CN107163899A - A kind of semiconductor transducer casting glue and preparation method thereof - Google Patents

A kind of semiconductor transducer casting glue and preparation method thereof Download PDF

Info

Publication number
CN107163899A
CN107163899A CN201710363086.8A CN201710363086A CN107163899A CN 107163899 A CN107163899 A CN 107163899A CN 201710363086 A CN201710363086 A CN 201710363086A CN 107163899 A CN107163899 A CN 107163899A
Authority
CN
China
Prior art keywords
parts
casting glue
semiconductor transducer
castor oil
titanium dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710363086.8A
Other languages
Chinese (zh)
Inventor
汪洋
李训红
汪雪婷
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Jiangsu Shi Rui Electronic Science And Technology Co Ltd
Original Assignee
Jiangsu Shi Rui Electronic Science And Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Jiangsu Shi Rui Electronic Science And Technology Co Ltd filed Critical Jiangsu Shi Rui Electronic Science And Technology Co Ltd
Priority to CN201710363086.8A priority Critical patent/CN107163899A/en
Publication of CN107163899A publication Critical patent/CN107163899A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J175/00Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
    • C09J175/04Polyurethanes
    • C09J175/08Polyurethanes from polyethers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30Low-molecular-weight compounds
    • C08G18/32Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3271Hydroxyamines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40High-molecular-weight compounds
    • C08G18/48Polyethers
    • C08G18/4825Polyethers containing two hydroxy groups
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00Polymeric products of isocyanates or isothiocyanates
    • C08G18/06Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666Compounds of group C08G18/48 or C08G18/52
    • C08G18/667Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6681Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/32 or C08G18/3271 and/or polyamines of C08G18/38
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/04Non-macromolecular additives inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/02Non-macromolecular additives
    • C09J11/06Non-macromolecular additives organic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J11/00Features of adhesives not provided for in group C09J9/00, e.g. additives
    • C09J11/08Macromolecular additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/206Applications use in electrical or conductive gadgets use in coating or encapsulating of electronic parts
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of semiconductor transducer casting glue and preparation method thereof.The casting glue includes raw material:Nickel foam, nano-sized carbon leads dioctyl phthalate, sodium citrate, sorbierite, polyvinylidene ethane, terminal hydroxy group polyoxypropyleneglycol, toluene di-isocyanate(TDI), digest cellulose, alkyd resin, dimethylbenzene, acrylic resin, castor oil, talcum powder, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, poly- propyl alcohol, deionized water, titanium dioxide, butanol.Weigh raw material;By nickel foam, nano-sized carbon, dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), digest cellulose, alkyd resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder mixed melting;Sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, butanol are mixed again, integral tune viscosity is finally stirred.Casting glue of the present invention is comprehensive good, and low for equipment requirements, production cost is low.

Description

A kind of semiconductor transducer casting glue and preparation method thereof
Technical field
The invention belongs to semiconductor transducer preparing technical field, and in particular to a kind of semiconductor transducer casting glue and Its preparation method.
Background technology
Casting glue is also known as electronic pastes, for the bonding of electronic component, sealing, embedding and coating protection.Electron pouring sealant Species is a lot, in terms of material type, is divided into epoxy resin embedding adhesive, organic siliconresin casting glue, polyurethane pouring sealant.At present, Electronics field application it is most be polyurethane pouring sealant, its excellent performance, damping, weatherability are strong, adhesive property is good, but lead Electrically poor, the electric charge being trapped on polyurethane pouring sealant breaks through the conductor gap of fish contact, rushes at problem, produces spark even quick-fried It is fried.Therefore, the electric conductivity for improving polyurethane pouring sealant is necessary.
The Chinese patent of application number 201410358073.8 discloses a kind of anti-lightning polyurethane pouring sealant and its preparation side Method.The casting glue includes uniformly containing metallic, the content of metallic in polyurethane pouring sealant, the polyurethane pouring sealant For the 0.01~0.5% of polyurethane pouring sealant quality.Preparation method, comprises the following steps:1)Prepare polyol component:By 167~ 309 grams of two or more PPGs vacuum dehydration at 110~120 DEG C, cools to 50 DEG C, add 1 gram catalyst, 0.01~0.02 gram of metallic, is well mixed, and logical nitrogen is packed, and obtains polyol component;2)Prepare polyisocyanates Component:
By 60~100 grams of PPG, 8~13 grams of epoxy resin, 67~110 grams of fire retardant at 110~120 DEG C Vacuum dehydration or drying process, cool to 40 DEG C, add 105~144 grams of isocyanates, and 70~80 DEG C are reacted 3~5 hours, Logical nitrogen is packed, and obtains polyisocyanate component;3)Prepare anti-lightning polyurethane pouring sealant:By polyol component and many isocyanides Acid esters component in mass ratio 1:1 is well mixed, and is placed in closed container, deaeration 15 minutes at 20~35 DEG C are poured into and wait to fill On sealing, room temperature solidification in 24 hours or heating rapid curing obtain anti-lightning polyurethane pouring sealant.Polyurethane of the present invention Casting glue uses epoxy resin, introduces polyurethane chain using the reactivity of its secondary hydroxyl and isocyanates, is met using epoxide group Thunderbolt the open loop of energy-absorbing scission of link and consume electric energy, with obtain anti-lightning effect;Polyurethane pouring sealant of the present invention uses metal Particle is to obtain antistatic aggregation, so as to play a part of anti-lightning;The preparation method of polyurethane pouring sealant of the present invention, Its technique is simple, and production power consumption is low, is produced without " three wastes ";Polyurethane pouring sealant prepared by the present invention can be used for outdoor electrical element Deng the embedding of component, play a part of anti-lightning, fire-retardant, waterproof and dustproof, damping and fixation after solidification.But embedding of the present invention The easy aging of glue, influences the service life of electronic product.
The content of the invention
In view of the shortcomings of the prior art, it is an object of the invention to provide a kind of semiconductor transducer casting glue and its system Preparation Method, the casting glue good fluidity, ageing resistance is strong, good weatherability, it is ensured that casting glue improves conductive on the premise of insulating Coefficient, reduces the risk of high-voltage breakdown.
To solve prior art problem, the technical scheme that the present invention takes is:
A kind of semiconductor transducer casting glue, including the raw material counted by weight:1-8 parts of nickel foam, nano-sized carbon 12-30 Part, lead 8-14 parts of dioctyl phthalate, 1-4 parts of sodium citrate, 0.8-1.8 parts of sorbierite, 1-4 parts of polyvinylidene ethane, end 12-43 parts of hydroxyl polyoxypropyleneglycol, 12-20 parts of toluene di-isocyanate(TDI), 1-6 parts of digest cellulose, alkyd resin 12-20 Part, 1-8 parts of dimethylbenzene, 5-8 parts of acrylic resin, 1-8 parts of castor oil, 1-7 parts of talcum powder, anhydrous cyclohexanone 12-30 parts, ammonia hydroxyl 2-9 parts of methylpropane, poly- propyl alcohol 22-39 parts, 9-22 parts of deionized water, 1-3 parts of titanium dioxide, 2-8 parts of butanol.
It is as improved, above-mentioned semiconductor transducer casting glue, including the raw material counted by weight:Nickel foam 2 Part, 14 parts of nano-sized carbon, 12 parts of dioctyl phthalate of neck, 3 parts of sodium citrate, 1.2 parts of sorbierite, 2.4 parts of polyvinylidene ethane, 22.7 parts of terminal hydroxy group polyoxypropyleneglycol, 14.8 parts of toluene di-isocyanate(TDI), 5.7 parts of digest cellulose, alkyd resin 14.5 Part, 6.5 parts of dimethylbenzene, 6.5 parts of acrylic resin, 3.4 parts of castor oil, 3 parts of talcum powder, anhydrous 24.5 parts of cyclohexanone, ammonia hydroxyl first 6.8 parts of base propane, poly- 25.8 parts of propyl alcohol, 14.8 parts of deionized water, 2.5 parts of titanium dioxide, 4.8 parts of butanol.
It is that the mesh number of titanium dioxide is 200-300 mesh as improved.
The preparation method of above-mentioned semiconductor transducer casting glue, comprises the following steps:Step 1, raw material is weighed;Step 2, By nickel foam, nano-sized carbon, neck dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), digest cellulose, alkyd Resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder mixed melting obtain composition A;Step 3, sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, butanol are mixed and obtains group Compound B;Step 4, composition B and castor oil are added in composition A and stirred, add deionized water regulation viscosity.
It is that the temperature melted in step 2 is 600-800 DEG C as improved.
It is that mixing speed is 120-180rpm in step 3 as improved.
Beneficial effect
Compared with prior art, casting glue electric conductivity of the present invention is improved, good fluidity, flexible, hardening time under low temperature Short, weatherability is strong, non-aging.Preparation method is simple, low for equipment requirements, low production cost.
Embodiment
Embodiment 1
A kind of semiconductor transducer casting glue, including the raw material counted by weight:1 part of nickel foam, 12 parts of nano-sized carbon leads benzene 8 parts of diformazan dioctyl phthalate, 1 part of sodium citrate, 0.8 part of sorbierite, 1 part of polyvinylidene ethane, terminal hydroxy group polyoxypropyleneglycol 12 parts, 12 parts of toluene di-isocyanate(TDI), 1-6 parts of digest cellulose, 12 parts of alkyd resin, 1 part of dimethylbenzene, 5 parts of acrylic resin, 1 part of castor oil, 1 part of talcum powder, anhydrous 12 parts of cyclohexanone, 2 parts of ammonia hydroxymethyl-propane, poly- 22 parts of propyl alcohol, 9 parts of deionized water, titanium 1 part of white powder, 2 parts of butanol.
The mesh number of the titanium dioxide is 200 mesh.
The preparation method of above-mentioned semiconductor transducer casting glue, comprises the following steps:Step 1, raw material is weighed;Step 2, By nickel foam, nano-sized carbon, neck dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), digest cellulose, alkyd Resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder mixed melting obtain composition A;Step 3, sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, butanol are mixed and obtains group Compound B;Step 4, composition B and castor oil are added in composition A and stirred, add deionized water regulation viscosity.
Wherein, the temperature melted in step 2 is 600 DEG C.
Mixing speed is 120rpm in step 3.
Casting glue prepared by embodiment 1 is transparent, and shore hardness 92, elongation at break 85% is hardening time 0.3s, anti-oxidant Time is long, 70 DEG C, and humidity is 20 times placements 60 days, and colloid turns yellow slightly.
Embodiment 2
A kind of semiconductor transducer casting glue, including the raw material counted by weight:2 parts of nickel foam, 14 parts of nano-sized carbon leads benzene 12 parts of diformazan dioctyl phthalate, 3 parts of sodium citrate, 1.2 parts of sorbierite, 2.4 parts of polyvinylidene ethane, terminal hydroxy group PPOX two 22.7 parts of alcohol, 14.8 parts of toluene di-isocyanate(TDI), 5.7 parts of digest cellulose, 14.5 parts of alkyd resin, 6.5 parts of dimethylbenzene, propylene 6.5 parts of acid resin, 3.4 parts of castor oil, 3 parts of talcum powder, anhydrous 24.5 parts of cyclohexanone, 6.8 parts of ammonia hydroxymethyl-propane, poly- propyl alcohol 25.8 parts, 14.8 parts of deionized water, 2.5 parts of titanium dioxide, 4.8 parts of butanol.
The mesh number of the titanium dioxide is 260 mesh.
The preparation method of above-mentioned semiconductor transducer casting glue, comprises the following steps:Step 1, raw material is weighed;Step 2, By nickel foam, nano-sized carbon, neck dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), digest cellulose, alkyd Resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder mixed melting obtain composition A;Step 3, sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, butanol are mixed and obtains group Compound B;Step 4, composition B and castor oil are added in composition A and stirred, add deionized water regulation viscosity.
Wherein, the temperature melted in step 2 is 700 DEG C.
Mixing speed is 150rpm in step 3.
Casting glue prepared by embodiment 2 is transparent, and shore hardness 95, elongation at break 88% is hardening time 0.2s, anti-oxidant Time is long, and 70 DEG C of humidity are 20% time placement 65 days, and colloid turns yellow slightly.
Embodiment 3
A kind of semiconductor transducer casting glue, including the raw material counted by weight:8 parts of nickel foam, 30 parts of nano-sized carbon leads benzene 14 parts of diformazan dioctyl phthalate, 4 parts of sodium citrate, 1.8 parts of sorbierite, 4 parts of polyvinylidene ethane, terminal hydroxy group polyoxypropyleneglycol 43 parts, 20 parts of toluene di-isocyanate(TDI), 6 parts of digest cellulose, 20 parts of alkyd resin, 1-8 parts of dimethylbenzene, 8 parts of acrylic resin, 8 parts of castor oil, 7 parts of talcum powder, anhydrous 30 parts of hexamethylene, 2-9 parts of ammonia hydroxymethyl-propane, poly- 39 parts of propyl alcohol, 22 parts of deionized water, titanium 3 parts of white powder, 8 parts of butanol.
Wherein, the mesh number of titanium dioxide is 300 mesh.
The preparation method of above-mentioned semiconductor transducer casting glue, comprises the following steps:Step 1, raw material is weighed;Step 2, By nickel foam, nano-sized carbon, neck dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), digest cellulose, alkyd Resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder mixed melting obtain composition A;Step 3, sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, butanol are mixed and obtains group Compound B;Step 4, composition B and castor oil are added in composition A and stirred, add deionized water regulation viscosity.
The temperature melted in step 2 is 800 DEG C.
Mixing speed is 180rpm in step 3.
Casting glue prepared by embodiment 3 is transparent, and shore hardness 88, elongation at break 85% is hardening time 0.3s, anti-oxidant Time is long, is placed 62 days at 70 DEG C, colloid turns yellow slightly.
Embodiment 4
A kind of semiconductor transducer casting glue, including the raw material counted by weight:1 part of nickel foam, 12 parts of nano-sized carbon leads benzene 8 parts of diformazan dioctyl phthalate, 1 part of sodium citrate, 0.8 part of sorbierite, 1 part of polyvinylidene ethane, terminal hydroxy group polyoxypropyleneglycol 12 parts, 12 parts of toluene di-isocyanate(TDI), 1-6 parts of digest cellulose, 12 parts of alkyd resin, 1 part of dimethylbenzene, 5 parts of acrylic resin, 1 part of castor oil, 1 part of talcum powder, anhydrous 12 parts of cyclohexanone, 2 parts of ammonia hydroxymethyl-propane, poly- 22 parts of propyl alcohol, 9 parts of deionized water, titanium 1 part of white powder, 2 parts of butanol.
The mesh number of the titanium dioxide is 200 mesh.
The preparation method of above-mentioned semiconductor transducer casting glue, comprises the following steps:Step 1, raw material is weighed;Step 2, By nickel foam, nano-sized carbon, neck dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), digest cellulose, alkyd Resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder mixed melting obtain composition A;Step 3, sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, butanol are mixed and obtains group Compound B;Step 4, composition B and castor oil are added in composition A and stirred, add deionized water regulation viscosity.
The temperature melted in step 2 is 800 DEG C.
Mixing speed is 180rpm in step 3.
Casting glue prepared by embodiment 4 is transparent, and shore hardness 94, elongation at break 88% is hardening time 0.2s, anti-oxidant Time is long, is placed 68 days at 70 DEG C, colloid turns yellow slightly.
It is seen from the above data that casting glue hardness of the present invention is big, stretch-proof, hardening time is short, anti-oxidant under high temperature Ability is strong, the Chinese patent with application number 201410358073.8《A kind of anti-lightning polyurethane pouring sealant and preparation method thereof》's Embodiment is compared, and performance is improved, and cost is lower, and step is simpler, is adapted to industrialization.

Claims (6)

1. a kind of semiconductor transducer casting glue, it is characterised in that including the raw material counted by weight:1-8 parts of nickel foam, 12-30 parts of nano-sized carbon, leads 8-14 parts of dioctyl phthalate, 1-4 parts of sodium citrate, 0.8-1.8 parts of sorbierite, polyvinylidene second 1-4 parts of alkane, 12-43 parts of terminal hydroxy group polyoxypropyleneglycol, 12-20 parts of toluene di-isocyanate(TDI), 1-6 parts of digest cellulose, alcohol 12-20 parts of acid resin, 1-8 parts of dimethylbenzene, 5-8 parts of acrylic resin, 1-8 parts of castor oil, 1-7 parts of talcum powder, anhydrous cyclohexanone 12-30 parts, 2-9 parts of ammonia hydroxymethyl-propane, poly- propyl alcohol 22-39 parts, 9-22 parts of deionized water, 1-3 parts of titanium dioxide, 2-8 parts of butanol.
2. a kind of semiconductor transducer casting glue according to claim 1, it is characterised in that including counting by weight Raw material:2 parts of nickel foam, 14 parts of nano-sized carbon leads 12 parts of dioctyl phthalate, 3 parts of sodium citrate, 1.2 parts of sorbierite, poly- second 2.4 parts of diene ethane, 22.7 parts of terminal hydroxy group polyoxypropyleneglycol, 14.8 parts of toluene di-isocyanate(TDI), digest cellulose 5.7 Part, 14.5 parts of alkyd resin, 6.5 parts of dimethylbenzene, 6.5 parts of acrylic resin, 3.4 parts of castor oil, 3 parts of talcum powder, anhydrous hexamethylene 24.5 parts of ketone, 6.8 parts of ammonia hydroxymethyl-propane, poly- 25.8 parts of propyl alcohol, 14.8 parts of deionized water, 2.5 parts of titanium dioxide, 4.8 parts of butanol.
3. a kind of semiconductor transducer casting glue according to claim 1, it is characterised in that the mesh number of titanium dioxide is 200-300 mesh.
4. the preparation method of a kind of semiconductor transducer casting glue according to claim 1, it is characterised in that step 1, Weigh raw material;Step 2, by nickel foam, nano-sized carbon, neck dioctyl phthalate, polyvinylidene ethane, toluene di-isocyanate(TDI), Digest cellulose, alkyd resin, dimethylbenzene, acrylic resin, anhydrous cyclohexanone, ammonia hydroxymethyl-propane, titanium dioxide and talcum powder Mixed melting obtains composition A;Step 3, by sodium citrate, sorbierite, terminal hydroxy group polyoxypropyleneglycol, castor oil, poly- propyl alcohol, Butanol mixes to obtain composition B;Step 4, composition B and castor oil are added in composition A and stirred, add deionized water Adjust viscosity.
5. a kind of preparation method of semiconductor transducer casting glue according to claim 4, it is characterised in that step 2 The temperature of middle melting is 600-800 DEG C.
6. a kind of preparation method of semiconductor transducer casting glue according to claim 4, it is characterised in that step 3 Middle mixing speed is 120-180rpm.
CN201710363086.8A 2017-05-22 2017-05-22 A kind of semiconductor transducer casting glue and preparation method thereof Pending CN107163899A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710363086.8A CN107163899A (en) 2017-05-22 2017-05-22 A kind of semiconductor transducer casting glue and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710363086.8A CN107163899A (en) 2017-05-22 2017-05-22 A kind of semiconductor transducer casting glue and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107163899A true CN107163899A (en) 2017-09-15

Family

ID=59815464

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710363086.8A Pending CN107163899A (en) 2017-05-22 2017-05-22 A kind of semiconductor transducer casting glue and preparation method thereof

Country Status (1)

Country Link
CN (1) CN107163899A (en)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643623A (en) * 2012-04-05 2012-08-22 艾伦塔斯电气绝缘材料(珠海)有限公司 Polyurethane resin potting adhesive with high bonding strength and preparation method thereof
CN104497946A (en) * 2015-01-26 2015-04-08 温州泓呈祥科技有限公司 Adhesive resistant to water and deformation
CN104673175A (en) * 2015-03-10 2015-06-03 济南骄泰信息技术有限公司 Electronic pouring sealant convenient to produce and preparation method thereof
CN104861919A (en) * 2014-11-22 2015-08-26 湖北回天新材料股份有限公司 Polyurethane pouring sealant without settlement during long-term storage and preparation method therefor
CN105482063A (en) * 2015-12-29 2016-04-13 浙江荣泰科技企业有限公司 Polyurethane pouring sealant and preparation method thereof
CN106244079A (en) * 2016-08-31 2016-12-21 惠州富盛绝缘材料有限公司 A kind of glue of the insulation tube of high temperature resistant low extraction

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102643623A (en) * 2012-04-05 2012-08-22 艾伦塔斯电气绝缘材料(珠海)有限公司 Polyurethane resin potting adhesive with high bonding strength and preparation method thereof
CN104861919A (en) * 2014-11-22 2015-08-26 湖北回天新材料股份有限公司 Polyurethane pouring sealant without settlement during long-term storage and preparation method therefor
CN104497946A (en) * 2015-01-26 2015-04-08 温州泓呈祥科技有限公司 Adhesive resistant to water and deformation
CN104673175A (en) * 2015-03-10 2015-06-03 济南骄泰信息技术有限公司 Electronic pouring sealant convenient to produce and preparation method thereof
CN105482063A (en) * 2015-12-29 2016-04-13 浙江荣泰科技企业有限公司 Polyurethane pouring sealant and preparation method thereof
CN106244079A (en) * 2016-08-31 2016-12-21 惠州富盛绝缘材料有限公司 A kind of glue of the insulation tube of high temperature resistant low extraction

Similar Documents

Publication Publication Date Title
EP2036860B1 (en) Spherical sintered ferrite particle, semiconductor sealing resin composition making use of the same and semiconductor device obtained therewith
CN102360835B (en) Epoxy resin pouring dry type transformer
CN111063501B (en) Preparation method of low-loss powder for producing integrally-formed inductor
CN102936394B (en) Dry outdoor type electric power complete equipment insulation casting material and preparation method thereof
CN102675601B (en) Low-warpage epoxy resin composite used for QFN (Quad Flat No Lead)
CN107828358A (en) A kind of low-k environment-friendly type underfill and preparation method thereof
CN104616850A (en) Method for preparing zinc oxide/epoxy resin composite voltage dependent resistor
CN104212405A (en) Anti-lightning-strike polyurethane pouring sealant and preparation method
SG10201406428QA (en) Semiconductor device
CN107163899A (en) A kind of semiconductor transducer casting glue and preparation method thereof
CN102888059B (en) Composite insulating material and preparation method thereof
CN103160233A (en) Cardanol modified epoxy pouring sealant and preparation method thereof
CN107674547B (en) A kind of two-step method low temperature consolidates magnet ring special powder and preparation method thereof fastly
CN101210162B (en) Semi-conductor adhesive and preparation method thereof
CN104810734A (en) Auxiliary device for disassembly and assembly of GIS conductor
CN112080221A (en) Conductive silver adhesive with long service time at room temperature and low-temperature curing function and preparation method thereof
CN108384143A (en) A kind of freeze proof fire-resistant cable material and preparation method thereof
TW201901709A (en) Dust core, method for producing said dust core, inductor provided with said dust core, and electronic/electrical device on which said inductor is mounted
CN102013612B (en) Manufacture process of sealed terminal board sintered with power insulator
CN110272709A (en) A kind of polyurethane pouring sealant of transparent yellowing-resistant and preparation method thereof
CN101591440A (en) A kind of epoxy resin modified by isocyanate terminated silicon rubber and preparation method thereof
CN107749340A (en) A kind of high reliability high current molding inductance and manufacture method
CN207517962U (en) Enhance the plugs and sockets of sealing performance
JP3893422B2 (en) Resin composition for sealing electrical and electronic devices
CN105220933A (en) A kind of steel tower cross-arm component

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20170915