CN107163909A - A kind of preparation method of blood glue adhesive - Google Patents
A kind of preparation method of blood glue adhesive Download PDFInfo
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- CN107163909A CN107163909A CN201710230604.9A CN201710230604A CN107163909A CN 107163909 A CN107163909 A CN 107163909A CN 201710230604 A CN201710230604 A CN 201710230604A CN 107163909 A CN107163909 A CN 107163909A
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- blood
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- preparation
- mass ratio
- glue adhesive
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J189/00—Adhesives based on proteins; Adhesives based on derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2206—Oxides; Hydroxides of metals of calcium, strontium or barium
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Materials For Medical Uses (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of preparation method of blood glue adhesive, the preparation method includes smudge cells after blood is mixed with water according to certain mass ratio, sequentially adds milk of lime, sodium bicarbonate, ethylene glycol, glucose sugar, sodium carboxymethylcellulose, urea, preservative according to certain mass ratio and stirring reaction obtains blood glue adhesive.The preparation method of blood glue adhesive of the present invention has preferable caking property and stability, can stablize the storage long period, can preferably be applied to wood bonding, and used raw material is cheap and easy to get, is adapted to industrialized production, no toxic and harmful gas release.
Description
Technical field
The invention belongs to technical field of adhesive preparation, and in particular to be a kind of preparation method of blood glue adhesive.
Background technology
Increasingly attention with people to household environment-friendlywater condition, for VOC gases, the You Jirong discharged in furniture
Agent etc. it is also proposed increasingly harsher requirement, in the adhesive of traditional furniture, organic solvent all be carried substantially, these are molten
Being difficult of agent discharges completely in a short time, and constantly slow for a long time can outwards produce, the healthy production that this will be to people
Raw influence.Adhesive is to be acted on by sticking for interface with cohesion etc., can make two or more product or material connection
Natural or synthesis a, organic or inorganic class material together, is called binder, traditionally referred to as glue.Letter and
Yan Zhi, adhesive is exactly that, by adhesive effect, can make to be sticked the material that thing is combined together." adhesive " is general standard art
Language, also including some other glue, clay, rubber cement, glue cream etc..Adhesive is widely used in human society, its raw material
Predominantly petroleum chemicals and natural reproducible resource.Wherein, people has been agreed with as the Environment-friendlyadhesive adhesive of raw material using renewable resource
Class environmental protection and sustainable development requirement, are the important directions in adhesive research.Blood glue adhesive is the gluing being made up of blood
Agent, wherein blood protein glue mainly use the blood of ox, pig and other domestic animals to be made up of raw material, and the water resistance of blood glue adhesive compares bean gum
Adhesive and cheese cement adhesive will get well, and bonding strength is also best in protein-based glue.But blood glue adhesive is solid
Glue-line is harder after change, cutter easy to wear, is easily corroded by mushroom, color is pitch black, and has off-odor, and jelly can not be deposited
Long, suitably with adjust with.
The content of the invention
The invention aims to overcome deficiency of the prior art, there is provided a kind of preparation method of blood glue adhesive.
To solve the above problems, the technical solution used in the present invention is as follows：
A kind of preparation method of blood glue adhesive, the preparation method is comprised the following steps that：
1) according to the mass ratio 1 of blood and water:Blood and water are well mixed by (2-4), pass through magnetic stirrer 10-
20min, obtains a liquid；
2) a liquid is placed in reactor, at ambient temperature, milk of lime and sodium bicarbonate powder is sequentially added into a liquid, is stirred
5-10min is mixed, b liquid is obtained, the mass ratio of the milk of lime of the addition and the quality of sodium bicarbonate and the blood in a liquid is (0.3-
0.6):(0.1-0.15):1, the mass concentration of milk of lime is 10-20%；
3) 25-35 DEG C of temperature is controlled, ethylene glycol and glucose sugar are added into b liquid, 30-50min is stirred, obtains c liquid, institute
The ethylene glycol and the quality of glucose sugar and the mass ratio of the blood in a liquid for stating addition are (0.15-0.3):(0.1-0.2):1；
4) 50-65 DEG C is warming up to, sodium carboxymethylcellulose and urea are sequentially added into c liquid, 20-40min is stirred, obtains
The mass ratio of d liquid, the sodium carboxymethylcellulose of the addition and the quality of urea and the blood in a liquid is (0.2-0.6):
(0.1-0.2):1；
5) 20-35 DEG C is cooled to, preservative is added into d liquid, 15-30min is stirred, blood glue adhesive is obtained, it is described to add
The mass ratio of the quality of the preservative entered and the blood in a liquid is (0.01-0.02):1.
As the improvement of above-mentioned technical proposal, the blood is pig blood.
As the improvement of above-mentioned technical proposal, the preservative is methylisothiazolinone.
As the improvement of above-mentioned technical proposal, the water is distilled water or boiler blow-down water.
Compared with prior art, beneficial effects of the present invention are as follows by the present invention：
The preparation method of blood glue adhesive of the present invention has preferable caking property and stability, can stablize and deposit
Long period, wood bonding can be preferably applied to, and used raw material is cheap and easy to get, is adapted to industrialized production, and nothing has
Malicious pernicious gas release.
Embodiment
Illustrate present disclosure below in conjunction with specific embodiments.
A kind of preparation method of blood glue adhesive, the preparation method is comprised the following steps that：
1) according to the mass ratio 1 of blood and water:Blood and water are well mixed by (2-4), pass through magnetic stirrer 10-
20min, crushes the cell in blood, obtains a liquid completely；
2) a liquid is placed in reactor, at ambient temperature, milk of lime and sodium bicarbonate powder is sequentially added into a liquid, is stirred
5-10min is mixed, b liquid is obtained, the mass ratio of the milk of lime of the addition and the quality of sodium bicarbonate and the blood in a liquid is (0.3-
0.6):(0.1-0.15):1, the mass concentration of milk of lime is 10-20%；
3) 25-35 DEG C of temperature is controlled, ethylene glycol and glucose sugar are added into b liquid, 30-50min is stirred, obtains c liquid, institute
The ethylene glycol and the quality of glucose sugar and the mass ratio of the blood in a liquid for stating addition are (0.15-0.3):(0.1-0.2):1；
4) 50-65 DEG C is warming up to, rise temperature can accelerate plastic, and sodium carboxymethylcellulose and urine are sequentially added into c liquid
Element, stirs 20-40min, obtains d liquid, the sodium carboxymethylcellulose of the addition and the quality of urea and the matter of the blood in a liquid
Amount is than being (0.2-0.6):(0.1-0.2):1；
5) 20-35 DEG C is cooled to, preservative is added into d liquid, 15-30min is stirred, blood glue adhesive is obtained, it is described to add
The mass ratio of the quality of the preservative entered and the blood in a liquid is (0.01-0.02):1,30-200min is stood when using to be made again
With such glue is relatively stablized.
The blood is that the protein content in pig blood, pig blood blood enriches the most, per 100g pig blood 16g containing protein,
The trace element such as iron 45mg, Yi Jixin, copper, is the exploitation of Efforts To Develop pig blood resource, reduces environmental pollution and creates favourable
Extensive purposes, and provide advantageous use for the pig blood of sick pig；The water be distilled water or boiler blow-down water, it is electroless
Matter, without dissociated ion, also without impurity, the effect that will not be chemically reacted.
Milk of lime belongs to air-setting inorganic coagulation material, can by with the cementing integral material of material in pig blood, for prepare
Adhesive is laid the foundation, and milk of lime lumps easily on reactor wall, and efficiency can be influenceed when excessive, or even because heated uneven and quick-fried
Fried, the dispersant of milk of lime is water；Sodium bicarbonate makees acidity regulator.
Ethylene glycol and glucose sugar dissolubility in water are good, have good stability, viscosity can be improved after reaction and is carried
High glued membrane toughness, and ferric ion can be reduced into micro ferrous ion by glucose sugar, because two in pig blood
Valency iron ion ingress of air is easy for that ferric ion can be oxidized to, therefore is reduced using glucose sugar, it is to avoid generation three
The complex compound influence adhesive color of valency iron ion.
Sodium carboxymethylcellulose is soluble in water, and solution is transparent, containing substantial amounts of protein in blood, and carboxymethyl cellulose
Sodium is extremely excellent to the emulsifiability of protein and the aqueous solution, and hydrogen bond can be formed between sodium carboxymethylcellulose and protein,
The hydrogen bond action of itself between protein molecule is reduced, so as to reduce the glue-line glued membrane intensity of adhesive, the abrasion of cutter is reduced
Degree, improves the tensile strength of glued membrane, is capable of the homogeneous emulsion of forming properties stabilization, and safe and reliable；Urea can be steady
Determine the pH in system, improve water resistance and resistance to ag(e)ing, and can be reacted generation carboxymethyl with sodium carboxymethylcellulose
Sodium cellulosate urea film, can be such that the solid constituent in adhesive is distributed evenly in solvent, make adhesive not stratified for a long time.
The preservative is methylisothiazolinone, and methylisothiazolinone is a kind of efficient germicide, heat-resisting, aqueous anti-
Rotten agent, has good effect for the growth for suppressing microorganism, can suppress the growth of bacterium, fungi, mould and mould, it is to avoid
Adhesive is corroded by mushroom, and methylisothiazolinone is colourless, there is certain smell, can effectively reduce the special of blood glue adhesive
Stink.
Be glued, including bonding, bonding, it is cementing, gluing, refer to that homogeneity or heterogeneous body surface are linked together with adhesive
Technology, lightweight, or sealing, most technological temperature low features, because adhesive bonding technique especially fit continuous with stress distribution
For the connection of unlike material, different-thickness, ultra-thin specification and complex component, so adhesive with fastest developing speed, application industry
It is extremely wide, and have significant impact to high-and-new science and technology progress and people's daily life improvement.
【Embodiment one】A kind of preparation method of blood glue adhesive, the preparation method is comprised the following steps that：
1) according to the mass ratio 1 of blood and water:2 are well mixed blood and water, by magnetic stirrer 20min,
Cell in broken blood, obtains a liquid；
2) a liquid is placed in reactor, at ambient temperature, milk of lime and sodium bicarbonate powder is sequentially added into a liquid, is stirred
5min is mixed, b liquid is obtained, the mass ratio of the milk of lime of the addition and the quality of sodium bicarbonate and the blood in a liquid is 0.3:0.1:
1, the mass concentration of milk of lime is 10 %；
3) 25 DEG C of temperature is controlled, ethylene glycol and glucose sugar are added into b liquid, 30min is stirred, obtains c liquid, the addition
The quality of ethylene glycol and glucose sugar is 0.15 with the mass ratio of the blood in a liquid:0.1:1；
4) 50 DEG C are warming up to, sodium carboxymethylcellulose and urea are sequentially added into c liquid, 20min is stirred, obtains d liquid, institute
The mass ratio for stating the sodium carboxymethylcellulose of addition and the quality of urea and the blood in a liquid is 0.2:0.1:1；
5) 20 DEG C are cooled to, preservative is added into d liquid, 15min is stirred, blood glue adhesive is obtained, the addition it is anti-
The mass ratio of the quality of rotten agent and the blood in a liquid is 0.01:1.
【Embodiment two】A kind of preparation method of blood glue adhesive, the preparation method is comprised the following steps that：
1) according to the mass ratio 1 of blood and water:3 are well mixed blood and water, by magnetic stirrer 15min,
The cell in blood is crushed completely, obtains a liquid；
2) a liquid is placed in reactor, at ambient temperature, milk of lime and sodium bicarbonate powder is sequentially added into a liquid, is stirred
8min is mixed, b liquid is obtained, the mass ratio of the milk of lime of the addition and the quality of sodium bicarbonate and the blood in a liquid is 0.45:
0.12:1, the mass concentration of milk of lime is 15%；
3) 30 DEG C of temperature is controlled, ethylene glycol and glucose sugar are added into b liquid, 40min is stirred, obtains c liquid, the addition
The quality of ethylene glycol and glucose sugar is 0.2 with the mass ratio of the blood in a liquid:0.15:1；
4) 58 DEG C are warming up to, sodium carboxymethylcellulose and urea are sequentially added into c liquid, 30min is stirred, obtains d liquid, institute
The mass ratio for stating the sodium carboxymethylcellulose of addition and the quality of urea and the blood in a liquid is 0.4:0.15:1；
5) 30 DEG C are cooled to, preservative is added into d liquid, 20min is stirred, blood glue adhesive is obtained, the addition it is anti-
The mass ratio of the quality of rotten agent and the blood in a liquid is 0.015:1.
【Embodiment three】A kind of preparation method of blood glue adhesive, the preparation method is comprised the following steps that：
1) according to the mass ratio 1 of blood and water:4 are well mixed blood and water, by magnetic stirrer 10min,
The cell in blood is crushed completely, obtains a liquid；
2) a liquid is placed in reactor, at ambient temperature, milk of lime and sodium bicarbonate powder is sequentially added into a liquid, is stirred
10min is mixed, b liquid is obtained, the mass ratio of the milk of lime of the addition and the quality of sodium bicarbonate and the blood in a liquid is 0.6:
0.15:1, the mass concentration of milk of lime is 20 %；
3) 35 DEG C of temperature is controlled, ethylene glycol and glucose sugar are added into b liquid, 50min is stirred, obtains c liquid, the addition
The quality of ethylene glycol and glucose sugar is 0.3 with the mass ratio of the blood in a liquid:0.2:1；
4) 65 DEG C are warming up to, sodium carboxymethylcellulose and urea are sequentially added into c liquid, 40min is stirred, obtains d liquid, institute
The mass ratio for stating the sodium carboxymethylcellulose of addition and the quality of urea and the blood in a liquid is 0.6:0.2:1；
5) 35 DEG C are cooled to, preservative is added into d liquid, 30min is stirred, blood glue adhesive is obtained, the addition it is anti-
The mass ratio of the quality of rotten agent and the blood in a liquid is 0.02:1.
Experiment is compared with the blood glue adhesive and common adhesives of above-described embodiment one, two, three below, rotation is used
Viscosimeter is tested adhesive viscosity, is respectively measured three times, takes a minimum reading value, viscosity in three sample testings
Unit:MPa.s, experimental data is as follows：
| Experimental subjects | Embodiment one | Embodiment two | Embodiment three | Common adhesives |
| Viscosity/mPa.s | 87 | 86 | 89 | 63 |
Thus experimental result can be drawn：The preparation method of blood glue adhesive of the present invention, with common adhesives phase
Compare, with preferable viscosity.
Experiment is compared with the blood glue adhesive and common adhesives of above-described embodiment one, two, three below, plank is entered
Row gluing, and be all divided into 5 × 5 grid, with using the plank of the blood glue adhesive gluing of embodiment one, two, three and
The plank of common adhesives gluing is used for one group, every group is tested at a temperature of 40 DEG C, 80 DEG C, 120 DEG C respectively, after 48h
The number of squares of remaining gluing on plank is counted, experimental data is as follows：
Thus experimental result can be drawn：The preparation method of blood glue adhesive of the present invention, with common adhesives phase
Compare, the number of squares of remaining gluing is significantly more than common adhesives on the plank at a temperature of 40 DEG C, 80 DEG C, 120 DEG C, bonds
Property, stability are preferable.
Understand that the preparation method of blood glue adhesive of the present invention has preferable bond by embodiment one, two, three
Property and stability, the storage long period can be stablized, wood bonding can be preferably applied to, and used raw material is inexpensively easy
, it is adapted to industrialized production, no toxic and harmful gas release.
Above content is made for the present invention in conjunction with specific embodiments describes in detail, it is impossible to assert that the present invention is specific real
Apply and be only limitted to these explanations.For those skilled in the art, before present inventive concept is not departed from
Put, some simple deduction or replace can also be made, the scope of protection of the invention should be all considered as belonging to.
Claims (4)
1. a kind of preparation method of blood glue adhesive, it is characterised in that the preparation method is comprised the following steps that：
1) according to the mass ratio 1 of blood and water:Blood and water are well mixed by (2-4), pass through magnetic stirrer 10-
20min, obtains a liquid；
2) a liquid is placed in reactor, at ambient temperature, sequentially adds milk of lime and sodium bicarbonate powder, stir 5-10min,
Obtain b liquid, the mass ratio of the milk of lime of the addition and the quality of sodium bicarbonate and the blood in a liquid is (0.3-0.6):(0.1-
0.15):1, the mass concentration of milk of lime is 10-20%；
3) 25-35 DEG C of temperature is controlled, ethylene glycol and glucose sugar are added into b liquid, 30-50min is stirred, obtains c liquid, the addition
Ethylene glycol and glucose sugar quality and a liquid in the mass ratio of blood be (0.15-0.3):(0.1-0.2):1；
4) 50-65 DEG C is warming up to, sodium carboxymethylcellulose and urea are sequentially added into c liquid, 20-40min is stirred, obtains d liquid,
The mass ratio of the sodium carboxymethylcellulose of the addition and the quality of urea and the blood in a liquid is (0.2-0.6):(0.1-
0.2):1；
5) 20-35 DEG C is cooled to, preservative is added into d liquid, 15-30min is stirred, obtains blood glue adhesive, the addition
The mass ratio of the quality of preservative and the blood in a liquid is (0.01-0.02):1.
2. a kind of preparation method of blood glue adhesive as claimed in claim 1, it is characterised in that the blood is pig blood.
3. a kind of preparation method of blood glue adhesive as claimed in claim 1, it is characterised in that the preservative is that methyl is different
Thiazolinone.
4. a kind of preparation method of blood glue adhesive as claimed in claim 1, it is characterised in that the water is distilled water or pot
Stove condensed water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710230604.9A CN107163909A (en) | 2017-04-11 | 2017-04-11 | A kind of preparation method of blood glue adhesive |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710230604.9A CN107163909A (en) | 2017-04-11 | 2017-04-11 | A kind of preparation method of blood glue adhesive |
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ID=59849599
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| CN201710230604.9A Pending CN107163909A (en) | 2017-04-11 | 2017-04-11 | A kind of preparation method of blood glue adhesive |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110286010A (en) * | 2019-06-06 | 2019-09-27 | 强安医疗器械有限公司 | Liquid sample-specific pretreatment liquid and preparation method thereof in a kind of rectum |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073217A (en) * | 2014-06-25 | 2014-10-01 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of high-quality blood glue |
| CN105542709A (en) * | 2016-02-01 | 2016-05-04 | 佛山市聚成生化技术研发有限公司 | Preparation method of blood glue adhesives and blood glue adhesives prepared by same |
-
2017
- 2017-04-11 CN CN201710230604.9A patent/CN107163909A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104073217A (en) * | 2014-06-25 | 2014-10-01 | 安徽神舟飞船胶业有限公司 | Formula and preparation process of high-quality blood glue |
| CN105542709A (en) * | 2016-02-01 | 2016-05-04 | 佛山市聚成生化技术研发有限公司 | Preparation method of blood glue adhesives and blood glue adhesives prepared by same |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110286010A (en) * | 2019-06-06 | 2019-09-27 | 强安医疗器械有限公司 | Liquid sample-specific pretreatment liquid and preparation method thereof in a kind of rectum |
| CN110286010B (en) * | 2019-06-06 | 2021-09-24 | 强安医疗器械有限公司 | Special pretreatment liquid for rectal fluid sample and preparation method thereof |
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Application publication date: 20170915 |