CN107163332A - A kind of electrical engineering cable oversheath - Google Patents

A kind of electrical engineering cable oversheath Download PDF

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Publication number
CN107163332A
CN107163332A CN201710341520.2A CN201710341520A CN107163332A CN 107163332 A CN107163332 A CN 107163332A CN 201710341520 A CN201710341520 A CN 201710341520A CN 107163332 A CN107163332 A CN 107163332A
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Prior art keywords
parts
paraffin
electrical engineering
weight
stirring
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CN201710341520.2A
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Chinese (zh)
Inventor
高凤谊
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Anhui Ruixin Automation Instrument Co Ltd
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Anhui Ruixin Automation Instrument Co Ltd
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Priority to CN201710341520.2A priority Critical patent/CN107163332A/en
Publication of CN107163332A publication Critical patent/CN107163332A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L15/00Compositions of rubber derivatives
    • C08L15/005Hydrogenated nitrile rubber
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/011Nanostructured additives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/014Additives containing two or more different additives of the same subgroup in C08K
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00Crosslinking

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  • Chemical & Material Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The invention discloses a kind of electrical engineering cable oversheath, its raw material includes by weight:140 148 parts of major ingredient, 24 parts of triethoxy trimethyl silane, 12 parts of caprolactam, 0.5 1 parts of IPOTMS isopropyloxy trimethylsilane, 1,1 pair of 12 parts of (t-butyl peroxy) hexamethylene, 1,1,3,312 parts of tetramethyl butyl hydroperoxide, 0.8 1.6 parts of barium stearate, 1.5 2.5 parts of chlorinated paraffin, 24 parts of disproportionated rosin, 80 90 parts of inserts.Electrical engineering cable oversheath proposed by the present invention, extensively, the destruction to cable material that can effectively prevent external force from bringing improves heat-resisting, the antibacterial grade of cable in electrical engineering, had a extensive future raw material sources.

Description

A kind of electrical engineering cable oversheath
Technical field
The present invention relates to cable cover(ing) technical field, more particularly to a kind of electrical engineering cable oversheath.
Background technology
Cable sheath material is located at the outside of cable core material, cable sheath material and the common structure of conductive core material inside cable Into cable, the pliability and intensity of cable sheath material are improved, is conducive to the long-term use of cable material in electrical engineering, mesh Although preceding people have studied some and improve the anti-brittle failure of cable sheath material, antibacterial, the method for heat endurance, but effect is not clear It is aobvious.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of electrical engineering cable oversheath, raw material Wide material sources, the destruction to cable material that can effectively prevent external force from bringing improves heat-resisting, the antibacterial of cable in electrical engineering Grade, has a extensive future.
A kind of electrical engineering cable oversheath proposed by the present invention, its raw material includes by weight:Major ingredient 140-148 Part, 2-4 parts of triethoxy trimethyl silane, 1-2 parts of caprolactam, 0.5-1 parts of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(uncle Butyl peroxy) 1-2 parts of hexamethylene, 1,1,3,3- 1-2 parts of tetramethyl butyl hydroperoxide, 0.8-1.6 parts of barium stearate, chlorination stone 1.5-2.5 parts of wax, 2-4 parts of disproportionated rosin, 80-90 parts of inserts.
Preferably, major ingredient includes by weight:60-70 parts of hydrogenated nitrile-butadiene rubber, 40-50 parts of ethylene-vinyl acetate gathers 30-40 parts of ethene.
Preferably, inserts includes by weight:20-30 parts of paraffin compound, 6-12 parts of nanomete talc powder calcines hard 10-20 parts of clay, 15-25 parts of kaolin, 5-9 parts of calcium carbonate.
Preferably, paraffin compound is prepared using following technique:Paraffin, stearic acid are mixed, heated, insulation adds ten Eight alkyl trimethyl ammonium bromides are stirred, heating, are continued to stir, are naturally cooled to room temperature, add galapectite powder, calgon, Water is stirred, centrifugation, removes lower sediment, adds hydrochloric acid, and heating stirring, suction filtration, solids is washed in neutrality, dry, pulverize Obtain paraffin compound.
Preferably, paraffin compound is prepared using following technique:By weight by 30-50 parts of paraffin, 6-12 parts of stearic acid Mixing, is heated, insulation, adds 6-12 parts of Cetyltrimethylammonium bromide stirrings, and heating continues to stir, naturally cools to room Temperature, adds 70-90 parts of galapectite powder, 8-12 parts of calgons, 220-260 parts of water stirrings, and centrifugation removes lower sediment, plus Enter 180-220 parts of concentration for 1-2mol/L hydrochloric acid, heating stirring, suction filtration, solids washs in neutrality, dry, pulverize and obtain Paraffin compound.
Preferably, paraffin compound is prepared using following technique:By weight by 30-50 parts of paraffin, 6-12 parts of stearic acid Mixing, is heated to 80-88 DEG C, is incubated 25-35min, adds 6-12 parts of Cetyltrimethylammonium bromide stirring 40-50min, rises Temperature continues to stir 10-20min, naturally cools to room temperature, add 70-90 parts of galapectite powder, 8-12 parts six inclined to 120-130 DEG C Sodium phosphate, 220-260 parts of water stir 1-2h, and mixing speed is 1000-1200r/min, centrifuge 10-18min, and centrifugal speed is 16000-20000r/min, removes lower sediment, and it is 1-2mol/L hydrochloric acid to add 180-220 parts of concentration, is warming up to 65-75 DEG C and stirs 20-40min, suction filtration are mixed, solids is washed in neutrality, and 120-130 DEG C of dry 3-5h, crushing obtains paraffin compound.
In paraffin compound, paraffin, stearic acid are compound to carry out disperse modified, dispersiveness to Cetyltrimethylammonium bromide Good, anti-microbial property is extremely excellent, then coordinates with galapectite powder, because galapectite powder is multi-layer hollow tubular structure, in six inclined phosphorus High with Cetyltrimethylammonium bromide bond strength under the cooperation of sour sodium, heat endurance is high, paraffin compound and acyl in oneself Amine, triethoxy trimethyl silane, IPOTMS isopropyloxy trimethylsilane complex role, can effectively promote compatibility between unclassified stores Good, density is high, and with certain toughness, it is to avoid occur brittle failure phenomenon.
The present invention is coordinated using ethylene-vinyl acetate, polyethylene, hydrogenated nitrile-butadiene rubber and paraffin compound, through 2,5- Dimethyl -2,5 di-t-butyl hexane, 1,1- pairs-(t-butyl peroxy) hexamethylene solidification, peroxidating can form high temperature resistant chemistry Key, and the degree of cross linking is high, and crosslinking is extremely closely knit, and hardness is big, and cost is low;Paraffin compound and barium stearate, chlorinated paraffin, discrimination Change rosin to coordinate, can effectively strengthen nanomete talc powder, calcining hard (china) clay, kaolin, calcium carbonate, antimony oxide in major ingredient The degree that is uniformly dispersed, on the premise of enhanced article hardness, toughness is preferable.Raw material sources of the present invention extensively, and can effectively be prevented The destruction to cable material that only external force is brought, improves heat-resisting, the antibacterial grade of cable in electrical engineering, and application prospect is wide It is wealthy.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of electrical engineering cable oversheath proposed by the present invention, its raw material includes by weight:148 parts of major ingredient, three 2 parts of ethoxytrimethylsilane, 2 parts of caprolactam, 0.5 part of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(t-butyl peroxy) ring 2 parts of hexane, 1,1,3,3- 1 part of tetramethyl butyl hydroperoxide, 1.6 parts of barium stearate, 1.5 parts of chlorinated paraffin, disproportionated rosin 4 Part, 80 parts of inserts.
Embodiment 2
A kind of electrical engineering cable oversheath proposed by the present invention, its raw material includes by weight:140 parts of major ingredient, three 4 parts of ethoxytrimethylsilane, 1 part of caprolactam, 1 part of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(t-butyl peroxy) hexamethylene 1 part of alkane, 1,1,3,3- 2 parts of tetramethyl butyl hydroperoxide, 0.8 part of barium stearate, 2.5 parts of chlorinated paraffin, 2 parts of disproportionated rosin, 90 parts of inserts.
Major ingredient includes by weight:60 parts of hydrogenated nitrile-butadiene rubber, 50 parts of ethylene-vinyl acetate, 30 parts of polyethylene.Filling Material includes by weight:30 parts of paraffin compound, 6 parts of nanomete talc powder calcines 20 parts of hard (china) clay, 15 parts of kaolin, carbonic acid 9 parts of calcium.
Paraffin compound is prepared using following technique:Paraffin, stearic acid are mixed, heated, insulation adds octadecyl three Methyl bromide ammonium is stirred, heating, is continued to stir, is naturally cooled to room temperature, adds galapectite powder, calgon, water stirring, from The heart, remove lower sediment, add hydrochloric acid, heating stirring, suction filtration, solids wash in neutrality, dry, pulverize obtain paraffin answer Compound.
Embodiment 3
A kind of electrical engineering cable oversheath proposed by the present invention, its raw material includes by weight:146 parts of major ingredient, three 2.5 parts of ethoxytrimethylsilane, 1.8 parts of caprolactam, 0.6 part of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(tert-butyl group mistake Oxygen) 1.8 parts of hexamethylene, 1,1,3,3- 1.5 parts of tetramethyl butyl hydroperoxide, 1.4 parts of barium stearate, 1.8 parts of chlorinated paraffin, discrimination Change 3.5 parts of rosin, 82 parts of inserts.
Major ingredient includes by weight:70 parts of hydrogenated nitrile-butadiene rubber, 40 parts of ethylene-vinyl acetate, 40 parts of polyethylene.Filling Material includes by weight:20 parts of paraffin compound, 12 parts of nanomete talc powder calcines 10 parts of hard (china) clay, 25 parts of kaolin, carbonic acid 5 parts of calcium.
Paraffin compound is prepared using following technique:40 parts of paraffin, 9 parts of stearic acid are mixed by weight, heats, protects Temperature, adds 9 parts of Cetyltrimethylammonium bromide stirrings, and heating continues to stir, naturally cools to room temperature, adds 80 parts of angstroms of Lip rivers Stone flour, 10 parts of calgons, 240 parts of water stirrings, centrifugation remove lower sediment, and it is 1.5mol/L salt to add 200 parts of concentration Acid, heating stirring, suction filtration, solids washs in neutrality, dry, pulverize and obtains paraffin compound.
Embodiment 4
A kind of electrical engineering cable oversheath proposed by the present invention, its raw material includes by weight:142 parts of major ingredient, three 3.5 parts of ethoxytrimethylsilane, 1.2 parts of caprolactam, 0.8 part of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(tert-butyl group mistake Oxygen) 1.2 parts of hexamethylene, 1,1,3,3- 1.7 parts of tetramethyl butyl hydroperoxide, 1 part of barium stearate, 2.2 parts of chlorinated paraffin, disproportionation 2.5 parts of rosin, 88 parts of inserts.
Major ingredient includes by weight:62 parts of hydrogenated nitrile-butadiene rubber, 48 parts of ethylene-vinyl acetate, 35 parts of polyethylene.Filling Material includes by weight:27 parts of paraffin compound, 8 parts of nanomete talc powder calcines 18 parts of hard (china) clay, 18 parts of kaolin, carbonic acid 8 parts of calcium.
Paraffin compound is prepared using following technique:30 parts of paraffin, 12 parts of stearic acid are mixed by weight, 80 are heated to DEG C, 35min is incubated, 6 parts of Cetyltrimethylammonium bromide stirring 50min is added, is warming up to 120 DEG C, continues to stir 20min, Room temperature is naturally cooled to, 70 parts of galapectite powder, 12 parts of calgons, 220 parts of water stirring 2h are added, mixing speed is 1000r/ Min, centrifuges 18min, centrifugal speed is 16000r/min, removes lower sediment, and it is 1mol/L hydrochloric acid to add 220 parts of concentration, is risen Temperature to 75 DEG C of stirring 20min, suction filtration, solids is washed in neutrality, and 130 DEG C of dry 3h, crushing obtains paraffin compound.
Embodiment 5
A kind of electrical engineering cable oversheath proposed by the present invention, its raw material includes by weight:144 parts of major ingredient, three 2.8 parts of ethoxytrimethylsilane, 1.6 parts of caprolactam, 0.7 part of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(tert-butyl group mistake Oxygen) 1.4 parts of hexamethylene, 1,1,3,3- 1.6 parts of tetramethyl butyl hydroperoxide, 1.2 parts of barium stearate, 1.9 parts of chlorinated paraffin, discrimination Change 2.8 parts of rosin, 84 parts of inserts.
Major ingredient includes by weight:68 parts of hydrogenated nitrile-butadiene rubber, 43 parts of ethylene-vinyl acetate, 38 parts of polyethylene.Filling Material includes by weight:23 parts of paraffin compound, 10 parts of nanomete talc powder calcines 12 parts of hard (china) clay, 22 parts of kaolin, carbonic acid 6 parts of calcium.
Paraffin compound is prepared using following technique:50 parts of paraffin, 6 parts of stearic acid are mixed by weight, 88 are heated to DEG C, 25min is incubated, 12 parts of Cetyltrimethylammonium bromide stirring 40min is added, is warming up to 130 DEG C, continues to stir 10min, Room temperature is naturally cooled to, 90 parts of galapectite powder, 8 parts of calgons, 260 parts of water stirring 1h are added, mixing speed is 1200r/ Min, centrifuges 10min, centrifugal speed is 20000r/min, removes lower sediment, and it is 2mol/L hydrochloric acid to add 180 parts of concentration, is risen Temperature to 65 DEG C of stirring 40min, suction filtration, solids is washed in neutrality, and 120 DEG C of dry 5h, crushing obtains paraffin compound.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto, Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.

Claims (6)

1. a kind of electrical engineering cable oversheath, it is characterised in that its raw material includes by weight:140-148 parts of major ingredient, three 2-4 parts of ethoxytrimethylsilane, 1-2 parts of caprolactam, 0.5-1 parts of IPOTMS isopropyloxy trimethylsilane, 1,1- double-(tert-butyl group Peroxide) 1-2 parts of hexamethylene, 1,1,3,3- 1-2 parts of tetramethyl butyl hydroperoxide, 0.8-1.6 parts of barium stearate, chlorinated paraffin 1.5-2.5 parts, 2-4 parts of disproportionated rosin, 80-90 parts of inserts.
2. electrical engineering cable oversheath according to claim 1, it is characterised in that major ingredient includes by weight:Hydrogenation 60-70 parts of nitrile rubber, 40-50 parts of ethylene-vinyl acetate, 30-40 parts of polyethylene.
3. electrical engineering cable oversheath according to claim 1 or claim 2, it is characterised in that inserts includes by weight: 20-30 parts of paraffin compound, 6-12 parts of nanomete talc powder calcines 10-20 parts of hard (china) clay, 15-25 parts of kaolin, calcium carbonate 5- 9 parts.
4. according to any one of the claim 1-3 electrical engineering cable oversheaths, it is characterised in that paraffin compound is used It is prepared by following technique:Paraffin, stearic acid are mixed, heated, insulation adds Cetyltrimethylammonium bromide and stirred, heating, after Continuous stirring, naturally cools to room temperature, adds galapectite powder, calgon, water stirring, and centrifugation removes lower sediment, adds salt Acid, heating stirring, suction filtration, solids washs in neutrality, dry, pulverize and obtains paraffin compound.
5. according to any one of the claim 1-4 electrical engineering cable oversheaths, it is characterised in that paraffin compound is used It is prepared by following technique:30-50 parts of paraffin, 6-12 parts of stearic acid are mixed by weight, heated, insulation adds 6-12 parts 18 Alkyl trimethyl ammonium bromide is stirred, heating, is continued to stir, is naturally cooled to room temperature, add 70-90 parts of galapectite powder, 8-12 parts Calgon, 220-260 parts of water stirrings, centrifugation removes lower sediment, and it is 1-2mol/L hydrochloric acid to add 180-220 parts of concentration, Heating stirring, suction filtration, solids washs in neutrality, dry, pulverize and obtains paraffin compound.
6. according to any one of the claim 1-5 electrical engineering cable oversheaths, it is characterised in that paraffin compound is used It is prepared by following technique:30-50 parts of paraffin, 6-12 parts of stearic acid are mixed by weight, 80-88 DEG C is heated to, is incubated 25- 35min, adds 6-12 parts of Cetyltrimethylammonium bromide stirring 40-50min, is warming up to 120-130 DEG C, continues to stir 10- 20min, naturally cools to room temperature, adds 70-90 parts of galapectite powder, 8-12 parts of calgons, 220-260 parts of water stirring 1- 2h, mixing speed is 1000-1200r/min, centrifuges 10-18min, centrifugal speed is 16000-20000r/min, removes lower floor Precipitation, it is 1-2mol/L hydrochloric acid to add 180-220 parts of concentration, is warming up to 65-75 DEG C of stirring 20-40min, and suction filtration, solids is washed Wash in neutrality, 120-130 DEG C of dry 3-5h, crushing obtains paraffin compound.
CN201710341520.2A 2017-05-16 2017-05-16 A kind of electrical engineering cable oversheath Withdrawn CN107163332A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964136A (en) * 2017-11-28 2018-04-27 安徽伟合电子科技有限公司 A kind of ageing-resistant cable for instrument of waterproof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160217883A1 (en) * 2013-09-30 2016-07-28 Jiangsu Dasheng Polymer Co., Ltd. A Halogen-Free Insulated Cable Material Used for 125C Irradiation Cross-Linked EPCV Photovoltaics and a Preparation Method Thereof
CN106279858A (en) * 2016-08-30 2017-01-04 安徽蓝德集团股份有限公司 A kind of good coal mine cable protective cover material of antibacterial mechanical property
CN106366384A (en) * 2016-08-30 2017-02-01 安徽蓝德集团股份有限公司 High-tenacity power cable sheathing compound

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160217883A1 (en) * 2013-09-30 2016-07-28 Jiangsu Dasheng Polymer Co., Ltd. A Halogen-Free Insulated Cable Material Used for 125C Irradiation Cross-Linked EPCV Photovoltaics and a Preparation Method Thereof
CN106279858A (en) * 2016-08-30 2017-01-04 安徽蓝德集团股份有限公司 A kind of good coal mine cable protective cover material of antibacterial mechanical property
CN106366384A (en) * 2016-08-30 2017-02-01 安徽蓝德集团股份有限公司 High-tenacity power cable sheathing compound

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107964136A (en) * 2017-11-28 2018-04-27 安徽伟合电子科技有限公司 A kind of ageing-resistant cable for instrument of waterproof

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