CN107151919A - Fire-retardant cord fabric of graphene and preparation method thereof - Google Patents
Fire-retardant cord fabric of graphene and preparation method thereof Download PDFInfo
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- CN107151919A CN107151919A CN201710464880.1A CN201710464880A CN107151919A CN 107151919 A CN107151919 A CN 107151919A CN 201710464880 A CN201710464880 A CN 201710464880A CN 107151919 A CN107151919 A CN 107151919A
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- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/41—Phenol-aldehyde or phenol-ketone resins
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
- D01F6/54—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polymers of unsaturated nitriles
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/90—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyamides
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/18—Synthetic fibres consisting of macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/26—Polymers or copolymers of unsaturated carboxylic acids or derivatives thereof
- D06M2101/28—Acrylonitrile; Methacrylonitrile
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
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- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/34—Polyamides
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
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- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
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Abstract
The present invention relates to fire-retardant cord fabric of a kind of graphene and preparation method thereof, shown cord fabric includes each component of following mass fraction：Graphene 0.5% -10%, section 80% -90%, dipping solution 5% -19.5%.Present invention graphene first is mixed with section, graphene composite fibre is made, the fire resistance and wearability of fiber in itself are improved, then twisted silk is made in composite fibre feeding straight twister, most the graphene cord fabric with good fire resistance is made into through Weaving-machine afterwards.This method preparation technology is simple to operation, with low cost, high financial profit, is adapted to large-scale industrial production.What the oxygen index (OI) of the graphene curtain cloth material of preparation more only changed latex system formulation or gum dipping process has very big lifting, while further improving its antistatic, wear resistance.
Description
Technical field
The present invention relates to cord fabric technical field of composite materials, specifically, be related to a kind of fire-retardant cord fabric of graphene and
Its preparation method.
Background technology
There is cord fabric good combination property to include chemical resistance, and higher case hardness, toughness in itself.
But its anti-flammability and anti-wear performance also need to further lifting, so as to strengthen the security in tire used.And it is traditional
Raising anti-flammability and wearability method to change latex system formulation or gum dipping process, process is complicated and changeable and produces effects not
Greatly, thus fiber fire resistance in itself is improved and wearability is only that the uneven inflammable and wear rate of solution cord fabric radiating is big etc. to ask
The key of topic.
Graphene is a kind of two-dimensional network structure for having carbon atom by hexagonal array, with excellent mechanical property
Can, electric conductivity and heat conductivility.Graphene oxide has carboxyl on the top layer of graphene, and epoxy radicals, hydroxyl etc. contains group
Stacking obtains more open between modification, each layer, in puffy.Simultaneous oxidation graphene is due to some oxygen-containing functional groups on surface
In the presence of, reduce its surface can, can have a good interfacial structure between organic polymer and inorganic filler, dispersiveness compared with
It is good, it is also easier to grafting.But graphene is added and improves its fire resistance in cord fabric and there are no any report.
The content of the invention
For the defect of prior art, it is an object of the invention to provide a kind of fire-retardant cord fabric of graphene and its preparation side
Method.By the compound obtained nano-composite fiber of section and graphene, the thermodynamic property of fiber in itself is improved, and then improve fiber
The performance such as fire-retardant, wear-resistant of cord fabric.
The purpose of the present invention is achieved through the following technical solutions：
The invention provides a kind of fire-retardant cord fabric of graphene, include each component of following mass fraction：
Graphene 0.5% -10%,
Section 80% -90%,
Dipping solution 5% -19.5%.
Preferably, the graphene is：Stone is peeled off in process for preparing graphenes by chemical vapour deposition, CO 2 supercritical expansion
Black alkene, the graphene oxide that chemical oxidation is peeled off, coupling agent modified graphene oxide, the modified oxidized stone of cationic surfactant
Black alkene, the graphene oxide that long-chain halogenated hydrocarbons is modified, the redox graphene of high-temperature heat expansion, obtained by low temperature thermal expansion also
Former graphene oxide, electrochemical stripping graphene, modified electrochemical stripping graphene, mechanical ball mill peels off graphene, three rollers
Grinding machinery peels off the one or more in graphene.
Preferably, described section is：Dacron polyester is cut into slices, PA sections, the one or several kinds in PAN sections.
Preferably, described dipping solution is：Solid content is 10% Resorcin-Formaldehyde-Latex (RFL).
Preferably, in the Resorcin-Formaldehyde-Latex, the mass ratio of formaldehyde and resorcinol is 1：(0.5-3).
Present invention also offers a kind of preparation method of the fire-retardant cord fabric of graphene, comprise the following steps：
A1, will section with graphene mixed at high speed, twin-screw extrusion, granulation；
A2, to through made from step A1 graphene composite master batch carry out spinning, then slow cooling be molded, oil, stretch and roll up
Around graphene nano composite fibre is made；
A3, twisted weave is made after twisted silk into graphene cord fabric in the graphene nano composite fibre；
A4, the graphene cord fabric for being made into step A3 immerse 2-8h in dipping solution, dry afterwards, drawing and setting, finally
Batched by storage cloth holder.
Preferably, in step A1, the mixed at high speed is specially：10000-20000 revs/min of rotating speed stirring 2-
8min；Mixed material particular diameter is 18-200 mesh.
Preferably, in step A2, the step of slow cooling is molded specifically uses annealing device, and slow cooling humidity 80% is side-blown
Wind 1-3m/s is cooled and shaped；The stretching is using to roller stretching, and the rotating speed to roller is 300-2500m/min.
Preferably, in step A2, the graphene composite master batch is carried out before spinning, need to through drying process, the drying
Temperature is 100-160 DEG C, and drying time 2-8 hour, dried graphene composite master batch water content is less than 50ppm.
Preferably, in step A3,130-160 DEG C of the drying temperature, setting temperature is 190-240 DEG C.
In the preparation method, if the scope of the parameter in each step is selected not within the above range, to obtained
The performance of cord fabric has undesirable effect.
Compared with prior art, the present invention has following beneficial effect：
Present invention graphene first is mixed with section, and graphene composite fibre is made, the anti-flammability of fiber in itself is improved
Energy and wearability, then twisted silk is made in composite fibre feeding straight twister, most it is made into afterwards through Weaving-machine with fire-retardant well
The graphene cord fabric of performance.This method preparation technology is simple to operation simultaneously, with low cost, high financial profit, is adapted to big rule
Mould industrialized production.The oxygen index (OI) of graphene curtain cloth material prepared by this method more only changes latex system formulation or impregnation work
Skill has very big lifting, while further improve its antistatic, wear resistance.
Embodiment
With reference to specific embodiment, the present invention is described in detail.Following examples will be helpful to the technology of this area
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that to the ordinary skill of this area
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection domain.
Following examples provide a kind of fire-retardant cord fabric of graphene, include each component of following mass fraction：
Graphene 0.5% -10%,
Section 80% -90%,
Dipping solution 5% -19.5%.
The graphene is：Graphene is peeled off in process for preparing graphenes by chemical vapour deposition, CO 2 supercritical expansion, is changed
The graphene oxide that oxidation is peeled off is learned, coupling agent modified graphene oxide, cationic surfactant modified graphene oxide is long
The graphene oxide that chain halogenated hydrocarbons is modified, the redox graphene of high-temperature heat expansion, the reduction-oxidation obtained by low temperature thermal expansion
Graphene, electrochemical stripping graphene, modified electrochemical stripping graphene, mechanical ball mill peels off graphene, three-roll grinder
Tool peels off the one or more in graphene.
Described section is：Dacron polyester is cut into slices, PA sections, the one or several kinds in PAN sections.
Described dipping solution is：Solid content is 10% Resorcin-Formaldehyde-Latex (RFL).
In the Resorcin-Formaldehyde-Latex, the volume ratio of formaldehyde and resorcinol is 1：(0.5-3).
Present invention also offers a kind of preparation method of the fire-retardant cord fabric of graphene, comprise the following steps：
A1, will section with graphene mixed at high speed, twin-screw extrusion, granulation；
A2, to through made from step A1 graphene composite master batch carry out spinning, then slow cooling be molded, oil, stretch and roll up
Around graphene nano composite fibre is made；
A3, twisted weave is made after twisted silk into graphene cord fabric in the graphene nano composite fibre；
A4, the graphene cord fabric for being made into step A3 immerse 2-8h in dipping solution, dry afterwards, drawing and setting, finally
Batched by storage cloth holder.
In step A1, the mixed at high speed is specially：10000-20000 revs/min of rotating speed stirring 2-8min；After mixing
Material particular diameter be 18-200 mesh.
In step A2, the step of slow cooling is molded specifically uses annealing device, slow cooling humidity 80%, cross air blasting 1-3m/s
It is cooled and shaped；The stretching is using to roller stretching, and the rotating speed to roller is 300-2500m/min.
In step A2, the graphene composite master batch is carried out before spinning, need to be through drying process, the temperature of the drying
100-160 DEG C, drying time 2-8 hour, dried graphene composite master batch water content is less than 50ppm.
In step A3,130-160 DEG C of the drying temperature, setting temperature is 190-240 DEG C.
Embodiment 1
A kind of fire-retardant cord fabric of graphene is present embodiments provided, includes each component of following mass fraction：Coupling agent changes
Property graphene oxide 2%, dacron polyester section 80%, dipping solution 17.5%.Described dipping solution is：Solid content be 10% between
The mass ratio of benzenediol-formaldehyde-latex, wherein formaldehyde and resorcinol is 1：1.
The preparation method concrete operation step of the fire-retardant cord fabric of graphene is as follows：
Step one：Section and graphene are dried, room temperature is subsequently cooled to, then carry out follow-up mixed at high speed step
Suddenly；The mode of mixed at high speed is 10000 revs/min of rotating speed stirring 2min, and the particle diameter of material is 100 mesh after mixing.
Step 2：Graphene-the composite master batch is dried after processing, feeding chamber is sent into, passes through screw extruder
Spinning is carried out into manifold, then by annealing device, cross air blasting is cooled and shaped, oiled, through to roller one, to roller two, to roller
Graphene-nano-composite fiber is made in three stretchings and last winding；Wherein, slow cooling humidity 80%, crosswind 1-3m/s, to roller one to
It is 300-2500m/min to the rotating speed of roller three.Drying temperature is 100-160 DEG C, drying time 2-8 hour, dried compound mother
Grain water content is less than 50ppm.
Step 3: composite fibre feeding straight twister is made into twisted silk, most graphene cord fabric is made into through Weaving-machine afterwards.
Step 4: the graphene cord fabric that twisted weave goes out is immersed into 6h in dipping solution, drying shed is sent into afterwards and is dried, temperature is dried
130-160 DEG C is spent, afterwards drawing and setting, setting temperature is 190-240 DEG C, finally batches obtained final graphene by storage cloth holder
Cord fabric composite.
Embodiment 2
A kind of fire-retardant cord fabric of graphene is present embodiments provided, includes each component of following mass fraction：High warm is swollen
Swollen redox graphene 5%, dacron polyester section 85%, dipping solution 10%.Described dipping solution is：Solid content is 10%
Resorcin-Formaldehyde-Latex, wherein the volume ratio of formaldehyde and resorcinol be 1：2.
The preparation method concrete operation step of the fire-retardant cord fabric of graphene is as follows：
Step one：Section and graphene are dried, room temperature is subsequently cooled to, then carry out follow-up mixed at high speed step
Suddenly；The mode of mixed at high speed is 20000 revs/min of rotating speed stirring 8min, and the particle diameter of material is 50 mesh after mixing.
Step 2：Graphene-the composite master batch is dried after processing, feeding chamber is sent into, passes through screw extruder
Spinning is carried out into manifold, then by annealing device, cross air blasting is cooled and shaped, oiled, through to roller one, to roller two, to roller
Graphene-nano-composite fiber is made in three stretchings and last winding；Wherein, slow cooling humidity 80%, crosswind 1-3m/s, to roller one to
It is 300-2500m/min to the rotating speed of roller three.Drying temperature is 100-160 DEG C, drying time 2-8 hour, dried compound mother
Grain water content is less than 50ppm.
Step 3: composite fibre feeding straight twister is made into twisted silk, most graphene cord fabric is made into through Weaving-machine afterwards.
Step 4: the graphene cord fabric that twisted weave goes out is immersed into 2h in dipping solution, drying shed is sent into afterwards and is dried, temperature is dried
130-160 DEG C is spent, afterwards drawing and setting, setting temperature is 190-240 DEG C, finally batches obtained final graphene by storage cloth holder
Cord fabric composite.
Embodiment 3
A kind of fire-retardant cord fabric of graphene is present embodiments provided, includes each component of following mass fraction：Chemical oxidation
The graphene oxide 10% of stripping, PAN sections 85%, dipping solution 5%.Described dipping solution is：Solid content is 10% isophthalic
The volume ratio of diphenol-formaldehyde-latex, wherein formaldehyde and resorcinol is 1：3.
The preparation method concrete operation step of the fire-retardant cord fabric of graphene is as follows：
Step one：Section and graphene are dried, room temperature is subsequently cooled to, then carry out follow-up mixed at high speed step
Suddenly；The mode of mixed at high speed is 20000 revs/min of rotating speed stirring 6min, and the particle diameter of material is 18-200 mesh after mixing.
Step 2：Graphene-the composite master batch is dried after processing, feeding chamber is sent into, passes through screw extruder
Spinning is carried out into manifold, then by annealing device, cross air blasting is cooled and shaped, oiled, through to roller one, to roller two, to roller
Graphene-nano-composite fiber is made in three stretchings and last winding；Wherein, slow cooling humidity 80%, crosswind 1-3m/s, to roller one to
It is 300-2500m/min to the rotating speed of roller three.Drying temperature is 100-160 DEG C, drying time 2-8 hour, dried compound mother
Grain water content is less than 50ppm.
Step 3: composite fibre feeding straight twister is made into twisted silk, most graphene cord fabric is made into through Weaving-machine afterwards.
Step 4: the graphene cord fabric that twisted weave goes out is immersed into 5h in dipping solution, drying shed is sent into afterwards and is dried, temperature is dried
130-160 DEG C is spent, afterwards drawing and setting, setting temperature is 190-240 DEG C, finally batches obtained final graphene by storage cloth holder
Cord fabric composite.
Embodiment 4
A kind of fire-retardant cord fabric of graphene is present embodiments provided, includes each component of following mass fraction：Carbon dioxide
Supercritical expansion peels off graphene 2%, PA sections 90%, dipping solution 8%.Described dipping solution is：Solid content be 10% between
The volume ratio of benzenediol-formaldehyde-latex, wherein formaldehyde and resorcinol is 1：0.5.
The preparation method concrete operation step of the fire-retardant cord fabric of graphene is as follows：
Step one：Section and graphene are dried, room temperature is subsequently cooled to, then carry out follow-up mixed at high speed step
Suddenly；The mode of mixed at high speed is 10000 revs/min of rotating speed stirring 2min, and the particle diameter of material is 18-200 mesh after mixing.
Step 2：Graphene-the composite master batch is dried after processing, feeding chamber is sent into, passes through screw extruder
Spinning is carried out into manifold, then by annealing device, cross air blasting is cooled and shaped, oiled, through to roller one, to roller two, to roller
Graphene-nano-composite fiber is made in three stretchings and last winding；Wherein, slow cooling humidity 80%, crosswind 1-3m/s, to roller one to
It is 300-2500m/min to the rotating speed of roller three.Drying temperature is 100-160 DEG C, drying time 2-8 hour, dried compound mother
Grain water content is less than 50ppm.
Step 3: composite fibre feeding straight twister is made into twisted silk, most graphene cord fabric is made into through Weaving-machine afterwards.
Step 4: the graphene cord fabric that twisted weave goes out is immersed into 6h in dipping solution, drying shed is sent into afterwards and is dried, temperature is dried
130-160 DEG C is spent, afterwards drawing and setting, setting temperature is 190-240 DEG C, finally batches obtained final graphene by storage cloth holder
Cord fabric composite.
Embodiment 5
A kind of fire-retardant cord fabric of graphene is present embodiments provided, includes each component of following mass fraction：Long-chain halo
The graphene oxide 2% that hydrocarbon is modified, PA sections 90%, dipping solution 8%.Described dipping solution is：Solid content is 10% isophthalic
The volume ratio of diphenol-formaldehyde-latex, wherein formaldehyde and resorcinol is 1：1.
The preparation method of the fire-retardant cord fabric of graphene is same as Example 1.
Embodiment 6
A kind of fire-retardant cord fabric of graphene is present embodiments provided, includes each component of following mass fraction：Coupling agent changes
Property graphene oxide 2%, dacron polyester section 80%, dipping solution 17.5%.Described dipping solution is：Solid content be 10% between
The mass ratio of benzenediol-formaldehyde-latex, wherein formaldehyde and resorcinol is 1：2.
The preparation method of the fire-retardant cord fabric of graphene is same as Example 1.
Comparative example 1
This comparative example provides a kind of fire-retardant cord fabric of graphene, and it is constituted and preparation method is substantially the same manner as Example 1,
It the difference is that only：The Resorcin-Formaldehyde-Latex that the dipping solution used in this comparative example is 15% for mass fraction.
Comparative example 2
This comparative example provides a kind of fire-retardant cord fabric of graphene, and it is constituted and preparation method is substantially the same manner as Example 1,
It the difference is that only：The Resorcin-Formaldehyde-Latex that the dipping solution used in this comparative example is 7.5% for mass fraction.
Performance test
The fire-retardant cord fabric of graphene prepared by each embodiment and comparative example carries out performance test, as a result as shown in table 1.
Table 1
As shown in Table 1, the result of comparative example is significantly worse than embodiment 1, illustrates that RFL solid content is too high or too low
The mechanical property and bonding force of cord fabric can be significantly affected.The effect of embodiment 1 is also better than other embodiment, illustrates using even
The mass ratio for joining resorcinol and formaldehyde in agent modified graphene oxide 2%, RFL is 1:When 1, can obtain optimum resistance combustion performance and
Mechanical property.
Concrete application approach of the present invention is a lot, and described above is only the preferred embodiment of the present invention.It should be pointed out that more than
Embodiment is merely to illustrate the present invention, and the protection domain being not intended to limit the invention.For the common skill of the art
For art personnel, under the premise without departing from the principles of the invention, some improvement can also be made, these improvement also should be regarded as this hair
Bright protection domain.
Claims (10)
1. a kind of fire-retardant cord fabric of graphene, it is characterised in that include each component of following mass fraction：
Graphene 0.5% -10%,
Section 80% -90%,
Dipping solution 5% -19.5%.
2. the fire-retardant cord fabric of graphene according to claim 1, it is characterised in that the graphene is：Chemical vapor deposition
Area method prepares graphene, and graphene is peeled off in CO 2 supercritical expansion, and the graphene oxide that chemical oxidation is peeled off, coupling agent changes
Property graphene oxide, cationic surfactant modified graphene oxide, long-chain halogenated hydrocarbons be modified graphene oxide, high warm
The redox graphene of expansion, the redox graphene obtained by low temperature thermal expansion, electrochemical stripping graphene, modified electricity
Chemical stripping graphene, mechanical ball mill peels off graphene, and three-roll grinder tool peels off the one or more in graphene.
3. the fire-retardant cord fabric of graphene according to claim 1, it is characterised in that described section is：Dacron polyester is cut
Piece, PA sections, the one or several kinds in PAN sections.
4. the fire-retardant cord fabric of graphene according to claim 1, it is characterised in that described dipping solution is：Solid content is
10% Resorcin-Formaldehyde-Latex.
5. the fire-retardant cord fabric of graphene according to claim 4, it is characterised in that the Resorcin-Formaldehyde-Latex
In, the mass ratio of formaldehyde and resorcinol is 1：(0.5-3).
6. a kind of preparation method of the fire-retardant cord fabric of graphene according to claim 1, it is characterised in that including following step
Suddenly：
A1, will section with graphene mixed at high speed, twin-screw extrusion, granulation；
A2, to through made from step A1 graphene composite master batch carry out spinning, then slow cooling be molded, oil, stretch and wind, i.e.,
Graphene nano composite fibre is made；
A3, twisted weave is made after twisted silk into graphene cord fabric in the graphene nano composite fibre；
A4, the graphene cord fabric for being made into step A3 immerse 2-8h in dipping solution, dry afterwards, drawing and setting, finally by storing up
Cloth holder is batched.
7. the preparation method of the fire-retardant cord fabric of graphene according to claim 6, it is characterised in that described in step A1
Mixed at high speed is specially：10000-20000 revs/min of rotating speed stirring 2-8min；Mixed material particular diameter is 18-200 mesh.
8. the preparation method of the fire-retardant cord fabric of graphene according to claim 6, it is characterised in that described in step A2
The step of slow cooling is molded specifically uses annealing device, and slow cooling humidity 80%, cross air blasting 1-3m/s is cooled and shaped；The stretching is used
To roller stretching, the rotating speed to roller is 300-2500m/min.
9. the preparation method of the fire-retardant cord fabric of graphene according to claim 6, it is characterised in that described in step A2
Graphene composite master batch is carried out before spinning, need to be through drying process, and the temperature of the drying is 100-160 DEG C, and drying time, 2-8 was small
When, dried graphene composite master batch water content is less than 50ppm.
10. the preparation method of the fire-retardant cord fabric of graphene according to claim 6, it is characterised in that described in step A3
130-160 DEG C of drying temperature, setting temperature is 190-240 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710464880.1A CN107151919A (en) | 2017-06-19 | 2017-06-19 | Fire-retardant cord fabric of graphene and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710464880.1A CN107151919A (en) | 2017-06-19 | 2017-06-19 | Fire-retardant cord fabric of graphene and preparation method thereof |
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| CN107151919A true CN107151919A (en) | 2017-09-12 |
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| CN201710464880.1A Pending CN107151919A (en) | 2017-06-19 | 2017-06-19 | Fire-retardant cord fabric of graphene and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109898173A (en) * | 2019-03-20 | 2019-06-18 | 江苏江山红化纤有限责任公司 | A kind of 6 fiber of colored polyamide and its production method |
| CN109898334A (en) * | 2019-03-21 | 2019-06-18 | 安徽工程大学 | A kind of thermally conductive dipped canvas and preparation method thereof |
| CN115584634A (en) * | 2022-10-25 | 2023-01-10 | 江阴市沙江纺织科技有限公司 | Environment-friendly impregnated cord fabric for tire and production process thereof |
| CN116988309A (en) * | 2023-08-01 | 2023-11-03 | 杭州帝凯工业布有限公司 | Antistatic flame-retardant nylon Long Lianzi cloth and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101269369A (en) * | 2008-04-25 | 2008-09-24 | 黎绍明 | Gelatinizing method for cord fabric and gelatinizing liquid |
| CN102199878A (en) * | 2011-04-12 | 2011-09-28 | 可隆（南京）特种纺织品有限公司 | Primary dip solution and dipping treatment method of polyester cord fabrics |
| CN105200547A (en) * | 2015-10-19 | 2015-12-30 | 沙嫣 | Preparation method of graphene-polyester nano-composite fiber |
-
2017
- 2017-06-19 CN CN201710464880.1A patent/CN107151919A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101269369A (en) * | 2008-04-25 | 2008-09-24 | 黎绍明 | Gelatinizing method for cord fabric and gelatinizing liquid |
| CN102199878A (en) * | 2011-04-12 | 2011-09-28 | 可隆（南京）特种纺织品有限公司 | Primary dip solution and dipping treatment method of polyester cord fabrics |
| CN105200547A (en) * | 2015-10-19 | 2015-12-30 | 沙嫣 | Preparation method of graphene-polyester nano-composite fiber |
Non-Patent Citations (1)
| Title |
|---|
| 郭怡: "《浸胶帘子布性能影响研究》", 30 April 2015, 国防工业出版社 * |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109898173A (en) * | 2019-03-20 | 2019-06-18 | 江苏江山红化纤有限责任公司 | A kind of 6 fiber of colored polyamide and its production method |
| CN109898334A (en) * | 2019-03-21 | 2019-06-18 | 安徽工程大学 | A kind of thermally conductive dipped canvas and preparation method thereof |
| CN109898334B (en) * | 2019-03-21 | 2021-05-04 | 安徽工程大学 | Heat-conducting impregnated canvas and preparation method thereof |
| CN115584634A (en) * | 2022-10-25 | 2023-01-10 | 江阴市沙江纺织科技有限公司 | Environment-friendly impregnated cord fabric for tire and production process thereof |
| CN115584634B (en) * | 2022-10-25 | 2024-01-19 | 江苏沙江化纤有限公司 | Environment-friendly dipped cord fabric for tire and production process thereof |
| CN116988309A (en) * | 2023-08-01 | 2023-11-03 | 杭州帝凯工业布有限公司 | Antistatic flame-retardant nylon Long Lianzi cloth and preparation method thereof |
| CN116988309B (en) * | 2023-08-01 | 2024-03-05 | 杭州帝凯工业布有限公司 | Antistatic flame-retardant nylon Long Lianzi cloth and preparation method thereof |
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