CN107163504A - A kind of building interior trim plate of safety and environmental protection and preparation method thereof - Google Patents
A kind of building interior trim plate of safety and environmental protection and preparation method thereof Download PDFInfo
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- CN107163504A CN107163504A CN201710498069.5A CN201710498069A CN107163504A CN 107163504 A CN107163504 A CN 107163504A CN 201710498069 A CN201710498069 A CN 201710498069A CN 107163504 A CN107163504 A CN 107163504A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L63/00—Compositions of epoxy resins; Compositions of derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G59/00—Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
- C08G59/14—Polycondensates modified by chemical after-treatment
- C08G59/1433—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds
- C08G59/1438—Polycondensates modified by chemical after-treatment with organic low-molecular-weight compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2227—Oxides; Hydroxides of metals of aluminium
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Emergency Medicine (AREA)
- General Chemical & Material Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of building interior trim plate of safety and environmental protection, include the raw material of following parts by weight：58~72 parts of epoxy resin, 22~46 parts of siloxanes, 15~34 parts of nano silicon, 10~16 parts of nano-aluminium oxide, 5~12 parts of nano mica powder, 3~6 parts of inorganic combustion inhibitor, 5~8 parts of dispersant, 2~6 parts of water reducer, 1~4 part of plasticizer, 0.5~1 part of catalyst, 1~3 part of crosslinking agent；Its preparation method includes the preparation of modified epoxy liquid, and auxiliary agent is mixed into, nano silicon, nano-aluminium oxide, the ultrasonic disperse of nano mica powder and inorganic combustion inhibitor.Building interior trim plate proposed by the present invention, rationally, safety and environmental protection, no noxious material volatilizees formula rate, intensity is high, heat resistance is good, is unlikely to deform, also with fire resistance, and preparation method is simple, equipment requirement is low, and production efficiency is high, industrialized production can be carried out, with theoretical and practical significance.
Description
Technical field
The present invention relates to building material technical field, more particularly to a kind of building interior trim plate of safety and environmental protection and its preparation side
Method.
Background technology
Trim panel is a kind of sheet material with decoration functions, because its performance is better than being widely used in automotive field and building
Field, such as arrangements for automotive doors, cabinet, wardrobe in house ornamentation etc..Existing trim panel can be divided into according to the difference of material：It is wooden
Trim panel, plastics trim panel, glass trim panel etc..The fire protecting performance and hardness of existing wooden trim panel are poor, are using
There is the potential safety hazard for causing fire in journey, the heavier mass of glass trim panel, rigidity are strong, and both transports to material cause difficulty,
It is simultaneously frangible in use.And the trim panel of plastic material compared to wooden trim panel and glass trim panel in weight and comprehensive
Certain advantage is respectively provided with terms of conjunction performance.But existing plastics trim panel there is also it is certain the drawbacks of, such as in plastics
There can be some volatile toxic substances in plaque, can slowly discharge in use, penetrating odor can be also distributed sometimes
Gas, healthy to user bring potential safety hazard.And the intensity difference of the trim panel of existing plastic material, load-bearing
Ability is weak, easily deforms.Particularly under the high temperature conditions, the release of noxious material, distributing for bad smell become with trim panel
The phenomenon of shape is even more serious.
The content of the invention
The invention aims to solve shortcoming present in prior art, and a kind of building of the safety and environmental protection proposed
Trim panel and preparation method thereof.
A kind of building interior trim plate of safety and environmental protection, includes the raw material of following parts by weight：58~72 parts of epoxy resin, siloxanes
22~46 parts, 15~34 parts of nano silicon, 10~16 parts of nano-aluminium oxide, 5~12 parts of nano mica powder, inorganic resistance
Fire 3~6 parts of agent, 5~8 parts of dispersant, 2~6 parts of water reducer, 1~4 part of plasticizer, 0.5~1 part of catalyst, crosslinking agent 1~3
Part.
It is preferred that, a kind of building interior trim plate of described safety and environmental protection includes the raw material of following parts by weight：Epoxy resin 60
~68 parts, 26~40 parts of siloxanes, 18~30 parts of nano silicon, 12~16 parts of nano-aluminium oxide, nano mica powder 6
~12 parts, 3~6 parts of inorganic combustion inhibitor, 6~8 parts of dispersant, 2~6 parts of water reducer, 1~4 part of plasticizer, catalyst 0.5~1
Part, 1~3 part of crosslinking agent.
It is preferred that, a kind of building interior trim plate of described safety and environmental protection includes the raw material of following parts by weight：Epoxy resin 64
Part, 34 parts of siloxanes, 25 parts of nano silicon, 14 parts of nano-aluminium oxide, 9 parts of nano mica powder, inorganic combustion inhibitor 5
Part, 7 parts of dispersant, 4 parts of water reducer, 2 parts of plasticizer, 0.7 part of catalyst, 2 parts of crosslinking agent.
It is preferred that, the weight part ratio of the epoxy resin and siloxanes is 1.2~4：1.
It is preferred that, the inorganic combustion inhibitor is the mixture of magnesium hydroxide and aluminium hydroxide, and magnesium hydroxide and hydroxide
The weight part ratio of aluminium is 1：1.2~2.5.
It is preferred that, the dispersant is any one in Sodium Polyacrylate and trimethyl isoamyl alcohol.
The invention also provides a kind of preparation method of the building interior trim plate of safety and environmental protection, comprise the following steps：
S1：Epoxy resin is placed in the kneading machine that temperature is 50~60 DEG C, heating and melting adds the silica of corresponding parts by weight
Alkane, crosslinking agent and catalyst, sealing 2~4h of reaction, produce modified epoxy liquid；
S2：Add the dispersant, water reducer and plasticizer of corresponding parts by weight into above-mentioned modified epoxy liquid, mixing 10~
20min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder and inorganic combustion inhibitor are sequentially added into mixed liquor A
Ultrasonic disperse is carried out, and nano silicon, nano-aluminium oxide, the addition speed of nano mica powder and inorganic combustion inhibitor are
20~60g/min.
Building interior trim plate proposed by the present invention, rationally, safety and environmental protection, no noxious material volatilization, intensity is high, resistance to for formula rate
Good in thermal property, is unlikely to deform, and also with fire resistance, epoxy resin is improved by siloxanes, makes the resistance to of epoxy resin
Hot, water proofing property and intensity are all significantly improved, then pass through silica, three oxygen of small, the easily scattered Nano grade of discrete particles
Change two aluminium and mica powder, the contact area of increase silica, alundum (Al2O3) and mica powder and other raw materials is obviously improved interior
The intensity of plaque, makes the bearing capacity enhancing of trim panel in use, is not susceptible to deformation, and the dioxy of Nano grade
SiClx, alundum (Al2O3) and mica powder, which are dispersed in trim panel, can strengthen the heat resistance of trim panel, make it in hot conditions
Under, intensity and hardness also keep constant, and addition magnesium hydroxide and aluminium hydroxide play fire-retardant work jointly in the trim panel
With significantly improving the flame retardant rating of trim panel, it is to avoid burning things which may cause a fire disaster spreads, and then avoids the presence of potential safety hazard, and trim panel
Produced without poisonous volatile substance, use safety and environmental protection；The invention also provides a kind of system of the building interior trim plate of safety and environmental protection
Preparation Method, the preparation method first prepares modified epoxy resin liquid, adds auxiliary agent, auxiliary agent is uniformly dissolved in modified resin
In liquid, last redisperse insoluble matter makes the performance of the scattered building interior trim plate evenly, finally prepared of insoluble matter more excellent
More, and color and luster and performance are homogeneous, preparation process is low for equipment requirements, and production efficiency is high, industrialized production can be carried out, with reason
By and practical significance.
Embodiment
The present invention is made with reference to specific embodiment further to explain.
Embodiment one
A kind of building interior trim plate of safety and environmental protection proposed by the present invention, includes the raw material of following parts by weight：66 parts of epoxy resin, silicon
38 parts of oxygen alkane, 26 parts of nano silicon, 16 parts of nano-aluminium oxide, 12 parts of nano mica powder, 1 part of magnesium hydroxide, hydrogen-oxygen
Change 2 parts of aluminium, 6 parts of Sodium Polyacrylate, 6 parts of water reducer, 1 part of plasticizer, 0.7 part of catalyst, 2 parts of crosslinking agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin is placed in during temperature is 60 DEG C of kneading machine, heating and melting, add corresponding parts by weight siloxanes,
Crosslinking agent and catalyst, sealing reaction 4h, produce modified epoxy liquid；
S2：The Sodium Polyacrylate, water reducer and plasticizer of corresponding parts by weight are added into above-mentioned modified epoxy liquid, is kneaded
10min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder, magnesium hydroxide and hydrogen are sequentially added into mixed liquor A
Aluminum oxide carries out ultrasonic disperse, and nano silicon, nano-aluminium oxide, the addition of nano mica powder and inorganic combustion inhibitor
Speed is 40g/min.
Embodiment two
A kind of building interior trim plate of safety and environmental protection proposed by the present invention, includes the raw material of following parts by weight：72 parts of epoxy resin, silicon
30 parts of oxygen alkane, 34 parts of nano silicon, 10 parts of nano-aluminium oxide, 12 parts of nano mica powder, 2 parts of magnesium hydroxide, hydrogen-oxygen
Change 4 parts of aluminium, 8 parts of trimethyl isoamyl alcohol, 2 parts of water reducer, 2 parts of plasticizer, 1 part of catalyst, 2 parts of crosslinking agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin is placed in during temperature is 50 DEG C of kneading machine, heating and melting, add corresponding parts by weight siloxanes,
Crosslinking agent and catalyst, sealing reaction 2h, produce modified epoxy liquid；
S2：Trimethyl isoamyl alcohol, water reducer and the plasticizer of corresponding parts by weight are added into above-mentioned modified epoxy liquid, is kneaded
10min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder, magnesium hydroxide and hydrogen are sequentially added into mixed liquor A
Aluminum oxide carries out ultrasonic disperse, and nano silicon, nano-aluminium oxide, the addition of nano mica powder and inorganic combustion inhibitor
Speed is 20g/min.
Embodiment three
A kind of building interior trim plate of safety and environmental protection proposed by the present invention, includes the raw material of following parts by weight：72 parts of epoxy resin, silicon
46 parts of oxygen alkane, 28 parts of nano silicon, 14 parts of nano-aluminium oxide, 10 parts of nano mica powder, 1.5 parts of magnesium hydroxide, hydrogen
3 parts of aluminum oxide, 6 parts of Sodium Polyacrylate, 2 parts of water reducer, 1 part of plasticizer, 0.5 part of catalyst, 3 parts of crosslinking agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin is placed in during temperature is 55 DEG C of kneading machine, heating and melting, add corresponding parts by weight siloxanes,
Crosslinking agent and catalyst, sealing reaction 3h, produce modified epoxy liquid；
S2：The Sodium Polyacrylate, water reducer and plasticizer of corresponding parts by weight are added into above-mentioned modified epoxy liquid, is kneaded
20min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder, magnesium hydroxide and hydrogen are sequentially added into mixed liquor A
Aluminum oxide carries out ultrasonic disperse, and nano silicon, nano-aluminium oxide, the addition of nano mica powder and inorganic combustion inhibitor
Speed is 30g/min.
Example IV
A kind of building interior trim plate of safety and environmental protection proposed by the present invention, includes the raw material of following parts by weight：62 parts of epoxy resin, silicon
26 parts of oxygen alkane, 15 parts of nano silicon, 16 parts of nano-aluminium oxide, 12 parts of nano mica powder, 1 part of magnesium hydroxide, hydrogen-oxygen
Change 2.5 parts of aluminium, 8 parts of Sodium Polyacrylate, 2 parts of water reducer, 1 part of plasticizer, 0.5 part of catalyst, 1 part of crosslinking agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin is placed in during temperature is 60 DEG C of kneading machine, heating and melting, add corresponding parts by weight siloxanes,
Crosslinking agent and catalyst, sealing reaction 4h, produce modified epoxy liquid；
S2：The Sodium Polyacrylate, water reducer and plasticizer of corresponding parts by weight are added into above-mentioned modified epoxy liquid, is kneaded
10min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder, magnesium hydroxide and hydrogen are sequentially added into mixed liquor A
Aluminum oxide carries out ultrasonic disperse, and nano silicon, nano-aluminium oxide, the addition of nano mica powder and inorganic combustion inhibitor
Speed is 50g/min.
Embodiment five
A kind of building interior trim plate of safety and environmental protection proposed by the present invention, includes the raw material of following parts by weight：60 parts of epoxy resin, silicon
30 parts of oxygen alkane, 22 parts of nano silicon, 12 parts of nano-aluminium oxide, 7 parts of nano mica powder, magnesium hydroxide part 1, hydroxide
2 parts of aluminium, 6 parts of trimethyl isoamyl alcohol, 4 parts of water reducer, 2 parts of plasticizer, 1 part of catalyst, 1 part of crosslinking agent.
Its preparation method, comprises the following steps：
S1：Epoxy resin is placed in during temperature is 50 DEG C of kneading machine, heating and melting, add corresponding parts by weight siloxanes,
Crosslinking agent and catalyst, sealing reaction 4h, produce modified epoxy liquid；
S2：Trimethyl isoamyl alcohol, water reducer and the plasticizer of corresponding parts by weight are added into above-mentioned modified epoxy liquid, is kneaded
20min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder, magnesium hydroxide and hydrogen are sequentially added into mixed liquor A
Aluminum oxide carries out ultrasonic disperse, and nano silicon, nano-aluminium oxide, the addition of nano mica powder and inorganic combustion inhibitor
Speed is 60g/min.
Performance detection is carried out to building interior trim plate prepared by embodiment one~five, testing result is as follows：
Wherein, heat-resistant experiment condition is 100 DEG C, 24h；"-" represents not find.
The hardness of building interior trim plate prepared by embodiment one~five can reach more than 97HA before heat-resistant experiment is not carried out,
Carrying out 100 DEG C, after 24h destructions, the phenomenon of no cracking and deformation, and hardness almost do not change, shows preparation of the present invention
Building interior trim plate heat resistance it is good, intensity is high, and is unlikely to deform under the high temperature conditions；Flame retardant rating result shows embodiment
The flame retardant rating of one~five building interior trim plate prepared can reach A grades, show good flame retardation effect, and the building interior trim plate prepared
The inside presence of formaldehydeless, toluene and benzene, safety and environmental protection.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (7)
1. the building interior trim plate of a kind of safety and environmental protection, it is characterised in that include the raw material of following parts by weight：Epoxy resin 58~72
Part, 22~46 parts of siloxanes, 15~34 parts of nano silicon, 10~16 parts of nano-aluminium oxide, nano mica powder 5~12
Part, 3~6 parts of inorganic combustion inhibitor, 5~8 parts of dispersant, 2~6 parts of water reducer, 1~4 part of plasticizer, 0.5~1 part of catalyst is handed over
Join 1~3 part of agent.
2. the building interior trim plate of a kind of safety and environmental protection according to claim 1, it is characterised in that including following parts by weight
Raw material：60~68 parts of epoxy resin, 26~40 parts of siloxanes, 18~30 parts of nano silicon, nano-aluminium oxide 12~
16 parts, 6~12 parts of nano mica powder, 3~6 parts of inorganic combustion inhibitor, 6~8 parts of dispersant, 2~6 parts of water reducer, plasticizer 1~4
Part, 0.5~1 part of catalyst, 1~3 part of crosslinking agent.
3. the building interior trim plate of a kind of safety and environmental protection according to claim 1, it is characterised in that including following parts by weight
Raw material：64 parts of epoxy resin, 34 parts of siloxanes, 25 parts of nano silicon, 14 parts of nano-aluminium oxide, nano mica powder 9
Part, 5 parts of inorganic combustion inhibitor, 7 parts of dispersant, 4 parts of water reducer, 2 parts of plasticizer, 0.7 part of catalyst, 2 parts of crosslinking agent.
4. the building interior trim plate of a kind of safety and environmental protection according to claim 1, it is characterised in that the epoxy resin and silicon
The weight part ratio of oxygen alkane is 1.2~4：1.
5. a kind of building interior trim plate of safety and environmental protection according to claim 1, it is characterised in that the inorganic combustion inhibitor is
The mixture of magnesium hydroxide and aluminium hydroxide, and the weight part ratio of magnesium hydroxide and aluminium hydroxide is 1：1.2~2.5.
6. the building interior trim plate of a kind of safety and environmental protection according to claim 1, it is characterised in that the dispersant is poly- third
Any one in olefin(e) acid sodium and trimethyl isoamyl alcohol.
7. the preparation method of the building interior trim plate of a kind of safety and environmental protection, it is characterised in that comprise the following steps：
S1：Epoxy resin is placed in the kneading machine that temperature is 50~60 DEG C, heating and melting adds the silica of corresponding parts by weight
Alkane, crosslinking agent and catalyst, sealing 2~4h of reaction, produce modified epoxy liquid；
S2：Add the dispersant, water reducer and plasticizer of corresponding parts by weight into above-mentioned modified epoxy liquid, mixing 10~
20min, produces mixed liquor A；
S3：Nano silicon, nano-aluminium oxide, nano mica powder and inorganic combustion inhibitor are sequentially added into mixed liquor A
Ultrasonic disperse is carried out, and nano silicon, nano-aluminium oxide, the addition speed of nano mica powder and inorganic combustion inhibitor are
20~60g/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710498069.5A CN107163504A (en) | 2017-06-27 | 2017-06-27 | A kind of building interior trim plate of safety and environmental protection and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710498069.5A CN107163504A (en) | 2017-06-27 | 2017-06-27 | A kind of building interior trim plate of safety and environmental protection and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107163504A true CN107163504A (en) | 2017-09-15 |
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ID=59826182
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710498069.5A Pending CN107163504A (en) | 2017-06-27 | 2017-06-27 | A kind of building interior trim plate of safety and environmental protection and preparation method thereof |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575450A (en) * | 2009-06-05 | 2009-11-11 | 朱录勤 | Novel silicon fibre multifunctional flexible decorating material and preparation method thereof |
| CN106317781A (en) * | 2016-08-30 | 2017-01-11 | 吴小慧 | Flame-retardant high-temperature-resistant decoration material and preparation method thereof |
| CN106751508A (en) * | 2016-12-15 | 2017-05-31 | 苏州科胜仓储物流设备有限公司 | A kind of flame retardant epoxy plastic plate and preparation method thereof |
-
2017
- 2017-06-27 CN CN201710498069.5A patent/CN107163504A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101575450A (en) * | 2009-06-05 | 2009-11-11 | 朱录勤 | Novel silicon fibre multifunctional flexible decorating material and preparation method thereof |
| CN106317781A (en) * | 2016-08-30 | 2017-01-11 | 吴小慧 | Flame-retardant high-temperature-resistant decoration material and preparation method thereof |
| CN106751508A (en) * | 2016-12-15 | 2017-05-31 | 苏州科胜仓储物流设备有限公司 | A kind of flame retardant epoxy plastic plate and preparation method thereof |
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Application publication date: 20170915 |
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