CN107152251A - Emergency treatment method for hydrogen sulfide in under-balanced drilling fluid ground circulation system - Google Patents

Emergency treatment method for hydrogen sulfide in under-balanced drilling fluid ground circulation system Download PDF

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Publication number
CN107152251A
CN107152251A CN201710567444.7A CN201710567444A CN107152251A CN 107152251 A CN107152251 A CN 107152251A CN 201710567444 A CN201710567444 A CN 201710567444A CN 107152251 A CN107152251 A CN 107152251A
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China
Prior art keywords
drilling fluid
hydrogen sulfide
under
controlling system
solid controlling
Prior art date
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Pending
Application number
CN201710567444.7A
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Chinese (zh)
Inventor
羡维伟
韩烈祥
陈科旭
张鹏
潘登
任伟
郑冲涛
刘小玮
刘先明
程艳
孙翊成
何嵬
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CNPC Chuanqing Drilling Engineering Co Ltd
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CNPC Chuanqing Drilling Engineering Co Ltd
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Publication date
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Priority to CN201710567444.7A priority Critical patent/CN107152251A/en
Publication of CN107152251A publication Critical patent/CN107152251A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/063Arrangements for treating drilling fluids outside the borehole by separating components
    • E21B21/067Separating gases from drilling fluids
    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21BEARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
    • E21B21/00Methods or apparatus for flushing boreholes, e.g. by use of exhaust air from motor
    • E21B21/06Arrangements for treating drilling fluids outside the borehole
    • E21B21/068Arrangements for treating drilling fluids outside the borehole using chemical treatment

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  • Engineering & Computer Science (AREA)
  • Geology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Mining & Mineral Resources (AREA)
  • Physics & Mathematics (AREA)
  • Environmental & Geological Engineering (AREA)
  • Fluid Mechanics (AREA)
  • Mechanical Engineering (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses an emergency treatment method for hydrogen sulfide in an underbalanced drilling fluid ground circulation system, and relates to the technical field of oil drilling and well drilling processes. The invention carries out real-time monitoring on hydrogen sulfide in the drilling fluid returned in the well, controls the drilling fluid treatment control process when the ground separation system can not completely separate toxic and harmful gases by adding three emergency safety measures of a sulfur removal agent, bypass backflow and circulating reinjection, and can also carry out treatment by adopting the combination of various methods, thereby avoiding the harm to personnel and environment caused by the volatilization of the toxic and harmful gases such as hydrogen sulfide and the like to the atmosphere in the solid control system to the maximum extent.

Description

The emergency processing method of hydrogen sulfide in the circulatory system of Under-balanced drilling fluid ground
Technical field
The present invention relates to oil drilling drilling technology field, it is mainly used in being air more specifically to one kind The emergency processing method of hydrogen sulfide in the drilling fluid ground circulatory system in the closed under balance pressure drilling circulatory system of isolation.
Background technology
The conventional under balance pressure drilling technique drilling fluid ground circulatory system mainly include choke manifold, multiphase separator, The processing unit such as solid controlling system and circulating tank.Liquid-gas separator in the circulatory system mainly for separating of with drilling fluid from pit shaft The formation gas inside returned out, in sulfur-bearing formation, includes the gases such as natural gas and hydrogen sulfide.If in the ground circulatory system In, multiphase separator can not be totally separated from processing formation gas, will cause to be expelled in the drilling fluid of solid controlling system have vulcanization Operating personnel are damaged by the possibility of hydrogen effusion.If the non-complete hydrogen sulfide gas of separating treatment is excessive, also can be right Equipment and downhole tool in the circulatory system cause corrosion-damaged.Therefore, such as under-balance drilling operation need to be carried out in sulfur-bearing formation When, it is necessary to a kind of process is provided to the stink damp in the circulatory system of conventional under balance pressure drilling technique drilling fluid ground Body carries out preventing the emergency processing of effusion.
State Intellectual Property Office disclosed a Publication No. CN101525993A in September in 2009 9 days, entitled " to contain The patent of invention of the monitoring of hydrogen sulfide and control method in sulphur formation underbalanced drilling ", the patent of invention is drilling fluid through overstocked Testing hydrogen sulfide content in drilling fluid is monitored when closing sampler, and the hydrogen sulfide content signal monitored is inputted to control system System, the amount of sulfur elimination needed for control system is converted into simultaneously sends instruction, and sulfur elimination is to four-phase separator and makes in drilling fluid for injection Hydrogen sulfide and sulfur elimination react to remove residual hydrogen sulfide.
It is above-mentioned excessively to add sulfur elimination into drilling fluid in the prior art in the processing method of hydrogen sulfide, can be to boring The performance of well liquid material affects, therefore can produce certain limitation to the addition of sulfur elimination, and limits and remove After the addition of sulphur agent, the elimination effect and efficiency of hydrogen sulfide will be influenceed.
The content of the invention
In order to overcome defect present in above-mentioned prior art and deficiency, the invention provides a kind of Under-balanced drilling fluid The emergency processing method of hydrogen sulfide in the circulatory system of face, goal of the invention of the invention is intended to solve sulfur elimination in the prior art and added When entering amount and receiving limitation, to the further processing of hydrogen sulfide, the hydrogen sulfide not being kept completely separate is removed, it is to avoid hydrogen sulfide gas cut drilling well Liquid evaporates into the injury to personnel, equipment and environment in atmospheric environment at solid controlling system, prevents the generation of contingency, meets The demand of safety and environmental protection drilling well.
In order to solve above-mentioned problems of the prior art, the present invention is achieved through the following technical solutions:
The emergency processing method of hydrogen sulfide in the circulatory system of Under-balanced drilling fluid ground, will be returned out containing vulcanization out of well first The drilling fluid of hydrogen enters multiphase separator after decompression and carries out liquid qi leel from the drilling fluid after separation is drained into solid controlling system; Before drilling fluid enters solid controlling system or when entering solid controlling system, testing hydrogen sulfide content in drilling fluid is monitored, when monitoring When hydrogen sulfide content is above standard and can not continue to drain into solid controlling system, injection sulfur elimination makes drilling well into multiphase separator Hydrogen sulfide in liquid reacts with sulfur elimination;It is characterized in that:Using any one in following two kinds of processing methods or two kinds Combination drilling fluid is handled;
A, open multiphase separator tapping line top set pipe passage, will not separate clean drilling fluid again re-injection to multiphase Separator inlet carries out multi-cycle separation again;
B, multiphase separator is handled after do not separate clean drilling fluid directly around solid controlling system, be injected into well and followed Ring processing.
It is described not separate clean drilling fluid, specifically refer to, when sulfur elimination addition is restricted, through multiphase separator After middle sulfur elimination is reacted with hydrogen sulfide in drilling fluid, it is impossible to be fully apparent from clean hydrogen sulfide, also exist containing partial vulcanization hydrogen In drilling fluid.
The drilling fluid containing hydrogen sulfide enters multiphase separator after decompression, specifically refers to:Contain hydrogen sulfide Drilling fluid carries out decompression processing by choke manifold, and the choke manifold is entered by way of one or more levels series connection to drilling fluid Row decompression.
The drilling fluid containing hydrogen sulfide enters multiphase separator after decompression and carries out liquid qi leel from the gas after separation Body is handled by desulfurization with burning.
It is described that hydrogen sulfide in drilling fluid is monitored, specifically refer to, using H2S detector to the sulphur in drilling fluid Change hydrogen to be monitored.
The H2S detector is arranged on solid controlling system.
The solid controlling system at least includes vibratory sieve, desander and centrifuge.
The multiphase separator is four-phase separator.
Compared with prior art, the beneficial technique effect that the present invention is brought is shown:
1st, unique advantage of the invention is using medicament injection, bypassing reflux stream and circulation three kinds of emergent safety measures of re-injection Method handles control technique come drilling fluid when controlling the surface separation system to be not completely separated toxic and harmful gas, also may be used Handled with the combination using the methods at different levels mentioned in the present invention, the toxic and harmful gas such as hydrogen sulfide are avoided to greatest extent Air is evaporated into solid controlling system to personnel and environmental pollution.
2nd, compared with prior art, because an excess amount of addition of medicament causes the performance to drilling fluid materialses certain shadow Ring, therefore the application is when medicament addition receives limitation, can take the knot of bypassing reflux stream, circulation re-injection or two ways The mode of conjunction, is further handled the drilling fluid for remaining hydrogen sulfide, the mode of bypassing reflux stream, by untreated clean drilling fluid Circular treatment is carried out, the reaction time of sulfur elimination and hydrogen sulfide in the case where medicament addition is restricted, can be extended, prevented The sulfur elimination only retained is impacted to the performance of drilling fluid materialses.
3rd, it is that the gas flow returned out on stratum is excessive, all separation equipments can not be complete by the way of circulation re-injection Full processing, and in the case of circulation can not being stopped, after directly multiphase separator is handled not separate clean drilling fluid direct Solid controlling system is bypassed, is injected into well and carries out circular treatment, bypass solid controlling system, prevent the leakage of hydrogen sulfide in drilling fluid, most Limits avoid the toxic and harmful gas such as hydrogen sulfide from evaporating into air in solid controlling system to personnel and environmental pollution.
Brief description of the drawings
Fig. 1 is the process flow diagram of the inventive method;
Fig. 2 is the method flow schematic diagram of the different process demand of the present invention.
Embodiment
Embodiment 1
As a preferred embodiment of the present invention, with reference to Figure of description 1, present embodiment discloses:
The emergency processing method of hydrogen sulfide in the circulatory system of Under-balanced drilling fluid ground, will be returned out containing vulcanization out of well first The drilling fluid of hydrogen enters multiphase separator after decompression and carries out liquid qi leel from the drilling fluid after separation is drained into solid controlling system; Before drilling fluid enters solid controlling system or when entering solid controlling system, testing hydrogen sulfide content in drilling fluid is monitored, when monitoring When hydrogen sulfide content is above standard and can not continue to drain into solid controlling system, injection sulfur elimination makes drilling well into multiphase separator Hydrogen sulfide in liquid reacts with sulfur elimination;Drilling fluid is handled using following processing methods;Open multiphase separator discharge opeing Pipeline top set pipe passage, separating clean drilling fluid, re-injection to multiphase separator inlet is circulated again again Separation.
Embodiment 2
As another preferred embodiment of the present invention, with reference to Figure of description 1, present embodiment discloses:
The emergency processing method of hydrogen sulfide in the circulatory system of Under-balanced drilling fluid ground, will be returned out containing vulcanization out of well first The drilling fluid of hydrogen enters multiphase separator after decompression and carries out liquid qi leel from the drilling fluid after separation is drained into solid controlling system; Before drilling fluid enters solid controlling system or when entering solid controlling system, testing hydrogen sulfide content in drilling fluid is monitored, when monitoring When hydrogen sulfide content is above standard and can not continue to drain into solid controlling system, injection sulfur elimination makes drilling well into multiphase separator Hydrogen sulfide in liquid reacts with sulfur elimination;Drilling fluid is handled using following processing methods;After multiphase separator is handled Do not separate clean drilling fluid directly around solid controlling system, be injected into well and carry out circular treatment.
Embodiment 3
As another preferred embodiment of the present invention, with reference to Figure of description 1, present embodiment discloses:
The emergency processing method of hydrogen sulfide in the circulatory system of Under-balanced drilling fluid ground, will be returned out containing vulcanization out of well first The drilling fluid of hydrogen enters four-phase separator after decompression and carries out liquid qi leel from the drilling fluid after separation is drained into solid controlling system; Before drilling fluid enters solid controlling system or when entering solid controlling system, testing hydrogen sulfide content in drilling fluid is monitored, when monitoring When hydrogen sulfide content is above standard and can not continue to drain into solid controlling system, injection sulfur elimination makes drilling well into four-phase separator Hydrogen sulfide in liquid reacts with sulfur elimination;Drilling fluid is handled using following processing methods;Using following two kinds of processing sides The combination of method is handled drilling fluid;Four-phase separator tapping line top set pipe passage is opened, it is clean by not separating Re-injection to four-phase separator inlet carries out multi-cycle separation again to drilling fluid again;Not separating after four-phase separator is handled is dry Net drilling fluid is injected into well directly around solid controlling system and carries out circular treatment.
Embodiment 4
Embodiments of the invention are provided below in conjunction with the accompanying drawings:Sulfur-bearing formation fluid is returned out to ground well head 1 with drilling fluid from pit shaft Afterwards, it is depressured by choke manifold 2 and multiphase separator 4 carries out liquid qi leel from the gas after separation is by desulfurization 6 and burning 7 Processing, the drilling fluid after separation can rely on the pressure of separator 4 to be immediately discharged to solid controlling system 10 by opening valve 17, work as separation , can be by opening valve 18 during insufficient pressure in device 4, and open positive displacement pump 19 to discharge drilling fluid.Pacify on solid controlling system 10 Equipped with H2S detector 25, the testing hydrogen sulfide content in drilling fluid for draining into solid controlling system 10 can be monitored in real time.On multiphase separator 4 H2S detector 26 is installed, the content of hydrogen sulfide in drilling fluid in multiphase separator can be monitored in real time;When the vulcanization of monitoring When hydrogen content is above standard and can not drain into solid controlling system 10, it can be handled by emergency trouble shooting measures.It is to beat automatically first Chemicals dosing plant 9 and its valve 14 are opened, is entered by pump 13 to being automatically injected the related agents such as sulfur elimination at the inlet of multiphase separator 4 Row removes and is provided with ball-and-seat 15 on sulphuring treatment, filling line, it is to avoid drilling fluid enters chemicals dosing plant 9.It should be noted that due to Performance on drilling fluid materialses is caused certain influence by an excess amount of addition of medicament.Now, if medicament addition is restricted, The tapping line top set pipe passage of multiphase separator 4 is automatically opened up first, that is, is opened valve 20, will not be separated clean drilling well Re-injection to multiphase separator enters inlet and carries out being also equipped with ball-and-seat 16 on multi-cycle separation again, the re-injection pipeline liquid again, Prevent that drilling fluid is directly entered tapping line on pressure duct.If the gas flow that stratum is returned out is excessive, all separation equipments are equal It can not completely handle, circulation can not be stopped again, then close valve 22 and valve 23, valve 21,24 be opened, by multiphase separator The still drilling fluid containing gas after 4 processing is injected directly around solid controlling system 10 and ground circulating tank 11 by slush pump 12 Circular treatment is carried out in well, the hydrogen sulfide emergency handling process side in the circulatory system of Under-balanced drilling fluid ground is so far completed Method.
In the present invention, all valves, instrument, pump and equipment etc. can use centralized Control or other known ways It is controlled.Present invention omits the handling process for returning out such as landwaste, oil phase material of other in drilling fluid, but its hydrogen sulfide Emergency processing flow is all contained in protection scope of the present invention.If carrying out drilling well on the stratum of elevated pressures, the present invention can be with The method of two grades or multiple-stage separator separation is adopted as, its emergency processing method is similar with the method for single-stage separator, two fractions It is as shown in Figure 2 from the emergent separation method schematic flow sheet of device.It can also be entered using the combination for the methods at different levels mentioned in the present invention Row processing, above method is all contained within protection scope of the present invention.
The foregoing is only presently preferred embodiments of the present invention, be not intended to limit the present invention, all basic principles in the present invention it Interior, any modification, equivalent substitution and improvements made etc. should be included in the scope of the protection.

Claims (8)

1. the emergency processing method of hydrogen sulfide in the circulatory system of Under-balanced drilling fluid ground, contains sulphur by what is returned out out of well first The drilling fluid for changing hydrogen enters multiphase separator progress liquid qi leel from the drilling fluid after separation drains into solid controlling system after decompression In;Before drilling fluid enters solid controlling system or when entering solid controlling system, testing hydrogen sulfide content in drilling fluid is monitored, works as monitoring Hydrogen sulfide content when being above standard and can not continue to drain into solid controlling system, injection sulfur elimination makes brill into multiphase separator Hydrogen sulfide in well liquid reacts with sulfur elimination;It is characterized in that:Using any one in following two kinds of processing methods or two The combination planted is handled drilling fluid;
A, open multiphase separator tapping line top set pipe passage, will not separate clean drilling fluid again re-injection to multiphase Separator inlet carries out multi-cycle separation again;
B, multiphase separator is handled after do not separate clean drilling fluid directly around solid controlling system, be injected into well and followed Ring processing.
2. the emergency processing method of hydrogen sulfide, its feature in the circulatory system of Under-balanced drilling fluid ground as claimed in claim 1 It is:It is described not separate clean drilling fluid, specifically refer to, when sulfur elimination addition is restricted, through in multiphase separator After sulfur elimination is reacted with hydrogen sulfide in drilling fluid, it is impossible to be fully apparent from clean hydrogen sulfide, also bored containing partial vulcanization hydrogen In well liquid.
3. the emergency processing method of hydrogen sulfide, its feature in the circulatory system of Under-balanced drilling fluid ground as claimed in claim 1 It is:The drilling fluid containing hydrogen sulfide enters multiphase separator after decompression, specifically refers to:Drilling well containing hydrogen sulfide Liquid carries out decompression processing by choke manifold, and the choke manifold is dropped by way of one or more levels series connection to drilling fluid Pressure.
4. the emergency processing method of hydrogen sulfide in the Under-balanced drilling fluid ground circulatory system as described in claim 1 or 3, it is special Levy and be:The drilling fluid containing hydrogen sulfide enters multiphase separator after decompression and carries out liquid qi leel from the gas after separation Body is handled by desulfurization with burning.
5. the emergency processing method of hydrogen sulfide, its feature in the circulatory system of Under-balanced drilling fluid ground as claimed in claim 1 It is:It is described that hydrogen sulfide in drilling fluid is monitored, specifically refer to, using H2S detector to the hydrogen sulfide in drilling fluid It is monitored.
6. the emergency processing method of hydrogen sulfide, its feature in the circulatory system of Under-balanced drilling fluid ground as claimed in claim 5 It is:The H2S detector is arranged on solid controlling system.
7. the emergency processing side of hydrogen sulfide in the Under-balanced drilling fluid ground circulatory system as described in claim 1,2,3,5 or 6 Method, it is characterised in that:The solid controlling system at least includes vibratory sieve, desander and centrifuge.
8. the emergency processing side of hydrogen sulfide in the Under-balanced drilling fluid ground circulatory system as described in claim 1,2,3,5 or 6 Method, it is characterised in that:The multiphase separator is four-phase separator.
CN201710567444.7A 2017-07-12 2017-07-12 Emergency treatment method for hydrogen sulfide in under-balanced drilling fluid ground circulation system Pending CN107152251A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108005600A (en) * 2017-12-25 2018-05-08 中国石油集团川庆钻探工程有限公司 Vacuum type closed vibrating screen
CN108104745A (en) * 2017-12-25 2018-06-01 中国石油集团川庆钻探工程有限公司 Safe and environment-friendly closed circulation drilling ground operation method
CN108194041A (en) * 2017-12-25 2018-06-22 中国石油集团川庆钻探工程有限公司 Method for removing hydrogen sulfide gas in well drilling
CN108222869A (en) * 2017-12-25 2018-06-29 中国石油集团川庆钻探工程有限公司 Safe and environment-friendly closed under-balanced drilling ground operation method
WO2019079666A1 (en) * 2017-10-19 2019-04-25 Saudi Arabian Oil Company Systems and methods comprising smart sample catcher for drilling operations
CN113494289A (en) * 2020-03-18 2021-10-12 中国海洋石油集团有限公司 Oil gas drilling hydrogen sulfide invasion early monitoring device based on semiconductor current transformation

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CN101525993A (en) * 2009-03-18 2009-09-09 中国石油集团川庆钻探工程有限公司 Method for monitoring and controlling hydrogen sulfide in sulfur-bearing formation underbalanced drilling
CN103615208A (en) * 2013-11-11 2014-03-05 中国石油集团川庆钻探工程有限公司 Liquid inlet mechanism of four-phase separator for well drilling and control method
CN203603804U (en) * 2013-11-21 2014-05-21 西南石油大学 Drilling fluid dynamic sulphur removal effect monitoring device
US20140339178A1 (en) * 2006-09-29 2014-11-20 M-I, Llc Shaker and degasser combination
CN206064127U (en) * 2016-09-18 2017-04-05 中海油(天津)管道工程技术有限公司 A kind of reaction unit of hypergravity medicament cyclic absorption hydrogen sulfide

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Publication number Priority date Publication date Assignee Title
US20140339178A1 (en) * 2006-09-29 2014-11-20 M-I, Llc Shaker and degasser combination
CN101463713A (en) * 2009-01-13 2009-06-24 中国石油集团川庆钻探工程有限公司钻采工艺技术研究院 Drilling fluid circulating and separating method for sulfur-containing stratum under-balance drilling operation
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CN103615208A (en) * 2013-11-11 2014-03-05 中国石油集团川庆钻探工程有限公司 Liquid inlet mechanism of four-phase separator for well drilling and control method
CN203603804U (en) * 2013-11-21 2014-05-21 西南石油大学 Drilling fluid dynamic sulphur removal effect monitoring device
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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019079666A1 (en) * 2017-10-19 2019-04-25 Saudi Arabian Oil Company Systems and methods comprising smart sample catcher for drilling operations
US10478754B2 (en) 2017-10-19 2019-11-19 Saudi Arabian Oil Company Systems and methods comprising smart sample catcher for drilling operations
CN111247307A (en) * 2017-10-19 2020-06-05 沙特阿拉伯石油公司 System and method including intelligent sample trap for drilling operations
US10722819B2 (en) 2017-10-19 2020-07-28 Saudi Arabian Oil Company Systems and methods comprising smart sample catcher for drilling operations
CN111247307B (en) * 2017-10-19 2021-05-25 沙特阿拉伯石油公司 System and method including intelligent sample trap for drilling operations
CN108005600A (en) * 2017-12-25 2018-05-08 中国石油集团川庆钻探工程有限公司 Vacuum type closed vibrating screen
CN108104745A (en) * 2017-12-25 2018-06-01 中国石油集团川庆钻探工程有限公司 Safe and environment-friendly closed circulation drilling ground operation method
CN108194041A (en) * 2017-12-25 2018-06-22 中国石油集团川庆钻探工程有限公司 Method for removing hydrogen sulfide gas in well drilling
CN108222869A (en) * 2017-12-25 2018-06-29 中国石油集团川庆钻探工程有限公司 Safe and environment-friendly closed under-balanced drilling ground operation method
CN113494289A (en) * 2020-03-18 2021-10-12 中国海洋石油集团有限公司 Oil gas drilling hydrogen sulfide invasion early monitoring device based on semiconductor current transformation
CN113494289B (en) * 2020-03-18 2023-09-01 中国海洋石油集团有限公司 Oil gas drilling hydrogen sulfide invasion early monitoring device based on semiconductor current transformation

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Application publication date: 20170912