CN107164604A - A kind of method that molten iron is incubated in ladle refining furnace - Google Patents

A kind of method that molten iron is incubated in ladle refining furnace Download PDF

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Publication number
CN107164604A
CN107164604A CN201710282577.XA CN201710282577A CN107164604A CN 107164604 A CN107164604 A CN 107164604A CN 201710282577 A CN201710282577 A CN 201710282577A CN 107164604 A CN107164604 A CN 107164604A
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China
Prior art keywords
molten iron
ladle
refining furnace
heat preserving
heating
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CN201710282577.XA
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CN107164604B (en
Inventor
刘玉伟
刘伟
王宝华
孔超
高建国
周艳群
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HBIS Co Ltd Chengde Branch
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HBIS Co Ltd Chengde Branch
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    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21CPROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
    • C21C7/00Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
    • C21C7/0075Treating in a ladle furnace, e.g. up-/reheating of molten steel within the ladle

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Treatment Of Steel In Its Molten State (AREA)
  • Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)

Abstract

The invention discloses a kind of molten iron in the heat preserving method of ladle refining furnace, it the described method comprises the following steps:(1) molten iron enters LF refining furnace;(2) thermometric and heating;(3) submerged arc;(4) heating and iron making;(5) ladle confirms.The present invention folds into molten iron in ladle on the premise of molten iron can not return to processing, and using ladle bottom blowing system, the ladle equipped with molten iron is carried out insulation operation in refining furnace, normally smelted after the molten iron of insulation is blended into converter after converter system recovery.When the present invention solves converter system exception in production, molten iron waits the problem of can not handling and long-time crouching bag to make the problem of ladle formation bag sticks together in iron bag for a long time.The inventive method had both reduced the loss of molten iron, turn avoid the problems such as influence ladle involucrum can not have enough to meet the need and take live place.

Description

A kind of method that molten iron is incubated in ladle refining furnace
Technical field
The invention belongs to metallurgical technology field, and in particular to a kind of method that molten iron is incubated in ladle refining furnace.
Technical background
With the continuous upgrading of steel products quality, various refining furnaces are increasing in the effect that steel-making region is played, and Steel-making region is progressively exited as the mixed iron blast between ironmaking and steel-making, Most current undertakes molten iron using hot-metal bottle or fish torpedo ladle Storage task, when converter system breaks down in production process, have molten iron before usual converter, after have molten steel, or even have down What is gone out melts down molten steel.Generally it can be incubated or be disposed using refining furnace in terms of molten steel to continuous casting into strand;And Molten iron will generally add substantial amounts of heat preserving agent and is incubated, and typically not surpass 16 hours in blowing out, molten iron by heat preserving agent insulation and The measures such as iron making pre-treatment crust, most of molten iron can be blended into converter and be made steel, be stained with the iron bag of molten iron wrapped by changing or The formal layout such as unpack in advance.If it exceeds 16 hours ladle stick together because cooling can form bag, the loss of molten iron had so both been caused, The normal week of ladle may mainly be influenceed then cause subsequent production passive.
The content of the invention
The technical problems to be solved by the invention are to provide a kind of method that molten iron is incubated in ladle refining furnace.
The principle that this method can be heated up using ladle refining furnace to high temperature metal liquid, realization is entered to molten iron in ladle The function of row insulation.It, which solves the molten iron crouching bag time, can cause molten iron can not be handled because being cooled to solidification more than 16h, mainly The normal week of ladle may be influenceed then cause subsequent production passive.
In order to solve the above technical problems, the technical solution used in the present invention is:A kind of guarantor of molten iron in ladle refining furnace Warm method, the described method comprises the following steps:
(1) molten iron enters LF refining furnace:Molten iron is slowly folded into the good ladle of bag condition, add heat preserving agent, ladle is hung to LF Refining furnace sits bag position, connects bottom blowing system;
(2) thermometric and heating:Ladle is opened to heating position and carries out thermometric, target temperature is warming up to;
(3) submerged arc:Out of feed bin submerged arc slag, slagging agent and lime material, implementation process arc-covering slag operation are added to ladle;
(4) heating and iron making:Heating is reached after target temperature every time, is stopped heating, is then further continued for warming temperature, so anti- It is multiple, until converter system possesses after working condition, outbound after temperature control to target temperature, by being transported to charging across flatcar Across, realize operation to converter iron making;
(5) ladle confirms:Confirm that ladle furnace converts rear packet splicing amount, coordinate smelting steel grade and be further continued for using.
The method of the invention is applied to molten iron, by vanadium extraction or pretreated half steel.
Add 0.5-1.0kg/ ton molten iron of heat preserving agent in step (1) of the present invention, heat preserving agent can use carbonization rice husk or Middle covering agent;The carbonization rice husk:Ash content≤36%, fixed carbon >=38%, H20≤1.5%;The middle covering agent is mainly changed Study point as follows:CaO:27-33%,AL2O3:9-11%,SiO2:29-35%.
Bottom blowing gas intensity 200-600 NL/min in step (1) of the present invention.
Increasing extent of temperature is 2-5 DEG C/min, 1300-1350 DEG C of target temperature in step (2) of the present invention.
Add in step (3) of the present invention 1.0-3.0kg/ tons of molten iron of slagging agent, 1.0-3.0kg/ tons of molten iron of submerged arc slag, 4.0-10.0kg/ tons of molten iron of lime;The submerged arc slag main chemical compositions are as follows:CaO:35-45%, AL2O3:10-20%, SiO2: 5-10%, CaF2:2-6%, Si:5-8%;The slagging agent main chemical compositions are as follows:CaF2≥85%。
Heat time≤10min of target temperature is reached in step (4) of the present invention every time, reaches and stops after target temperature Only warming temperature is further continued for after heating 90-120min.
The ladle after is not arranged production in step (5) of the present invention the low-carbon steel grade of C≤0.10%.
The mentality of designing of the present invention is as follows:
Principle is that possess the theoretical foundation heated up to high temperature metal liquid using ladle refining furnace.A kind of high temperature metal liquid is going out Under conditions of existing possible solidification, the high temperature metal liquid can be folded into a ladle for possessing good bottom blowing condition, utilized A kind of method that ladle refining furnace is incubated.
On the premise of producing for a long time occurs in converter system, molten iron can not be returned again when, at this moment molten iron is folded into In ladle, using ladle bottom blowing system, the ladle equipped with molten iron is carried out insulation operation in refining furnace, after after converter system recovery The molten iron of insulation is blended into converter to be smelted.
When the present invention successfully can solve the problem that the pneumatic steelmaking system off-time is longer, under conditions of molten iron can not be returned, Molten iron is folded into ladle, is successfully incubated in refining furnace, it is to avoid 4 wrap the generation sticked together, realize and reproduce Hou Tiebao Turnover and the reduction of cost.
It is using the beneficial effect produced by above-mentioned technical proposal:1st, the present invention possesses to high temperature using ladle refining furnace The theoretical foundation of metal liquid heating, on the premise of molten iron can not return to processing, molten iron is folded into ladle, utilizes Ladle Bottom System is blown, the ladle equipped with molten iron is carried out insulation operation in refining furnace, the molten iron of insulation is blended into after after converter system recovery Converter is normally smelted.2nd, when the present invention solves converter system exception in production, molten iron is waited in iron bag for a long time The problem of can not handling.3rd, the inventive method, which solves long-time crouching bag, can make the problem of ladle formation bag sticks together.4th, it is of the invention Method had both reduced the loss of molten iron, turn avoid the problems such as influence ladle involucrum can not have enough to meet the need and take live place.
Embodiment
With reference to specific embodiment, the present invention is further detailed explanation.
Embodiment 1
The first iron clad regimen condition being incubated in 2#LF stoves is as follows:
It is 1231 DEG C that molten iron, which enters temperature behind LF stations, submerged arc slag and each 1.2kg/ tons of molten iron of slagging agent is added from feed bin, using 8 grades Long arc heats 9min, the NL/min of bottom blowing gas intensity 300, and 1256 DEG C of thermometric, averagely 2.8 DEG C/min of heating add submerged arc slag again 7.5kg/ tons of molten iron of 1.6kg/ tons of molten iron and lime, using 4 grades of heating 9min, 1302 DEG C of thermometric, then the 4min that heats up, thermometric 1326 DEG C, output addition heat preserving agent(Carbonization rice husk)1.0kg/ tons of molten iron.It is spaced 37 DEG C of temperature drop after 90min, then (8+5) min in two times Heating, later per in 110min, heats 13min, stirs and waits 7min, interval wait 90min, so repeatedly, last out-station temperature 1325 DEG C, there is a little packet splicing after iron making.
Embodiment 2
The second iron clad regimen condition being incubated in 2#LF stoves is as follows:
It is 1223 DEG C that molten iron, which enters temperature behind LF stations, submerged arc slag and each 1.5kg/ tons of molten iron of slagging agent is added from feed bin, using 6 grades Long arc heats 9min, the NL/min of bottom blowing gas intensity 400, and 1246 DEG C of thermometric, averagely 2.6 DEG C/min of heating add submerged arc slag again 8.0kg/ tons of molten iron of 1.5kg/ tons of molten iron and lime, and 4 grades of heating 10min, 1288 DEG C of thermometric, then the 10min that heats up, thermometric 1317 DEG C, output addition heat preserving agent(Middle covering agent)0.5kg/ tons of molten iron;34 DEG C of temperature drop after 120min is spaced, then in two times (8+5) Min heats up, and per in 140min, heats 13min, stirs and waits 7min, interval wait 120min, so repeatedly, last out-station temperature 1314 DEG C, there is a little packet splicing after iron making.
Embodiment 3
The first iron clad regimen condition being incubated in 1#LF stoves is as follows:
Molten iron arrives at a station 1266 DEG C of temperature, adds submerged arc slag and each 2.0kg/ tons of molten iron of slagging agent from feed bin, is added using 8 grades of long arcs Hot 9min, the NL/min of bottom blowing gas intensity 500,1293 DEG C of thermometric, averagely heated up 3 DEG C/min, and 1.0kg/ tons of submerged arc slag is added again 9.0kg/ tons of molten iron of molten iron and lime, and 4 grades of heating 7min, 1329 DEG C of thermometric add heat preserving agent(Middle covering agent)0.8kg/ 37 DEG C of temperature drop after ton molten iron, interval 100min, then (8+7) min that heats up in two times, later in every 120min, heat 15min, turn over The 5min such as stir, be spaced 100min, so repeatedly, last 1329 DEG C of out-station temperature, without packet splicing after iron making.
Embodiment 4
The second iron clad regimen condition being incubated in 1#LF stoves is as follows:
Molten iron arrives at a station 1279 DEG C of temperature, adds submerged arc slag and each 1.0kg/ tons of molten iron of slagging agent from feed bin, is added using 6 grades of long arcs Heat 9 min, the NL/min of bottom blowing gas intensity 600,1312 DEG C of thermometric, averagely 3.6 DEG C/min of heating add submerged arc slag 1.5kg/ again Ton 5.0kg/ tons of molten iron of molten iron and lime, and 4 grades of heating 7min, 1344 DEG C of thermometric add heat preserving agent(Carbonization rice husk)0.5kg/ 39 DEG C of temperature drop after ton molten iron, interval 100min, then (8+7) min that heats up in two times, later in every 120min, heat 15min, turn over The 5min such as stir, be spaced 100min, so repeatedly, last 1347 DEG C of out-station temperature, without packet splicing after iron making.
Embodiment 5
The first iron clad regimen condition being incubated in 1#LF stoves is as follows:
Molten iron is arrived at a station 1256 DEG C of temperature, and 0.5kg/ tons of molten iron of submerged arc slag, 3.0kg/ tons of iron of slagging agent are separately added into from feed bin Water, heats 10min, bottom blowing gas intensity 200NL/min, 1276 DEG C of thermometric, averagely 2 DEG C/min of heating add again using 8 grades of long arcs 10.0kg/ tons of molten iron of 0.5kg/ tons of molten iron of submerged arc slag and lime, and 4 grades of heating 7min, 1300 DEG C of thermometric add heat preserving agent(In Covering agent)37 DEG C of temperature drop after 0.9kg/ tons of molten iron, interval 100min, then (8+7) min that heats up in two times, later per 120min In, heat 15min, stir wait 5min, interval 100min, so repeatedly, last 1321 DEG C of out-station temperature, without packet splicing after iron making.
Embodiment 6
The second iron clad regimen condition being incubated in 1#LF stoves is as follows:
Molten iron is arrived at a station 1276 DEG C of temperature, and submerged arc slag and each 1.0kg/ ton molten iron of slagging agent are added from feed bin, using 6 grades of long arcs heating 9min, bottom blowing gas intensity 350NL/min, 1321 DEG C of thermometric, averagely heated up 5.0 DEG C/min, and 1.0kg/ tons of iron of submerged arc slag are added again 4.0kg/ tons of molten iron of water and lime, and 4 grades of heating 7min, 1350 DEG C of thermometric add heat preserving agent(Carbonization rice husk)0.6kg/ tons of iron 39 DEG C of temperature drop after water, interval 100min, then (8+7) min that heats up in two times, later in every 120min, heat 15min, stir 5min, is spaced 100min, so repeatedly, last 1347 DEG C of out-station temperature, without packet splicing after iron making.
Ladle after is not arranged production the low-carbon steel grade and steel grade that residual elements are required of C≤0.10%.
Above example is only used to illustrative and not limiting technical scheme, although with reference to above-described embodiment to this hair It is bright to be described in detail, it will be understood by those within the art that:Still the present invention can be modified or be waited With replacement, any modification or partial replacement without departing from the spirit and scope of the present invention, it all should cover the power in the present invention Among sharp claimed range.

Claims (8)

1. a kind of molten iron is in the heat preserving method of ladle refining furnace, it is characterised in that the described method comprises the following steps:
(1) molten iron enters LF refining furnace:Molten iron is slowly folded into the good ladle of bag condition, add heat preserving agent, ladle is hung to LF Refining furnace sits bag position, connects bottom blowing system;
(2) thermometric and heating:Ladle is opened to heating position and carries out thermometric, target temperature is warming up to;
(3) submerged arc:Out of feed bin submerged arc slag, slagging agent and lime material, implementation process arc-covering slag operation are added to ladle;
(4) heating and iron making:Heating is reached after target temperature every time, is stopped heating, is then further continued for warming temperature, so anti- It is multiple, until converter system possesses after working condition, outbound after temperature control to target temperature, by being transported to charging across flatcar Across, realize operation to converter iron making;
(5) ladle confirms:Confirm ladle packet splicing amount, coordinate smelting steel grade and be further continued for using.
2. a kind of molten iron according to claim 1 is in the heat preserving method of ladle refining furnace, it is characterised in that methods described is fitted For molten iron, by vanadium extraction or pretreated half steel.
3. a kind of molten iron according to claim 1 is in the heat preserving method of ladle refining furnace, it is characterised in that the step (1) 0.5-1.0kg/ tons of molten iron of heat preserving agent are added in, heat preserving agent can use carbonization rice husk or middle covering agent;The carbonization rice Shell:Ash content≤36%, fixed carbon >=38%, H20≤1.5%;The middle covering agent main chemical compositions are as follows:CaO:27-33%, AL2O3:9-11%,SiO2:29-35%.
4. a kind of molten iron according to claim 1 is in the heat preserving method of ladle refining furnace, it is characterised in that the step (1) bottom blowing gas intensity 200-600NL/min in.
5. a kind of molten iron according to claim 1-4 any one is in the heat preserving method of ladle refining furnace, it is characterised in that Increasing extent of temperature is 2-5 DEG C/min, 1300-1350 DEG C of target temperature in the step (2).
6. a kind of molten iron according to claim 1 is in the heat preserving method of ladle refining furnace, it is characterised in that the step (3) 1.0-3.0kg/ tons of molten iron of slagging agent, 1.0-3.0kg/ tons of molten iron of submerged arc slag, 4.0-10.0kg/ tons of molten iron of lime are added in; The submerged arc slag main chemical compositions are as follows:CaO:35-45%, AL2O3:10-20%, SiO2:5-10%, CaF2:2-6%, Si:5- 8%;The slagging agent main chemical compositions are as follows:CaF2≥85%。
7. a kind of molten iron according to claim 1-4 any one is in the heat preserving method of ladle refining furnace, it is characterised in that Heat time≤10min of target temperature is reached in the step (4) every time, reaches and stops heating 90- after target temperature Warming temperature is further continued for after 120min.
8. a kind of molten iron according to claim 1-4 any one is in the heat preserving method of ladle refining furnace, it is characterised in that The ladle after is not arranged production in the step (5) the low-carbon steel grade of C≤0.10%.
CN201710282577.XA 2017-04-26 2017-04-26 A kind of method that molten iron is kept the temperature in ladle refining furnace Expired - Fee Related CN107164604B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112522474A (en) * 2020-12-01 2021-03-19 攀钢集团西昌钢钒有限公司 Method for controlling LF refining end point temperature

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2675722A1 (en) * 1991-04-25 1992-10-30 Peugeot Apparatus for filling holding furnaces
CN1336442A (en) * 2000-07-29 2002-02-20 江苏淮钢集团有限公司 Hot loading process of molten iron in electric furnace and conveying vehicle for blast furnace molten iron
CN103170612A (en) * 2013-04-12 2013-06-26 北京首钢国际工程技术有限公司 Melting method of bonded iron on hot-metal ladle
CN105779693A (en) * 2016-04-20 2016-07-20 江苏迪萨机械有限公司 Covering and uncovering device of LF furnace

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2675722A1 (en) * 1991-04-25 1992-10-30 Peugeot Apparatus for filling holding furnaces
CN1336442A (en) * 2000-07-29 2002-02-20 江苏淮钢集团有限公司 Hot loading process of molten iron in electric furnace and conveying vehicle for blast furnace molten iron
CN103170612A (en) * 2013-04-12 2013-06-26 北京首钢国际工程技术有限公司 Melting method of bonded iron on hot-metal ladle
CN105779693A (en) * 2016-04-20 2016-07-20 江苏迪萨机械有限公司 Covering and uncovering device of LF furnace

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112522474A (en) * 2020-12-01 2021-03-19 攀钢集团西昌钢钒有限公司 Method for controlling LF refining end point temperature

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