CN107163769A - The pricking-proof explosion-proof coating of superhigh intensity and the pricking-proof explosion-proof tire containing the coating - Google Patents
The pricking-proof explosion-proof coating of superhigh intensity and the pricking-proof explosion-proof tire containing the coating Download PDFInfo
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- CN107163769A CN107163769A CN201710555557.5A CN201710555557A CN107163769A CN 107163769 A CN107163769 A CN 107163769A CN 201710555557 A CN201710555557 A CN 201710555557A CN 107163769 A CN107163769 A CN 107163769A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/04—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to rubbers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C19/00—Tyre parts or constructions not otherwise provided for
- B60C19/12—Puncture preventing arrangements
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D151/00—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers
- C09D151/06—Coating compositions based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Coating compositions based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Mechanical Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Tires In General (AREA)
Abstract
Pricking-proof explosion-proof tire the present invention relates to a kind of pricking-proof explosion-proof coating of superhigh intensity and containing the coating, wherein the pricking-proof explosion-proof coating of superhigh intensity include A coatings and B coatings；The B coating sprayings are on A coatings；The each component mass percent that the A is applied is：Butyl rubber 15~25%；Unsaturated carboxylic acid 3~8%；Thermosetting resin 10~18%；Radical initiator 1~2%；Solvent 60~70%；The B coatings it include following components by weight percentage：The octene copolymer of ethene 1 (POE)：52~70%；Alathon：0.1 5%；The butylene amorphous copolymer of ethylene, propylene 1：10 20%；Plasticizer：10 20%；Activated Calcium carbonate：5 15%；Radical initiator：0.1 0.7%；Grafted monomers：0.1 10%.
Description
Technical field
Pricking-proof explosion-proof tire the present invention relates to a kind of pricking-proof explosion-proof coating of superhigh intensity and containing the coating.
Background technology
The present whole nation is with the presence of more than 75% automobile tire potential safety hazard according to statistics, and more than 37% wheel crown part has nail
Sub or other sharppointed articles are stabbed, the traffic accident of domestic highway 50% be as caused by tire hidden danger, so, tire
Safety cause the great attention of clan owning cars.
The A of Chinese patent CN 103102866 disclose a kind of intelligent glue of adhesive type tyre pricking proof explosion-proof leakage-proof, including following
Component and parts by weight：Rubber 20-25, carbon black 15-20, zinc oxide 1-2, pitch 30-50, accelerator 1-2, binding agent 5-8；Will
Rubber, carbon black, zinc oxide, pitch, accelerator is placed in reactor, is heated to 110-180 DEG C, stirs 1 hour, adds binding agent
Stirring 10 minutes, this is polymer intelligent activity poly rubber alloy；Adhesive type pricking-proof explosion-proof leakproof intelligence glue is by anti-sticking isolated form paper membrane
With polymer intelligent activity poly rubber alloy composition, remain flexible colloidal state after use and never solidify, cementability is strong, and pliability is good,
Ductility spy lives, with intelligent self-healing function.But the time of the materials repairing wound is oversize, cause leakage-proof mending material repairing
When multiple leak, inside tires gas has lost that it is enough, and influence car is continued to run with.
And size coat used in tire leakproof mending material traditional at present is substantially pressure-sensitive hot melt adhesive system, example
Such as Chinese patent CN200610030984 polymer leakage-proof mending materials and its puncture-proof tire containing the coating, a kind of macromolecule
Leakage-proof mending material, it is constituted and proportioning is：
CN200710036418.8 discloses a kind of resistance to bundle, shellproof, leakage-proof safety tyre, without being appointed to tire inner wall
What damaging processing, only has the polymer leakage-proof mending bullet that a layer thickness is 2~8mm by the inner-wall spraying to tubeless tyre
Property colloid, tire can be enable in -45 DEG C of low temperature to+120 DEG C of high temperature, with it is resistance to prick, shellproof, leak resistance.
But the tire leakproof of currently available technology, sizing material that is explosion-proof, putting bundle belong to pressure-sensitive hot melt adhesive system, exist just like
Under several shortcomings：
1, temperature range only has -45~120 DEG C, and according to the test of national rubber tyre inspection center, summer is high at a high speed
In the case of temperature, temperature reaches 130~150 DEG C in card passenger tyre.Actual operation requirements can not be met.
2, traditional tire leakproof mending material can only accomplish anti-tie and bulletproof function.Trace it to its cause and be that it is stretched
Intensity and toughness are smaller, especially under 60 degree of high-temperature conditions, and anti-tie function is only limitted to the nail of 6mm diameters, it is impossible to accomplish to prevent
Quick-fried function, that is, it can not prevent from crossing the accident of blowing out that larger foreign matter is caused under tire high-speed case.
3, traditional tire leakproof mending material, which is only limited, to be used alone in passenger car half steel tire.Trace it to its cause and be
Its tensile strength and toughness are smaller.Because passenger car half steel tire tread has steel wire floor, inner gas pressure is 3.0bar；And it is electronic
Car, motorcycle oblique vacuum do not have steel wire floor, and inner gas pressure is also 3.0bar, thus at high temperature, after bundle nail puller goes out, tire
Wound size coat needs very high anti-plasticating capacity；And although card passenger tyre has a steel wire floor, but the blowing pressure
10bar is reached, so at high temperature, after bundle nail puller goes out, tire wound coating needs superpower anti-plasticating capacity, withstands
10bar air pressure inside.
In summary, traditional pressure-sensitive hot melt adhesive system can not meet practical application, it is impossible to marketing.
The content of the invention
For above-mentioned deficiency of the prior art, the present invention provides one kind and electricity can rubbed bias tire, All-steel tire, oblique
Vacuum tyre, passenger car half steel vacuum tyre, card can go out all steel vacuum tyre and escalate into the safe pricking-proof explosion-proof protecting tyre of superelevation and temperature
Scope be -55 degree~180 degree, still possess under 80 degree of high temperature the superhigh intensity of higher tensile strength pricking-proof explosion-proof coating and
Using the safe pricking-proof explosion-proof protecting tyre of the superelevation of the coating.
To realize above technical purpose, the technical scheme is that:A kind of pricking-proof explosion-proof coating of superhigh intensity, including
A coatings and B coatings；The B coating sprayings are on A coatings；
The each component mass percent that the A is applied is：
The B coatings it include following components by weight percentage
Preferably, the grafted monomers are Y- glycidyl ether oxygen propyl trimethoxy silicanes, Y- (methacryloxypropyls
Base) propyl trimethoxy silicane, Y- Mercaptopropyltriethoxysilanes, vinyltrimethoxy silane, vinyl triethoxyl
Silane, tertiary ethylene carbonate, propionate, vinyl butyrate, maleat, maleic anhydride, itaconic anhydride, vinyl
Glycidol ether, Malaysia acid glycidyl ester, glycidyl acrylate, GMA, 2- cyclohexene -1-
One or both of base glycidol ether, cyclohexene -4- glycidyl carboxylates are mixed above.
Preferably, ethylene-l-octane copolymer (POE) molecular weight is 10000-20000.
Preferably, the radical initiator be double (t-amyl peroxy) ethyl butyrates of 3,3-, di-t-butyl peroxide,
The uncle of peroxidating two defend base, t-butylcumylperoxide, two-(tert-butylperoxyiso-propyl) benzene, 2,5- dimethyl -2,5- it is double -
One or both of (t-butyl peroxy) hexane, cumyl peroxide are mixed above.
Preferably, the B coatings also include free radical activator, ultraviolet absorber, light stabilizer, antioxidant, plasticising
One or both of agent is mixed above.
Preferably, the free radical activator be can be rolled into a ball containing alkene or activity H compound.
Preferably, described can roll into a ball as triallyl isocyanate, triallyl cyanate, dimethyl allene containing alkene
Sour glycol ester, a phenyl-bismaleimide, trimethylolpropane trimethacrylate, trimethylol propane trimethyl acrylic acid
One or both of ester, phthalic acid diisopropyl alkene ester, 1,2- polybutadiene, ethidine polybutene are mixed above.
To realize above technical purpose, the technical scheme is that:A kind of pricking-proof explosion-proof coating of use superhigh intensity
The safe pricking-proof explosion-proof protecting tyre of superelevation, including protecting tyre body, the inwall of the protecting tyre body is coated with A coatings
With B coatings；The B coating sprayings are on A coatings.
Preferably, the thickness of the A coatings is 0.2-3 millimeters, the thickness of the B coatings is 3-15 millimeters.
Preferably, described protecting tyre body, which is electricity, rubs bias tire, All-steel tire, oblique vacuum, passenger car partly
Steel vacuum tyre or card can go out all steel vacuum tyre.
Above description can be seen that the present invention and possess advantages below：The pricking-proof explosion-proof coating phase of the superhigh intensity of the present invention
For prior art, it can realize effectively bonding, excellent heat resistance the beneficial effects of the present invention are the B coatings of the present invention and surpass
Strong cohesive strength, and maintain the excellent physical property of polyolefine material, chemical stability and good processability.Can be big
Exposure is used more than 50 years in gas, can meet the use requirement of various types of vacuum tire pricking-proof explosion-proofs.
And POE good-extensibilities itself, and in the absence of double bond structure, resistance to ag(e)ing is excellent, can in an atmosphere expose and use
More than 50 years, in summary various performances of polymer so that the B coatings produced have excellent high and low temperature resistance,
Ageing-resistant performance, tensile property are strong, and product pliability is moderate；And adhesive strength is solid and reliable, it is easy to spraying, production cost is low,
Technique is simple, environmentally safe, is a kind of environmentally friendly material.
The pricking-proof explosion-proof tire of the use of pricking-proof explosion-proof coating of superhigh intensity of the present invention coating is used simultaneously in life
Technique is simple in production, it is only necessary to sprayed after being heated by sizing material, while both having kept the characteristic of tire originally in itself constant
And resistance to bundle, the fluctuation of explosion-proof and resisting temperature are promoted to the raising of a matter.
Brief description of the drawings
Accompanying drawing 1 is the profile of the pricking-proof explosion-proof tire of the present invention.
Brief description of the drawings:1st, protecting tyre body, 2, A coatings, 3, B coatings.
Embodiment
A kind of pricking-proof explosion-proof coating of superhigh intensity, including A coatings and B coatings；The B coating sprayings are on A coatings；Institute
State A painting each component mass percent be：
The B coatings it include following components by weight percentage：
The grafted monomers are Y- glycidyl ether oxygen propyl trimethoxy silicanes, Y- (methacryloxy) propyl group three
Methoxy silane, Y- Mercaptopropyltriethoxysilanes, vinyltrimethoxy silane, VTES, tertiary carbon
Vinyl acetate, propionate, vinyl butyrate, maleat, maleic anhydride, itaconic anhydride, vinylglycidyl
Ether, Malaysia acid glycidyl ester, glycidyl acrylate, GMA, 2- cyclohexene -1- bases shrink sweet
One or both of oily ether, cyclohexene -4- glycidyl carboxylates are mixed above.
Heretofore described grafted monomers are the compound of functional group containing alkene or epoxy-functional, can by addition or
Ring-opening reaction and be grafted to the polar monomer that resin macromolecular gets on.The purpose of grafted monomers and effect are by by polyfunctional group
Compound is grafted on matrix resin to improve adhesion strength of the matrix resin to different substrate materials.
In order to ensure that the coating has excellent cohesive strength, matrix resin is with ethene/1- octene copolymers (POE)
Main, ethylene-l-octane copolymer (POE) molecular weight is that not only can guarantee that POE's is interior under 10000-20000, this parameter
Poly- intensity can also improve the mobility of composition, beneficial to processing.In order to improve heat resistance on the basis of matrix resin.
The Alathon density is 0.90-0.95g/cm3。
Because Alathon belongs to high crystalline material, addition can excessively cause the decline of elasticity, therefore its consumption
It must control 5% and less；But if the consumption of Alathon is too low or without Alathon, can cause to gather again
The heat resistance of compound does not reach the requirement of application.In order to balance the heat resistance and cohesive strength of PE-POE binary systems, applicant
It was found that this terpolymer of ethylene-propylene -1- butylene amorphous copolymers, because the crystallization tendency of propylene is higher than ethene,
Therefore a number of crystallite area is more readily formed in the polypropylene segments in the polymer, and physics plays in polymeric inner in the crystallite area
The effect of the strong point, so as to improve the heat resistance of polymer, simultaneously because crystalline region region and ratio are small so that the polymer has
There is excellent cohesive strength.Therefore, ethylene-propylene -1- butylene amorphous copolymer is added in the present invention to substitute part ethene
Homopolymer, can balance the heat resistance and cohesive strength of PE-POE binary systems, its two kinds of performances is optimal balance, its
Consumption is controlled between 10-20%.In order that vistanex has caking property, trigger resin macromolecular radical grafted polar
Monomeric groups, initiator of the invention selects radical initiator.
The radical initiator is 3,3- double (t-amyl peroxy) ethyl butyrate, di-t-butyl peroxide, peroxidating two
Uncle defends base, t-butylcumylperoxide, two-(tert-butylperoxyiso-propyl) benzene, 2,5- dimethyl -2,5- pair-(tert-butyl group mistake
Oxygen) hexane, one or both of cumyl peroxide be mixed above.
The B coatings also include one kind in free radical activator, ultraviolet absorber, light stabilizer, antioxidant, plasticizer
Or two or more mixing.
Free radical activator can play a part of Nitroxyl stable radical, extend radical life, reduce macromolecular
The cross-linking reaction degree occurred between free radical due to coupling termination and the degradation reaction degree occurred due to P fractures, are carried
High grafting efficiency.
The free radical activator be can be rolled into a ball containing alkene or activity H compound.
It is described to be rolled into a ball as triallyl isocyanate, triallyl cyanate, ethylene glycol dimethacrylate containing alkene
Ester, a phenyl-bismaleimide, trimethylolpropane trimethacrylate, trimethylol-propane trimethacrylate, adjacent benzene
One or both of dioctyl phthalate diisopropyl alkene ester, 1,2- polybutadiene, ethidine polybutene are mixed above.
The ultraviolet absorber is selected from benzophenone compound or benzotriazole compound.
The benzophenone compound or benzotriazole compound can be 2- (2 '-hydroxyl -5 '-t-octyl phenyl)
BTA, 2-hydroxy-4-n-octoxybenzophenone, N- (2- ethylphenyls)-N- (2- ethoxyl phenenyls) oxamide.
Mixture 2 of the described light stabilizer more than hindered amines, preferably one of following or two of which, 2,6,
6- tetramethyl -4- pyridines alcohol fatty acid ester, double (2,2,6,6- tetramethyls _ 4_ piperidyls) sebacates, succinic acid and the light bases of 4- -
Polymer, the 4- benzoyloxys -2,2 of 2,2,6,6- tetramethyl -1- piperazine cry ethanol, 6,6- tetramethyl piperidines.Described antioxygen
Agent is selected from Hinered phenols antioxidant, suffocated amine antioxidant, phosphite ester kind antioxidant and thioether kind antioxidant；It is preferred that hindered phenol
Kind antioxidant and phosphite ester kind antioxidant are used in combination.The present invention can also add plasticizer to improve rheological performance, improve life
Efficiency is produced, described plasticizer preferably is selected from paraffinic mineral oil and aromatic mineral oil, preferably paraffinic mineral oil；They can be with
Composition is improved to the wellability of material to be bonded, adhesive property is further improved.
When using active carbonic acid need to be made by silane coupler activity processing in heretofore described precipitated calcium carbonate
Calcium, it is strong to calcium carbonate covering property because the POE molecular weight distributions selected in the present invention are narrower, calcium carbonate through activity processing with
POE compatibilities are good, are difficult to separate out from product.
The preparation method of B coatings, it, which comprises the following steps, premixes each component according to the above-mentioned component of the present invention and consumption
After uniform, melting graft reaction is carried out at 210-230 DEG C using double screw extruder, is then cooled down by device, grain is made
Shape, sheet and membranaceous blob of viscose.Then sprayed by SPM tire spraying equipments, be sprayed on treated A coating surfaces,
It is cooled to 80 degree or so.
The A coating productions：Make butyl rubber and unsaturated carboxylic acid in the presence of a free-radical initiator, in a solvent
And reacted 1~3 hour at temperature 60 C~80 DEG C, thermosetting resin is added, mixes, produces thermosetting unsaturated carboxylic acid-modified
The solution of butyl rubber, wherein solvent can arbitrarily be beneficial to the solvent of reaction progress such as toluene, petroleum ether；Described insatiable hunger
It is selected from the total one or more combinations of maleic acid and its acid anhydrides, acrylic acid and methacrylic acid with carboxylic acid；Described free radical
Initiator can be selected from TBHP, one or more combinations of benzoyl peroxide and azodiisobutyronitrile；Institute
The thermosetting resin stated is phenolic resin, Lauxite, melamine formaldehyde resin, epoxy resin, unsaturated-resin, furans
One or more combinations in resin, furane resins etc..
Using the safe pricking-proof explosion-proof protecting tyre of the superelevation of the pricking-proof explosion-proof coating of superhigh intensity, including protecting tyre sheet
Body, the inwall of the protecting tyre body is coated with A coatings and B coatings；The B coating sprayings are on A coatings；The A coatings 2
Thickness be 0.2-3 millimeter, the thickness of the B coatings 3 is 3-15 millimeters；Described protecting tyre body 1 be electricity rub bias tire,
All-steel tire, oblique vacuum, passenger car half steel vacuum tyre or card can go out all steel vacuum tyre；Specifically refer to A coatings and pass through spray gun
The inside tires after cleaning or grinding process are sprayed under normal temperature, solvent volatilization completely are waited or completely after drying, then
The B coatings of 240 DEG C~260 DEG C of spraying, wherein can be with producing the moon in B coatings containing the carboxylic acid monomer being grafted on butyl rubber
Cation exchange, reaches the molecular level bonding of AB coatings；The thermosetting resin added simultaneously, bar is excited in B coating high-temps
Under part, heat cure reaction is produced, it is perfect Nian Jie with tire inner wall inner liner.
Entered below with the safe pricking-proof explosion-proof protecting tyre of superelevation of the pricking-proof explosion-proof coating of the use superhigh intensity of the present invention
Row is tested and parameter detecting on the spot,
Test on the spot：The three OPTIOM K415 205/55R16 equipped with popular board SVW7167ASD types passenger car
91V types tire carries out related experiment, and provides experimental data for it：
| Test tire | Installation site | Loading of tire (kg) | Inflate tire pressure (kg) |
| 01 | It is left front | 395 | 240 |
| 02 | Before the right side | 385 | 240 |
| 03 | Spare tyre | 0 | 200 |
Experimental project and result：
Parameter detecting：
The pricking-proof explosion-proof coating of the superhigh intensity of the present invention is relative to prior art, and the beneficial effects of the present invention are this hair
Bright B coatings can realize effectively bonding, excellent heat resistance and superpower cohesive strength, and it is excellent to maintain polyolefine material
Physical property, chemical stability and good processability.It can in an atmosphere expose using more than 50 years, can meet various types of
The use requirement of vacuum tire pricking-proof explosion-proof.
And POE good-extensibilities itself, and in the absence of double bond structure, resistance to ag(e)ing is excellent, can in an atmosphere expose and use
More than 50 years, in summary various performances of polymer so that the B coatings produced have excellent high and low temperature resistance,
Ageing-resistant performance, tensile property are strong, and product pliability is moderate；And adhesive strength is solid and reliable, it is easy to spraying, production cost is low,
Technique is simple, environmentally safe, is a kind of environmentally friendly material.
The pricking-proof explosion-proof coating of the use superhigh intensity of the pricking-proof explosion-proof coating of the superhigh intensity of the present invention is used simultaneously
The safe pricking-proof explosion-proof protecting tyre technique in production of superelevation is simple, it is only necessary to sprayed after being heated by sizing material, together
When both kept the characteristic of tire in itself constant and by it is resistance to prick, the fluctuation of explosion-proof and resisting temperature is promoted to the raising of a matter.
The present invention and embodiments thereof are described above, the description does not have restricted, shown in specification
Simply one of embodiments of the present invention, actual structure is not limited thereto.If all in all ordinary skill of this area
Personnel are enlightened by it, without departing from the spirit of the invention, are designed and the technical scheme phase without creative
As frame mode and embodiment, protection scope of the present invention all should be belonged to.
Claims (10)
1. a kind of pricking-proof explosion-proof coating of superhigh intensity, it is characterised in that：Including A coatings and B coatings；The B coating sprayings are in A
On coating；
The each component mass percent that the A is applied is：
The B coatings it include following components by weight percentage
2. the pricking-proof explosion-proof coating of superhigh intensity according to claim 1, it is characterised in that：The grafted monomers contract for Y-
Water glycerine ether oxygen propyl trimethoxy silicane, Y- (methacryloxy) propyl trimethoxy silicane, the second of Y- mercaptopropyis three
TMOS, vinyltrimethoxy silane, VTES, tertiary ethylene carbonate, propionate, butyric acid second
Alkene ester, maleat, maleic anhydride, itaconic anhydride, vinyl glycidyl ether, Malaysia acid glycidyl ester, acrylic acid
Ethylene oxidic ester, GMA, 2- cyclohexene -1- bases glycidol ether, cyclohexene -4- glycidyl carboxylics
One or both of acid esters is mixed above.
3. the pricking-proof explosion-proof coating of superhigh intensity according to claim 1, it is characterised in that：Ethene -1- the octenes are total to
Polymers (POE) molecular weight is 10000-20000.
4. the pricking-proof explosion-proof coating of superhigh intensity according to claim 1, it is characterised in that：The radical initiator is
3,3- double (t-amyl peroxy) ethyl butyrates, di-t-butyl peroxide, the uncle of peroxidating two defend base, t-butylcumylperoxide,
In two-(tert-butylperoxyiso-propyl) benzene, 2,5- dimethyl -2,5- pair-(t-butyl peroxy) hexane, cumyl peroxide
One or more mixing.
5. the pricking-proof explosion-proof coating of superhigh intensity according to claim 1, it is characterised in that：The B coatings are also included certainly
It is mixed above by one or both of base activator, ultraviolet absorber, light stabilizer, antioxidant, plasticizer.
6. the pricking-proof explosion-proof coating of superhigh intensity according to claim 5, it is characterised in that：The free radical activator be containing
Have alkene can roll into a ball or activity H compound.
7. the pricking-proof explosion-proof coating of superhigh intensity according to claim 6, it is characterised in that：Described can be rolled into a ball containing alkene be
Triallyl isocyanate, triallyl cyanate, GDMA, a phenyl-bismaleimide, three hydroxyls
Propane tri, trimethylol-propane trimethacrylate, phthalic acid diisopropyl alkene ester, 1,2- polybutadienes
One or both of alkene, ethidine polybutene are mixed above.
8. a kind of safe pricking-proof explosion-proof protecting tyre of superelevation of pricking-proof explosion-proof coating of use superhigh intensity, including protecting tyre sheet
Body (1), it is characterised in that：The inwall of the protecting tyre body (1) is coated with A coatings (2) and B coatings (3)；The B coatings
(3) it is sprayed on A coatings (2).
9. the safe pricking-proof explosion-proof protecting tyre of superelevation according to claim 9, it is characterised in that：The thickness of the A coatings (2)
Spend for 0.2-3 millimeters, the thickness of the B coatings (3) is 3-15 millimeters.
10. the safe pricking-proof explosion-proof protecting tyre of superelevation according to claim 9, it is characterised in that：Described protecting tyre
Body (1) be electricity rub bias tire, All-steel tire, oblique vacuum, passenger car half steel vacuum tyre or card can go out all steel vacuum tyre.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710555557.5A CN107163769A (en) | 2017-07-08 | 2017-07-08 | The pricking-proof explosion-proof coating of superhigh intensity and the pricking-proof explosion-proof tire containing the coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710555557.5A CN107163769A (en) | 2017-07-08 | 2017-07-08 | The pricking-proof explosion-proof coating of superhigh intensity and the pricking-proof explosion-proof tire containing the coating |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113272382A (en) * | 2018-10-29 | 2021-08-17 | 伊利诺斯工具制品有限公司 | Tire dressing composition and method of making the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999179A (en) * | 2007-01-12 | 2007-07-18 | 张海龙 | Pricking resistant, bullet-proof, leakage-proof safety tyre, its manufacturing method and its used polymer leakage-proof mending material |
| CN102774057A (en) * | 2012-08-08 | 2012-11-14 | 中国建筑材料科学研究总院苏州防水研究院 | Macromolecule pre-laid waterproof coiled material |
| CN103059785A (en) * | 2012-12-25 | 2013-04-24 | 江苏鹿山光伏科技有限公司 | Heat resistant type transparent polyolefin hot melt adhesive and preparing method thereof |
-
2017
- 2017-07-08 CN CN201710555557.5A patent/CN107163769A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN100999179A (en) * | 2007-01-12 | 2007-07-18 | 张海龙 | Pricking resistant, bullet-proof, leakage-proof safety tyre, its manufacturing method and its used polymer leakage-proof mending material |
| CN102774057A (en) * | 2012-08-08 | 2012-11-14 | 中国建筑材料科学研究总院苏州防水研究院 | Macromolecule pre-laid waterproof coiled material |
| CN103059785A (en) * | 2012-12-25 | 2013-04-24 | 江苏鹿山光伏科技有限公司 | Heat resistant type transparent polyolefin hot melt adhesive and preparing method thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113272382A (en) * | 2018-10-29 | 2021-08-17 | 伊利诺斯工具制品有限公司 | Tire dressing composition and method of making the same |
| US11820907B2 (en) | 2018-10-29 | 2023-11-21 | Illinois Tool Works Inc. | Tire dressing composition and methods of making thereof |
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Application publication date: 20170915 |