CN107174960A - A kind of method that utilization nano bubble is aerated decelerating membrane pollution - Google Patents

A kind of method that utilization nano bubble is aerated decelerating membrane pollution Download PDF

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Publication number
CN107174960A
CN107174960A CN201710307965.9A CN201710307965A CN107174960A CN 107174960 A CN107174960 A CN 107174960A CN 201710307965 A CN201710307965 A CN 201710307965A CN 107174960 A CN107174960 A CN 107174960A
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China
Prior art keywords
shower nozzle
film
nano bubble
membrane
nano
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CN201710307965.9A
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Inventor
李攀
于水利
徐斌
张国晟
龚超
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Tongji University
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Tongji University
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D65/00Accessories or auxiliary operations, in general, for separation processes or apparatus using semi-permeable membranes
    • B01D65/02Membrane cleaning or sterilisation ; Membrane regeneration
    • B01D65/06Membrane cleaning or sterilisation ; Membrane regeneration with special washing compositions
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/18Use of gases
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/16Regeneration of sorbents, filters

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention provides a kind of aeration method of nano-bubble generating apparatus, film contamination resistance can be significantly lifted, efficient stable flux is maintained.The method generation that the nano bubble is combined using pressure air-dissolving and hydraulic shear, generating means is made up of parts such as water tank, gas-liquid mixed water pump, nano bubble shower nozzles.In order to reach the purpose of above-mentioned decelerating membrane pollution, the technical solution adopted in the present invention is:Nano bubble shower nozzle is arranged in angle on the film surface of various materials and all kinds of film devices at a certain distance, and in film device running, nano-bubble generating apparatus is opened simultaneously, the nano bubble for producing certain air water when diameter rinses film surface and fenestra, so as to substitute the mode of conventional microporous aeration, the fouling membrane degree for slowing down that water pollutant is caused in film operation is reached.Angle between the nano bubble shower nozzle and film device is preferably arranged to plumbness.

Description

A kind of method that utilization nano bubble is aerated decelerating membrane pollution
Technical field
The invention belongs to Membrane cleaning technical field, more particularly to a kind of nano-bubble generating apparatus slows down film running The method of middle fouling membrane.
Background technology
Membrane technology as a kind of water technology, have that effluent characteristics are good, floor space is small in the advanced treating of waste water, The advantages of automaticity is high.Based on above advantage, film process has been widely applied to Water purification and various waste water advanced places In the technique of reason.But serious membrane pollution problem hampers a wide range of popularization of this technology.How to solve in film running The flux that fouling membrane is caused, which declines problem, turns into the greatest problem that all kinds of waste water are more preferably economically handled using membrane technology.It is existing Tradition to reduce the method for film operation pollution be micro-pore aeration method, this method is simple and easy to apply, but to the control of fouling membrane not Ideal, the micro-pore aeration method of on-line operation can not reach the good effect that flux declines and reduces fouling membrane that slows down.
The content of the invention
In order to overcome the above-mentioned deficiencies of the prior art, the invention provides a kind of aeration side of nano-bubble generating apparatus Method, can significantly lift film contamination resistance, maintain efficient stable flux.The nano bubble uses pressure air-dissolving and waterpower The method generation being combined is sheared, generating means is made up of parts such as water tank, gas-liquid mixed water pump, nano bubble shower nozzles.
In order to reach the purpose of above-mentioned decelerating membrane pollution, the technical solution adopted in the present invention is:By nano bubble shower nozzle It is arranged on the film surface of various materials and all kinds of film devices, and in film device running, will be received with angle at a certain distance Rice bubble generator is opened simultaneously, the nano bubble flushing film surface and fenestra of the certain air water of generation when diameter, so as to substitute The mode of conventional microporous aeration, reaches the fouling membrane degree for slowing down that water pollutant is caused in film operation.
Angle between the nano bubble shower nozzle and film device is preferably arranged to plumbness.
In the present invention, described membrane material refers to various microfiltration membranes and milipore filter;Wherein, the micro-filtration membrane material can To be Kynoar (PVDF), polysulfones (PSF), polyacrylonitrile (PAN), polyvinyl chloride (PVC), polypropylene (PP), but not It is only limitted to this;The ultrafiltration membrane material can be Kynoar (PVDF), polyether sulfone (PES), polypropylene (PP), polyethylene (PE), polysulfones (PS), polypropylene nitrile (PAN), polytetrafluoroethylene (PTFE) (PTFE), it is not limited to this.
In the present invention, described membrane module is various microfiltration membranes and hyperfiltration membrane assembly, specifically include Flat Membrane, tubular membrane, Rolled film and hollow-fibre membrane, but it is not limited only to this.
In the present invention, described nano-bubble generating apparatus is pressure air-dissolving occurring mode, device mainly by suction line, Outlet pipeline, four structure compositions of gas-liquid mixed water pump and nano bubble shower nozzle.
In the present invention, described nano bubble shower nozzle can be divided into access type and open type, according to membrane module used not Together, the shower nozzle of use is also corresponding different.
In the present invention, described nano bubble shower nozzle, it has following corresponding arrangement according to the difference of membrane module:
(1) plate type membrane assembly and curtain hollow fiber film assembly:Using open type shower nozzle, as shown in Figure 1, shower nozzle edge Flat Membrane center line is arranged symmetrically, and is specifically divided into and is arranged vertically and is arranged in parallel.Perpendicular to the shower nozzle outlet side of film apart from film surface away from From 5cm-10cm is maintained at, one group is arranged per 10-15cm from plate center along plate length;And bottom is parallel to the shower nozzle of film Also to be arranged symmetrically, shower nozzle top arranges one per 5-10cm apart from film bottom 3-7cm from plate bottom center along plate is wide Group.
(2) tubular membrane component:Using access type shower nozzle, shower nozzle is accessed into tubular membrane top and carries out on-line cleaning;For list Tubular membrane component, membrane module water inlet is directly accessed by shower nozzle, and water inlet 1-2cm is stretched on shower nozzle top;For multitube film group Part, membrane module water inlet is directly accessed by shower nozzle, and water inlet 2-3cm is stretched on shower nozzle top.
(3) rolled membrane module:Using access type shower nozzle, shower nozzle is directly accessed membrane module water inlet, shower nozzle top is stretched into Water inlet 1-2cm.
(4) hollow fiber film type component:Using access type shower nozzle, shower nozzle is directly accessed membrane module water inlet, shower nozzle top Water inlet 2-3cm is stretched at end.
In the present invention, described nano bubble gas-water ratio and nano bubble diameter, according to different type membrane module by following Relevant parameter is run:
(1) plate type membrane assembly and curtain hollow fiber film assembly:Nano-bubble generator is divided into three kinds of operating conditions:
1. the shower nozzle of vertical film surface is only opened:Nano-bubble generator gas-water ratio is adjusted to 1:10-1:20, nano bubble is straight Footpath is 1nm-1 μm;
2. the shower nozzle of parallel film surface is only opened:Nano-bubble generator gas-water ratio is adjusted to 1:10-1:20, nano bubble is straight Footpath is 1nm-1 μm;
3. the shower nozzle of vertical film surface and parallel film surface is opened simultaneously:Nano-bubble generator gas-water ratio is adjusted to 1:10-1: 20, a diameter of 1nm-1 μm of nano bubble;
(2) tubular membrane component:Nano-bubble generator gas-water ratio is adjusted to 1:10-1:40, a diameter of 1nm-1 of nano bubble μm;
(3) rolled membrane module:Nano-bubble generator gas-water ratio is adjusted to 1:10-1:40, a diameter of 1nm-1 of nano bubble μm;
(4) hollow fiber film type component:Nano-bubble generator gas-water ratio is adjusted to 1:10-1:40, nano bubble diameter For 1nm-1 μm;
In the present invention, described waste water can be all types of industries waste water, include but are not limited to what is gone out given in embodiment Handle case.
It is characteristic of the invention that physical cleaning effect of the first public utilization nano bubble in film running, to film table Face and fenestra are effectively rinsed, compared with prior art, can slow down significantly in membrane filtration processes pollutant on film surface with Attachment in fenestra, and flushing action can be produced to attached pollutant so that fouling membrane is effectively controlled.In actual case In example operation, common film filter is contrasted using the membrane flux of nano bubble on-line cleaning, 90% can be maintained in long-time More than.
Brief description of the drawings
The nano bubble of accompanying drawing 1 handles the nozzle layout of sprinkler schematic diagram of Flat Membrane and curtain hollow fiber film assembly.
The nozzle layout of sprinkler schematic diagram of the nano bubble of accompanying drawing 2 processing tubular type, rolling and hollow-fibre membrane.
In figure:1st, water pump;2nd, inlet gage;3rd, inlet valve;4th, hyperfiltration membrane assembly;5th, reactive tank water tank;6th, circulate Water pump;7th, electromagnetic flowmeter;8th, water pump water outlet tube valve;9th, water feeding of water pump tube valve;10th, tube valve is emptied.
Embodiment
Technical scheme is further described with reference to embodiment, but is not limited thereto, it is every right Technical solution of the present invention is modified or equivalent substitution, without departing from the spirit and scope of technical solution of the present invention, all should be contained Cover in protection scope of the present invention.
Embodiment 1
One kind nano bubble method processing ternary oil recovery waste water Kynoar (PVDF) Flat Membrane and curtain doughnut The method of the on-line cleaning of membrane module, its process is:Flat Membrane or curtain hollow-fibre membrane are immersed in film device (such as accompanying drawing Shown in 1);Nano bubble shower nozzle is arranged by diagramatic way, and 5cm is maintained at apart from film surface distance perpendicular to the shower nozzle outlet side of film, One group is arranged per 10cm from plate center along plate length;And bottom parallel to film shower nozzle also to be arranged symmetrically, shower nozzle top away from From film bottom 3cm, one group is arranged per 5cm from plate bottom center along plate is wide;While membrane filtration, gas nano bubble hair is opened Generating apparatus, regulation gas-water ratio is 1:10-1:20, nano bubble diameter control is 10-100 nanometers.1. when only opening vertical film surface Shower nozzle when, in the presence of nano bubble on-line cleaning, membrane flux can maintain more than 92% all the time.2. when only opening parallel During the shower nozzle of film surface, membrane flux can maintain more than 95% all the time.3. when the shower nozzle for opening vertical film surface and parallel film surface simultaneously When, membrane flux can maintain more than 97% all the time.
Embodiment 2
One kind nano bubble method processing ternary oil recovery waste water Kynoar (PVDF) Flat Membrane and curtain doughnut The method of the on-line cleaning of membrane module, its process is:Flat Membrane or curtain hollow-fibre membrane are immersed in film device (such as accompanying drawing Shown in 1);Nano bubble shower nozzle is arranged by diagramatic way, and 10cm is maintained at apart from film surface distance perpendicular to the shower nozzle outlet side of film, One group is arranged per 15cm from plate center along plate length;And bottom parallel to film shower nozzle also to be arranged symmetrically, shower nozzle top away from From film bottom 7cm, one group is arranged per 10cm from plate bottom center along plate is wide;While membrane filtration, nano bubble hair is opened Generating apparatus, regulation gas-water ratio is 1:10-1:20, nano bubble diameter control is 10-200 nanometers.1. when only opening vertical film surface Shower nozzle when, in the presence of nano bubble on-line cleaning, membrane flux can maintain more than 90% all the time.2. when only opening parallel During the shower nozzle of film surface, membrane flux can maintain more than 93% all the time.3. when the shower nozzle for opening vertical film surface and parallel film surface simultaneously When, membrane flux can maintain more than 95% all the time.
Experimental example 3
The side of one kind on-line cleaning of nano bubble method processing fish meal processing waste water polytetrafluoroethylene (PTFE) (PTFE) tubular membrane Method, its process is:Nano bubble shower nozzle is directly accessed tubular membrane component water inlet (as shown in Figure 2), shower nozzle top is stretched into Water inlet 1cm;While membrane filtration, nano-bubble generating apparatus is opened, regulation gas-water ratio is 1:10-1:40, nano bubble Diameter control is that this method can make polytetrafluoroethylene (PTFE) membrane flux maintain more than 92.4% all the time within 200 nanometers.And similarity condition Under, only shower nozzle top is stretched into water inlet distance is changed to 2cm, and this method can make polytetrafluoroethylene (PTFE) membrane flux maintain 93.7% all the time More than.
Experimental example 4
A kind of method of the on-line cleaning of use nano bubble method processing dyeing waste water polyether sulfone rolled film, its process is:Will Nano bubble shower nozzle is directly accessed rolled membrane module water inlet (as shown in Figure 2), and water inlet 1cm is stretched on shower nozzle top;In film While filtering, nano-bubble generating apparatus is opened, regulation gas-water ratio is 1:10-1:40, nano bubble diameter control is received for 200 Within rice, this method can make polytetrafluoroethylene (PTFE) membrane flux maintain more than 91.4% all the time.And under similarity condition, only by shower nozzle top Stretch into water inlet distance and be changed to 2cm, this method can make polytetrafluoroethylene (PTFE) membrane flux maintain more than 93.4% all the time.
Experimental example 5
A kind of method of the on-line cleaning of use nano bubble method processing electroplating wastewater hollow-fibre membrane, its process is:It will receive Rice bubble shower nozzle is directly accessed rolled membrane module water inlet (as shown in Figure 2), and water inlet 2cm is stretched on shower nozzle top;In film mistake While filter, nano-bubble generating apparatus is opened, regulation gas-water ratio is 1:10-1:40, nano bubble diameter control is 200 sodium rices Within, this method can make polytetrafluoroethylene (PTFE) membrane flux maintain more than 90.7% all the time.And under similarity condition, only stretch shower nozzle top Enter water inlet distance and be changed to 3cm, this method can make polytetrafluoroethylene (PTFE) membrane flux maintain more than 92.2% all the time.

Claims (10)

1. a kind of method that utilization nano bubble is aerated decelerating membrane pollution, it is characterized in that, by nano bubble shower nozzle at a certain distance It is arranged on all kinds of film devices of various materials (or function film surface), and in film device running, nano bubble is sent out Generating apparatus is opened simultaneously, and the nano bubble for producing certain air water when diameter rinses the film surface and fenestra of all kinds of film devices.
2. the method that utilization nano bubble according to claim 1 slows down fouling membrane in film running, it is characterised in that Its film object handled is various microfiltration membranes and milipore filter;Wherein, the membrane material can be Kynoar (PVDF), gather Sulfone (PSF), polyacrylonitrile (PAN), polyvinyl chloride (PVC), polypropylene (PP), polyether sulfone (PES), polyethylene (PE), polytetrafluoro Ethene (PTFE) etc., but it is not limited only to this.
3. the method that utilization nano bubble according to claim 1 slows down fouling membrane in film running, it is characterised in that The applicable membrane module of this method is various microfiltration membranes and hyperfiltration membrane assembly, specifically includes Flat Membrane, tubular membrane, rolled film and hollow Tunica fibrosa, but it is not limited only to this.
4. the method that utilization nano bubble according to claim 1 slows down film operation pollution, it is characterised in that used Nano-bubble generating apparatus is various pressure air-dissolving nano-bubble generating apparatus, a diameter of 1nm-1 μ of its nano bubble that can be produced M, uses gas-water ratio for 1:10-1:Between 100.
5. the utilization nano bubble according to claim 1 and 4 slows down the method for fouling membrane in film running, its feature It is the shower nozzle of used nano-bubble generating apparatus, access type and open type can be divided into, according to membrane module used not Together, the shower nozzle of use is also corresponding different.
6. the method that the utilization nano bubble according to claim Isosorbide-5-Nitrae and 5 slows down fouling membrane in film running, it is special Levy and be shower nozzle used by different type membrane module using following arrangement:
(1) plate type membrane assembly and curtain hollow fiber film assembly:Using open type shower nozzle, as shown in Figure 1, shower nozzle is along flat board Film center line is arranged symmetrically, and is specifically divided into and is arranged vertically and is arranged in parallel.Protected perpendicular to the shower nozzle outlet side of film apart from film surface distance Hold in 5cm-10cm, one group is arranged per 10-15cm from plate center along plate length;And bottom is also symmetrical parallel to the shower nozzle of film Arrangement, shower nozzle top arranges one group per 5-10cm apart from film bottom 3-7cm from plate bottom center along plate is wide.
(2) tubular membrane component:Using access type shower nozzle, shower nozzle is accessed into tubular membrane top;For single hose membrane module, by shower nozzle Membrane module water inlet is directly accessed, water inlet 1-2cm is stretched on shower nozzle top;For multitube membrane module, shower nozzle is directly accessed Water inlet 2-3cm is stretched on membrane module water inlet, shower nozzle top.
(3) rolled membrane module:Using access type shower nozzle, shower nozzle is directly accessed membrane module water inlet, shower nozzle top is stretched into water Mouth 1-2cm.
(4) hollow fiber film type component:Using access type shower nozzle, shower nozzle is directly accessed membrane module water inlet, shower nozzle top is stretched Enter water inlet 2-3cm.
7. according to claim Isosorbide-5-Nitrae, the method that the utilization nano bubble described in 5 and 6 slows down fouling membrane in film running, its It is characterised by that nano-bubble generator is run according to different type membrane module by following parameter:
(1) plate type membrane assembly and curtain hollow fiber film assembly:Nano-bubble generator is divided into three kinds of operating conditions:
1. the shower nozzle of vertical film surface is only opened:Generator gas-water ratio is adjusted to 1:10-1:20, a diameter of 1nm-1 μm of nano bubble;
2. the shower nozzle of parallel film surface is only opened:Generator gas-water ratio is adjusted to 1:10-1:20, a diameter of 1nm-1 μm of nano bubble;
3. the shower nozzle of vertical film surface and parallel film surface is opened simultaneously:Generator gas-water ratio is adjusted to 1:10-1:20, nano bubble is straight Footpath is 1nm-1 μm;
(2) tubular membrane component:Generator gas-water ratio is adjusted to 1:10-1:40, a diameter of 1nm-1 μm of nano bubble;
(3) rolled membrane module:Generator gas-water ratio is adjusted to 1:10-1:40, a diameter of 1nm-1 μm of nano bubble;
(4) hollow fiber film type component:Generator gas-water ratio is adjusted to 1:10-1:40, a diameter of 1nm-1 μm of nano bubble.
8. the method that the utilization nano bubble according to claim 1 slows down film operation pollution, it is characterised in that it is adapted to In the microfiltration membranes and milipore filter of various materials, various types of microfiltration membranes, hyperfiltration membrane assembly are also suitable for.
9. the method that the utilization nano bubble according to claim 1 slows down film operation pollution, it is characterised in that this method Applicable object, including all types of industries wastewater treatment, Water purification.
10. the method that the utilization nano bubble according to claim 1 slows down film operation pollution, it is characterised in that described Angle between nano bubble shower nozzle and film device is preferably arranged to plumbness.
CN201710307965.9A 2017-05-04 2017-05-04 A kind of method that utilization nano bubble is aerated decelerating membrane pollution Pending CN107174960A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108499365A (en) * 2018-03-26 2018-09-07 湖州科滤膜技术有限公司 A kind of water purification miillpore filter pipe outer wall automatic cleaning apparatus
CN108640389A (en) * 2018-05-31 2018-10-12 同济大学 The method and micro-nano bubble-vacuum membrane distillation for handling waste water desalination couple desalination system
CN112823051A (en) * 2018-07-03 2021-05-18 复成膜业有限公司 Closely spaced flat submerged membranes and fine bubble aeration
CN114028952A (en) * 2021-11-10 2022-02-11 中国石油大学(北京) Membrane separation device and system capable of effectively reducing membrane pollution
CN115400599A (en) * 2022-09-22 2022-11-29 广东汇祥环境科技有限公司 Green and efficient device and method for cleaning MBR membrane in offline recovery manner by using micro-nano bubbles

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102698607A (en) * 2012-06-06 2012-10-03 北京中农天陆微纳米气泡水科技有限公司 Membrane cleaning device applicable to submerged membrane bioreactor

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102698607A (en) * 2012-06-06 2012-10-03 北京中农天陆微纳米气泡水科技有限公司 Membrane cleaning device applicable to submerged membrane bioreactor

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108499365A (en) * 2018-03-26 2018-09-07 湖州科滤膜技术有限公司 A kind of water purification miillpore filter pipe outer wall automatic cleaning apparatus
CN108499365B (en) * 2018-03-26 2020-12-01 徐州云创物业服务有限公司 Automatic cleaning device for outer wall of water purification microporous filter membrane pipe
CN108640389A (en) * 2018-05-31 2018-10-12 同济大学 The method and micro-nano bubble-vacuum membrane distillation for handling waste water desalination couple desalination system
CN112823051A (en) * 2018-07-03 2021-05-18 复成膜业有限公司 Closely spaced flat submerged membranes and fine bubble aeration
CN114028952A (en) * 2021-11-10 2022-02-11 中国石油大学(北京) Membrane separation device and system capable of effectively reducing membrane pollution
CN115400599A (en) * 2022-09-22 2022-11-29 广东汇祥环境科技有限公司 Green and efficient device and method for cleaning MBR membrane in offline recovery manner by using micro-nano bubbles

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