CN107164714A - A kind of method for repairing and mending containing titanium composite panel - Google Patents
A kind of method for repairing and mending containing titanium composite panel Download PDFInfo
- Publication number
- CN107164714A CN107164714A CN201710293131.7A CN201710293131A CN107164714A CN 107164714 A CN107164714 A CN 107164714A CN 201710293131 A CN201710293131 A CN 201710293131A CN 107164714 A CN107164714 A CN 107164714A
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- Prior art keywords
- repairing
- titanium
- composite panel
- plate
- titanium plate
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/12—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the method of spraying
- C23C4/131—Wire arc spraying
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C4/00—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge
- C23C4/04—Coating by spraying the coating material in the molten state, e.g. by flame, plasma or electric discharge characterised by the coating material
- C23C4/06—Metallic material
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Coating By Spraying Or Casting (AREA)
- Laminated Bodies (AREA)
Abstract
It is to be repaired at the local damage on the composite board of titanium alloy to cladding plate using Titanium Powder core-wire material as welding wire specially using Supersonic Arc Spraying Technique the invention discloses a kind of method for repairing and mending containing titanium composite panel.Due to high using Particle Velocity of Supersonic Arc Spraying, titanium plate hardness after repairing is high, it is big with metal substrate bond strength, it is well combined in the damaged remaining titanium plate of buffering area with titanium plate part after repairing, the repairing of titanium plate anticorrosive for the different in nature thermal structure parts titaniferous composite surface of large scale has important effect.Present invention process is simple, strong operability, efficiency high, multiple continuous spray can be achieved, with higher economic value.
Description
Technical field
The invention belongs to, to the repairing technique field containing titanium composite panel, be specially a kind of repairing using Ultrasonic Arc Sprayed
The method of anticorrosive titanium plate.
Background technology
The density of titanium is small, is only equivalent to the 57% of steel, and titanium has the advantage of steel (intensity is high) and aluminium (quality is light) concurrently simultaneously.It is high
Purity titanium has good plasticity, and in room temperature, titanium is not acted on chlorine, dilute sulfuric acid, watery hydrochloric acid and nitric acid, in actual conditions
Lower titanium is very stable in many media.Titanium is corrosion resistant in the media such as oxidisability, neutral and week reduction because titanium
Affinity with oxygen is very big, in atmosphere or in oxygen-containing medium, one layer of titanium Surface Creation it is fine and close, adhesive force is strong, inertia is big
Oxide-film, protects Titanium base not to be corroded.Therefore going deep into new technological revolution and the industrial revolution, titanium will turn into after
" the 3rd metal " emerged after iron, aluminium.The society that is widely used as of titanium or titanium alloy brings huge economic benefit, is changing
The fields such as work, metallurgy, vacuum salt production, electric power produce huge income.
Using the corrosion resistance of titanium or titanium alloy, one layer of titanium plate, system are combined on other metallic plates with the method for blast weldering
Into composite plate can effectively protect metallic matrix from environmental corrosion.But during weldering of exploding, there is subregion weldering
Close poor, so as to cause foaming between titanium plate and substrate to swell titanium plate, traditional processing method is that titanium plate is all removed into weight
New blast weldering only removes bump and carries out soldering with welding gun in damaged area, such solution complex operation, consumption
When it is longer, realize that efficiency is low.The present invention using Ultrasonic Arc Sprayed to titanium plate breakage repair, to equipment requirement compared with
It is low, the easy to operate easy report and patent realized, yet there are no correlation.
The content of the invention
It is an object of the invention to overcome the deficiencies of the prior art and provide one kind be well combined with substrate, layer structure into
Divide uniform, free from flaw and the method for repairing and mending containing titanium composite panel being mingled with.
The technical scheme is that:A kind of method for repairing and mending containing titanium composite panel, comprises the following steps:
(1)Titanium plate breakage progress containing titanium composite panel is pre-processed as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
(2)Blasting treatment is carried out to titanium plate breakage:It is 40~60mm that spray gun muzzle, which is adjusted, with workpiece distance, adjusts air pressure regulation
Valve is to 3~6bai(40 ~ 80 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
(3)Titanium plate is repaired using Supersonic Arc Spraying Technique;Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal;
(4)The repairing sheet metal of preparation is cooled to room temperature, that is, completes repair technology.
Further, described is using titanium alloy sheet as cladding plate, with steel, iron, aluminium alloy, copper alloy or magnesium containing titanium composite panel
Sheet alloy is as substrate, the composite plate being prepared from through explosion welding technique.
Further, the step(3)Titanium alloy hot spraying powder core-wire material, its titanium elements mass fraction be 90%~
99.6%。
Further, the step(3)Ultrasonic Arc Sprayed technological parameter be:Spraying rate is 300~400m/s,
Wire vent speed is 10~15m/s, and spray distance is 110~130cm, 80~90 ° of spray angle.
Further, the step(4)Repair layer consistency it is high, aperture is less than 3 ~ 4nm;Main phase structure is Ti,
A small amount of TiO2;Hardness is 480~680Hv.
The beneficial effects of the invention are as follows:
1. the method for the repairing of the titanium plate containing titanium composite panel of the present invention, the present invention can be damaged to titanium plate using hand-held spraying equipment
Place and buffering area carry out repairing treatment, and spray efficiency is high, and multiple continuous spray can be achieved, and prepared repair layer is uniform, is difficult
Deformation is come off, and thickness can be controlled, with stronger operability, can field patch or on-line operation.
2. the method for repairing and mending containing titanium composite panel that the present invention is provided, supersonic electric arc is high with spraying particle velocity, after repairing
Titanium plate hardness is high, can reach 680HV, and titanium plate is big with substrate bond strength, in the damaged remaining titanium plate layer of buffering area and titanium after repairing
Flaggy is well combined, and does not have difference in mechanical property, and the titanium plate space after repairing is small, sprayed particle fine uniform, sprays workpiece
Thermal stress is small, indeformable, flawless tendency.
Brief description of the drawings
Fig. 1 is the surface microscopic topographic figure of steel substrate skin patching titanium plate.
Fig. 2 is the cross-section morphology figure of steel substrate skin patching titanium plate and substrate.
Fig. 3 is the cross-section morphology figure of steel substrate skin patching titanium plate and original residual titanium plate.
Reference:A- steel substrates, the original titanium plates of B-, C- repairing sheet metals.
Embodiment
Embodiment 1
A kind of method for repairing and mending containing titanium composite panel, comprises the following steps:
1. pair titanium plate breakage progress containing titanium composite panel pre-processes as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
2. pair titanium plate breakage carries out blasting treatment:It is 50mm to adjust spray gun muzzle and workpiece distance, regulation air pressure-adjusting valve to
4.5bai(60 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
3. repair titanium plate using Supersonic Arc Spraying Technique.Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal.Technological parameter is:Spraying rate is 380m/s, and wire vent speed is 15m/s,
Spray distance is 120cm, 90 ° of spray angle;
4. the repairing sheet metal of preparation is cooled into room temperature, that is, complete repair technology.
Embodiment 2
A kind of method for repairing and mending containing titanium composite panel, comprises the following steps:
1. pair titanium plate breakage progress containing titanium composite panel pre-processes as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
2. pair titanium plate breakage carries out blasting treatment:It is 60mm to adjust spray gun muzzle and workpiece distance, regulation air pressure-adjusting valve to
6bai(80 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
3. repair titanium plate using Supersonic Arc Spraying Technique.Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal.Technological parameter is:Spraying rate is 380m/s, and wire vent speed is 10m/s,
Spray distance is 120cm, 90 ° of spray angle;
4. the repairing sheet metal of preparation is cooled into room temperature, that is, complete repair technology.
Embodiment 3
A kind of method for repairing and mending containing titanium composite panel, comprises the following steps:
1. pair titanium plate breakage progress containing titanium composite panel pre-processes as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
2. pair titanium plate breakage carries out blasting treatment:It is 40mm to adjust spray gun muzzle and workpiece distance, regulation air pressure-adjusting valve to
3bai(40 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
3. repair titanium plate using Supersonic Arc Spraying Technique.Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal.Technological parameter is:Spraying rate is 300m/s, and wire vent speed is 10m/s,
Spray distance is 110cm, 80 ° of spray angle;
4. the repairing sheet metal of preparation is cooled into room temperature, that is, complete repair technology.
Embodiment 4
A kind of method for repairing and mending containing titanium composite panel, comprises the following steps:
1. pair titanium plate breakage progress containing titanium composite panel pre-processes as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
2. pair titanium plate breakage carries out blasting treatment:It is 50mm to adjust spray gun muzzle and workpiece distance, regulation air pressure-adjusting valve to
4.5bai(60 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
3. repair titanium plate using Supersonic Arc Spraying Technique.Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal.Technological parameter is:Spraying rate is 300m/s, and wire vent speed is 12m/s,
Spray distance is 110cm, 80 ° of spray angle;
4. the repairing sheet metal of preparation is cooled into room temperature, that is, complete repair technology.
Embodiment 5
A kind of method for repairing and mending containing titanium composite panel, comprises the following steps:
1. pair titanium plate breakage progress containing titanium composite panel pre-processes as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
2. pair titanium plate breakage carries out blasting treatment:It is 55mm to adjust spray gun muzzle and workpiece distance, regulation air pressure-adjusting valve to
4.5bai(60 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
3. repair titanium plate using Supersonic Arc Spraying Technique.Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal.Technological parameter is:Spraying rate is 350m/s, and wire vent speed is 12m/s,
Spray distance is 130cm, 85 ° of spray angle;
4. the repairing sheet metal of preparation is cooled into room temperature, that is, complete repair technology.
Structural characterization is carried out to the titanium plate after the steel substrate skin patching of embodiment 1.
The surface microscopic topographic of titanium plate after steel substrate skin patching is as shown in Figure 1, it is known that put down on the titanium plate surface after repairing
Whole flawless, zero defect.
Steel substrate is arrived because the titanium plate part of base steel plate surface is directly damaged, Fig. 2 gives the metallic plate and base after repairing
The cross-section morphology figure of plate, it is known that metallic plate is combined preferably with substrate, flawless is present.
Fig. 3 is metallic plate and the cross-section morphology figure of original residual titanium plate after steel substrate skin patching, it is known that original residual
Titanium plate is stayed to be well combined with repairing sheet metal, middle flawless and stomata is seldom.
The method of repairing titanium plate of the invention containing titanium composite panel, technique is simple, and it is convenient to prepare, and supersonic electric arc is with spraying grain
Sub- speed is high, and spray efficiency is high, and multiple continuous spray can be achieved, and titanium plate hardness is high after repairing, can reach 680HV, steel substrate with
Titanium plate bond strength is big, is well combined in the damaged remaining titanium plate of buffering area with metallic plate after repairing, for the different in nature thermojunction of large scale
The repairing of the anticorrosive titanium plate of structure parts surface has very important effect.
The foregoing is only a specific embodiment of the invention, but protection scope of the present invention is not limited thereto, any
The change or simple replacement expected without creative work, should all be included within the scope of the present invention.
Claims (5)
1. a kind of method for repairing and mending containing titanium composite panel, it is characterised in that comprise the following steps:
(1)Titanium plate breakage progress containing titanium composite panel is pre-processed as follows:Decontamination cleaning is carried out to breakage, then using sand
Paper is polishing to 2000 mesh step by step, and 10~15min is cleaned with acetone ultrasonic wave, drying;
(2)Blasting treatment is carried out to titanium plate breakage:It is 40~60mm that spray gun muzzle, which is adjusted, with workpiece distance, adjusts air pressure regulation
Valve is to 3~6bai(40 ~ 80 pounds/cun 2), until titanium plate surface is in uniform frosted shape;
(3)Titanium plate is repaired using Supersonic Arc Spraying Technique;Select titanium alloy as hot spraying powder core-wire material, use thermic lance
Carry out Ultrasonic Arc Sprayed and prepare repairing sheet metal;
(4)The repairing sheet metal of preparation is cooled to room temperature, that is, completes repair technology.
2. the method for repairing and mending according to claim 1 containing titanium composite panel, it is characterised in that:Described is with titanium containing titanium composite panel
Alloy sheets are as cladding plate, using steel, iron, aluminium alloy, copper alloy or magnesium alloy plate as substrate, through explosion welding technique preparation
Into composite plate.
3. the method for repairing and mending according to claim 1 containing titanium composite panel, it is characterised in that:The step(3)Titanium alloy
Hot spraying powder core-wire material, its titanium elements mass fraction is 90%~99.6%.
4. the method for repairing and mending according to claim 1 containing titanium composite panel, it is characterised in that:The step(3)Supersonic speed
Electric arc spraying process parameter is:Spraying rate be 300~400m/s, wire vent speed be 10~15m/s, spray distance be 110~
130cm, 80~90 ° of spray angle.
5. the method for repairing and mending according to claim 1 containing titanium composite panel, it is characterised in that:The step(4)Repair layer
Consistency is high, and aperture is less than 3 ~ 4nm;Main phase structure is Ti, a small amount of TiO2;Hardness is 480~680Hv.
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Cited By (2)
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CN107130205A (en) * | 2017-05-03 | 2017-09-05 | 成都晟翔科技有限公司 | It is a kind of for environment-friendly type regeneration salt of QPQ techniques and its preparation method and application |
CN108193160A (en) * | 2018-02-06 | 2018-06-22 | 河南泰邦厨具有限公司 | Cooker spraying method |
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