CN107151516A - A kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity - Google Patents
A kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity Download PDFInfo
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- CN107151516A CN107151516A CN201710534337.4A CN201710534337A CN107151516A CN 107151516 A CN107151516 A CN 107151516A CN 201710534337 A CN201710534337 A CN 201710534337A CN 107151516 A CN107151516 A CN 107151516A
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D167/00—Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/02—Monomers containing only one unsaturated aliphatic radical
- C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
- C08F212/06—Hydrocarbons
- C08F212/08—Styrene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/03—Powdery paints
- C09D5/033—Powdery paints characterised by the additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3045—Sulfates
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity, it is characterised in that including following components by weight percent raw material：Super-weatherable polyether resin 60 65%；TGIC curing agent 4.5 5%；Levelling agent 1 2%；Smooth degasifier 1 2%；Polymer builder 1 6%；Ultraviolet absorber 1 2%；Curing catalysts 0.2 0.5%；Color stuffing 18 31.3%.The coating of the present invention, which adds ultra-violet absorber, can improve the ageing resistance of film, and can not only improve the weatherability and cold resistance of coating, and can reduce processing temperature.
Description
Technical field
The invention belongs to technical field of coatings, it is related to a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity.
Background technology
Powdery paints, commonly referred to as boiled oil paint, are a kind of friendly products of environmental protection, can provide more multi items and more
Many colors.As a kind of solvent-free decoration and protective materials, powdery paints is excellent with its clean environment firendly, low energy consumption and low cost etc.
Put and be widely used in every field.The decoration and protection effect of powdery paints are constantly proposed more with the development people of society
High requirement, the exterior design of pursuit is more and more rich and varied, and this proposes new direction to powdery paints development.
Powdery paints transfer technique is, first by transfer printing wood grain powder paint on aluminium section bar, after film-forming, to stick
After woodgrained paper, by Thermal-printing Technology, the pattern of woodgrained paper is transferred on film, wood grain effect is clear, true to nature.It is clear to obtain
Clear transfer figure line, the general crosslink density of thermal transfer powdery paints is big, causes painting membrane rigidity strong but poor toughness, limits outdoor turn
Print application of the powdery paints on aftershaping aluminium section bar.
The content of the invention
It is an object of the invention to provide a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity, the coating is added
Ultra-violet absorber can improve the ageing resistance of film, and can not only improve the weatherability and cold resistance of coating, and
And processing temperature can be reduced.
The purpose of the present invention can be achieved through the following technical solutions：
A kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity, including following components by weight percent raw material：
Super-weatherable polyether resin 60-65%；
TGIC curing agent 4.5-5%；
Levelling agent 1-2%；
Smooth degasifier 1-2%；
Polymer builder 1-6%；
Ultraviolet absorber 1-2%；
Curing catalysts 0.2-0.5%；
Color stuffing 18-31.3%.
The super-weatherable polyether resinous acid value is 25-45mgKOH/g.
Preferably, the super-weatherable polyether resinous acid value is 28-38mgKOH/g.
The number-average molecular weight of the polymer builder is 4000-22000.
Preferably, the number-average molecular weight of the polymer builder is 5000-8000, and glass transition temperature is 50-80 DEG C.
The polymer builder is synthesized using free radical solution polymerization method, from acrylic acid trifluoro ethyl ester or the fluorine of acrylic acid five
Propyl ester, hydroxy-ethyl acrylate or hydroxypropyl acrylate, methoxy polyethylene glycol acrylate monomer, other vinyl monomer conducts
Reaction monomers, reaction solution, selection AMBN, peroxide are used as using one kind in benzene,toluene,xylene, the tert-butyl alcohol
Change the one or two of benzoyl, di t-amyl peroxide ethene as initiator, the consumption of initiator is monomer gross mass
1-5%.
The polymer builder is formed by following components through free radical solution polymerization：10-20wt% fluorinated acrylamide
Esters of gallic acid monomer, 8-15wt% hydroxy acrylic acid esters monomers, 5-20wt% long chain acrylate class monomers, 45-77wt% its
His vinyl monomer.
The consumption of the initiator is the 1-5% of four kinds of monomer gross mass.
The fluoroacrylate monomer is acrylic acid trifluoro ethyl ester, trifluoroethyl methacrylate, the fluorine of acrylic acid five
Propyl ester, the fluorine propyl ester of methacrylic acid five, methacrylic acid octafluoro pentyl ester, the fluorine nonyl ester of methacrylic acid 17, methacrylic acid ten
One kind in seven fluorine last of the ten Heavenly stems esters.
Preferably, the fluoroacrylate monomer is acrylic acid trifluoro ethyl ester or the fluorine propyl ester of acrylic acid five.
The hydroxy acrylic acid esters monomer is hydroxy-ethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, first
One kind in base hydroxypropyl acrylate, octyl hydroxystearate, 4- hydroxyl butyl propyleneglycol acid esters.
Preferably, the hydroxy acrylic acid esters monomer is hydroxy-ethyl acrylate or hydroxypropyl acrylate.
The long chain acrylate class monomer is methoxy polyethylene glycol acrylate monomer.
Other described vinyl monomers are one in esters of acrylic acid, methyl acrylic ester, Styrene and its derivatives
Kind.
A kind of preparation process of the extra-weather-proof thermal transfer printable powder paint compositions of high tenacity is：
Raw material are put into compounding jar together according to the ratio, are pre-mixed according to 5 minutes * 3 times, Ran Hou
Extrusion, tabletting on extruder, 100 DEG C of one area of extrusion temperature, two 110 DEG C of areas, then the broken progress of sheet stock is finely divided, coarse powder is led to
Overwinding sub-sieve crosses 200 mesh sieves and obtains 20-50 microns of fine powder for final powdery paints.
Beneficial effects of the present invention：
Resin part of the present invention using the super-weatherable polyether resin of specific acid number as powdery paints, is added by acrylic acid trifluoro
Ethyl ester or the fluorine propyl ester of acrylic acid five, hydroxy-ethyl acrylate or hydroxypropyl acrylate, methoxy polyethylene glycol acrylate monomer, its
His vinyl monomer is as reaction monomers, and the polymer builder synthesized using radical polymerization effectively improves powdery paints
Coating after the toughness of coating, curing transfer not only has a super-weathering resistance energy, and has fabulous toughness concurrently and relatively sharp
Figure line aesthetic property, it is adaptable to the high-grade application of aftershaping open air aluminium.
Certainly, any product for implementing the present invention it is not absolutely required to while reaching all the above advantage.
Embodiment
Embodiment 1
(1) by 10g acrylic acid trifluoro ethyl ester, 8g hydroxy-ethyl acrylate, 5g methoxy polyethylene glycol acrylate lists
Body, 75g styrene, 1g AMBN are made into monomer mixture.In the three-necked flask that 100g toluene is added to 500ml
And the stirring that heats up.When solvent refluxing, start that monomer mixture is added dropwise, drip within 2-2.5 hours, continue the insulation reaction that flows back
2h.Desolvation is concentrated under reduced pressure, temperature is no more than 170 DEG C, and blowing, cooling, coarse crushing while hot, obtained polymer is helped
Agent, Tg is 80 DEG C, number-average molecular weight 21200；
(2) the extra-weather-proof thermal transfer printable powder paint compositions of a kind of high tenacity, including following components by weight percent raw material：
Super-weatherable polyether resin 60%；
TGIC curing agent 4.5%；
Levelling agent 1%；
Smooth degasifier 1%；
Polymer builder 1%；
Ultraviolet absorber 1%；
Curing catalysts 0.2%；
Filler 20.8%；
Pigment 10.5%；
Super-weatherable polyether resin：Anhui Shenjian New Material Co.Ltd SJ4588；
Levelling agent：The PV88 of German moral letter profit chemistry；
Smooth degasifier：The six prompt sensible new material Co., Ltd SA500 of peace；
Ultraviolet absorber：German BASF405；
Curing catalysts：The six prompt sensible new material Co., Ltd K7318 of peace；
Blanc fixe：The blanc fixe of Shaanxi enrichment chemical industry Co., Ltd；
Titanium dioxide：Jiangsu Zhentai Chemical Industry Co., Ltd. ZR940+.
Raw material are put into according to aforementioned proportion together in compounding jar be pre-mixed → extruder extrusion → tabletting →
Crushing → sieving → finished product.
Comparative example 1
The preparation process be the same as Example 1 of the present embodiment powder paint compositions, the difference is that without polymer in being formulated
Auxiliary agent.
Embodiment 2
(1) by 15g the fluorine propyl ester of acrylic acid five, 12g hydroxypropyl acrylate, 13g methoxy polyethylene glycol acrylates
Monomer, 57g ethyl acrylate, 1g AMBN are made into monomer mixture.100g toluene is added three mouthfuls of 500ml
In flask and the stirring that heats up.When solvent refluxing, start that monomer mixture is added dropwise, drip within 2-2.5 hours, continue the insulation that flows back
React 2h.Desolvation is concentrated under reduced pressure, temperature is no more than 170 DEG C, and polymer is made in blowing, cooling, coarse crushing while hot
Auxiliary agent, Tg is 67 DEG C, number-average molecular weight 14500；
(2) the extra-weather-proof thermal transfer printable powder paint compositions of a kind of high tenacity, including following components by weight percent raw material：
Super-weatherable polyether resin 65%；
TGIC curing agent 5%；
Levelling agent 2%；
Smooth degasifier 2%；
Polymer builder 6%；
Ultraviolet absorber 2%；
Curing catalysts 0.5%；
Filler 11.8%；
Pigment 6.2%；
Super-weatherable polyether resin：Anhui Shenjian New Material Co.Ltd SJ4588；
Levelling agent：The PV88 of German moral letter profit chemistry；
Smooth degasifier：The six prompt sensible new material Co., Ltd SA500 of peace；
Ultraviolet absorber：German BASF405；
Curing catalysts：The six prompt sensible new material Co., Ltd K7318 of peace；
Blanc fixe：The blanc fixe of Shaanxi enrichment chemical industry Co., Ltd；
Titanium dioxide：Jiangsu Zhentai Chemical Industry Co., Ltd. ZR940+.
Raw material are put into according to aforementioned proportion together in compounding jar be pre-mixed → extruder extrusion → tabletting →
Crushing → sieving → finished product.
Comparative example 2
The preparation process be the same as Example 2 of the present embodiment, the difference is that without polymer builder in being formulated.
Embodiment 3
(1) by 15g acrylic acid trifluoro ethyl ester, 12g hydroxypropyl acrylate, 13g methoxy polyethylene glycol acrylates
Monomer, 57g EMA, 1g AMBN are made into monomer mixture.100g toluene is added 500ml's
In three-necked flask and the stirring that heats up.When solvent refluxing, start that monomer mixture is added dropwise, drip within 2-2.5 hours, continue to flow back
Insulation reaction 2h.Desolvation is concentrated under reduced pressure, temperature is no more than 170 DEG C, and blowing, cooling, coarse crushing while hot is made poly-
Compound auxiliary agent, Tg is 50 DEG C, number-average molecular weight 8300；
(2) the extra-weather-proof thermal transfer printable powder paint compositions of a kind of high tenacity, including following components by weight percent raw material：
Super-weatherable polyether resin 63%；
TGIC curing agent 4.8%；
Levelling agent 1.5%；
Smooth degasifier 1.5%；
Polymer builder 4%；
Ultraviolet absorber 1.5%；
Curing catalysts 0.4%；
Filler 15%；
Pigment 8.3%；
Super-weatherable polyether resin：Anhui Shenjian New Material Co.Ltd SJ4588；
Levelling agent：The PV88 of German moral letter profit chemistry；
Smooth degasifier：The six prompt sensible new material Co., Ltd SA500 of peace；
Ultraviolet absorber：German BASF405；
Curing catalysts：The six prompt sensible new material Co., Ltd K7318 of peace；
Blanc fixe：The blanc fixe of Shaanxi enrichment chemical industry Co., Ltd；
Titanium dioxide：Jiangsu Zhentai Chemical Industry Co., Ltd. ZR940+.
Raw material are put into according to aforementioned proportion together in compounding jar be pre-mixed → extruder extrusion → tabletting →
Crushing → sieving → finished product.
Comparative example 3
The preparation process be the same as Example 3 of the present embodiment, the difference is that without polymer builder in being formulated.
Spraying coating process comprises the following steps：
(1) powdery paints sprays to aluminium shape surface using high pressure electrostatic painting method；
(2) workpiece is put under the conditions of 200 DEG C and toasts 10min, be allowed to be fully cured；
(3) after after workpiece cooling, then by transfer paper with special thermal transfer glue even spread on a test piece
Cover and wipe smooth；
(4) workpiece after processing is put under 160 DEG C of baking conditions and toasts 5min；
(5) after cooling down, transfer paper of tearing, the powdery paints film after being transferred.
The various performance indications of film obtained by above-described embodiment and comparative example are tested, test result is as shown in table 1：
Table 1：The various performance indications of film obtained by embodiment and comparative example
Artificially roughening is carried out to above-mentioned film, test event is tested for QUB-V, test condition is 50 DEG C of UV light
According to 4 hours, 40 DEG C of Water, steam circulations were tested 4 hours, and test result is shown in Table 2：
Table 2：The relation of ginkgo seeds time and light-protection rate in embodiment and comparative example
Present invention disclosed above preferred embodiment is only intended to help and illustrates the present invention.Preferred embodiment is not detailed
All details of narration, it is only described embodiment that the invention is not limited yet.Obviously, according to the content of this specification,
It can make many modifications and variations.This specification is chosen and specifically describes these embodiments, is to preferably explain the present invention
Principle and practical application so that skilled artisan can be best understood by and utilize the present invention.The present invention is only
Limited by claims and its four corner and equivalent.
Claims (10)
1. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity, it is characterised in that including following components by weight percent raw material：
Super-weatherable polyether resin 60-65%；
TGIC curing agent 4.5-5%；
Levelling agent 1-2%；
Smooth degasifier 1-2%；
Polymer builder 1-6%；
Ultraviolet absorber 1-2%；
Curing catalysts 0.2-0.5%；
Color stuffing 18-31.3%.
2. according to a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity of root described in claim 1, it is characterised in that its
Preparation flow comprises the following steps：
Raw material are put into compounding jar together according to aforementioned proportion, are pre-mixed according to 5 minutes * 3 times, then in extrusion
Extrusion, tabletting on machine, 100 DEG C of one area of extrusion temperature, two 110 DEG C of areas, then the broken progress of sheet stock is finely divided, coarse powder is passed through into rotation
Sub-sieve crosses 200 mesh sieves and obtains 20-50 microns of fine powder for final powdery paints.
3. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
Super-weatherable polyether resinous acid value is stated for 25-45mgKOH/g.
4. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
Polymer builder is stated to be formed through free radical solution polymerization by following components：
10-20wt% fluoroacrylate monomer；
8-15wt% hydroxy acrylic acid esters monomers；
5-20wt% long chain acrylate class monomers；
Other vinyl monomers of 45-77wt%.
5. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
The number-average molecular weight for the polymer builder stated is 8000-22000, and glass transition temperature is 50-80 DEG C.
6. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
Fluoroacrylate monomer is stated for acrylic acid trifluoro ethyl ester, trifluoroethyl methacrylate, the fluorine propyl ester of acrylic acid five, methyl-prop
In the fluorine propyl ester of olefin(e) acid five, methacrylic acid octafluoro pentyl ester, the fluorine nonyl ester of methacrylic acid 17, the fluorine last of the ten Heavenly stems ester of methacrylic acid 17
It is a kind of.
7. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
Hydroxy acrylic acid esters monomer is stated for hydroxy-ethyl acrylate, hydroxypropyl acrylate, hydroxyethyl methacrylate, hydroxyethyl methacrylate
One kind in propyl ester, octyl hydroxystearate, 4- hydroxyl butyl propyleneglycol acid esters.
8. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
Long chain acrylate class monomer is stated for methoxy polyethylene glycol acrylate monomer.
9. a kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity according to claim 1, it is characterised in that institute
It is one kind in esters of acrylic acid, methyl acrylic ester, Styrene and its derivatives to state other vinyl monomers.
10. the extra-weather-proof thermal transfer printable powder paint compositions of a kind of high tenacity according to claim 1, it is characterised in that
The polymer builder is synthesized using free radical solution polymerization method, from acrylic acid trifluoro ethyl ester or the fluorine propyl ester of acrylic acid five, third
Olefin(e) acid hydroxyl ethyl ester or hydroxypropyl acrylate, methoxy polyethylene glycol acrylate monomer, other vinyl monomers are single as reaction
Body, reaction solution, selection AMBN, benzoyl peroxide first are used as using one kind in benzene,toluene,xylene, the tert-butyl alcohol
Acyl, the one or two of di t-amyl peroxide ethene are as initiator, and the consumption of initiator is the 1-5% of monomer gross mass.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201710534337.4A CN107151516A (en) | 2017-07-03 | 2017-07-03 | A kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity |
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| CN201710534337.4A CN107151516A (en) | 2017-07-03 | 2017-07-03 | A kind of extra-weather-proof thermal transfer printable powder paint compositions of high tenacity |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418395A (en) * | 2017-09-15 | 2017-12-01 | 立邦涂料（天津）有限公司 | A kind of transparent polyester type powdery paints, preparation method and applications |
| CN107603430A (en) * | 2017-09-20 | 2018-01-19 | 江南载福粉末涂料（张家港）有限公司 | A kind of thermal transfer powdery paints and preparation method thereof |
| CN109880492A (en) * | 2019-02-20 | 2019-06-14 | 六安科瑞达新型材料有限公司 | A kind of high tenacity scratch resistance powdery paints |
| CN110396355A (en) * | 2019-07-15 | 2019-11-01 | 江西睿智环保科技有限公司 | Extra-weather-proof 3D transfer printing wood grain powdery paints preparation method, coating and purposes |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106318144A (en) * | 2016-08-24 | 2017-01-11 | 六安科瑞达新型材料有限公司 | High-definition and paper-tearing wood grain powder paint for aluminium profile |
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2017
- 2017-07-03 CN CN201710534337.4A patent/CN107151516A/en active Pending
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106318144A (en) * | 2016-08-24 | 2017-01-11 | 六安科瑞达新型材料有限公司 | High-definition and paper-tearing wood grain powder paint for aluminium profile |
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| 代少俊等: "《涂料和黏合剂》", 31 August 2014, 江苏大学出版社 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107418395A (en) * | 2017-09-15 | 2017-12-01 | 立邦涂料（天津）有限公司 | A kind of transparent polyester type powdery paints, preparation method and applications |
| CN107418395B (en) * | 2017-09-15 | 2022-02-08 | 立邦涂料（天津）有限公司 | Transparent polyester type powder coating, preparation method and application thereof |
| CN107603430A (en) * | 2017-09-20 | 2018-01-19 | 江南载福粉末涂料（张家港）有限公司 | A kind of thermal transfer powdery paints and preparation method thereof |
| CN109880492A (en) * | 2019-02-20 | 2019-06-14 | 六安科瑞达新型材料有限公司 | A kind of high tenacity scratch resistance powdery paints |
| CN110396355A (en) * | 2019-07-15 | 2019-11-01 | 江西睿智环保科技有限公司 | Extra-weather-proof 3D transfer printing wood grain powdery paints preparation method, coating and purposes |
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Application publication date: 20170912 |