CN107164950A - Fabric surface coats the preparation method of metal - Google Patents
Fabric surface coats the preparation method of metal Download PDFInfo
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- CN107164950A CN107164950A CN201710424844.2A CN201710424844A CN107164950A CN 107164950 A CN107164950 A CN 107164950A CN 201710424844 A CN201710424844 A CN 201710424844A CN 107164950 A CN107164950 A CN 107164950A
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- Prior art keywords
- solution
- distilled water
- fabric
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- 239000004744 fabric Substances 0.000 title claims abstract description 162
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 30
- 239000002184 metal Substances 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims description 48
- 239000011521 glass Substances 0.000 claims abstract description 90
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 64
- 239000002131 composite material Substances 0.000 claims abstract description 63
- 238000007747 plating Methods 0.000 claims abstract description 63
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 57
- 239000000835 fiber Substances 0.000 claims abstract description 53
- 238000000034 method Methods 0.000 claims abstract description 50
- 239000003638 chemical reducing agent Substances 0.000 claims abstract description 29
- 230000008569 process Effects 0.000 claims abstract description 24
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 239000000126 substance Substances 0.000 claims abstract description 20
- 238000007788 roughening Methods 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 206010070834 Sensitisation Diseases 0.000 claims abstract description 5
- 230000008313 sensitization Effects 0.000 claims abstract description 5
- 230000004913 activation Effects 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 104
- 239000007788 liquid Substances 0.000 claims description 75
- 239000012153 distilled water Substances 0.000 claims description 68
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 52
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 36
- 238000003756 stirring Methods 0.000 claims description 34
- 239000010949 copper Substances 0.000 claims description 28
- 238000005406 washing Methods 0.000 claims description 25
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 22
- 229920000049 Carbon (fiber) Polymers 0.000 claims description 18
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 18
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 18
- 230000003213 activating effect Effects 0.000 claims description 16
- 230000001235 sensitizing effect Effects 0.000 claims description 16
- 229910052802 copper Inorganic materials 0.000 claims description 14
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 13
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 229910052709 silver Inorganic materials 0.000 claims description 13
- 239000004332 silver Substances 0.000 claims description 12
- 239000001509 sodium citrate Substances 0.000 claims description 12
- 238000004821 distillation Methods 0.000 claims description 11
- 229910052759 nickel Inorganic materials 0.000 claims description 11
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(I) nitrate Inorganic materials [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 claims description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 8
- 230000009514 concussion Effects 0.000 claims description 8
- XLYOFNOQVPJJNP-ZSJDYOACSA-N heavy water Substances [2H]O[2H] XLYOFNOQVPJJNP-ZSJDYOACSA-N 0.000 claims description 8
- 229910017052 cobalt Inorganic materials 0.000 claims description 7
- 239000010941 cobalt Substances 0.000 claims description 7
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 7
- 229910021205 NaH2PO2 Inorganic materials 0.000 claims description 6
- LGQLOGILCSXPEA-UHFFFAOYSA-L nickel sulfate Chemical compound [Ni+2].[O-]S([O-])(=O)=O LGQLOGILCSXPEA-UHFFFAOYSA-L 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 5
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 claims description 4
- 229910052927 chalcanthite Inorganic materials 0.000 claims description 4
- 229910000363 nickel(II) sulfate Inorganic materials 0.000 claims description 4
- 229910021580 Cobalt(II) chloride Inorganic materials 0.000 claims description 2
- AVTYONGGKAJVTE-UHFFFAOYSA-L potassium tartrate Chemical class [K+].[K+].[O-]C(=O)C(O)C(O)C([O-])=O AVTYONGGKAJVTE-UHFFFAOYSA-L 0.000 claims description 2
- 239000001472 potassium tartrate Substances 0.000 claims description 2
- 235000011005 potassium tartrates Nutrition 0.000 claims description 2
- 238000007781 pre-processing Methods 0.000 abstract description 6
- 239000011248 coating agent Substances 0.000 abstract description 5
- 238000000576 coating method Methods 0.000 abstract description 5
- 230000003197 catalytic effect Effects 0.000 abstract description 3
- 239000008139 complexing agent Substances 0.000 abstract description 3
- 230000008021 deposition Effects 0.000 abstract description 3
- 239000012530 fluid Substances 0.000 abstract description 3
- 239000000243 solution Substances 0.000 description 104
- 239000000463 material Substances 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 8
- 238000011049 filling Methods 0.000 description 7
- 235000011114 ammonium hydroxide Nutrition 0.000 description 5
- 101100008048 Caenorhabditis elegans cut-4 gene Proteins 0.000 description 4
- 229910002666 PdCl2 Inorganic materials 0.000 description 4
- 229910021626 Tin(II) chloride Inorganic materials 0.000 description 4
- 239000005020 polyethylene terephthalate Substances 0.000 description 4
- 230000004044 response Effects 0.000 description 4
- 235000011083 sodium citrates Nutrition 0.000 description 4
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical class [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 4
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 3
- 238000007772 electroless plating Methods 0.000 description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- -1 sodium hypophosphites Chemical class 0.000 description 3
- 235000002906 tartaric acid Nutrition 0.000 description 3
- 239000011975 tartaric acid Substances 0.000 description 3
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- 238000004176 ammonification Methods 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 230000003115 biocidal effect Effects 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000003365 glass fiber Substances 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 239000012567 medical material Substances 0.000 description 2
- 238000001338 self-assembly Methods 0.000 description 2
- 229910001961 silver nitrate Inorganic materials 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- BPHVHMBNGQRCNN-UHFFFAOYSA-N 2,3-dihydroxybutanedioic acid;potassium Chemical compound [K].OC(=O)C(O)C(O)C(O)=O BPHVHMBNGQRCNN-UHFFFAOYSA-N 0.000 description 1
- 241000208340 Araliaceae Species 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 235000005035 Panax pseudoginseng ssp. pseudoginseng Nutrition 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000005253 cladding Methods 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- GVPFVAHMJGGAJG-UHFFFAOYSA-L cobalt dichloride Chemical class [Cl-].[Cl-].[Co+2] GVPFVAHMJGGAJG-UHFFFAOYSA-L 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 230000001276 controlling effect Effects 0.000 description 1
- 230000002079 cooperative effect Effects 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000008434 ginseng Nutrition 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- IKDUDTNKRLTJSI-UHFFFAOYSA-N hydrazine hydrate Chemical class O.NN IKDUDTNKRLTJSI-UHFFFAOYSA-N 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000006722 reduction reaction Methods 0.000 description 1
- 238000010025 steaming Methods 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/83—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with metals; with metal-generating compounds, e.g. metal carbonyls; Reduction of metal compounds on textiles
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
- C23C18/1872—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
- C23C18/1886—Multistep pretreatment
- C23C18/1893—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
- C23C18/34—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents
- C23C18/36—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron using reducing agents using hypophosphites
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/38—Coating with copper
- C23C18/40—Coating with copper using reducing agents
- C23C18/405—Formaldehyde
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/42—Coating with noble metals
- C23C18/44—Coating with noble metals using reducing agents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/20—Halides of elements of Groups 4 or 14 of the Periodic Table, e.g. zirconyl chloride
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/28—Halides of elements of Groups 8, 9, 10 or 18 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/38—Oxides or hydroxides of elements of Groups 1 or 11 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/40—Fibres of carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemically Coating (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention discloses a kind of in glass fabric and the chemical plating method of carbon fibre fabric surface clad, mainly includes the following steps that：Glass fabric and carbon fibre fabric are surface-treated by preprocessing process first, to assign the catalytic activity that its surface is certain, specific preprocessing process includes oil removing, roughening, sensitization and activation step.Then using chemical plating method in the glass fabric or carbon fibre fabric plating metal on surface by pretreatment, made composite has excellent electric conductivity or magnetic property.By changing the technological parameters such as the main salt in chemical plating fluid, complexing agent, reducing agent consumption, reaction temperature and time, the deposition velocity and integrality of coating can be controlled, so as to realize the regulation and control to conductivity of composite material energy and microscopic appearance.
Description
Technical field
Metallic composite is coated the present invention relates to fabric surface, specially one kind is in carbon fibre fabric or glass fibers
The chemical plating metal method of dimensional fabric surface clad.
Background technology
Fabric surface coats multiple performance of the metallic composite because having fabric and metal concurrently, such as flexible, low
Density, high conductivity, high-tensile and antibiotic property etc., its cooperative effect is in functional stuffing, flexible conducting material, shielding material
The fields such as material, medical material have very wide application prospect.The preparation method of fabric surface cladding metal has a lot,
Such as thermal reduction, sputtering method, self-assembly method, electroless plating method.K. Wangyu etc. [K. Wangyu, et al,
Carbohyd. Polym., 2015,115,317-324] Ag/ bafta composites, the material are prepared using thermal reduction
With excellent electric conductivity and antibiotic property；O. [O. Baghriche, et al, the Surf. Coat. such as Baghriche
Tech., 2012, 206:2410-2416] sputtering method is used in dacron (PET) surface deposited metal Ag films；R. H.
Guo etc. [R. H. Guo, et al, J. Appl. Polym. Sci., 2012,1-8] is first using self-assembly method in PET
Fabric face formation active membrane, the Ag/PET composites with stronger binding ability are prepared secondly by electroless plating method；L.
[L. Yonghee, et al., the Nano. Lett., 2013,13 such as Yonghee:5753-5761.] first using chemistry
Plating method prepares Ni/PET flexible conductive composite materials, and then it is further combined with PU and prepares solar energy charging battery.
In the method for preparing metal/fabric composite, electroless plating method be a kind of technique it is simple, with low cost,
Use extensive method.In recent years, using chemical plating method in inorganic, organic material（Or fiber, polymer）Plated Deng on matrix
The research of metal is more, whether powder, tubing, complex-shaped heterotypic material or flaky material, can obtain coating compared with
Smooth and fine and close composite, and plating metal species also more such as Ni, Cu, Co, Ag metal and its alloy, this is combined
Material has wide application in fields such as shielding material, flexible material and medical materials.
The content of the invention
It is an object of the invention to provide a kind of in glass fabric or the chemistry of carbon fibre fabric surface clad
Method for plating metal, the features such as with low-density, low cost, high flexibility.
The present invention is to adopt the following technical scheme that to realize：
A kind of fabric surface coats the preparation method of metal（I.e. in glass fabric or carbon fibre fabric Surface coating gold
The chemical plating method of category）, comprise the following steps：
（1）Glass fabric or carbon fibre fabric surface are pre-processed：
Glass fabric surface preparation：（a）Oil removing：Glass fabric is placed in acetone soln, 30 DEG C of temperature, constant temperature
Wash standby after concussion 20min；（b）Roughening：Glass fabric after oil removing is added to 40g/L sodium hydroxide coarsening solution
In, temperature 60 C, isothermal vibration 30min is washed standby；（c）Sensitization：Glass fabric Jing Guo roughening treatment is added to
In 30g/L sensitizing solution, 35 DEG C of temperature, isothermal vibration 20min is washed standby；（d）Activation：By by the glass of sensitized treatment
Fabric is added in 0.1g/L activating solution, 30 DEG C of temperature, isothermal vibration 20min, is washed standby；
The process for preparation of the sensitizing solution is specially：Weigh 1.5g SnCl2It is put in beaker, adds 1mL hydrochloric acid, treat
SnCl2Add distilled water to be dissolved to 50mL after being completely dissolved, form sensitizing solution.
The process for preparation of the activating solution is specially：Weigh 0.1g PdCl2It is put in beaker, adds 1mL hydrochloric acid, treat
PdCl2Add distilled water to be dissolved to 1000mL after being completely dissolved, form activating solution.
The pretreatment of carbon fibre fabric：（a）Carbon fibre fabric is added in acetone soln, 30 DEG C of temperature, isothermal vibration
Washed after 20min standby；（b）The fine fabric of the carbon of oil removal treatment is roughened, coarsening solution is concentrated sulfuric acid solution, room temperature concussion
1h, is washed standby；（c）Carbon fibre fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 30 DEG C of temperature, constant temperature
20min is shaken, is washed standby；（d）Carbon fibre fabric after sensitized treatment is added in 0.2g/L activating solution, temperature 30
DEG C, isothermal vibration 20min is washed standby；
The process for preparation of the sensitizing solution is specially：Weigh 1.5g SnCl2It is put in beaker, adds 1mL hydrochloric acid, treat
SnCl2Add distilled water to be dissolved to 50mL after being completely dissolved, form sensitizing solution.
The process for preparation of the activating solution is specially：Weigh 0.2g PdCl2It is put in beaker, adds 2mL hydrochloric acid, treat
PdCl2Add distilled water to be dissolved to 1000mL after being completely dissolved, form activating solution.
（2）It is prepared by metal and fabric composite
, Ni/ glass cloth composites preparation process：Pretreated glass fabric is placed in chemical nickel plating
Solution（A liquid）Container in, when being then heated to 80 DEG C, be added dropwise reductant solution（B liquid）After form plating solution（Its volume is equal to A
Liquid adds B liquid）, react after 10~60min, washing, drying；
What the nickel plating solution was prepared concretely comprises the following steps：Weigh 0.2~1.6g metal salts NiSO4·6H2O and 0.4~1.6g
Na3C6H5O7·2H2O adds 0.5~2.5mL 25wt% NH in a small amount of distilled water after stirring and dissolving3·H2O, then with steaming
Distilled water is settled to 30mL, forms A liquid.
The configuration process of the reductant solution is specially：Weigh 0.1~1.6g NaH2PO2·H2O, is dissolved in
In 10mL distilled water, after stirring, fully dissolving, B liquid is formed.
, Co/ glass cloth composites preparation process：Pretreated glass fabric is placed in chemistry
Plate cobalt liquor（A liquid）Container in, when being then heated to 60~90 DEG C, be added dropwise reductant solution（B liquid）After form plating solution（Its body
Product adds B liquid equal to A liquid）, react after 10~120min, washing, drying；
The preparation of the plating cobalt liquor is concretely comprised the following steps：Weigh 1~3g metal salts CoCl2·6H2O and 2.0~4.5g
Na3C6H5O7·2H2O adds 2~10mL 25wt% NH in a small amount of distilled water after stirring and dissolving3·H2O, then with distillation
Water is settled to 90mL, forms A liquid.
The configuration process of the reductant solution is specially：Weigh 1.0~5.0g NaH2PO2·H2O, is dissolved in
In 10mL distilled water, after stirring, fully dissolving, B liquid is formed.
, Ag/ glass cloth composites preparation process：Pretreated glass fabric is placed in reduction
Agent solution（A liquid）Container in, when being then heated to 30 DEG C, be added dropwise silver ammino solution（B liquid）After form plating solution（Its volume is equal to A
Liquid adds B liquid）, react after 10~60min, washing, drying；
What the reductant solution was prepared concretely comprises the following steps：Weigh 0.2~1.2g C6H12O6、2.0mL C2H5OH and 0.08g
C4H6O6In a small amount of distilled water, after stirring and dissolving, 20mL is then settled to distilled water, A liquid is formed.
The configuration process of the silver ammino solution is specially：Weigh 0.2~1.0g metal salts AgNO3It is dissolved in a small amount of distilled water
In, 0.5~3.0mL 25wt% NH is added after stirring and dissolving3·H2O, the NaOH solution for then adding 10mL to contain 0~0.4g, then
20mL is settled to distilled water, B liquid is formed.
, Cu/ glass cloth composites preparation process：Pretreated glass fabric is placed in copper facing
Solution（A liquid）Container in, when being then heated to 50~80 DEG C, be added dropwise reductant solution（B liquid）After form plating solution（Its volume etc.
Add B liquid in A liquid）, react after 30min, washing, drying；
What the copper plating solution was prepared concretely comprises the following steps：Weigh 0.25~1.5g CuSO4·5H2O and 1.0~3.0g tartaric acid
Potassium is dissolved in a small amount of distilled water, after stirring and dissolving, and 40mL is then settled to distilled water, forms A liquid.
The configuration process of the reductant solution is specially：0.2~1.0g NaOH are weighed to be dissolved in a small amount of distilled water,
0.25~1.5mL 37wt% HCHO is added after stirring and dissolving, 10mL is then settled to distilled water, B liquid is formed.
, Ni/ carbon fabric composite materials preparation process：Pretreated carbon fibre fabric is placed in chemical nickel plating
Solution（A liquid）Container in, when being then heated to 55~95 DEG C, be added dropwise reducing agent（B liquid）After form plating solution（Its volume is equal to A
Liquid adds B liquid）, react after 30min, washing, drying；
What the nickel-plating liquid was prepared concretely comprises the following steps：Weigh 1.0g metal salts NiSO4·6H2O、0.5g Na3C6H5O7·2H2O and
0.5~2.5g C4H6O6In a small amount of distilled water, 1.5~3.5mL 25wt% NH is added after stirring and dissolving3·H2O, Ran Houyong
Distilled water is settled to 30mL, forms A liquid.
The configuration process of the reductant solution is specially：Weigh 0.25~1.5g NaH2PO2·H2O, is dissolved in
In 10mL distilled water, after stirring, fully dissolving, B liquid is formed.
, Ag/ carbon fabric composite materials preparation process：Pretreated carbon fibre fabric is placed in reducing agent
Solution（A liquid）Container in, when being then heated to 30~70 DEG C, be added dropwise silver ammino solution（B liquid）After form plating solution（Its volume is equal to
A liquid adds B liquid）, react after 30min, washing, drying；
What the reductant solution was prepared concretely comprises the following steps：Weigh 0.3~1.5g C6H12O6、2.5mL C2H5OH and 0.1g
C4H6O6In a small amount of distilled water, after stirring and dissolving, 20mL is then settled to distilled water, A liquid is formed.
The configuration process of the silver ammino solution is specially：Weigh 0.4~1.5g metal salts AgNO3It is dissolved in a small amount of distillation
In water, 2.0mL 25wt% NH is added after stirring and dissolving3·H2O, the NaOH solution for then adding 10mL to contain 0.2~1.0g, then
20mL is settled to distilled water, B liquid is formed.
, Cu/ carbon fabric composite materials preparation process：Pretreated carbon fibre fabric is placed in copper facing molten
Liquid（A liquid）Container in, when being then heated to 35~75 DEG C, be added dropwise reductant solution（B liquid）After form plating solution（Its volume is equal to
A liquid adds B liquid）, react after 10~60min, washing, drying；
What the copper plating solution was prepared concretely comprises the following steps：Weigh 1.0g CuSO4·5H2O and 2.5g Na3C6H5O7·2H2O dissolves
In a small amount of distilled water, after stirring and dissolving, 0.2~1.0g NaOH is added, 49mL is then settled to distilled water, A liquid is formed.
The configuration process of the reductant solution is specially：B liquid is 0.5~2.5mL N2H4·H2O solution.
It is contemplated that using chemical plating method glass fabric or carbon fibre fabric surface plate respectively argent,
Nickel, copper and cobalt（Just for glass fabric）, glass fabric and carbon fibre fabric are entered by preprocessing process first
Row surface treatment, makes its surface have certain catalytic activity, and specific preprocessing process includes oil removing, roughening, sensitization and lived
Change four steps；Then using chemical plating method in the glass fabric or carbon fibre fabric surface gold-plating by pretreatment
Category, gained metal/fabric composite has excellent electric conductivity or magnetic property.By controlling the master in chemical plating fluid
The technological parameters such as salt, complexing agent, reducing agent consumption, reaction temperature and time, can control the deposition velocity and integrality of coating,
So as to realize the regulation and control to conductivity of composite material energy and microscopic appearance.Wherein, glass fabric and carbon fibre fabric are carried out
The coarsening solution of pretreatment, sensitizing solution, activating solution preparation it is also very crucial, different preprocessing solution to glass fabric and
The pretreating effect of carbon fibre fabric is different, also directly affects the combination of metal and glass fabric and carbon fibre fabric
Ability.
The present invention is reasonable in design, gold-plated in glass fabric or carbon fibre fabric surface difference using chemical plating method
Category, is obtained with low-density, low cost, high conduction performance（Magnetic property）Composite, have in electromagnetic shielding field extensive
Application, can meet contemporary lightweight, efficiently, widescreen shielding etc. technical requirements.
Brief description of the drawings
Fig. 1 represents the SEM pictures of Ni/ glass cloth composites in embodiment 1.
Fig. 2 represents Fig. 1 partial enlarged drawing.
Fig. 3 represents the SEM pictures of Co/ glass cloth composites in embodiment 2.
Fig. 4 represents Fig. 3 partial enlarged drawing.
Fig. 5 represents the SEM pictures of Ag/ glass cloth composites in embodiment 3.
Fig. 6 represents Fig. 5 partial enlarged drawing.
Fig. 7 represents the SEM pictures of Cu/ glass cloth composites in embodiment 4.
Fig. 8 represents Fig. 7 partial enlarged drawing.
Fig. 9 represents the SEM pictures of Ni/ carbon fabric composite materials in embodiment 5.
Figure 10 represents Fig. 9 partial enlarged drawing.
Figure 11 represents the SEM pictures of Ag/ carbon fabric composite materials in embodiment 6.
Figure 12 represents Figure 11 partial enlarged drawing.
Figure 13 represents the SEM pictures of Cu/ carbon fabric composite materials in embodiment 7.
Figure 14 represents Figure 13 partial enlarged drawing.
Embodiment
The specific embodiment of the present invention is described in detail below.
The preparation method of the present invention that metal is coated in fabric surface, mainly includes：Pass through pretreatment first
Process is surface-treated to glass fabric and carbon fibre fabric, to assign the catalytic activity that its surface is certain, specifically
Preprocessing process includes oil removing, roughening, sensitization and activation step；Then using chemical plating method in the glass fibers by pretreatment
Dimensional fabric or carbon fibre fabric plating metal on surface, made composite have excellent electric conductivity or magnetic property.
By changing the technological parameters such as the main salt in chemical plating fluid, complexing agent, reducing agent consumption, reaction temperature and time,
The deposition velocity and integrality of coating can be controlled, so as to realize the regulation and control to conductivity of composite material energy and microscopic appearance.
It is specific embodiment below.
Embodiment 1
A kind of chemical nickel plating method in glass fabric surface clad nickel, comprises the following steps：
（1）Glass fabric surface preparation：
Cut 4 × 5cm2The glass fabric of size is placed in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
It is standby；Then the glass fabric after oil removing is added in 40g/L sodium hydroxide coarsening solution, temperature 60 C, constant temperature shake
30min is swung, is washed standby；Glass fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 35 DEG C of temperature,
Isothermal vibration 20min, is washed standby；It will be added to by the glass fabric of sensitized treatment in 0.1g/L activating solution, temperature
30 DEG C of degree, isothermal vibration 20min is washed standby.
（2）The preparation of Ni/ glass cloth composites
1g nickel sulfates and 1g sodium citrates are weighed, in the beaker for being added sequentially to fill a small amount of distilled water, after stirring and dissolving, is added
25wt% ammoniacal liquor 1.5mL, is then settled to 30mL with distilled water, is afterwards added to above-mentioned treated glass fabric
A liquid is used as in the solution of preparation；1.2g sodium hypophosphites then are weighed, are dissolved in 10mL distilled water, are stirred, fully
Reducing solution B liquid is used as after dissolving.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 80 DEG C, B is added dropwise
Liquid, forms terminating reaction after plating solution 40mL, reaction 1h, dries 2h with distillation water washing 3 times, 60 DEG C, obtain after being all added dropwise
Ni/ glass cloth composites.
The volume resistivity value of the Ni/ glass cloth composites of the present embodiment is shown in Table 1；Ni/ glass fabrics
The SEM pictures of composite are shown in Fig. 1,2.
Embodiment 2
A kind of electroless cobalt plating method in glass fabric surface clad cobalt, comprises the following steps：
（1）Glass fabric surface preparation
Cut 4 × 5cm2The glass fabric of size is placed in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
It is standby；Then the glass fabric after oil removing is added in 40g/L sodium hydroxide coarsening solution, temperature 60 C, constant temperature shake
30min is swung, is washed standby；Glass fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 35 DEG C of temperature,
Isothermal vibration 20min, is washed standby；It will be added to by the glass fabric of sensitized treatment in 0.1g/L activating solution, temperature
30 DEG C of degree, isothermal vibration 20min is washed standby.
（2）The preparation of Co/ glass cloth composites
2.5g cobalt chlorides and 3.5g sodium citrates are weighed, in the beaker for being added sequentially to fill a small amount of distilled water, after stirring and dissolving,
25wt% ammoniacal liquor 6mL is added, 90mL is then settled to distilled water, afterwards above-mentioned treated glass fabric is added
A liquid is used as into the solution of preparation；2.0g sodium hypophosphites are weighed, are dissolved in 10mL distilled water, are stirred, it is fully molten
Reducing solution B liquid is used as after solution.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 85 DEG C, B is added dropwise
Liquid, forms after being all added dropwise and stops reaction after plating solution 100mL, question response 80min, is dried at the rear water washing 3 times, 60 DEG C with distillation
2h, obtains Co/ glass cloth composites.
The volume resistivity value of the Co/ glass cloth composites of the present embodiment is shown in Table 1；Co/ glass fabrics
The SEM pictures of composite are shown in Fig. 3,4.
Embodiment 3
A kind of chemical silver plating method in glass fabric surface clad silver, comprises the following steps：
（1）Glass fabric surface preparation
Cut 4 × 5 cm2The glass fabric of size is placed in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
It is standby；Then the glass fabric after oil removing is added in 40g/L sodium hydroxide coarsening solution, temperature 60 C, constant temperature shake
30min is swung, is washed standby；Glass fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 35 DEG C of temperature,
Isothermal vibration 20min, is washed standby；It will be added to by the glass fabric of sensitized treatment in 0.1g/L activating solution, temperature
30 DEG C of degree, isothermal vibration 20min is washed standby.
（2）The preparation of Ag/ glass cloth composites
0.8g glucose and 0.08g tartaric acid are weighed, in the beaker for being added sequentially to fill a small amount of distilled water, after stirring and dissolving,
2.0mL ethanol is added, 20mL is then settled to distilled water, above-mentioned treated glass fabric is added to matched somebody with somebody afterwards
A liquid is used as in the solution of system；0.8g silver nitrates are weighed, are dissolved in 10mL distilled water, are stirred, are fully added dropwise after dissolving
2.0mL ammoniacal liquor becomes to solution to be clarified, then into solution plus a certain amount of sodium hydroxide solution, finally the ammonification aqueous solution again
Until solution clarification, is then settled to 20mL with distilled water, is used as B liquid.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 30 DEG C, B is added dropwise
Liquid, forms after being all added dropwise and stops reaction after plating solution 40mL, the min of question response 30, is dried at the rear water washing 3 times, 60 DEG C with distillation
2h, obtains Ag/ glass cloth composites.
The volume resistivity value of the Ag/ glass cloth composites of the present embodiment is shown in Table 1；Ag/ glass fabrics
The SEM pictures of composite are shown in Fig. 5,6.
Embodiment 4
A kind of electroless copper plating method in glass fabric surface clad copper, comprises the following steps：
（1）Glass fabric surface preparation
Cut 4 × 5cm2The glass fabric of size is placed in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
It is standby；Then the glass fabric after oil removing is added in 40g/L sodium hydroxide coarsening solution, temperature 60 C, constant temperature shake
30min is swung, is washed standby；Glass fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 35 DEG C of temperature,
Isothermal vibration 20min, is washed standby；It will be added to by the glass fabric of sensitized treatment in 0.1g/L activating solution, temperature
30 DEG C of degree, isothermal vibration 20min is washed standby.
（2）The preparation of Cu/ glass cloth composites
0.5g copper sulphate and 2.5g potassium tartrates are weighed, afterwards will be upper in the beaker for being added sequentially to fill 40mL distilled water
Treated glass fabric is stated to be added in the solution of preparation as A liquid；0.5g sodium hydroxides then are weighed, are dissolved
In a small amount of distilled water, stirring, fully dissolving after plus 1.5mL formalin, after be dissolved to distilled water 10mL as also
Stoste B liquid.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 60 DEG C, B is added dropwise
Liquid, forms after being all added dropwise and is dried at terminating reaction after plating solution 50mL, question response 30min, the rear water washing 3 times, 60 DEG C with distillation
2h, obtains Cu/ glass cloth composites.
The volume resistivity value of the Cu/ glass cloth composites of the present embodiment is shown in Table 1；Cu/ glass fabrics
The SEM pictures of composite are shown in Fig. 7,8.
Embodiment 5
A kind of chemical nickel plating method in carbon fibre fabric surface clad nickel, comprises the following steps：
（1）Carbon fibre fabric surface preparation
It is cut to 4 × 5cm2The carbon fibre fabric of size is added in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
Wash standby；Then the fine fabric of the carbon of oil removal treatment is roughened, coarsening solution is concentrated sulfuric acid solution, room temperature concussion 1h is washed standby
With；Carbon fibre fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 30 DEG C of temperature, isothermal vibration 20min is washed
Wash standby；Carbon fibre fabric after sensitized treatment is added in 0.2g/L activating solution, 30 DEG C of temperature, isothermal vibration 20min,
Washing is standby.
（2）The preparation of Ni/ carbon fabric composite materials
1.0g nickel sulfates and 0.5g sodium citrates and 1.5g tartaric acid are weighed, is added sequentially to fill the beaker of a small amount of distilled water
In, after stirring and dissolving, 25wt% ammoniacal liquor 2.5mL is added, 30mL is then settled to distilled water, afterwards will be above-mentioned treated
Carbon fibre fabric is added in the solution of preparation as A liquid；0.5g sodium hypophosphites then are weighed, are dissolved in 10mL's
In distilled water, reducing solution B liquid is used as after stirring, fully dissolving.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 85 DEG C, B is added dropwise
Liquid, forms terminating reaction after plating solution 40mL, reaction 30min, dries 2h with distillation water washing 3 times, 60 DEG C, obtain after being all added dropwise
To Ni/ carbon fabric composite materials.
The volume resistivity value of the Ni/ carbon fabric composite materials of the present embodiment is shown in Table 1；Ni/ carbon fibre fabrics are combined
The SEM pictures of material are shown in Figure 12,13.
Embodiment 6
A kind of chemical silver plating method in carbon fibre fabric surface clad silver, comprises the following steps：
（1）Carbon fibre fabric surface preparation
It is cut to 4 × 5cm2The carbon fibre fabric of size is added in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
Wash standby；Then the fine fabric of the carbon of oil removal treatment is roughened, coarsening solution is concentrated sulfuric acid solution, room temperature concussion 1h is washed standby
With；Carbon fibre fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 30 DEG C of temperature, isothermal vibration 20min is washed
Wash standby；Carbon fibre fabric after sensitized treatment is added in 0.2g/L activating solution, 30 DEG C of temperature, isothermal vibration 20min,
Washing is standby.
（2）The preparation of Ag/ carbon fabric composite materials
1.2g glucose and 0.1g tartaric acid are weighed, in the beaker for being added sequentially to fill a small amount of distilled water, after stirring and dissolving, plus
Enter 2.5mL ethanol, 20mL is then settled to distilled water, above-mentioned treated carbon fibre fabric is added to preparation afterwards
A liquid is used as in solution；1.0g silver nitrates are weighed, are dissolved in 10mL distilled water, are stirred, 2.0mL fully is added dropwise after dissolving
Ammoniacal liquor become to solution and clarify, then into solution plus a certain amount of sodium hydroxide solution, finally again the ammonification aqueous solution until
Solution is clarified, and is then settled to 20mL with distilled water, is used as B liquid.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 30 DEG C, B is added dropwise
Liquid, forms after being all added dropwise and stops reaction after plating solution 40mL, question response 30min, is dried at the rear water washing 3 times, 60 DEG C with distillation
2h, obtains Ag/ carbon fabric composite materials.
The volume resistivity value of the Ag/ carbon fabric composite materials of the present embodiment is shown in Table 1；Ag/ carbon fibre fabrics are combined
The SEM pictures of material are shown in Figure 11,12.
Embodiment 7
A kind of electroless copper plating method in carbon fibre fabric surface clad copper, comprises the following steps：
（1）Carbon fibre fabric surface preparation
It is cut to 4 × 5cm2The carbon fibre fabric of size is added in acetone soln, 30 DEG C of temperature, is washed after isothermal vibration 20min
Wash standby；Then the fine fabric of the carbon of oil removal treatment is roughened, coarsening solution is concentrated sulfuric acid solution, room temperature concussion 1h is washed standby
With；Carbon fibre fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 30 DEG C of temperature, isothermal vibration 20min is washed
Wash standby；Carbon fibre fabric after sensitized treatment is added in 0.2g/L activating solution, 30 DEG C of temperature, isothermal vibration 20min,
Washing is standby.
（2）The preparation of Cu/ carbon fabric composite materials
1.0g copper sulphate and 2.5g sodium citrates are weighed, in the beaker for being added sequentially to fill a small amount of distilled water, after stirring and dissolving,
0.2g NaOH dissolvings are added, 49mL is then settled to distilled water, afterwards above-mentioned treated carbon fibre fabric is added to
A liquid is used as in the solution of preparation；1.0mL hydrazine hydrates are used as reducing solution B liquid.
The beaker for filling A liquid is placed in water bath chader and heated, when burning cup temperature rises to 65 DEG C, is added dropwise
B liquid, forms terminating reaction after plating solution 50mL, reaction 20min, 2h is dried with distillation water washing 3 times, 60 DEG C after being all added dropwise,
Obtain Cu/ carbon fabric composite materials.
The volume resistivity value of the Cu/ carbon fabric composite materials of the present embodiment is shown in Table 1；Cu/ carbon fibre fabrics are combined
The SEM pictures of material are shown in Figure 13,14.
The volume resistivity value of corresponding composite such as table 1 in each embodiment：
Table 1
。
It should be noted last that, the above embodiments are merely illustrative of the technical solutions of the present invention and it is unrestricted, although ginseng
It is described in detail according to the embodiment of the present invention, it will be understood by those within the art that, to technical scheme
Modify or equivalent substitution, without departure from the spirit and scope of technical scheme, it all should cover claim
In protection domain.
Claims (1)
1. a kind of fabric surface coats the preparation method of metal, it is characterised in that：Comprise the following steps：
（1）Glass fabric or carbon fibre fabric surface are pre-processed：
Glass fabric surface preparation：（a）Oil removing：Glass fabric is placed in acetone soln, 30 DEG C of temperature, constant temperature
Wash standby after concussion 20min；（b）Roughening：Glass fabric after oil removing is added to 40g/L sodium hydroxide coarsening solution
In, temperature 60 C, isothermal vibration 30min is washed standby；（c）Sensitization：Glass fabric Jing Guo roughening treatment is added to
In 30g/L sensitizing solution, 35 DEG C of temperature, isothermal vibration 20min is washed standby；（d）Activation：By by the glass of sensitized treatment
Fabric is added in 0.1g/L activating solution, 30 DEG C of temperature, isothermal vibration 20min, is washed standby；
The pretreatment of carbon fibre fabric：（a）Carbon fibre fabric is added in acetone soln, 30 DEG C of temperature, isothermal vibration 20min
After wash standby；（b）The fine fabric of the carbon of oil removal treatment is roughened, coarsening solution is concentrated sulfuric acid solution, room temperature concussion 1h, washing
It is standby；（c）Carbon fibre fabric Jing Guo roughening treatment is added in 30g/L sensitizing solution, 30 DEG C of temperature, isothermal vibration
20min, is washed standby；（d）Carbon fibre fabric after sensitized treatment is added in 0.2g/L activating solution, 30 DEG C of temperature, it is permanent
Temperature concussion 20min, is washed standby；
（2）It is prepared by metal and fabric composite
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image002.jpg, Ni/ glass cloth composites preparation process：Pretreated glass fabric is placed in chemical nickel plating molten
In the container of liquid, when being then heated to 80 DEG C, it is added dropwise after reductant solution and forms plating solution, after 10~60min of reaction, washing, baking
It is dry；
What the nickel plating solution was prepared concretely comprises the following steps：Weigh 0.2~1.6g metal salts NiSO4·6H2O and 0.4~1.6g
Na3C6H5O7·2H2O adds 0.5~2.5mL 25wt% NH in distilled water after stirring and dissolving3·H2O, then with distillation
Water is settled to 30mL；
The configuration process of the reductant solution is specially：Weigh 0.1~1.6g NaH2PO2·H2O, is dissolved in 10mL's
In distilled water, stirring, fully dissolving；
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image004.jpg, Co/ glass cloth composites preparation process：Pretreated glass fabric is placed in electroless cobalt plating
In the container of solution, when being then heated to 60~90 DEG C, it is added dropwise after reductant solution and forms plating solution, after 10~120min of reaction,
Washing, drying；
What the plating cobalt liquor was prepared concretely comprises the following steps：Weigh 1~3g metal salts CoCl2·6H2O and 2.0~4.5g
Na3C6H5O7·2H2O adds 2~10mL 25wt% NH in distilled water after stirring and dissolving3·H2O, it is then fixed with distilled water
Hold to 90mL；
The configuration process of the reductant solution is specially：Weigh 1.0~5.0g NaH2PO2·H2O, is dissolved in 10mL's
In distilled water, stirring, fully dissolving；
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image006.jpg, Ag/ glass cloth composites preparation process：Pretreated glass fabric is placed in reducing agent molten
In the container of liquid, when being then heated to 30 DEG C, it is added dropwise after silver ammino solution and forms plating solution, after 10~60min of reaction, washing, drying；
What the reducing solution was prepared concretely comprises the following steps：Weigh 0.2~1.2g C6H12O6、2.0mL C2H5OH and 0.08g
C4H6O6In distilled water, after stirring and dissolving, then 20mL is settled to distilled water；
The configuration process of the silver ammino solution is specially：Weigh 0.2~1.0g metal salts AgNO3It is dissolved in distilled water, stirs molten
0.5~3.0mL 25wt% NH is added after solution3·H2O, the NaOH solution for then adding 10mL to contain 0~0.4g, then uses distilled water
It is settled to 20mL；
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image008.jpg, Cu/ glass cloth composites preparation process：Pretreated glass fabric is placed in copper plating solution
Container in, when being then heated to 50~80 DEG C, plating solution is formed after reductant solution is added dropwise, after reaction 30min, washing, drying；
What the copper plating solution was prepared concretely comprises the following steps：Weigh 0.25~1.5g CuSO4·5H2O and 1.0~3.0g potassium tartrates
It is dissolved in distilled water, after stirring and dissolving, is then settled to 40mL with distilled water；
The configuration process of the reductant solution is specially：Weigh 0.2~1.0g NaOH to be dissolved in distilled water, stirring and dissolving
0.25~1.5mL 37wt% HCHO is added afterwards, is then settled to 1mL with distilled water；
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image010.jpg, Ni/ carbon fabric composite materials preparation process：Pretreated carbon fibre fabric is placed in chemical nickel-plating solution
Container in, when being then heated to 55~95 DEG C, plating solution is formed after reductant solution is added dropwise, after reaction 30min, washing, drying；
What the nickel-plating liquid was prepared concretely comprises the following steps：Weigh 1.0g metal salts NiSO4·6H2O、0.5g Na3C6H5O7·2H2O and
0.5~2.5g C4H6O6In distilled water, 1.5~3.5mL 25wt% NH is added after stirring and dissolving3·H2O, then with distillation
Water is settled to 30mL；
The configuration process of the reductant solution is specially：Weigh 0.25~1.5g NaH2PO2·H2O, is dissolved in 10mL
Distilled water in, stirring, fully dissolving；
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image012.jpg, Ag/ carbon fabric composite materials preparation process：Pretreated carbon fibre fabric is placed in reductant solution
In container, when being then heated to 30~70 DEG C, it is added dropwise after silver ammino solution and forms plating solution, after reaction 30min, washing, drying；
What the reductant solution was prepared concretely comprises the following steps：Weigh 0.3~1.5g C6H12O6、2.5mL C2H5OH and 0.1g
C4H6O6In distilled water, after stirring and dissolving, then 20mL is settled to distilled water；
The configuration process of the silver ammino solution is specially：Weigh 0.4~1.5g metal salts AgNO3It is dissolved in distilled water, stirs
2.0mL 25wt% NH is added after dissolving3·H2O, the NaOH solution for then adding 10mL to contain 0.2~1.0g is then fixed with distilled water
Hold to 20mL；
Explanation: D:\cpc\cases\inventions\a993b2ea-59af-4316-b2bc-89c025a8befd\new\100001\dest_path_image014.jpg, Cu/ carbon fabric composite materials preparation process：Pretreated carbon fibre fabric is placed in the appearance of copper plating solution
In device, when being then heated to 35~75 DEG C, it is added dropwise after reductant solution and forms plating solution, after 10~60min of reaction, washing, drying；
What the copper plating solution was prepared concretely comprises the following steps：Weigh 1.0g CuSO4·5H2O and 2.5g Na3C6H5O7·2H2O dissolves
In distilled water, after stirring and dissolving, 0.2~1.0g NaOH is added, then 49mL is settled to distilled water；
The configuration process of the reductant solution is specially：0.5~2.5mL N2H4·H2O solution.
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| CN108085968A (en) * | 2017-12-05 | 2018-05-29 | 武汉纺织大学 | A kind of preparation method of metallic coated fabric |
| CN108660743A (en) * | 2018-05-08 | 2018-10-16 | 浙江理工大学 | A kind of preparation method of single side silver coating fabric |
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| CN110205611A (en) * | 2019-06-25 | 2019-09-06 | 北京理工大学 | A kind of method of quartz fibre chemical nickel phosphorus plating |
| CN115626781A (en) * | 2022-11-11 | 2023-01-20 | 杭州师范大学 | Metal-plated glass fiber with metal oxide as medium and preparation method thereof |
| CN116676810A (en) * | 2023-04-06 | 2023-09-01 | 南京工业大学 | Nickel-plated carbon fiber paper for electromagnetic shielding material and preparation method thereof |
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