CN107164945A - Composite bed non-woven fabrics preparation method, bonded fabric product - Google Patents

Composite bed non-woven fabrics preparation method, bonded fabric product Download PDF

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Publication number
CN107164945A
CN107164945A CN201710338878.XA CN201710338878A CN107164945A CN 107164945 A CN107164945 A CN 107164945A CN 201710338878 A CN201710338878 A CN 201710338878A CN 107164945 A CN107164945 A CN 107164945A
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Prior art keywords
calcium hydroxide
hydroxide particle
woven fabrics
woven
composite bed
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李晓娇
李彪
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Chongqing Hui Ke Ke Technology Co Ltd
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Priority to CN201710338878.XA priority Critical patent/CN107164945A/en
Priority to CN201911172730.9A priority patent/CN110846885A/en
Priority to CN201911173519.9A priority patent/CN110699946A/en
Priority to CN201911172755.9A priority patent/CN110846886A/en
Priority to CN201911172756.3A priority patent/CN110846887A/en
Priority to CN201911172713.5A priority patent/CN110846884A/en
Publication of CN107164945A publication Critical patent/CN107164945A/en
Pending legal-status Critical Current

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    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/32Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/36Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
    • D06M11/44Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/34Sputtering
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/04Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/06Inorganic compounds or elements
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M16/00Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Microbiology (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
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Abstract

The present invention provides a kind of composite bed non-woven fabrics preparation method, bonded fabric product, when preparing composite bed non-woven fabrics, first prepares non-woven substrate, and calcium hydroxide particle coating is then plated at least one side of non-woven substrate.Calcium hydroxide particle has extremely strong sterilization, antibacterial action, and calcium hydroxide particle can consumingly destroy protease in bacterial body, make protease loss of activity, cause bacterial death.Contact, proceed as described above again and again after bacterium is killed by calcium hydroxide particle, then with other bacterium colonies, reach the sterilization antibacterial of continuation.Therefore, the present invention is coated with calcium hydroxide particle coating in the one or both sides of non-woven substrate, and the bacterium that can be will accumulate on the face and virus are killed, with excellent sterilization, antibiotic effect.Cause also all possess lasting sterilization antibacterial ability using product made from the composite bed non-woven fabrics simultaneously.And calcium hydroxide particle is greatly reduced compared to silver ion cost, reduces the application cost of non-woven fabrics antibiotic and sterilizing.

Description

Composite bed non-woven fabrics preparation method, bonded fabric product
Technical field
The present invention relates to non-woven fabrics field, and in particular to a kind of composite bed non-woven fabrics preparation method, bonded fabric product.
Background technology
Non-woven fabrics (Non Woven) is also known as adhesive-bonded fabric, is made up of fiber orient or random, is environmental protection of new generation Material, with moistureproof, ventilative, flexible, light weight, not combustion-supporting, easy decomposition, nontoxic nonirritant, rich color, it is cheap, Recyclable the features such as, application is widely used in production and life.For example its paper nappy, sanitary napkin, protection pad, wet tissue, All it is widely used on the products such as adhesive bandage, mouth mask, food pack;These application scenarios are required for non-woven fabrics to possess antibacterial The ability of sterilization, and be all to increase silver ion in non-woven fabrics to realize antibiotic and sterilizing function at present.
Silver particles can as oxidation reaction catalyst, destruction Saccharomyces mycetin in-SH bond, bacterium is not closed effectively Into the protein needed for its existence or nutrition.Silver particles also can be in water or air as the catalyst for producing elemental oxygen, to reach To the bactericidal effect as hydrogen peroxide.Though being good air disinfection agent through studies have shown that Nano Silver, its bactericidal mechanism can Can be different because of the difference of strain, it has been investigated that the aerial antibacterial effect of argentiferous clothing is than conventional silver nitrate solution etc. more It is good.
Silver also has remarkable antibiotic and sterilization functions.General antibiotic can only averagely be played a role to 6 kinds of germs, but Silver can eliminate 650 kinds of germs.Silver ion can slacken the ferment for power effect of being labored in germ body, it is thus possible to prevent side effect and disease The patience reinforcing of bacterium, fundamentally controls the breeding of germ.So-called Nano Silver is, by " silver " nanosizing in noble metal, then to use On the various consumer goods.But current nanocrystallization technology all focuses on the technical research for how preparing nanoparticle, then with other Mode is attached on application product, and its Nano Silver prepares that cost is prohibitively expensive in itself, causes its application cost on non-woven fabrics Height, limits its popularization and application.
The content of the invention
The present invention provides a kind of composite bed non-woven fabrics preparation method, bonded fabric product, to solve existing non-woven fabrics using silver Ion carries out antibiotic and sterilizing, causes the problem of application cost is high.
In order to solve the above technical problems, the present invention provides a kind of composite bed non-woven fabrics preparation method, including:
Prepare non-woven substrate;
Calcium hydroxide particle coating is plated at least one side of the non-woven substrate.
In an embodiment of the present invention, the calcium hydroxide particle coating is by natural nano level calcium hydroxide particle group Into the calcium hydroxide particle thickness of coating is 10 nanometers of 100 nanometers of ∽.
In an embodiment of the present invention, the calcium hydroxide particle in following animality calcium source at least one Kind:
Scallop shell, abalone shells, conch shell, surfing clam shell, sea urchin shell, coral shell and eggshell.
In an embodiment of the present invention, calcium hydroxide particle coating is plated at least one side of the non-woven substrate Including:
Calcium hydroxide particle coating is plated on the front of the non-woven substrate or the back side.
In an embodiment of the present invention, using vacuum evaporation, sputtering at least one side of the non-woven substrate The mode of plating or ion plating forms calcium hydroxide particle coating.
In an embodiment of the present invention, formed using sputtering plating mode at least one side of the non-woven substrate During calcium hydroxide particle coating, the process conditions of the sputtering plating are as follows:
The sputtering target material used is calcium hydroxide particle, and sputter gas is pure hydrogen;In sputter procedure, dressing base material Temperature is room temperature, and target temperature is less than or equal to 80 degrees Celsius, and background vacuum is less than (2-6) * 10-4Pa;Work pressure during sputtering Strong is 0.1-5Pa, sputtering power is 30 ∽ 50W, and sputtering time is no less than l/min;Kept during sputtering between substrate and target away from From for 30 millimeters of 170 millimeters of ∽.
In an embodiment of the present invention, prepare after non-woven substrate, at least one side of the non-woven substrate Before plating calcium hydroxide particle coating, in addition to:
Sided corona treatment is carried out to the face of calcium hydroxide particle coating to be formed on the non-woven substrate.
In an embodiment of the present invention, the non-woven substrate for preparing is included calcium alginate fibre and cellulose fiber Dimension is mixed with non-woven substrate;
The non-woven substrate in the following manner in either type prepare:
Calcium alginate staple in bulk and cellulose staple in bulk are carried out into mixed splitting or integrating comb, acupuncture to be prepared from;
By calcium alginate staple in bulk after dividing and being combed into net, carry out composite acupuncture with cellulose spunlace non-woven cloth and be prepared from;
By calcium alginate staple in bulk after dividing and being combed into net, carry out composite acupuncture with cellulose woven fabric and be prepared from.
In an embodiment of the present invention, the cellulose fibre is selected from following at least one:Cotton fiber, flaxen fiber and Viscose rayon.
In order to solve the above problems, present invention also offers a kind of bonded fabric product, including composite bed as described above without Spin composite bed non-woven fabrics made from cloth preparation method;The bonded fabric product is that paper nappy, sanitary napkin, protection pad, wet tissue, wound can Patch, mouth mask or food pack.
In order to solve the above problems, present invention also offers a kind of bonded fabric product, by composite bed as described above without Cloth is spun to be made;The bonded fabric product is paper nappy, sanitary napkin, protection pad, wet tissue, adhesive bandage, mouth mask or food pack.
The beneficial effects of the invention are as follows:
Composite bed non-woven fabrics preparation method that the present invention is provided, bonded fabric product, when preparing composite bed non-woven fabrics, are first prepared Non-woven substrate, then plates calcium hydroxide particle coating at least one side of non-woven substrate.Calcium hydroxide particle has pole Strong sterilization, antibacterial action, calcium hydroxide particle can consumingly destroy protease in bacterial body, make protease loss of activity, Cause bacterial death.Contacted after bacterium is killed by calcium hydroxide particle, then with other bacterium colonies, above-mentioned mistake is carried out again and again Journey, reaches the sterilization antibacterial of continuation.Therefore, the present invention is coated with calcium hydroxide particle plating in the one or both sides of non-woven substrate Layer, the bacterium that can be will accumulate on the face and virus are killed, with excellent sterilization, antibiotic effect.Cause simultaneously multiple using this The product such as paper nappy, sanitary napkin, protection pad, wet tissue, adhesive bandage, mouth mask, food pack made from layer non-woven fabrics is closed also all to possess Lasting sterilization antibacterial ability.And calcium hydroxide particle is greatly reduced compared to silver ion cost, reduces non-woven fabrics antibacterial and kill The application cost of bacterium.
Brief description of the drawings
Fig. 1 is the composite bed nonwoven fabric construct schematic diagram one that the embodiment of the present invention one is provided;
Fig. 2 is the composite bed nonwoven fabric construct schematic diagram two that the embodiment of the present invention one is provided;
Fig. 3 is the composite bed nonwoven fabric construct schematic diagram three that the embodiment of the present invention one is provided;
Fig. 4 is the calcium hydroxide particle extracting method schematic flow sheet that the embodiment of the present invention two is provided;
Fig. 5 is the composite bed non-woven fabrics preparation method schematic flow sheet that the embodiment of the present invention three is provided;
Fig. 6 is the SANITARY NAPKIN CONSTRUCTION schematic diagram that the embodiment of the present invention four is provided;
Fig. 7 is the sectional view in sanitary napkin A-A directions in Fig. 6;
Fig. 8 is the adhesive bandage structural representation one that the embodiment of the present invention four is provided;
Fig. 9 is the adhesive bandage structural representation two that the embodiment of the present invention four is provided.
Embodiment
The some embodiments of the present invention will be specifically described below;Obviously, described embodiment is the present invention one Section Example, rather than whole embodiments.Based on the embodiment in the present invention, those of ordinary skill in the art are not making Go out the every other embodiment obtained under the premise of creative work, belong to the scope of protection of the invention.In addition, unless in text There is other explanation, (especially in the claims) used in this manual " one ", "the" and similar term should be understood that To include odd number and plural form.
Embodiment one:
This implementation provides a kind of composite bed non-woven fabrics, including non-woven substrate and is incorporated into the non-woven substrate at least one Calcium hydroxide particle coating on face.Calcium hydroxide particle has extremely strong sterilization, antibacterial action, and calcium hydroxide particle can be strong Protease in bacterial body is destroyed strongly, is made protease loss of activity, is caused bacterial death.When bacterium is killed by calcium hydroxide particle Afterwards, then with other bacterium colonies contact, proceed as described above again and again, reach the sterilization antibacterial of continuation.Therefore, the present embodiment Calcium hydroxide particle coating is coated with the one or both sides of non-woven substrate, the bacterium and virus that can be will accumulate on the face kill Extremely, with excellent sterilization, antibiotic effect.Cause to utilize paper nappy, sanitary napkin, shield made from the composite bed non-woven fabrics simultaneously The products such as pad, wet tissue, adhesive bandage, mouth mask, food pack also all possess lasting sterilization antibacterial ability, and compared to silver ion into Originally it is greatly reduced, reduces the application cost of non-woven fabrics antibiotic and sterilizing.
It should be appreciated that the non-woven substrate in the present embodiment can be the non-woven substrate of various materials, for example should Non-woven substrate can be mixed for calcium alginate fibre with cellulose fibre, or polyester smooth surface filament nonwoven is fabric Into, or polyurethane smooth surface continuous yarn non-woven fabrics are made, or polypropylene smooth surface continuous yarn non-woven fabrics are made, or polyethylene smooth surface filament nonwoven Cloth is made, or polyethylene terephthalate smooth surface continuous yarn non-woven fabrics are made, or polyamide smooth surface continuous yarn non-woven fabrics are made, or Acrylonitrile smooth surface continuous yarn non-woven fabrics are made, or polyvinyl chloride macromolecule material smooth surface continuous yarn non-woven fabrics are made.
Non-woven substrate in the present embodiment includes front and back, the present embodiment can in the front of non-woven substrate and Combined at least one side at the back side and calcium hydroxide particle coating is set.And at least one side of the front and back in non-woven substrate It is upper plating calcium hydroxide particle coating mode can using any plating by the way of, including but not limited to vacuum evaporation, sputtering plate or Ion plating, the calcium hydroxide particle coating obtained accordingly is vacuum evaporation calcium hydroxide particle coating, sputtering plating calcium hydroxide Particle coating or ion plating calcium hydroxide particle coating.
It is shown in Figure 1, include non-woven substrate 11 in composite bed non-woven fabrics shown in the figure and combination is arranged at nonwoven The positive calcium hydroxide particle coating 12 of cloth layer 11.The thickness of calcium hydroxide particle coating 12 is 10 nanometers of 100 nanometers of ∽, tool Body could be arranged to 10 nanometers of 40 nanometers of ∽.
It is shown in Figure 2, include non-woven substrate 21 in composite bed non-woven fabrics shown in the figure and combination is arranged at nonwoven The calcium hydroxide particle coating 22 at the back side of cloth layer 21.The thickness of calcium hydroxide particle coating 22 is 10 nanometers of 100 nanometers of ∽, tool Body could be arranged to 40 nanometers of 10 nanometers of ∽ or 60 nanometers of 40 ∽.
It is shown in Figure 3, include non-woven substrate 31 in composite bed non-woven fabrics shown in the figure and combination is arranged at nonwoven The back side of cloth layer 31 and positive calcium hydroxide particle coating 32.The thickness of calcium hydroxide particle coating 32 is 10 nanometers of ∽ 100 nanometers, it specifically could be arranged to 40 nanometers of 10 nanometers of ∽ or 100 nanometers of 60 ∽.
It should be appreciated that the face that calcium hydroxide particle coating is set on non-woven substrate in the present embodiment can basis The concrete application scene of non-woven fabrics is flexibly set, and the thickness of calcium hydroxide particle coating can also specifically should according to non-woven fabrics Flexibly selected with scene.
In addition, in the present embodiment, being tightly combined in order that obtaining calcium hydroxide particle coating with non-woven substrate, being difficult to take off Separation is opened, the reliability and service life of non-woven fabrics is lifted, can be first in non-woven substrate setting calcium hydroxide particle to be combined The face of coating carries out sided corona treatment, and sided corona treatment is a kind of shock treatment, and it makes the surface of stock have higher tack. That is, in the present embodiment non-woven substrate be combined with calcium hydroxide particle coating for the face after sided corona treatment.
In order to lift the feature of environmental protection of composite bed non-woven fabrics, security and reduce its prepare, application cost, in the present embodiment Calcium hydroxide particle coating can be made up of natural calcium hydroxide particle.In a kind of example, the calcium hydroxide in the present embodiment Particle coating is made up of natural nano level calcium hydroxide particle or natural micron order calcium hydroxide particle.
Specifically, the calcium hydroxide particle in the present embodiment can come from least one of following animality calcium source:
Scallop shell, abalone shells, conch shell, surfing clam shell, sea urchin shell, coral shell and eggshell.
It can be seen that the composite bed non-woven fabrics that the present embodiment is provided is made up of non-woven substrate and plating calcium hydroxide particle coating, hydrogen Calcium oxide particle has extremely strong sterilization, antibacterial action so that composite bed non-woven fabrics and the utilization composite bed non-woven fabrics are obtained The product such as paper nappy, sanitary napkin, protection pad, wet tissue, adhesive bandage, mouth mask, food pack also all possess lasting sterilization antibacterial Ability.And calcium hydroxide particle is greatly reduced compared to silver ion cost, reduces the application cost of non-woven fabrics antibiotic and sterilizing, more Promoted the use of beneficial to it, benefit masses.
Embodiment two:
The present embodiment is illustrated in the way of a kind of extraction calcium hydroxide particle from animality calcium source.
Calcium hydroxide particle is made by the following methods shown in Fig. 4 in the present embodiment:
S401:Animality calcium source is cleaned.
At least one of animality calcium source in the present embodiment:Scallop shell, abalone shells, conch shell, surfing clam shell, sea urchin Shell, coral shell and eggshell.The present embodiment can be using ultrasonic wave cleaning when being cleaned to animality calcium source, it would however also be possible to employ Other effective cleaning ways are cleaned, washing etc..
S402:Animality calcium source after cleaning is subjected to multisection type high-temperature calcination.
The present embodiment can carry out continuous multisection type high-temperature calcination to the animality calcium source after cleaning, for example, can carry out Continuous eight segmentations high-temperature calcination, the temperature control specifically calcined is:Normal temperature -300-600-900-1200-900-600-300- Normal temperature.
S403:The obtained composition using calcium hydroxide as main component of water reaction is added into calcined product.
S404:Obtained composition is subjected to grainy treatment, and centrifuged under vacuum conditions or under inert gas Dehydration obtains calcium hydroxide particle.
Grainy treatment in the present embodiment can be handled for micron particlesization processing, or nano-scale particleization, example It can such as be processed as between 0.1 micron to 500 microns of particle diameter average out to.Grainy treatment in the present embodiment can pass through Milled processed, progress can also handle by other means and obtain nanoscale or micron-sized calcium hydroxide particle.
In the present embodiment, when calcium hydroxide particle is made through the above way, in obtained product can also comprising roc ion, At least one of magnesium ion, zinc ion, aluminium ion, manganese ion, plasma selenium., can be as needed by it for these ions It is removed, can also be retained according to the actual requirements, or even according to adding corresponding ion outside content value of demand.
For example in a kind of example, calcium hydroxide particle coating also includes roc ion, magnesium ion, zinc ion, aluminium ion, manganese At least one of trace elements such as ion, plasma selenium.Wherein, micro- content is the calcium hydroxide of every 100 parts by weight Particle adds the trace element of 1 parts by weight to 5 parts by weight.
Embodiment three:
A kind of composite bed non-woven fabrics preparation method is present embodiments provided, it is shown in Figure 5, including:
S501:Prepare non-woven substrate.
The preparation method of non-woven substrate in the present embodiment can be by the way of any non-woven substrate, herein no longer Repeat.
S502:Calcium hydroxide particle coating is plated at least one side of non-woven substrate.
Calcium hydroxide particle coating is made up of natural level calcium hydroxide particle in the step, and the calcium hydroxide particle coating Thickness can be 10 nanometers of 100 nanometers of ∽.Certainly specific thickness can flexibly be set according to the actual requirements.
In S502, plating calcium hydroxide particle coating includes at least one side of non-woven substrate:
Calcium hydroxide particle coating is plated on the front of non-woven substrate or the back side;Or in the front of non-woven substrate and the back of the body Calcium hydroxide particle coating is plated simultaneously in face., can be in non-woven fabrics when plating calcium hydroxide particle coating is formed on non-woven substrate In at least one side of basic unit calcium hydroxide particle coating is formed by the way of vacuum evaporation, sputtering plating or ion plating.
Vacuum evaporation refers under a high vacuum, by the evaporation and condensation of calcium hydroxide particle, make calcium hydroxide particle thin The attached work of layer is in nonwoven fabric base layer surface.
The technological requirement vacuum of plating is sputtered in 1*10-3Torr or so, i.e. 1.3*10-3Pa vacuum state is filled with inertia Gas hydrogen (Ar), and high voltage direct current is added between non-woven substrate and calcium hydroxide particle target (negative electrode), due to brightness The electron excitation inert gas that light electric discharge (glow discharge) is produced, produces plasma, and plasma is by calcium hydroxide The atom of particle target is driven out of, is deposited on non-woven substrate.
Ion plating is a kind of plated film new technology grown up on the basis of vacuum evaporation and sputtering plating, by various gases Discharge mode is incorporated into vapour deposition field, and whole vapor deposition processes are all carried out in the plasma;Ion plating is significantly Film layer particle energy is improved, the film layer of more excellent properties can be obtained, is a new technology for quickly growing, being favored.
The present embodiment forms calcium hydroxide particle coating in use sputtering plating mode at least one side of non-woven substrate When, the process conditions for sputtering plating are as follows:
The sputtering target material used is calcium hydroxide particle, and sputter gas is pure hydrogen;In sputter procedure, dressing base material Temperature is room temperature, and target temperature is less than or equal to 80 degrees Celsius, and background vacuum is less than (2-6) * 10-4Pa;Work pressure during sputtering It is 0.1-5Pa by force, sputtering power is 30 ∽ 50W, and sputtering time is no less than l/min;Kept during sputtering between substrate and target Distance is 30 millimeters of 170 millimeters of ∽.
In the present embodiment, after S501 prepares non-woven substrate, S502 plates hydrogen-oxygen at least one side of non-woven substrate Before change calcium particle coating, in addition to:
Sided corona treatment is carried out to the face of calcium hydroxide particle coating to be formed on non-woven substrate, can so cause hydrogen-oxygen Change calcium particle coating to be tightly combined with non-woven substrate, be difficult to disengage separation, lift the reliability and service life of non-woven fabrics.
In the present embodiment, preparing non-woven substrate includes calcium alginate fibre and cellulose fibre being mixed with non-woven fabrics Basic unit;The mass ratio of calcium alginate fibre and cellulose fibre can be 10:90-90:10.
Non-woven substrate can in the following manner in (it is to be understood that being not limited in the following manner) either type system It is standby to obtain:
Calcium alginate staple in bulk and cellulose staple in bulk are carried out into mixed splitting or integrating comb, acupuncture to be prepared from;
By calcium alginate staple in bulk after dividing and being combed into net, carry out composite acupuncture with cellulose spunlace non-woven cloth and be prepared from;
By calcium alginate staple in bulk after dividing and being combed into net, carry out composite acupuncture with cellulose woven fabric and be prepared from.
Cellulose fibre can be selected from following at least one in the present embodiment:Cotton fiber, flaxen fiber and viscose rayon.
In addition, in the present embodiment, can also be in calcium hydroxide particle coating in order to further lift antibiotic and sterilizing effect Increase silver ion, the measurer body added can flexibly be set according to the actual requirements.
Example IV:
A kind of bonded fabric product is present embodiments provided, the bonded fabric product includes passing through composite bed nonwoven as described above Composite bed non-woven fabrics made from cloth preparation method.Bonded fabric product in the present embodiment can for paper nappy, sanitary napkin, protection pad, Wet tissue, adhesive bandage, mouth mask or food pack.Exemplary say is carried out with the application example of a kind of sanitary napkin and adhesive bandage below It is bright.
Shown in Fig. 6-Fig. 7, the sanitary napkin in the example includes sanitary napkin body 61 and is arranged on sanitary napkin body both sides band There is the flap 62 of binding function, sanitary napkin body 61 is by pure cotton spun lacing layer of cloth 63, composite bed non-woven fabrics 64, active carbon layer 69, suction Water cushion 65 and waterproof layer 66 are constituted, and pure cotton spun lacing layer of cloth 63 is arranged under the upper surface of sanitary napkin body 1, pure cotton spun lacing layer of cloth 63 Side is provided with composite bed non-woven fabrics 64, and the lower section of composite bed non-woven fabrics 64 is provided with adsorptive pads 65, and the decentralization of adsorptive pads 65 is provided with waterproof layer 66, Pure cotton spun lacing layer of cloth 63 is arranged on the upper surface of sanitary napkin body 61, and pure cotton spun lacing layer of cloth 63 plays Waterproof Breathable, isolates bacterium, The effect for keeping private parts dry and comfortable, the lower section of pure cotton spun lacing layer of cloth 63 is provided with composite bed non-woven fabrics 64, and composite bed non-woven fabrics 64 has strong The sterilization of effect, anti-inflammation goes the effect eliminated the unusual smell, can effectively suppress bacteria breed, it is ensured that private parts health, composite bed non-woven fabrics 64 lower sections are provided with adsorptive pads 65, and adsorptive pads are macromolecule water uptake pad, and adsorptive pads 65 can quickly sop up the crimson blood under menstruation row, improve It is dry-ness outside sanitary napkin, prevent bacteria breed, active carbon layer 69 is provided between adsorptive pads 65 and composite bed non-woven fabrics 64, is carried To water imbibition and the function of eliminating the unusual smell, the decentralization of adsorptive pads 65 is provided with waterproof layer 66, and waterproof layer 66 can prevent the dirt that adsorptive pads 65 are inhaled Blood makes underpants dirty.
Shown in Fig. 8-Fig. 9, the adhesive bandage (also referred to as medical application) in the example is prepared including one by alginate fibre Base material 81, one be located at the inner surface of base material 81 non-drying glue layer 82 and one be adhered to non-drying glue layer 82 middle part adsorptive pads 83, the adhesive bandage also includes an off-style paper layer 84, and the off-style paper layer 84 is attached to the non-drying glue layer 82 and the adsorptive pads On 83;The non-drying glue layer 82 is provided with air-vent 85, and the top of the adsorptive pads 83 is to be evenly distributed with composite bed non-woven fabrics 86, bottom is hydrogel layer 87.
A cross-shaped through hole 88, and ten on base material 81 are equipped with the base material 81 and non-drying glue layer 82 of the side of adsorptive pads 83 Cross-shaped through hole on font through hole and non-drying glue layer 82 is overlapped, and can be used for guiding catheter.
The air-vent 85 of non-drying glue layer 83 is triangle.It should be appreciated that non-drying glue layer upper and lower sides air-vent 85 may be used also Think circular or square or oval.
In use, medical application is pasted on into wound, changed according to service condition.The top of adhesive bandage adsorptive pads To be evenly distributed with the nonwoven layer of calcium hydroxide particle coating, calcium ion has hemostasis, sterilizing function, and the bottom of adsorptive pads is Hydrogel layer, will not produce scleroma, and non-drying glue layer is provided with air-vent, can keep good gas permeability and flexibility.Should Adhesive bandage pliability is high, and easy to use, good permeability, good water absorption, adhesion wound are easily loosened, patient comfort, bag Stab mouth tight, therapeutic effect is good.
Application basis for other products such as paper nappy, protection pad, wet tissue, mouth mask or food packs can be according to above-mentioned Example by that analogy, will not be repeated here.
Above content is to combine the further description that specific embodiment is made to the embodiment of the present invention, it is impossible to recognized The specific implementation of the fixed present invention is confined to these explanations.For general technical staff of the technical field of the invention, Without departing from the inventive concept of the premise, some simple deduction or replace can also be made, the present invention should be all considered as belonging to Protection domain.

Claims (10)

1. a kind of composite bed non-woven fabrics preparation method, it is characterised in that including:
Prepare non-woven substrate;
Calcium hydroxide particle coating is plated at least one side of the non-woven substrate.
2. composite bed non-woven fabrics preparation method as claimed in claim 1, it is characterised in that the calcium hydroxide particle coating by Natural nano level calcium hydroxide particle composition, the calcium hydroxide particle thickness of coating is 10 nanometers of 100 nanometers of ∽.
3. composite bed non-woven fabrics preparation method as claimed in claim 1, it is characterised in that the calcium hydroxide particle come from At least one of lower animality calcium source:
Scallop shell, abalone shells, conch shell, surfing clam shell, sea urchin shell, coral shell and eggshell.
4. composite bed non-woven fabrics preparation method as claimed in claim 1, it is characterised in that in the non-woven substrate at least Simultaneously upper plating calcium hydroxide particle coating includes:
Calcium hydroxide particle coating is plated on the front of the non-woven substrate or the back side.
5. the composite bed non-woven fabrics preparation method as described in claim any one of 1-4, it is characterised in that in the nonwoven fabric base In at least one side of layer calcium hydroxide particle coating is formed by the way of vacuum evaporation, sputtering plating or ion plating.
6. composite bed non-woven fabrics preparation method as claimed in claim 5, it is characterised in that using sputtering plating mode in the nothing When spinning formation calcium hydroxide particle coating at least one side of cloth layer, the process conditions of the sputtering plating are as follows:
The sputtering target material used is calcium hydroxide particle, and sputter gas is pure hydrogen;In sputter procedure, the temperature of dressing base material For room temperature, target temperature is less than or equal to 80 degrees Celsius, and background vacuum is less than (2-6) * 10-4Pa;Operating pressure during sputtering is 0.1-5Pa, sputtering power is 30 ∽ 50W, and sputtering time is no less than l/min;The distance between substrate and target is kept to be during sputtering 30 millimeters of 170 millimeters of ∽.
7. the composite bed non-woven fabrics preparation method as described in claim any one of 1-4, it is characterised in that prepare non-woven substrate Afterwards, at least one side of the non-woven substrate before plating calcium hydroxide particle coating, in addition to:
Sided corona treatment is carried out to the face of calcium hydroxide particle coating to be formed on the non-woven substrate.
8. the composite bed non-woven fabrics preparation method as described in claim any one of 1-4, it is characterised in that described to prepare non-woven fabrics Basic unit includes calcium alginate fibre and cellulose fibre being mixed with non-woven substrate;
The non-woven substrate in the following manner in either type prepare:
Calcium alginate staple in bulk and cellulose staple in bulk are carried out into mixed splitting or integrating comb, acupuncture to be prepared from;
By calcium alginate staple in bulk after dividing and being combed into net, carry out composite acupuncture with cellulose spunlace non-woven cloth and be prepared from;
By calcium alginate staple in bulk after dividing and being combed into net, carry out composite acupuncture with cellulose woven fabric and be prepared from.
9. composite bed non-woven fabrics preparation method as claimed in claim 8, it is characterised in that the cellulose fibre is selected from following It is at least one:Cotton fiber, flaxen fiber and viscose rayon.
10. a kind of bonded fabric product, it is characterised in that fabric including the composite bed nonwoven as described in claim any one of 1-9 Composite bed non-woven fabrics made from Preparation Method;The bonded fabric product is paper nappy, sanitary napkin, protection pad, wet tissue, adhesive bandage, mouth mask Or food pack.
CN201710338878.XA 2017-05-15 2017-05-15 Composite bed non-woven fabrics preparation method, bonded fabric product Pending CN107164945A (en)

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CN201911172730.9A CN110846885A (en) 2017-05-15 2017-05-15 Preparation method of composite layer non-woven fabric
CN201911173519.9A CN110699946A (en) 2017-05-15 2017-05-15 Preparation method of composite layer non-woven fabric
CN201911172755.9A CN110846886A (en) 2017-05-15 2017-05-15 Preparation method of composite layer non-woven fabric
CN201911172756.3A CN110846887A (en) 2017-05-15 2017-05-15 Preparation method of composite layer non-woven fabric
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CN201911173519.9A Division CN110699946A (en) 2017-05-15 2017-05-15 Preparation method of composite layer non-woven fabric
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CN201911172713.5A Withdrawn CN110846884A (en) 2017-05-15 2017-05-15 Composite layer nonwoven fabric product
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