CN104532214A - Preparation method of high-performance conductive glass fiber - Google Patents
Preparation method of high-performance conductive glass fiber Download PDFInfo
- Publication number
- CN104532214A CN104532214A CN201410839503.8A CN201410839503A CN104532214A CN 104532214 A CN104532214 A CN 104532214A CN 201410839503 A CN201410839503 A CN 201410839503A CN 104532214 A CN104532214 A CN 104532214A
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- Prior art keywords
- glass fibre
- preparation
- solution
- glass fiber
- nickel plating
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/18—Pretreatment of the material to be coated
- C23C18/1851—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material
- C23C18/1872—Pretreatment of the material to be coated of surfaces of non-metallic or semiconducting in organic material by chemical pretreatment
- C23C18/1886—Multistep pretreatment
- C23C18/1893—Multistep pretreatment with use of organic or inorganic compounds other than metals, first
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemically Coating (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
The invention discloses a preparation method of a high-performance conductive glass fiber, and relates to the technical field of production of glass fibers. The preparation method comprises four process steps of purification and coarsening treatment, sensitization and activation treatment, cleaning and chemical nickel plating. According to the preparation method disclosed by the invention, a layer of a conductive metal is plated on the surface of the glass fiber by adopting a nickel plating method to ensure that the glass fiber has good conductivity; by completing purification, coarsening, sensitization and activation treatments of the glass fiber in the prior period of nickel plating, nickel can be well combined with the glass fiber; the glass fiber is relatively good in luster, high in plated layer stability and difficult in oxidation; and optimized sensitizing solution and palladium chloride activating solution accelerate the proceeding of later-period nickel plating and shorten the reaction time. The preparation method is simple in whole process and strong in operability.
Description
Technical field
The present invention relates to glass fibre production technical field, be specifically related to a kind of preparation method of high-performance conductive glass fibre.
Background technology
Along with developing rapidly of electronic industry, electronic instrument is day by day universal, but, these are that the electronic machine of shell in use likely becomes electromagnetic wave emission source and pollutes electromagnetic space with plastics, or be subject to outside electromagnetic interference as reception source, flase operation is there is in electromagnetic interference (EM I) by making the electronic machine of unshielded function, affect the normal work of instrument, in order to solve the problem, plastics as electronics enclosure must be given with electroconductibility, make it have the ability of shielding electromagnetic wave, make plastics have conductivity and have two kinds of basic skills, one sprays one deck conducting material at frosting, as metal etc., another kind method is that conductive filler material and mixed with resin prepare conductive plastics.
In recent years, adopt conductive fibrous filler and resin base material compound to prepare the conductive plastics with shielding properties and become a study hotspot, conventional kinds of fibers has: steel fiber, carbon fiber, organic fibre etc., but these fibrous packing want widespread use also by price, mechanical property, the restriction of the aspects such as electrical property, metallized glass fiber due to intensity high, good conductivity, easy-formation, low cost and other advantages, because of but a kind of conductive filler material of excellence, application number is the production technique that CN 201410220597.0 discloses a kind of electroconductive glass fibre, the moiety of described electroconductive glass fibre is the host glass of weight percent 95%-70% and the nanometer silver of weight percent 5%-30%, the step preparing the production technique of described electroconductive glass fibre is: will produce the melting sources of host glass, pull into glass fiber, glass fibre is immersed nano-silver colloid solution 15-20S, after its surface is fully covered by described nano-silver colloid, with 70 DEG C of hot blast dryings, tentatively obtained electroconductive glass fibre, described electroconductive glass fibre is put into deionized water and soak 40-60S, dry and can obtain the strong glass fibre finished product of conductivity, the present embodiment production cost is relatively low, and nano-silver colloid is prepared simple to operation, the conductivity of silver is best in all metals, glass fibre can be played a role in more field, but this kind of glass fibre also exists the more weak problem of conductivity, and overall preparation technology is not easy to operate.
Summary of the invention
It is high that problem to be solved by this invention is to provide a kind of electroconductibility, the preparation method of the simple high-performance conductive glass fibre of technique.
To achieve these goals, the technical scheme that the present invention takes for: the preparation method of a kind of high-performance conductive glass fibre provided, comprises the steps:
(1) purification, roughening treatment: first ready glass fibre is carried out high temperature oil removal treatment, enable its surface be flooded profit, for roughening treatment is ready, then flood 3-6min with coarsening solution, the temperature controlling coarsening solution is 30-40 DEG C;
(2) sensitization, activation treatment: the glass fibre in step (1) after roughening treatment is put in sensitizing solution and places 10-20min, after sensitized treatment, glass fibre is put in activation solution and place 10-15min;
(3) clean: by the distilled water of the glass fibre after process in step (2) cleaning 3-4 time;
(4) chemical nickel plating: the glass fibre after cleaning up through step (3) is put in plating solution and carries out chemical nickel plating and can obtain product.
Preferably, in described step (2), sensitizing solution used is specially the titanium chloride sensitizing solution that concentration is 10g/l.
Preferably, in described step (2) so that activation solution is specially the Palladous chloride activation solution that concentration is 0.25g/l.
Preferably, in described step (4), plating solution chemical constitution used comprises single nickel salt, copper sulfate, inferior sodium phosphate and formaldehyde.
Adopt technical scheme of the present invention, the method of nickel plating is adopted to plate one deck conducting metal at fiberglass surfacing, make it have good conductivity, by having carried out the purification of glass fibre, alligatoring, sensitization and activation treatment early stage in nickel plating, nickel can be combined with glass fibre well, the gloss of glass fibre is better, and coating stability is high, not easily oxidized, preferred titanium chloride sensitizing solution and Palladous chloride activation solution accelerate the carrying out of later stage nickel plating, shorten the reaction times, integrated artistic is simple, workable.
Embodiment
The technique means realized for making the present invention, creation characteristic, reaching object and effect is easy to understand, below in conjunction with embodiment, setting forth the present invention further.
embodiment 1:
A preparation method for high-performance conductive glass fibre, comprises the steps:
(1) purification, roughening treatment: first ready glass fibre is carried out high temperature oil removal treatment, enable its surface be flooded profit, for roughening treatment is ready, then flood 3-6min with coarsening solution, the temperature controlling coarsening solution is 30-40 DEG C;
(2) sensitization, activation treatment: the glass fibre in step (1) after roughening treatment being put into concentration is place 15min in the titanium chloride sensitizing solution of 10g/l, glass fibre being put into concentration after sensitized treatment is place 13min in the Palladous chloride activation solution of 0.25g/l;
(3) clean: the glass fibre distilled water after process in step (2) is cleaned 4 times;
(4) chemical nickel plating: put in plating solution by the glass fibre after cleaning up through step (3) and carry out chemical nickel plating and can obtain product, wherein, plating solution chemical constitution used comprises single nickel salt, copper sulfate, inferior sodium phosphate and formaldehyde.
Based on above-mentioned, the method of nickel plating is adopted to plate one deck conducting metal at fiberglass surfacing, make it have good conductivity, by having carried out the purification of glass fibre, alligatoring, sensitization and activation treatment early stage in nickel plating, nickel can be combined with glass fibre well, the gloss of glass fibre is better, and coating stability is high, not easily oxidized, preferred titanium chloride sensitizing solution and Palladous chloride activation solution accelerate the carrying out of later stage nickel plating, shorten the reaction times, integrated artistic is simple, workable.
Obvious specific implementation of the present invention is not subject to the restrictions described above; as long as have employed the improvement of the various unsubstantialities that method of the present invention is conceived and technical scheme is carried out; or design of the present invention and technical scheme directly applied to other occasion, all within protection scope of the present invention without to improve.
Claims (4)
1. a preparation method for high-performance conductive glass fibre, is characterized in that: comprise the steps:
(1) purification, roughening treatment: first ready glass fibre is carried out high temperature oil removal treatment, enable its surface be flooded profit, for roughening treatment is ready, then also flood 3-6min with thick liquid, the temperature controlling coarsening solution is 30-40 DEG C;
(2) sensitization, activation treatment: the glass fibre in step (1) after roughening treatment is put in sensitizing solution and places 10-20min, after sensitized treatment, glass fibre is put in activation solution and place 10-15min;
(3) clean: by the distilled water of the glass fibre after process in step (2) cleaning 3-4 time;
(4) chemical nickel plating: the glass fibre after cleaning up through step (3) is put in plating solution and carries out chemical nickel plating and can obtain product.
2. the preparation method of a kind of high-performance conductive glass fibre according to claim 1, is characterized in that: in described step (2), sensitizing solution used is specially the titanium chloride sensitizing solution that concentration is 10g/l.
3. the preparation method of a kind of high-performance conductive glass fibre according to claim 1, is characterized in that: so that activation solution is specially the Palladous chloride activation solution that concentration is 0.25g/l in described step (2).
4. a preparation method for a kind of high-performance conductive glass fibre according to claim 1, is characterized in that: plating solution chemical constitution used in described step (4) comprises single nickel salt, copper sulfate, inferior sodium phosphate and formaldehyde.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410839503.8A CN104532214A (en) | 2014-12-30 | 2014-12-30 | Preparation method of high-performance conductive glass fiber |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410839503.8A CN104532214A (en) | 2014-12-30 | 2014-12-30 | Preparation method of high-performance conductive glass fiber |
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| CN104532214A true CN104532214A (en) | 2015-04-22 |
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| CN201410839503.8A Pending CN104532214A (en) | 2014-12-30 | 2014-12-30 | Preparation method of high-performance conductive glass fiber |
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Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844019A (en) * | 2015-04-28 | 2015-08-19 | 安徽丹凤集团桐城玻璃纤维有限公司 | Preparation process for glass fiber |
| CN104963064A (en) * | 2015-07-01 | 2015-10-07 | 安徽丹凤电子材料股份有限公司 | Production process of glass fiber anti-static cloth |
| CN105350044A (en) * | 2015-12-04 | 2016-02-24 | 太仓市建兴石英玻璃厂 | Electroplating pretreatment method for quartz glass |
| CN107164950A (en) * | 2017-06-08 | 2017-09-15 | 中北大学 | Fabric surface coats the preparation method of metal |
| CN110106580A (en) * | 2019-04-30 | 2019-08-09 | 巢湖市翔宇渔具有限公司 | A kind of processing method of corrosion-resistant luminous fishing net |
| CN110872705A (en) * | 2018-08-30 | 2020-03-10 | 广州倬粤动力新能源有限公司 | Process for plating metal layer on surface of glass fiber |
| CN110872177A (en) * | 2018-08-30 | 2020-03-10 | 广州倬粤动力新能源有限公司 | Device for plating metal layer on surface of glass fiber |
| CN112521029A (en) * | 2020-11-30 | 2021-03-19 | 北京宇航系统工程研究所 | Method for improving thermal conductivity of glass fiber |
| CN113896924A (en) * | 2021-10-09 | 2022-01-07 | 佛山市佳世达薄膜科技有限公司 | Metal glass modified release film |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701603A (en) * | 2012-05-29 | 2012-10-03 | 中南大学 | Preparation method for copper/zinc coating on surface of glass fiber |
-
2014
- 2014-12-30 CN CN201410839503.8A patent/CN104532214A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102701603A (en) * | 2012-05-29 | 2012-10-03 | 中南大学 | Preparation method for copper/zinc coating on surface of glass fiber |
Non-Patent Citations (5)
| Title |
|---|
| 刘西德 等: ""玻璃纤维表面化学镀镍的研究"", 《化工技术与开发》 * |
| 李丽波 等: ""玻璃纤维表面化学镀镍的工艺研究"", 《稀有金属材料与工程》 * |
| 李鹏 等: ""玻璃纤维化学镀Ni-Cu-P合金的研究"", 《材料科学与工艺》 * |
| 陈莉云 等: ""玻璃纤维化学镀镍工艺条件的优化研究"", 《兵器材料科学与工程》 * |
| 鲍红权 等: ""化学镀金属导电玻璃纤维制备与性能研究"", 《玻璃纤维》 * |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104844019A (en) * | 2015-04-28 | 2015-08-19 | 安徽丹凤集团桐城玻璃纤维有限公司 | Preparation process for glass fiber |
| CN104963064A (en) * | 2015-07-01 | 2015-10-07 | 安徽丹凤电子材料股份有限公司 | Production process of glass fiber anti-static cloth |
| CN105350044A (en) * | 2015-12-04 | 2016-02-24 | 太仓市建兴石英玻璃厂 | Electroplating pretreatment method for quartz glass |
| CN107164950A (en) * | 2017-06-08 | 2017-09-15 | 中北大学 | Fabric surface coats the preparation method of metal |
| CN110872705A (en) * | 2018-08-30 | 2020-03-10 | 广州倬粤动力新能源有限公司 | Process for plating metal layer on surface of glass fiber |
| CN110872177A (en) * | 2018-08-30 | 2020-03-10 | 广州倬粤动力新能源有限公司 | Device for plating metal layer on surface of glass fiber |
| CN110106580A (en) * | 2019-04-30 | 2019-08-09 | 巢湖市翔宇渔具有限公司 | A kind of processing method of corrosion-resistant luminous fishing net |
| CN112521029A (en) * | 2020-11-30 | 2021-03-19 | 北京宇航系统工程研究所 | Method for improving thermal conductivity of glass fiber |
| CN113896924A (en) * | 2021-10-09 | 2022-01-07 | 佛山市佳世达薄膜科技有限公司 | Metal glass modified release film |
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Application publication date: 20150422 |