CN107164061A - A kind of metal lubrication oil - Google Patents

A kind of metal lubrication oil Download PDF

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Publication number
CN107164061A
CN107164061A CN201710535996.XA CN201710535996A CN107164061A CN 107164061 A CN107164061 A CN 107164061A CN 201710535996 A CN201710535996 A CN 201710535996A CN 107164061 A CN107164061 A CN 107164061A
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China
Prior art keywords
parts
acid
lubrication oil
peroxide
metal lubrication
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CN201710535996.XA
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Chinese (zh)
Inventor
徐仙峰
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Hefei Jun Choose Electrical Equipment Co
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Hefei Jun Choose Electrical Equipment Co
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Priority to CN201710535996.XA priority Critical patent/CN107164061A/en
Publication of CN107164061A publication Critical patent/CN107164061A/en
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    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/02—Water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106—Naphthenic fractions
    • C10M2203/1065—Naphthenic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/06—Peroxides; Ozonides
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/121—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms
    • C10M2207/123—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of seven or less carbon atoms polycarboxylic
    • C—CHEMISTRY; METALLURGY
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    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10—Carboxylix acids; Neutral salts thereof
    • C10M2207/12—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • C10M2207/126—Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids monocarboxylic
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/104—Polyethers, i.e. containing di- or higher polyoxyalkylene groups of alkylene oxides containing two carbon atoms only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/10—Macromolecular compoundss obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/103—Polyethers, i.e. containing di- or higher polyoxyalkylene groups
    • C10M2209/108—Polyethers, i.e. containing di- or higher polyoxyalkylene groups etherified
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
    • C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044—Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/10—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring
    • C10M2219/104—Heterocyclic compounds containing sulfur, selenium or tellurium compounds in the ring containing sulfur and carbon with nitrogen or oxygen in the ring
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
    • C10M2223/02—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having no phosphorus-to-carbon bonds
    • C10M2223/04—Phosphate esters
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
    • C10M2227/06—Organic compounds derived from inorganic acids or metal salts
    • C10M2227/061—Esters derived from boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12—Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/24—Emulsion properties
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/64—Environmental friendly compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Abstract

The invention provides a kind of metal lubrication oil, including 30 60 parts of mineral oil, 5 10 parts of polypentaerythritol acrylate, 5 15 parts of aliphatic acid, 05 parts of hydramine borate, 15 parts of zinc stearate, 5 10 parts of petroleum sodium sulfonate, 36 parts of dodecenylsuccinic acid sodium, 13 parts of HPMA, 35 parts of triethanolamine, 25 parts of AEO carboxylic acid, 5 10 parts of isomery AEO, the raw material such as 15 parts of initiator.Good lubrication, cooling effect are can reach using the present invention, energy-saving and emission-reduction, environmental protection effect significantly, and reduce use cost.

Description

A kind of metal lubrication oil
Technical field
The present invention relates to technical field of lubricating oil, and in particular to a kind of metal lubrication oil.
Background technology
Traditional metal cutting process carries out a large amount of shower formula lubrications using mineral oil or vegetable oil or cutting fluid and cooled down, The usage amount of lubricant is big, and not only waste of resource, causes the huge pollution of processing site and environment, while can also have a strong impact on behaviour Make the healthy of workman.Advocate energy-saving and emission-reduction, environmental protection, green production today, be badly in need of a kind of new metal cutting Lubricating oil for machining.Minimal Quantity Lubrication Technology is the metallic green New Machining Technology grown up in recent years, is exactly added in metal cutting The good lubricating oil of extreme pressure anti-wear, lubricity is sprayed on process tool and finished surface using lubricating system with trace amount during work It is lubricated, cools down, cutting oil, liquid usage amount is big when solving traditional processing, waste the problems such as leakage rate is big.Existing micro profit In sliding technology using lubricating oil there are these for the use of：Easily broken power, workpiece have cut, workpiece to be easily corroded.This The product of class is main to be controlled domestic market by external producer, and their product price is high, and use cost is high, seriously constrains The development of national industry.
The content of the invention
The purpose of the present invention is that there is provided the lubricating oil that a kind of cost is low, lubricity is good for problem of the prior art.
In order to achieve the above object, the present invention is achieved through the following technical solutions：
A kind of metal lubrication oil, including following raw material by weight：
30-60 parts of mineral oil, 5-10 parts of polypentaerythritol acrylate,
5-15 parts of aliphatic acid, 0-5 parts of hydramine borate,
1-5 parts of zinc stearate, 5-10 parts of petroleum sodium sulfonate,
3-6 parts of dodecenylsuccinic acid sodium, 1-3 parts of HPMA,
3-5 parts of triethanolamine, 2-5 parts of AEO carboxylic acid,
5-10 parts of isomery AEO, 1-5 parts of initiator,
1-3 parts of glycerine, 2-6 parts of cycloalkanes base oil,
10-20 parts of self-emulsifying ester, 5-10 parts of phosphate,
1-2 parts of corrosion inhibiter, 1-5 parts of OIT,
4-8 parts of water.
Further, the metal lubrication oil includes following raw material by weight：
43 parts of mineral oil, 8 parts of polypentaerythritol acrylate,
12 parts of aliphatic acid, 3 parts of hydramine borate,
3 parts of zinc stearate, 7 parts of petroleum sodium sulfonate,
4 parts of dodecenylsuccinic acid sodium, 2 parts of HPMA,
4 parts of triethanolamine, 4 parts of AEO carboxylic acid,
7 parts of isomery AEO, 4 parts of initiator,
2 parts of glycerine, 4 parts of cycloalkanes base oil,
13 parts of self-emulsifying ester, 8 parts of phosphate,
1 part of corrosion inhibiter, 3 parts of OIT,
6 parts of water.
Further, the aliphatic acid is the one or more in the saturation or unrighted acid that carbon number is 8-24 Mixture.
Further, the aliphatic acid is isooctyl acid, n-capric acid, laurate, myristic acid, palmitic acid, oleic acid, stearic acid In one or more of mixtures.
Further, the initiator is dibenzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tertiary fourth Base hydrogen peroxide, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, the tertiary fourth of peroxidating trimethylacetic acid Base ester, methyl ethyl ketone peroxide, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate, peroxide Change one or more mixtures in two diethyl hexylcarbonates, azodiisobutyronitrile and ABVN.
Further, the matter average molecular weight of the HPMA is 1000, the AEO carboxylic acid Carbon number is carbon atom in 18-20, the isomery fatty alcohol group of the isomery AEO in fatty alcohol group Number is 13-15.
Further, the hydramine borate is selected from the one kind carried out by hydramine and boric acid in the product of esterification generation Or several mixtures.
Further, the zinc stearate is 300 mesh stearic acid zinc powders.
The present invention compared with prior art, with following beneficial effect：
Using polypentaerythritol acrylate, aliphatic acid, hydramine borate and zinc stearate, make the present invention that there is fine extreme pressure to resist Mill property and lubricity and biodegradability；Polypentaerythritol acrylate has good lubricity and biodegradability, Aliphatic acid has good lubricity and extreme pressure anti-wear, and biological degradability is good；Hydramine borate greasy property is good, prevents Rust excellent performance；Oil-soluble inhibitor and maleic anhydride, the fatty alcohol polyoxy of the compositions such as mineral oil, petroleum sodium sulfonate, triethanolamine Vinethene carboxylic acid, isomery AEO are compounded so that they being capable of formation electrolyte solution soluble in water, tool There are more excellent antirust and emulsifiability.The present invention can extend the service life of metal knife, strengthen its polar emollient effect, plus More preferably, the fraction defective of product reduces till now 0.03% to work metallic article finish by original 2.1%, has saved cost, has improved Production efficiency；Minimum quantity lubrication device is coordinated to use the present invention, usage amount can be reduced to original less than 5%, reached good Lubrication well, cooling effect, energy-saving and emission-reduction, environmental protection effect significantly, reduce use cost.
Embodiment
With reference to embodiment, the invention will be further described.
Embodiment 1
A kind of metal lubrication oil, including following raw material：
30 grams of mineral oil, 10 grams of polypentaerythritol acrylate,
5 grams of aliphatic acid, 5 grams of hydramine borate,
1 gram of zinc stearate, 10 grams of petroleum sodium sulfonate,
3 grams of dodecenylsuccinic acid sodium, 3 grams of HPMA,
3 grams of triethanolamine, 5 grams of AEO carboxylic acid,
5 grams of isomery AEO, 5 grams of initiator,
1 gram of glycerine, 6 grams of cycloalkanes base oil,
10 grams of self-emulsifying ester, 10 grams of phosphate,
1 gram of corrosion inhibiter, 5 grams of OIT,
4 grams of water.
The aliphatic acid is one or more of mixtures in the saturation that carbon number is 8-24 or unrighted acid.
The aliphatic acid is one kind in isooctyl acid, n-capric acid, laurate, myristic acid, palmitic acid, oleic acid, stearic acid Or several mixtures.
The initiator is dibenzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide Hydrogen, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, peroxide Change MEK, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate, dicetyl peroxydicarbonate One or more mixtures in ethylhexyl, azodiisobutyronitrile and ABVN.
The matter average molecular weight of the HPMA is 1000, the fatty alcohol group of the AEO carboxylic acid Middle carbon number is 18-20, and carbon number is 13-15 in the isomery fatty alcohol group of the isomery AEO.
The hydramine borate is one or more of in the product of esterification generation selected from being carried out by hydramine and boric acid Mixture.
Embodiment 2
A kind of metal lubrication oil, including following raw material：
60 grams of mineral oil, 5 grams of polypentaerythritol acrylate,
15 grams of aliphatic acid,
5 grams of zinc stearate, 5 grams of petroleum sodium sulfonate,
6 grams of dodecenylsuccinic acid sodium, 1 gram of HPMA,
5 grams of triethanolamine, 2 grams of AEO carboxylic acid,
10 grams of isomery AEO, 1 gram of initiator,
3 grams of glycerine, 2 grams of cycloalkanes base oil,
20 grams of self-emulsifying ester, 5 grams of phosphate,
2 grams of corrosion inhibiter, 1 gram of OIT,
8 grams of water.
The aliphatic acid is one or more of mixtures in the saturation that carbon number is 8-24 or unrighted acid.
The aliphatic acid is one kind in isooctyl acid, n-capric acid, laurate, myristic acid, palmitic acid, oleic acid, stearic acid Or several mixtures.
The initiator is dibenzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide Hydrogen, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, peroxide Change MEK, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate, dicetyl peroxydicarbonate One or more mixtures in ethylhexyl, azodiisobutyronitrile and ABVN.
The matter average molecular weight of the HPMA is 1000, the fatty alcohol group of the AEO carboxylic acid Middle carbon number is 18-20, and carbon number is 13-15 in the isomery fatty alcohol group of the isomery AEO.
The hydramine borate is one or more of in the product of esterification generation selected from being carried out by hydramine and boric acid Mixture.
Embodiment 3
A kind of metal lubrication oil, including following raw material：
43 grams of mineral oil, 8 grams of polypentaerythritol acrylate,
12 grams of aliphatic acid, 3 grams of hydramine borate,
3 grams of zinc stearate, 7 grams of petroleum sodium sulfonate,
4 grams of dodecenylsuccinic acid sodium, 2 grams of HPMA,
4 grams of triethanolamine, 4 grams of AEO carboxylic acid,
7 grams of isomery AEO, 4 grams of initiator,
2 grams of glycerine, 4 grams of cycloalkanes base oil,
13 grams of self-emulsifying ester, 8 grams of phosphate,
1 gram of corrosion inhibiter, 3 grams of OIT,
6 grams of water.
The aliphatic acid is one or more of mixtures in the saturation that carbon number is 8-24 or unrighted acid.
The aliphatic acid is one kind in isooctyl acid, n-capric acid, laurate, myristic acid, palmitic acid, oleic acid, stearic acid Or several mixtures.
The initiator is dibenzoyl peroxide, lauroyl peroxide, isopropyl benzene hydroperoxide, tert-butyl hydroperoxide Hydrogen, di-t-butyl peroxide, cumyl peroxide, peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, peroxide Change MEK, cyclohexanone peroxide, di-isopropyl peroxydicarbonate, di-cyclohexylperoxy di-carbonate, dicetyl peroxydicarbonate One or more mixtures in ethylhexyl, azodiisobutyronitrile and ABVN.
The matter average molecular weight of the HPMA is 1000, the fatty alcohol group of the AEO carboxylic acid Middle carbon number is 18-20, and carbon number is 13-15 in the isomery fatty alcohol group of the isomery AEO.
The hydramine borate is one or more of in the product of esterification generation selected from being carried out by hydramine and boric acid Mixture.
The present invention has the present invention using polypentaerythritol acrylate, aliphatic acid, hydramine borate and zinc stearate Fine extreme pressure anti-wear and lubricity and biodegradability；Polypentaerythritol acrylate has good lubricity and biology Degradability, aliphatic acid has good lubricity and extreme pressure anti-wear, and biological degradability is good；Hydramine borate lubricity Can be good, rustless property is good；Oil-soluble inhibitor and maleic anhydride, the fat of the compositions such as mineral oil, petroleum sodium sulfonate, triethanolamine Fat alcohol APEO carboxylic acid, isomery AEO are compounded so that they soluble in water can form electrolysis Matter solution, with more excellent antirust and emulsifiability.The present invention can extend the service life of metal knife, strengthen its polarity profit Sliding effect, more preferably, the fraction defective of product reduces 0.03%, saving till now to processing metallic article finish by original 2.1% Cost, improves production efficiency；By the present invention coordinate minimum quantity lubrication device use, usage amount can reduce to original 5% with Under, good lubrication, cooling effect are reached, energy-saving and emission-reduction, environmental protection effect significantly, reduce use cost.
The preferred embodiments of the present invention are these are only, are not intended to limit the invention, although with reference to the foregoing embodiments The present invention is described in detail, for those skilled in the art, it still can be to foregoing embodiments institute The technical scheme of record is modified, or carries out equivalent substitution to which part technical characteristic.It is all the present invention spirit and Within principle, any modification made, equivalent substitution, improve etc., it should be included in the scope of the protection.

Claims (8)

1. a kind of metal lubrication oil, it is characterised in that including following raw material by weight：
30-60 parts of mineral oil, 5-10 parts of polypentaerythritol acrylate,
5-15 parts of aliphatic acid, 0-5 parts of hydramine borate,
1-5 parts of zinc stearate, 5-10 parts of petroleum sodium sulfonate,
3-6 parts of dodecenylsuccinic acid sodium, 1-3 parts of HPMA,
3-5 parts of triethanolamine, 2-5 parts of AEO carboxylic acid,
5-10 parts of isomery AEO, 1-5 parts of initiator,
1-3 parts of glycerine, 2-6 parts of cycloalkanes base oil,
10-20 parts of self-emulsifying ester, 5-10 parts of phosphate,
1-2 parts of corrosion inhibiter, 1-5 parts of OIT,
4-8 parts of water.
2. a kind of metal lubrication oil according to claim 1, it is characterised in that the metal lubrication oil is included below by weight Measure the raw material of part meter：
43 parts of mineral oil, 8 parts of polypentaerythritol acrylate,
12 parts of aliphatic acid, 3 parts of hydramine borate,
3 parts of zinc stearate, 7 parts of petroleum sodium sulfonate,
4 parts of dodecenylsuccinic acid sodium, 2 parts of HPMA,
4 parts of triethanolamine, 4 parts of AEO carboxylic acid,
7 parts of isomery AEO, 4 parts of initiator,
2 parts of glycerine, 4 parts of cycloalkanes base oil,
13 parts of self-emulsifying ester, 8 parts of phosphate,
1 part of corrosion inhibiter, 3 parts of OIT,
6 parts of water.
3. a kind of metal lubrication oil according to claim 1, it is characterised in that the aliphatic acid is that carbon number is 8-24 Saturation or unrighted acid in one or more of mixtures.
4. a kind of metal lubrication oil according to claim 1, it is characterised in that the aliphatic acid be isooctyl acid, n-capric acid, One or more of mixtures in laurate, myristic acid, palmitic acid, oleic acid, stearic acid.
5. a kind of metal lubrication oil according to claim 1, it is characterised in that the initiator is diphenyl peroxide first Acyl, lauroyl peroxide, isopropyl benzene hydroperoxide, TBHP, di-t-butyl peroxide, cumyl peroxide, Peroxidized t-butyl perbenzoate, peroxidating trimethylacetic acid tertiary butyl ester, methyl ethyl ketone peroxide, cyclohexanone peroxide, the carbon of peroxidating two Sour diisopropyl ester, di-cyclohexylperoxy di-carbonate, dicetyl peroxydicarbonate ethylhexyl, azodiisobutyronitrile and azo two are different One or more mixtures in heptonitrile.
6. a kind of metal lubrication oil according to claim 1, it is characterised in that the matter average molecular weight of the HPMA For 1000, carbon number is 18-20, the isomery poly alkyl alcohol in the fatty alcohol group of the AEO carboxylic acid Carbon number is 13-15 in the isomery fatty alcohol group of oxygen vinethene.
7. a kind of metal lubrication oil according to claim 1, it is characterised in that the hydramine borate be selected from by hydramine and Boric acid carries out one or more of mixtures in the product of esterification generation.
8. a kind of metal lubrication oil according to claim 1, it is characterised in that the zinc stearate is 300 mesh stearic acid Zinc powder.
CN201710535996.XA 2017-07-04 2017-07-04 A kind of metal lubrication oil Withdrawn CN107164061A (en)

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CN105112132A (en) * 2015-07-16 2015-12-02 路伯润滑油（苏州）有限公司 Emulsified rust prevention oil and preparation method thereof
CN105112129A (en) * 2015-09-28 2015-12-02 龚灿锋 Flame-retardant, acid-proof, alkali-proof and anti-bacterial lubricating oil for mechanical bearing
CN105296081A (en) * 2015-10-16 2016-02-03 上海金兆节能科技有限公司 Degradable minimal quantity lubrication oil and preparation method thereof
CN105294898A (en) * 2015-10-16 2016-02-03 上海金兆节能科技有限公司 Poly pentaerythritol acrylate, preparation method thereof and operation for preparing trace-amount lubricating oil through same

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CN105038938A (en) * 2015-09-09 2015-11-11 路伯润滑油（苏州）有限公司 Aviation magnalium cutting fluid and preparation method thereof
CN105112129A (en) * 2015-09-28 2015-12-02 龚灿锋 Flame-retardant, acid-proof, alkali-proof and anti-bacterial lubricating oil for mechanical bearing
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CN117025277B (en) * 2023-06-14 2024-06-04 无锡中石油润滑脂有限责任公司 Biodegradable lubricating grease for large ship lift and preparation method thereof

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