.

c i, according to 15: 1, dissolving softened water and sodium chloride, and filtering to obtain a sodium chloride solution; the softened water accounts for 1.5 percent of the total weight of the prepared methanol, and the sodium chloride accounts for 0.1 percent.

c ii, mixing the residual softened water in the components according to the proportion in the step c i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 15.9 percent of the total weight of the prepared methanol, and the methanol accounts for 88.95 percent.

Example 9: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

90% of methanol, 9.9% of softened water and less than or equal to 0.1% of sodium chloride.

c i, according to 10: 1, dissolving softened water and sodium chloride, and filtering to obtain a sodium chloride solution; the softened water accounts for 1 percent of the total weight of the prepared methanol, and the sodium chloride accounts for 0.1 percent.

c ii, mixing the residual softened water in the components according to the proportion in the step c i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 8.9 percent of the total weight of the prepared methanol, and the methanol accounts for 90 percent.

Example 10: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

75-90% of methanol, 9.9-24.9% of softened water and less than or equal to 0.1% of potassium chloride.

In this example, 75% of methanol, 24.9% of demineralized water, and 0.1% of potassium chloride were used.

d i, according to 20: 1, dissolving softened water and potassium chloride, and filtering to obtain a potassium chloride solution; the softened water accounts for 2 percent of the total weight of the prepared methanol, and the potassium chloride accounts for 0.1 percent.

d ii, mixing the residual softened water in the components according to the proportion in the step d i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 22.9 percent of the total weight of the prepared methanol, and the methanol accounts for 75 percent.

And d iii, uniformly mixing the potassium chloride solution with the solution II to obtain the prepared methanol.

The formula product is smokeless and tasteless in combustion, and the flame temperature is 1100 ℃ and 1300 ℃.

Example 11: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

82.5 percent of methanol, 17.4 percent of softened water and less than or equal to 0.1 percent of potassium chloride.

d i, according to 15: 1, dissolving softened water and potassium chloride, and filtering to obtain a potassium chloride solution; the softened water accounts for 1.5 percent of the total weight of the prepared methanol, and the potassium chloride accounts for 0.1 percent.

d ii, mixing the residual softened water in the components according to the proportion in the step d i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 15.9 percent of the total weight of the prepared methanol, and the methanol accounts for 88.95 percent.

Example 12: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

90% of methanol, 9.9% of softened water and less than or equal to 0.1% of potassium chloride.

d i, according to 10: 1, dissolving softened water and potassium chloride, and filtering to obtain a potassium chloride solution; the softened water accounts for 1 percent of the total weight of the prepared methanol, and the potassium chloride accounts for 0.1 percent.

d ii, mixing the residual softened water in the components according to the proportion in the step d i with methanol to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest softened water accounts for 8.9 percent of the total weight of the prepared methanol, and the methanol accounts for 90 percent.

Example 13: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

75-90% of methanol, 9.9-24.9% of softened water and less than or equal to 0.1% of mixed salt.

In this example, 75% of methanol, 24.9% of demineralized water, and 0.1% of mixed salt were used.

The mixed salt comprises copper sulfate pentahydrate, ferrocene and sodium chloride, and the ratio of the copper sulfate pentahydrate to the ferrocene to the sodium chloride is 1:1: 1.

when in preparation, the mixed salt copper sulfate pentahydrate, the ferrocene and the sodium chloride are mixed according to the weight ratio of 1:1: 1.

e i, according to 20: 1, dissolving methanol and mixed salt, and filtering to obtain a mixed salt methanol solution; the methanol accounts for 2 percent of the total weight of the prepared methanol, and the mixed salt accounts for 0.1 percent.

e ii, mixing the residual methanol taken from the components according to the proportion in the step e i with softened water to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The residual methanol accounts for 73 percent of the total weight of the prepared methanol, and the softened water accounts for 24.9 percent.

And e iii, uniformly mixing the mixed salt methanol solution with the solution II to obtain the prepared methanol.

Example 14: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

82.5% of methanol, 17.4% of softened water and 0.1% of mixed salt.

e i, according to 15: 1, dissolving methanol and mixed salt, and filtering to obtain a mixed salt methanol solution; the methanol accounts for 1.5 percent of the total weight of the prepared methanol, and the mixed salt accounts for 0.1 percent.

e ii, mixing the residual methanol taken from the components according to the proportion in the step e i with softened water to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The residual methanol accounts for 81.5 percent of the total weight of the prepared methanol, and the softened water accounts for 17.4 percent.

Example 15: an environment-friendly high-hydrogen energy biological alcohol oil fuel comprises the following components:

The prepared methanol comprises the following components:

90% of methanol, 9.9% of softened water and 0.1% of mixed salt.

e i, according to 10: 1, dissolving methanol and mixed salt, and filtering to obtain a mixed salt methanol solution; the methanol accounts for 1 percent of the total weight of the prepared methanol, and the mixed salt accounts for 0.1 percent.

e ii, mixing the residual methanol taken from the components according to the proportion in the step e i with softened water to obtain a solution II; and standing the solution II for more than one hour to improve the stability of the product. The rest methanol accounts for 89 percent of the total weight of the prepared methanol, and the softened water accounts for 9.9 percent.

In addition, the mixed salt may be a mixture of ferrocene and copper sulfate pentahydrate, ferrocene and sodium chloride, ferrocene and potassium chloride, copper sulfate pentahydrate and sodium chloride, copper sulfate pentahydrate and potassium chloride, sodium chloride and potassium chloride, or ferrocene and copper sulfate pentahydrate and sodium chloride and potassium chloride.

The alcohol-based fuel component is measured by weight part, and the methanol component is prepared by weight part.

According to the invention, salts, water and methanol are blended to ensure complete combustion and oxidation, the products are carbon dioxide and water, and the combustion products are highly clean and pollution-free; the salt can catalyze and promote combustion, reduce the generation of macromolecular substances in the combustion process and ensure stable and sufficient combustion.

The foregoing shows and describes the general principles, essential features, and advantages of the invention. It will be understood by those skilled in the art that the present invention is not limited to the embodiments described above, and the preferred embodiments of the present invention are described in the above embodiments and the description, and are not intended to limit the present invention. The scope of the invention is defined by the appended claims and equivalents thereof.

Claims

1. The environment-friendly high-hydrogen-energy biological alcohol oil fuel is characterized by comprising the following components:

the prepared methanol comprises the following components:

the preparation method of the prepared methanol comprises the following steps:

2. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 1, characterized in that: the salts comprise copper salts and/or iron salts and/or sodium salts and/or potassium salts.

3. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 1, characterized in that: the salts comprise ferrocene and/or copper sulfate pentahydrate and/or sodium chloride and/or potassium chloride.

4. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 1, characterized in that: the salts include ferrocene, copper sulfate pentahydrate and sodium chloride.

5. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 4, characterized in that: the weight ratio of the ferrocene, the copper sulfate pentahydrate and the sodium chloride is 1:1: 1.

6. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 3, wherein the preparation method for preparing the methanol comprises the following steps:

7. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 3, characterized in that: the preparation method for preparing the methanol comprises the following steps:

8. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 3, characterized in that: the preparation method for preparing the methanol comprises the following steps:

c ii, mixing the softened water taken from the components according to the proportion in the step c i with methanol to obtain a solution II;

9. The environment-friendly high-hydrogen energy bio-alcohol oil fuel of claim 3, characterized in that: the preparation method for preparing the methanol comprises the following steps:

d ii, mixing the residual softened water in the components according to the proportion in the step d i with methanol to obtain a solution II;

10. The method for preparing the environment-friendly high-hydrogen energy bio-alcohol oil fuel according to any one of claims 1 to 9, characterized by comprising the following steps: