CN107164031A

CN107164031A - A kind of metal antirusting agent with excellent greasy property

Info

Publication number: CN107164031A
Application number: CN201710220743.3A
Authority: CN
Inventors: 林伟; 江海涛; 江海波; 江浩
Original assignee: Tianchang Runda Metal Antirust Auxiliary Co Ltd
Current assignee: Tianchang Runda Metal Antirust Auxiliary Co Ltd
Priority date: 2017-04-06
Filing date: 2017-04-06
Publication date: 2017-09-15

Abstract

The invention discloses a kind of metal antirusting agent with excellent greasy property, its raw material includes sulfoacid calcium, adipic acid isooctanol ester, hendecane dicarboxylic acid iso-heptanol ester, dimeric dibasic acid di-isooctyl, zinc dialkyl dithiophosphate, adjacent benzene front three phenolic ester, chlorinated paraffin, sulfide isobutene, modified lubricant, modified lubricating auxiliary agent, the molten ammoniacal copper quaternary of amine, calgon, sulphur dodecenylsuccinic acid, zinc naphthenate, BTA, sodium olefin sulfonate, sodium tripolyphosphate, diammonium hydrogen phosphate, aliphatic acid, dialkyldithiocarbamacompositions sodium, polyisobutene succinimide, methyl benzoate, polytetrafluoroethylene (PTFE), butylene, NPE, fatty acid methyl ester ethoxylate sulfoacid calcium, DBSA and ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.The metal antirusting agent of the present invention has excellent oil removing clean-up performance, good antirust property.

Description

A kind of metal antirusting agent with excellent greasy property

Technical field

The present invention relates to the technical field of antirust agent, more particularly to a kind of metal antirusting agent with excellent greasy property.

Background technology

Metal is during storage, transport and use, due to by the steam in ambiance, oxygen, acid, alkali, salt and carbon The influence of the materials such as compound, can occur under conditions of certain temperature, humidity and time duration physics, chemical change and repair Decorations, in order to improve metallicity, the metal waste that reduction corrosion is caused to metal surface, it is necessary to carry out antirust treatment.

All there is oil stain and spot in many metal surfaces in metal, had a strong impact on metal and prevented when carrying out the coating of antirust agent The coating of rust agent, reduces the rustless property of metal antirusting agent, it is impossible to meets the demand that actual use is, therefore needs design one badly The metal antirusting agent with excellent greasy property is planted to solve the problems of the prior art.

The content of the invention

To solve technical problem present in background technology, the present invention proposes that a kind of metal with excellent greasy property is prevented Rust agent, good antirust property, and with excellent oil removing clean-up performance.

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes by weight：Sulfonic acid 4-8 parts of calcium, 4-9 parts of adipic acid isooctanol ester, 2-5 parts of hendecane dicarboxylic acid iso-heptanol ester, 1-6 parts of dimeric dibasic acid di-isooctyl, dioxane 2-8 parts of base zinc dithiophosphate, adjacent 3-5 parts of benzene front three phenolic ester, 2-4 parts of chlorinated paraffin, 1-3 parts of sulfide isobutene, modified lubrication 2-5 parts of agent, modified 3-9 parts of lubricating auxiliary agent, molten ammoniacal copper quaternary 4-8 parts of amine, 1-3 parts of calgon, sulphur dodecenylsuccinic acid 4-8 Part, 4-8 parts of zinc naphthenate, 2-5 parts of BTA, 1-6 parts of sodium olefin sulfonate, 3-6 parts of sodium tripolyphosphate, diammonium hydrogen phosphate 3- 6 parts, 3-6 parts of aliphatic acid, 4-9 parts of dialkyldithiocarbamacompositions sodium, 2-5 parts of polyisobutene succinimide, benzoic acid first 1-6 parts of ester, 3-9 parts of polytetrafluoroethylene (PTFE), 1-5 parts of butylene, 2-5 parts of NPE, fatty acid methyl ester ethoxylate 2-8 parts of sulfoacid calcium, 3-6 parts of DBSA, 4-8 parts of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.

Preferably, dimeric dibasic acid di-isooctyl is prepared by following technique：Dimeric dibasic acid and isooctanol are well mixed, in 350-650r/min rotating speeds stir 20-40min, then add benzene and p-methyl benzenesulfonic acid is well mixed, be warming up to 60-80 DEG C, guarantor Warm 20-40min, is stirred at reflux, and is cooled to room temperature, is washed after distillation with sodium hydroxide solution, then with 70-90 DEG C of distillation washing Wash to pH to 7, vacuum dehydration obtains dimeric dibasic acid di-isooctyl.

Preferably, in the preparation technology of dimeric dibasic acid di-isooctyl, dimeric dibasic acid, isooctanol, the weight of benzene and p-methyl benzenesulfonic acid Than for 3-6：2-5：1-3：3-6.

Preferably, modified lubricant is prepared by following technique：Polyethylene glycol is pumped into polymer reactor, is warming up to 100-120 DEG C, vacuumize, then add ammonium persulfate and be well mixed, be warming up to 130-150 DEG C, vacuumize and be passed through High Purity Nitrogen Gas shielded, then adds APEO and is well mixed, it is 120-140 DEG C to control temperature, and pressure is less than 0.35MPa, insulation drop 0.2MPa is depressed into, 20-40min is incubated, Silane coupling reagent KH-570 is then added and is well mixed, leads to nitrogen temperature to 60-80 DEG C, 90-110 DEG C is continuously heating to, cooling discharge is modified lubricant.

Preferably, in the preparation technology of modified lubricant, polyethylene glycol, ammonium persulfate, APEO and silane coupled Agent KH-570 weight ratio is 3-6：2-5：1-3：2-5.

Preferably, modified lubricating auxiliary agent is prepared by following technique：By refined rapeseed oil and alkaline permanganate solution It is well mixed, 20-40min is stirred in 650-850r/min rotating speeds, boric acid is then added and is well mixed, be warming up to 110-130 DEG C, 0.5-1.5h is incubated, triethanolamine is subsequently added into and is well mixed, stir 0.5-1.5h, be cooled to room temperature, vacuum distillation, after purification Obtain being modified lubricating auxiliary agent.

Preferably, in the preparation technology of modified lubricating auxiliary agent, refined rapeseed oil, alkaline permanganate solution, boric acid and three The weight ratio of monoethanolamine is 4-9：2-5：1-3：3-5.

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes sulfoacid calcium, adipic acid Isooctanol ester, hendecane dicarboxylic acid iso-heptanol ester, dimeric dibasic acid di-isooctyl, zinc dialkyl dithiophosphate, adjacent benzene front three phenolic ester, chlorine Fossil waxes, sulfide isobutene, modified lubricant, modified lubricating auxiliary agent, the molten ammoniacal copper quaternary of amine, calgon, sulphur laurylene base fourth Diacid, zinc naphthenate, BTA, sodium olefin sulfonate, sodium tripolyphosphate, diammonium hydrogen phosphate, aliphatic acid, dialkyl dithio Carbamic acid sodium, polyisobutene succinimide, methyl benzoate, polytetrafluoroethylene (PTFE), butylene, NPE, fat Fatty acid methyl esters ethoxylate sulfoacid calcium, DBSA and ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.Wherein, Dimeric dibasic acid di-isooctyl is stirred by the way that dimeric dibasic acid and isooctanol are well mixed, and then adds benzene and p-methyl benzenesulfonic acid mixing is equal It is even, it is incubated after heating, is stirred at reflux, is cooled to room temperature, is washed after distillation with sodium hydroxide solution, is then washed with distilled water to PH, vacuum dehydration obtains dimeric dibasic acid di-isooctyl, in the preparation for the metal antirusting agent for applying to the present invention, not only effectively increases Lubricity and antioxygenic property is further increased, because dimeric dibasic acid di-isooctyl is degradable lubricating additive, and passed through Prepare dimeric dibasic acid di-isooctyl apply to the present invention metal antirusting agent in can effectively improve environmental-protecting performance.Wherein, modified profit Lubrication prescription is pressed by the way that polyethylene glycol is pumped into polymer reactor, and heating is vacuumized, and is then added ammonium persulfate and is well mixed, rises Temperature, vacuumizes and is passed through high pure nitrogen protection, then add APEO and be well mixed, then insulation adds silane coupled Agent KH-570 is well mixed, and leads to nitrogen temperature, is continued to heat up, cooling discharge is modified lubricant, is applied to the gold of the present invention In the preparation for belonging to antirust agent, reduction abrasion can be played a part of to metal, reduce friction, save in energy consumption, lubricant molecule Polar molecule occur on surface of friction pair cohesive force between oriented attachment, binding molecule presence make it is intermolecular by it is very tight, So as to generate thin film, low shear strength area is formed in metal surface, there is reduction friction.Wherein, modified lubrication is helped Agent is stirred by the way that refined rapeseed oil and alkaline permanganate solution are well mixed, and is then added boric acid and is well mixed, heating, Insulation, is subsequently added into triethanolamine and is well mixed, and stirring is cooled to after room temperature, vacuum distillation, purification to obtain being modified lubrication and helped Agent, modified lubricating auxiliary agent has excellent antiwear and reducing friction performance, N high reaction activity, the carrier function and boron of vegetable seed oil molecule Electron deficient and the adsorbed film that is formed of synergy and friction chemical reaction film of three effectively increase the technology of the present invention The abrasion resistant extreme-pressure of antirust agent is gone, and the modification lubricating auxiliary agent of synthesis has good biodegradability, and is not contained in itself Malicious element, is a kind of environmentally friendly lubricating additive.The metal antirusting agent that the present invention is obtained is biodegradable, and with excellent Oil removing spatter property, and with excellent environmental-protecting performance.

Embodiment

The present invention is described in detail with reference to specific embodiment, it should be appreciated that embodiment is served only for illustrating this hair It is bright, rather than for limiting the invention, any modification made on the basis of the present invention, equivalent substitution etc. are in this hair In bright protection domain.

In embodiment, the parts by weight of sulfoacid calcium can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of adipic acid isooctanol ester can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 Part, 8 parts, 8.5 parts, 9 parts；The parts by weight of hendecane dicarboxylic acid iso-heptanol ester can for 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 Part, 5 parts；The parts by weight of dimeric dibasic acid di-isooctyl can for 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 Part, 5.5 parts, 6 parts；The parts by weight of zinc dialkyl dithiophosphate can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；Adjacent benzene The parts by weight of front three phenolic ester can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of chlorinated paraffin can for 2 parts, 2.5 Part, 3 parts, 3.5 parts, 4 parts；The parts by weight of sulfide isobutene can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；Modified lubricant Parts by weight can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；The parts by weight of modified lubricating auxiliary agent can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 parts；The weight of the molten ammoniacal copper quaternary of amine Part can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The parts by weight of calgon can be 1 Part, 1.5 parts, 2 parts, 2.5 parts, 3 parts；The parts by weight of sulphur dodecenylsuccinic acid can be 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；Cycloalkanes The parts by weight of sour zinc can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts；The weight of BTA It can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts to measure part；The parts by weight of sodium olefin sulfonate can for 1 part, 1.5 Part, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of sodium tripolyphosphate can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；The parts by weight of diammonium hydrogen phosphate can for 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 Part, 5.5 parts, 6 parts；The parts by weight of aliphatic acid can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Dialkyl disulfides For carbamic acid sodium parts by weight can for 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts, 8.5 parts, 9 Part；The parts by weight of polyisobutene succinimide can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Benzoic acid first The parts by weight of ester can be 1 part, 1.5 parts, 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Polytetrafluoro The parts by weight of ethene can be 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts, 9 parts；The parts by weight of butylene can for 1 part, 2 parts, 3 parts, 4 Part, 5 parts；The parts by weight of NPE can be 2 parts, 2.5 parts, 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts；Aliphatic acid The parts by weight of FMEE sulfoacid calcium can be 2 parts, 3 parts, 4 parts, 5 parts, 6 parts, 7 parts, 8 parts；DBSA Parts by weight can be 3 parts, 3.5 parts, 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts；Ethoxylized fatty alcohol APEO sulfuric acid The parts by weight of sodium can be 4 parts, 4.5 parts, 5 parts, 5.5 parts, 6 parts, 6.5 parts, 7 parts, 7.5 parts, 8 parts.

Embodiment 1

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes by weight：Sulfonic acid 6 parts of calcium, 6.5 parts of adipic acid isooctanol ester, 3.5 parts of hendecane dicarboxylic acid iso-heptanol ester, 3.5 parts of dimeric dibasic acid di-isooctyl, dialkyl group 5 parts of zinc dithiophosphate, adjacent 4 parts of benzene front three phenolic ester, 3 parts of chlorinated paraffin, 2 parts of sulfide isobutene, 3.5 parts of modified lubricant, change 6 parts of lubricating auxiliary agent of property, 6 parts of the molten ammoniacal copper quaternary of amine, 2 parts of calgon, 6 parts of sulphur dodecenylsuccinic acid, 6 parts of zinc naphthenate, benzene And 3.5 parts of triazole, 3.5 parts of sodium olefin sulfonate, 4.5 parts of sodium tripolyphosphate, 4.5 parts of diammonium hydrogen phosphate, 4.5 parts of aliphatic acid, two 6.5 parts of alkyl nabam, 3.5 parts of polyisobutene succinimide, 3.5 parts of methyl benzoate, polytetrafluoroethylene (PTFE) 6 Part, 3 parts of butylene, 3.5 parts of NPE, 5 parts of fatty acid methyl ester ethoxylate sulfoacid calcium, DBSA 4.5 parts, 6 parts of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.

Dimeric dibasic acid di-isooctyl is prepared by following technique：4.5 parts of dimeric dibasic acids and 3.5 parts of isooctanol are mixed by weight Close uniform, 30min is stirred in 500r/min rotating speeds, then add 2 parts of benzene and 4.5 parts of p-methyl benzenesulfonic acid are well mixed, be warming up to 70 DEG C, 30min is incubated, is stirred at reflux, is cooled to room temperature, is washed after distillation with sodium hydroxide solution, then with 80 DEG C of distilled water Washing is to pH to 7, and vacuum dehydration obtains dimeric dibasic acid di-isooctyl.

Modified lubricant is prepared by following technique：4.5 parts of polyethylene glycol are pumped into polymer reactor by weight, 110 DEG C are warming up to, is vacuumized, 3.5 parts of ammonium persulfates is then added and is well mixed, be warming up to 140 DEG C, vacuumize and be passed through high-purity Nitrogen is protected, and is then added 2 parts of APEOs and is well mixed, and it is 130 DEG C to control temperature, and pressure is less than 0.35MPa, insulation drop 0.2MPa is depressed into, 30min is incubated, 3.5 parts of Silane coupling reagent KH-570s is then added and is well mixed, leads to nitrogen temperature to 70 DEG C, 100 DEG C are continuously heating to, cooling discharge is modified lubricant.

Modified lubricating auxiliary agent is prepared by following technique：It is by weight that 6.5 parts of refined rapeseed oils and 3.5 parts of alkalescence are high Potassium manganate solution is well mixed, and 30min is stirred in 750r/min rotating speeds, is then added 2 parts of boric acid and is well mixed, is warming up to 120 DEG C, 1h is incubated, 4 parts of triethanolamines is subsequently added into and is well mixed, stir 1h, changed after being cooled to room temperature, vacuum distillation, purification Property lubricating auxiliary agent.

Embodiment 2

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes by weight：Sulfonic acid 4 parts of calcium, 9 parts of adipic acid isooctanol ester, 2 parts of hendecane dicarboxylic acid iso-heptanol ester, 6 parts of dimeric dibasic acid di-isooctyl, dialkyl dithio 2 parts of trbasic zinc phosphate, adjacent 5 parts of benzene front three phenolic ester, 2 parts of chlorinated paraffin, 3 parts of sulfide isobutene, 2 parts of modified lubricant, modified lubrication are helped 9 parts of agent, 4 parts of the molten ammoniacal copper quaternary of amine, 3 parts of calgon, 4 parts of sulphur dodecenylsuccinic acid, 8 parts of zinc naphthenate, BTA 2 Part, 6 parts of sodium olefin sulfonate, 3 parts of sodium tripolyphosphate, 6 parts of diammonium hydrogen phosphate, 3 parts of aliphatic acid, dialkyldithiocarbamacompositions sodium 9 parts, 2 parts of polyisobutene succinimide, 6 parts of methyl benzoate, 3 parts of polytetrafluoroethylene (PTFE), 5 parts of butylene, Nonyl pheno 2 parts of ether, 8 parts of fatty acid methyl ester ethoxylate sulfoacid calcium, 3 parts of DBSA, ethoxylized fatty alcohol polyoxyethylene 8 parts of ether sodium sulfate.

Dimeric dibasic acid di-isooctyl is prepared by following technique：3 parts of dimeric dibasic acids and 5 parts of isooctanol are mixed equal by weight It is even, 40min is stirred in 350r/min rotating speeds, 1 part of benzene is then added and 6 parts of p-methyl benzenesulfonic acid is well mixed, be warming up to 60 DEG C, guarantor Warm 40min, is stirred at reflux, and is cooled to room temperature, is washed after distillation with sodium hydroxide solution, then with 70 DEG C of distillation water washings to pH To 7, vacuum dehydration obtains dimeric dibasic acid di-isooctyl.

Modified lubricant is prepared by following technique：3 parts of polyethylene glycol are pumped into polymer reactor by weight, risen Temperature is vacuumized to 120 DEG C, is then added 2 parts of ammonium persulfates and is well mixed, is warming up to 150 DEG C, vacuumizes and be passed through high pure nitrogen Protection, then adds 1 part of APEO and is well mixed, it is 140 DEG C to control temperature, and pressure is less than 0.35MPa, and insulation is depressurized to 0.2MPa, is incubated 20min, then adds 5 parts of Silane coupling reagent KH-570s and is well mixed, and leads to nitrogen temperature to 60 DEG C, continues to rise Temperature is to 110 DEG C, and cooling discharge is modified lubricant.

Modified lubricating auxiliary agent is prepared by following technique：By weight by 4 parts of refined rapeseed oils and 5 parts of alkaline permanganic acid Potassium solution is well mixed, and 40min is stirred in 650r/min rotating speeds, is then added 1 part of boric acid and is well mixed, and is warming up to 130 DEG C, guarantor Warm 0.5h, is subsequently added into 5 parts of triethanolamines and is well mixed, stir 0.5h, changed after being cooled to room temperature, vacuum distillation, purification Property lubricating auxiliary agent.

Embodiment 3

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes by weight：Sulfonic acid 8 parts of calcium, 4 parts of adipic acid isooctanol ester, 5 parts of hendecane dicarboxylic acid iso-heptanol ester, 1 part of dimeric dibasic acid di-isooctyl, dialkyl dithio 8 parts of trbasic zinc phosphate, adjacent 3 parts of benzene front three phenolic ester, 4 parts of chlorinated paraffin, 1 part of sulfide isobutene, 5 parts of modified lubricant, modified lubrication are helped 3 parts of agent, 8 parts of the molten ammoniacal copper quaternary of amine, 1 part of calgon, 8 parts of sulphur dodecenylsuccinic acid, 4 parts of zinc naphthenate, BTA 5 Part, 1 part of sodium olefin sulfonate, 6 parts of sodium tripolyphosphate, 3 parts of diammonium hydrogen phosphate, 6 parts of aliphatic acid, dialkyldithiocarbamacompositions sodium 4 parts, 5 parts of polyisobutene succinimide, 1 part of methyl benzoate, 9 parts of polytetrafluoroethylene (PTFE), 1 part of butylene, Nonyl pheno 5 parts of ether, 2 parts of fatty acid methyl ester ethoxylate sulfoacid calcium, 6 parts of DBSA, ethoxylized fatty alcohol polyoxyethylene 4 parts of ether sodium sulfate.

Dimeric dibasic acid di-isooctyl is prepared by following technique：6 parts of dimeric dibasic acids and 2 parts of isooctanol are mixed equal by weight It is even, 20min is stirred in 650r/min rotating speeds, 3 parts of benzene is then added and 3 parts of p-methyl benzenesulfonic acid is well mixed, be warming up to 80 DEG C, guarantor Warm 20min, is stirred at reflux, and is cooled to room temperature, is washed after distillation with sodium hydroxide solution, then with 90 DEG C of distillation water washings to pH To 7, vacuum dehydration obtains dimeric dibasic acid di-isooctyl.

Modified lubricant is prepared by following technique：6 parts of polyethylene glycol are pumped into polymer reactor by weight, risen Temperature is vacuumized to 100 DEG C, is then added 5 parts of ammonium persulfates and is well mixed, is warming up to 130 DEG C, vacuumizes and be passed through high pure nitrogen Protection, then adds 3 parts of APEOs and is well mixed, it is 120 DEG C to control temperature, and pressure is less than 0.35MPa, and insulation is depressurized to 0.2MPa, is incubated 40min, then adds 2 parts of Silane coupling reagent KH-570s and is well mixed, and leads to nitrogen temperature to 80 DEG C, continues to rise Temperature is to 90 DEG C, and cooling discharge is modified lubricant.

Modified lubricating auxiliary agent is prepared by following technique：By weight by 9 parts of refined rapeseed oils and 2 parts of alkaline permanganic acid Potassium solution is well mixed, and 20min is stirred in 850r/min rotating speeds, is then added 3 parts of boric acid and is well mixed, and is warming up to 110 DEG C, guarantor Warm 1.5h, is subsequently added into 3 parts of triethanolamines and is well mixed, stir 1.5h, changed after being cooled to room temperature, vacuum distillation, purification Property lubricating auxiliary agent.

Embodiment 4

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes by weight：Sulfonic acid 5 parts of calcium, 8 parts of adipic acid isooctanol ester, 3 parts of hendecane dicarboxylic acid iso-heptanol ester, 5 parts of dimeric dibasic acid di-isooctyl, dialkyl dithio 3 parts of trbasic zinc phosphate, adjacent 4.5 parts of benzene front three phenolic ester, 2.5 parts of chlorinated paraffin, 2.5 parts of sulfide isobutene, 3 parts of modified lubricant, modification 5 parts of the molten ammoniacal copper quaternary of 8 parts of lubricating auxiliary agent, amine, 2.5 parts of calgon, 5 parts of sulphur dodecenylsuccinic acid, 7 parts of zinc naphthenate, benzene And 3 parts of triazole, 5 parts of sodium olefin sulfonate, 4 parts of sodium tripolyphosphate, 5 parts of diammonium hydrogen phosphate, 4 parts of aliphatic acid, dialkyl dithio 8 parts of carbamic acid sodium, 3 parts of polyisobutene succinimide, 5 parts of methyl benzoate, 4 parts of polytetrafluoroethylene (PTFE), 4 parts of butylene, nonyl 3 parts of phenol polyethenoxy ether, 7 parts of fatty acid methyl ester ethoxylate sulfoacid calcium, 4 parts of DBSA, ethoxylated fat 7 parts of alcohol polyethenoxy ether sodium sulfate.

Dimeric dibasic acid di-isooctyl is prepared by following technique：4 parts of dimeric dibasic acids and 4 parts of isooctanol are mixed equal by weight It is even, 35min is stirred in 380r/min rotating speeds, 1.5 parts of benzene is then added and 5 parts of p-methyl benzenesulfonic acid is well mixed, be warming up to 65 DEG C, 35min is incubated, is stirred at reflux, is cooled to room temperature, is washed after distillation with sodium hydroxide solution, then with 75 DEG C of distillation water washings extremely PH to 7, vacuum dehydration obtains dimeric dibasic acid di-isooctyl.

Modified lubricant is prepared by following technique：4 parts of polyethylene glycol are pumped into polymer reactor by weight, risen Temperature is vacuumized to 115 DEG C, is then added 3 parts of ammonium persulfates and is well mixed, is warming up to 145 DEG C, vacuumizes and be passed through high pure nitrogen Protection, then adds 1.5 parts of APEOs and is well mixed, it is 135 DEG C to control temperature, and pressure is less than 0.35MPa, insulation decompression To 0.2MPa, 25min is incubated, 4 parts of Silane coupling reagent KH-570s is then added and is well mixed, leads to nitrogen temperature to 65 DEG C, continues 105 DEG C are warming up to, cooling discharge is modified lubricant.

Modified lubricating auxiliary agent is prepared by following technique：By weight by 5 parts of refined rapeseed oils and 4 parts of alkaline permanganic acid Potassium solution is well mixed, and 35min is stirred in 680r/min rotating speeds, is then added 1.5 parts of boric acid and is well mixed, is warming up to 125 DEG C, 0.8h is incubated, 4.5 parts of triethanolamines is subsequently added into and is well mixed, stir 0.8h, room temperature is cooled to, vacuum distillation is obtained after purification To modified lubricating auxiliary agent.

Embodiment 5

A kind of metal antirusting agent with excellent greasy property proposed by the present invention, its raw material includes by weight：Sulfonic acid 7 parts of calcium, 5 parts of adipic acid isooctanol ester, 4 parts of hendecane dicarboxylic acid iso-heptanol ester, 2 parts of dimeric dibasic acid di-isooctyl, dialkyl dithio 7 parts of trbasic zinc phosphate, adjacent 3.5 parts of benzene front three phenolic ester, 3.5 parts of chlorinated paraffin, 1.5 parts of sulfide isobutene, 4 parts of modified lubricant, modification 7 parts of the molten ammoniacal copper quaternary of 4 parts of lubricating auxiliary agent, amine, 1.5 parts of calgon, 7 parts of sulphur dodecenylsuccinic acid, 5 parts of zinc naphthenate, benzene And 4 parts of triazole, 2 parts of sodium olefin sulfonate, 5 parts of sodium tripolyphosphate, 4 parts of diammonium hydrogen phosphate, 5 parts of aliphatic acid, dialkyl dithio 5 parts of carbamic acid sodium, 4 parts of polyisobutene succinimide, 2 parts of methyl benzoate, 8 parts of polytetrafluoroethylene (PTFE), 2 parts of butylene, nonyl 4 parts of phenol polyethenoxy ether, 3 parts of fatty acid methyl ester ethoxylate sulfoacid calcium, 5 parts of DBSA, ethoxylated fat 5 parts of alcohol polyethenoxy ether sodium sulfate.

Dimeric dibasic acid di-isooctyl is prepared by following technique：5 parts of dimeric dibasic acids and 3 parts of isooctanol are mixed equal by weight It is even, 25min is stirred in 620r/min rotating speeds, 2.5 parts of benzene is then added and 4 parts of p-methyl benzenesulfonic acid is well mixed, be warming up to 75 DEG C, 25min is incubated, is stirred at reflux, is cooled to room temperature, is washed after distillation with sodium hydroxide solution, then with 85 DEG C of distillation water washings extremely PH to 7, vacuum dehydration obtains dimeric dibasic acid di-isooctyl.

Modified lubricant is prepared by following technique：5 parts of polyethylene glycol are pumped into polymer reactor by weight, risen Temperature is vacuumized to 105 DEG C, is then added 4 parts of ammonium persulfates and is well mixed, is warming up to 135 DEG C, vacuumizes and be passed through high pure nitrogen Protection, then adds 2.5 parts of APEOs and is well mixed, it is 125 DEG C to control temperature, and pressure is less than 0.35MPa, insulation decompression To 0.2MPa, 35min is incubated, 3 parts of Silane coupling reagent KH-570s is then added and is well mixed, leads to nitrogen temperature to 75 DEG C, continues 95 DEG C are warming up to, cooling discharge is modified lubricant.

Modified lubricating auxiliary agent is prepared by following technique：By weight by 8 parts of refined rapeseed oils and 3 parts of alkaline permanganic acid Potassium solution is well mixed, and 25min is stirred in 820r/min rotating speeds, is then added 2.5 parts of boric acid and is well mixed, is warming up to 115 DEG C, 1.2h is incubated, 3.5 parts of triethanolamines is subsequently added into and is well mixed, stir 1.2h, room temperature is cooled to, vacuum distillation is obtained after purification To modified lubricating auxiliary agent.

The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims

1. a kind of metal antirusting agent with excellent greasy property, it is characterised in that its raw material includes by weight：Sulfoacid calcium 4- 8 parts, 4-9 parts of adipic acid isooctanol ester, 2-5 parts of hendecane dicarboxylic acid iso-heptanol ester, 1-6 parts of dimeric dibasic acid di-isooctyl, dialkyl group two 2-8 parts of D2EHDTPA zinc, adjacent 3-5 parts of benzene front three phenolic ester, 2-4 parts of chlorinated paraffin, 1-3 parts of sulfide isobutene, modified lubricant 2-5 Part, modified 3-9 parts of lubricating auxiliary agent, molten ammoniacal copper quaternary 4-8 parts of amine, 1-3 parts of calgon, 4-8 parts of sulphur dodecenylsuccinic acid, ring 4-8 parts of alkanoic acid zinc, 2-5 parts of BTA, 1-6 parts of sodium olefin sulfonate, 3-6 parts of sodium tripolyphosphate, 3-6 parts of diammonium hydrogen phosphate, 3-6 parts of aliphatic acid, 4-9 parts of dialkyldithiocarbamacompositions sodium, 2-5 parts of polyisobutene succinimide, methyl benzoate 1-6 Part, 3-9 parts of polytetrafluoroethylene (PTFE), 1-5 parts of butylene, 2-5 parts of NPE, fatty acid methyl ester ethoxylate sulfoacid calcium 2-8 parts, 3-6 parts of DBSA, 4-8 parts of ethoxylized fatty alcohol polyethenoxy ether sodium sulfate.

2. the metal antirusting agent according to claim 1 with excellent greasy property, it is characterised in that dimeric dibasic acid two is different pungent Ester is prepared by following technique：Dimeric dibasic acid and isooctanol are well mixed, 20-40min is stirred in 350-650r/min rotating speeds, Then add benzene and p-methyl benzenesulfonic acid is well mixed, be warming up to 60-80 DEG C, be incubated 20-40min, be stirred at reflux, be cooled to room Temperature, is washed after distillation with sodium hydroxide solution, and then with 70-90 DEG C of distillation water washing to pH to 7, vacuum dehydration obtains dimeric dibasic acid Di-isooctyl.

3. the metal antirusting agent according to claim 1 or 2 with excellent greasy property, it is characterised in that dimeric dibasic acid two In the preparation technology of different monooctyl ester, dimeric dibasic acid, isooctanol, the weight ratio of benzene and p-methyl benzenesulfonic acid are 3-6：2-5：1-3：3-6.

4. the metal antirusting agent with excellent greasy property according to claim any one of 1-3, it is characterised in that modified Lubricant is prepared by following technique：Polyethylene glycol is pumped into polymer reactor, 100-120 DEG C is warming up to, vacuumizes, so Ammonium persulfate is added afterwards to be well mixed, 130-150 DEG C is warming up to, and is vacuumized and is passed through high pure nitrogen protection, then adds polyoxy Vinethene is well mixed, and it is 120-140 DEG C to control temperature, and pressure is less than 0.35MPa, and insulation is depressurized to 0.2MPa, is incubated 20- 40min, then adds Silane coupling reagent KH-570 and is well mixed, lead to nitrogen temperature to 60-80 DEG C, be continuously heating to 90-110 DEG C, cooling discharge is modified lubricant.

5. the metal antirusting agent with excellent greasy property according to claim any one of 1-4, it is characterised in that modified In the preparation technology of lubricant, polyethylene glycol, ammonium persulfate, the weight ratio of APEO and Silane coupling reagent KH-570 are 3- 6：2-5：1-3：2-5.

6. the metal antirusting agent with excellent greasy property according to claim any one of 1-5, it is characterised in that modified Lubricating auxiliary agent is prepared by following technique：Refined rapeseed oil and alkaline permanganate solution are well mixed, in 650-850r/ Min rotating speeds stir 20-40min, then add boric acid and are well mixed, be warming up to 110-130 DEG C, be incubated 0.5-1.5h, then add Enter triethanolamine to be well mixed, stir 0.5-1.5h, be cooled to after room temperature, vacuum distillation, purification and obtain being modified lubricating auxiliary agent.

7. a kind of metal antirusting agent with excellent greasy property according to claim any one of 1-6, it is characterised in that In the preparation technology of modified lubricating auxiliary agent, refined rapeseed oil, alkaline permanganate solution, the weight ratio of boric acid and triethanolamine are 4-9：2-5：1-3：3-5.