CN107151409A - Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof - Google Patents
Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof Download PDFInfo
- Publication number
- CN107151409A CN107151409A CN201710284764.1A CN201710284764A CN107151409A CN 107151409 A CN107151409 A CN 107151409A CN 201710284764 A CN201710284764 A CN 201710284764A CN 107151409 A CN107151409 A CN 107151409A
- Authority
- CN
- China
- Prior art keywords
- parts
- compound
- retardant
- ageing
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
- C08L27/18—Homopolymers or copolymers or tetrafluoroethene
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of fire-retardant and ageing-resistant CABLE MATERIALS, it is made up of following raw material：4 third fluorubber, maleic anhydride grafted ethene acetate copolymer, ethylene propylene diene rubber, gas-phase silica, mica powder, APP, boric acid melamine, nano zine oxide, dilauryl thiodipropionate, age resistor, antioxidant 1010, stearic acid monoglyceride, silane coupler, trioctyl trimellitate (TOTM), tetrabutyl titanate, turpentine oil, ultra-violet absorber.The invention also discloses the preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS.Fire-retardant and ageing-resistant CABLE MATERIALS prepared by the present invention combines the advantage of 4 third fluorubber, maleic anhydride grafted ethene acetate copolymer and ethylene propylene diene rubber, with good mechanical property, pass through reasonable adjusting component, with good flame retardant effect and antiageing effect, the service life of cable is extended, with wide market prospects.
Description
Technical field
The present invention relates to CABLE MATERIALS technical field, specifically a kind of fire-retardant and ageing-resistant CABLE MATERIALS and preparation method thereof.
Background technology
Wire cable insulating and sheath are commonly called as CABLE MATERIALS with plastics, and which includes a variety of product such as rubber, plastics, nylon
Kind.CABLE MATERIALS manufacturing enterprise is using cable manufacturing enterprise as user, as long as live wire cabling requirements just have the market of CABLE MATERIALS.Electricity
Insulating barrier mouthful is almost required in line cable product in addition to the bare wire product such as steel-cored aluminium strand, electromagnetic wire.Current China live wire
, there are upgrading urban and rural power grids, development of the West Regions and communications facility large area upgrading in nearly 5000 of cable manufacturing enterprise to electricity again
The great demand of line cable product, thus from the point of view of a period of time, CABLE MATERIALS has extensive market development prospect in China.
With expanding economy, market has more strict and multifarious requirement to the performance indications of CABLE MATERIALS.Constantly
The property indices of raising CABLE MATERIALS are the necessary process of social development with the demand for meeting Market Diversification.Traditional cable
There are poor flame retardant properties in material, not ageing-resistant defect, in use, influences the service life of electric wire, also easily draws
Ignition calamity.The good and ageing-resistant cable of market demand fire resistance.
The content of the invention
It is an object of the invention to provide a kind of fire-retardant and ageing-resistant CABLE MATERIALS and preparation method thereof, to solve the above-mentioned back of the body
The problem of being proposed in scape technology.
To achieve the above object, the present invention provides following technical scheme：
A kind of fire-retardant and ageing-resistant CABLE MATERIALS, is made up of the raw material below according to parts by weight：4 third 110-115 parts of fluorubber,
Maleic anhydride grafted ethene -23-27 parts of acetate copolymer, 40-45 parts of ethylene propylene diene rubber, 10-15 parts of gas-phase silica,
13-17 parts of mica powder, 9-13 parts of APP, 5-9 parts of boric acid melamine, 4-7 parts of nano zine oxide, thiodipropionic acid dilauryl
Ester 2-5 parts of osmanthus, 3-6 parts of age resistor, 5-10 parts of antioxidant 1010,10-14 parts of stearic acid monoglyceride, silane coupler 0.5-
1.0 parts, 1-2 parts of trioctyl trimellitate (TOTM), 2-5 parts of tetrabutyl titanate, 3-6 parts of turpentine oil, 2-3 parts of ultra-violet absorber.
It is used as further scheme of the invention：It is made up of the raw material below according to parts by weight：4 third fluorubber 111-114
Part, maleic anhydride grafted ethene -24-26 parts of acetate copolymer, 41-44 parts of ethylene propylene diene rubber, gas-phase silica 11-14
Part, 14-16 parts of mica powder, 10-12 parts of APP, 6-8 parts of boric acid melamine, 5-6 parts of nano zine oxide, thio-2 acid
3-4 parts of dilauryl, 4-5 parts of age resistor, 6-8 parts of antioxidant 1010,11-13 parts of stearic acid monoglyceride, silane coupler
0.6-0.9 parts, 1.3-1.7 parts of trioctyl trimellitate (TOTM), 3-4 parts of tetrabutyl titanate, 4-5 parts of turpentine oil, ultra-violet absorber
2.4-2.8 part.
It is used as further scheme of the invention：It is made up of the raw material below according to parts by weight：4 third 113 parts of fluorubber,
25 parts of maleic anhydride grafted ethene-acetate copolymer, 43 parts of ethylene propylene diene rubber, 12 parts of gas-phase silica, mica powder 15
Part, 11 parts of APP, 7 parts of boric acid melamine, 6 parts of nano zine oxide, 3 parts of dilauryl thiodipropionate, age resistor 4.5
Part, 7 parts of antioxidant 1010,12 parts of stearic acid monoglyceride, 0.8 part of silane coupler, 1.5 parts of trioctyl trimellitate (TOTM), titanic
Sour 4 parts of four butyl ester, 4.5 parts of turpentine oil, 2.6 parts of ultra-violet absorber.
It is used as further scheme of the invention：The age resistor is antioxidant NBC.
It is used as further scheme of the invention：The ultra-violet absorber is UV531.
The preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS, step is as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 450-500 DEG C is heated to, is incubated 2-3h, first is obtained and mixes
Material；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 800-1000 revs/min of lower sanded treatment 40-50min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 65-70 DEG C, by 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer throwing
Enter banburying 3-4min in banbury, banbury is warming up to 73-78 DEG C, and put into ethylene propylene diene rubber and gas-phase silica, after
Continuous banburying 5-6min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 4-5min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 6-8min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Compared with prior art, the beneficial effects of the invention are as follows：
Fire-retardant and ageing-resistant CABLE MATERIALS prepared by the present invention combines 4 third fluorubber, maleic anhydride grafted ethene-acetic acid second
The advantage of ester copolymer and ethylene propylene diene rubber, with good mechanical property, by reasonable adjusting component, with good resistance
Fuel efficiency fruit and antiageing effect, and by adding ultra-violet absorber, improve product crack resistance energy, extend the use of cable
Life-span, with wide market prospects.
Embodiment
Technical scheme is described in more detail with reference to embodiment.
Embodiment 1
A kind of fire-retardant and ageing-resistant CABLE MATERIALS, is made up of the raw material below according to parts by weight：4 third 110 parts of fluorubber, Malaysia
It is 23 parts of anhydride grafted ethylene-acetate copolymer, 40 parts of ethylene propylene diene rubber, 10 parts of gas-phase silica, 13 parts of mica powder, poly-
9 parts of ammonium phosphate, 5 parts of boric acid melamine, 4 parts of nano zine oxide, 2 parts of dilauryl thiodipropionate, 3 parts of age resistor, antioxygen
1,010 5 parts of agent, 10 parts of stearic acid monoglyceride, 0.5 part of silane coupler, 1 part of trioctyl trimellitate (TOTM), tetrabutyl titanate 2
Part, 3 parts of turpentine oil, 2 parts of ultra-violet absorber.Wherein, the age resistor is antioxidant NBC, and the ultra-violet absorber is
UV531。
In the present embodiment, the preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS, step is as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 450 DEG C is heated to, is incubated 2h, obtain the first compound；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 800 revs/min of lower sanded treatment 40min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 65 DEG C, 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer input are close
Banburying 3min in mill, 73 DEG C are warming up to by banbury, and put into ethylene propylene diene rubber and gas-phase silica, continue banburying
5min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 4min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 6min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Embodiment 2
A kind of fire-retardant and ageing-resistant CABLE MATERIALS, is made up of the raw material below according to parts by weight：4 third 111 parts of fluorubber, Malaysia
It is 24 parts of anhydride grafted ethylene-acetate copolymer, 41 parts of ethylene propylene diene rubber, 14 parts of gas-phase silica, 16 parts of mica powder, poly-
12 parts of ammonium phosphate, 6 parts of boric acid melamine, 5 parts of nano zine oxide, 3 parts of dilauryl thiodipropionate, 4 parts of age resistor, antioxygen
1,010 8 parts of agent, 13 parts of stearic acid monoglyceride, 0.9 part of silane coupler, 1.7 parts of trioctyl trimellitate (TOTM), the fourth of positive metatitanic acid four
3 parts of ester, 4 parts of turpentine oil, 2.8 parts of ultra-violet absorber.Wherein, the age resistor is antioxidant NBC, the ultra-violet absorber
For UV531.
In the present embodiment, the preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS, step is as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 460 DEG C is heated to, is incubated 2h, obtain the first compound；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 850 revs/min of lower sanded treatment 43min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 67 DEG C, 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer input are close
Banburying 3min in mill, 74 DEG C are warming up to by banbury, and put into ethylene propylene diene rubber and gas-phase silica, continue banburying
5min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 4min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 6min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Embodiment 3
A kind of fire-retardant and ageing-resistant CABLE MATERIALS, is made up of the raw material below according to parts by weight：4 third 113 parts of fluorubber, Malaysia
It is 25 parts of anhydride grafted ethylene-acetate copolymer, 43 parts of ethylene propylene diene rubber, 12 parts of gas-phase silica, 15 parts of mica powder, poly-
It is 11 parts of ammonium phosphate, 7 parts of boric acid melamine, 6 parts of nano zine oxide, 3 parts of dilauryl thiodipropionate, 4.5 parts of age resistor, anti-
1,010 7 parts of oxygen agent, 12 parts of stearic acid monoglyceride, 0.8 part of silane coupler, 1.5 parts of trioctyl trimellitate (TOTM), positive metatitanic acid four
4 parts of butyl ester, 4.5 parts of turpentine oil, 2.6 parts of ultra-violet absorber.Wherein, the age resistor is antioxidant NBC, and the ultraviolet is inhaled
Receipts agent is UV531.
In the present embodiment, the preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS, step is as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 480 DEG C is heated to, is incubated 2.5h, obtain the first compound；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 900 revs/min of lower sanded treatment 45min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 68 DEG C, 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer input are close
Banburying 3.5min in mill, 75 DEG C are warming up to by banbury, and put into ethylene propylene diene rubber and gas-phase silica, continue banburying
5.5min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 4.5min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 7min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Embodiment 4
A kind of fire-retardant and ageing-resistant CABLE MATERIALS, is made up of the raw material below according to parts by weight：4 third 114 parts of fluorubber, Malaysia
It is 26 parts of anhydride grafted ethylene-acetate copolymer, 44 parts of ethylene propylene diene rubber, 11 parts of gas-phase silica, 14 parts of mica powder, poly-
10 parts of ammonium phosphate, 8 parts of boric acid melamine, 6 parts of nano zine oxide, 4 parts of dilauryl thiodipropionate, 5 parts of age resistor, antioxygen
1,010 6 parts of agent, 11 parts of stearic acid monoglyceride, 0.6 part of silane coupler, 1.3 parts of trioctyl trimellitate (TOTM), the fourth of positive metatitanic acid four
4 parts of ester, 5 parts of turpentine oil, 2.4 parts of ultra-violet absorber.Wherein, the age resistor is antioxidant NBC, the ultra-violet absorber
For UV531.
In the present embodiment, the preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS, step is as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 490 DEG C is heated to, is incubated 2.5h, obtain the first compound；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 900 revs/min of lower sanded treatment 50min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 68 DEG C, 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer input are close
Banburying 4min in mill, 76 DEG C are warming up to by banbury, and put into ethylene propylene diene rubber and gas-phase silica, continue banburying
5.5min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 4min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 7min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Embodiment 5
A kind of fire-retardant and ageing-resistant CABLE MATERIALS, is made up of the raw material below according to parts by weight：4 third 115 parts of fluorubber, Malaysia
It is 27 parts of anhydride grafted ethylene-acetate copolymer, 45 parts of ethylene propylene diene rubber, 15 parts of gas-phase silica, 17 parts of mica powder, poly-
13 parts of ammonium phosphate, 9 parts of boric acid melamine, 7 parts of nano zine oxide, 5 parts of dilauryl thiodipropionate, 6 parts of age resistor, antioxygen
1,010 10 parts of agent, 14 parts of stearic acid monoglyceride, 1.0 parts of silane coupler, 2 parts of trioctyl trimellitate (TOTM), tetrabutyl titanate
5 parts, 6 parts of turpentine oil, 3 parts of ultra-violet absorber.Wherein, the age resistor is antioxidant NBC, and the ultra-violet absorber is
UV531。
In the present embodiment, the preparation method of described fire-retardant and ageing-resistant CABLE MATERIALS, step is as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 500 DEG C is heated to, is incubated 3h, obtain the first compound；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 1000 revs/min of lower sanded treatment 50min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 70 DEG C, 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer input are close
Banburying 4min in mill, 78 DEG C are warming up to by banbury, and put into ethylene propylene diene rubber and gas-phase silica, continue banburying
6min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 5min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 8min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Fire-retardant and ageing-resistant CABLE MATERIALS prepared by the present invention combines 4 third fluorubber, maleic anhydride grafted ethene-vinegar
The advantage of acetoacetic ester copolymer and ethylene propylene diene rubber, with good mechanical property, by reasonable adjusting component, with good
Flame retardant effect and antiageing effect, and by adding ultra-violet absorber, improve product crack resistance energy, extend cable
Service life, with wide market prospects.
The better embodiment to the present invention is explained in detail above, but the present invention is not limited to above-mentioned embodiment party
, can also be on the premise of present inventive concept not be departed from formula, the knowledge that one skilled in the relevant art possesses
Various changes can be made.
Claims (6)
1. a kind of fire-retardant and ageing-resistant CABLE MATERIALS, it is characterised in that be made up of the raw material below according to parts by weight：4 third fluorine rubbers
110-115 parts of glue, maleic anhydride grafted ethene -23-27 parts of acetate copolymer, 40-45 parts of ethylene propylene diene rubber, gas phase are white
10-15 parts of carbon black, 13-17 parts of mica powder, 9-13 parts of APP, 5-9 parts of boric acid melamine, 4-7 parts of nano zine oxide, sulphur
For 2-5 parts of dipropionic acid dilauryl, 3-6 parts of age resistor, 5-10 parts of antioxidant 1010,10-14 parts of stearic acid monoglyceride, silicon
0.5-1.0 parts of alkane coupling agent, 1-2 parts of trioctyl trimellitate (TOTM), 2-5 parts of tetrabutyl titanate, 3-6 parts of turpentine oil, ultraviolet are inhaled
Receive 2-3 parts of agent.
2. according to claim 1 fire-retardant and ageing-resistant CABLE MATERIALS, it is characterised in that by below according to the original of parts by weight
Material composition：4 third 111-114 parts of fluorubber, maleic anhydride grafted ethene -24-26 parts of acetate copolymer, ethylene-propylene-diene monomer
41-44 parts of glue, 11-14 parts of gas-phase silica, 14-16 parts of mica powder, 10-12 parts of APP, 6-8 parts of boric acid melamine,
5-6 parts of nano zine oxide, 3-4 parts of dilauryl thiodipropionate, 4-5 parts of age resistor, 6-8 parts of antioxidant 1010, stearic acid list
11-13 parts of glyceride, 0.6-0.9 parts of silane coupler, 1.3-1.7 parts of trioctyl trimellitate (TOTM), 3-4 parts of tetrabutyl titanate,
4-5 parts of turpentine oil, 2.4-2.8 parts of ultra-violet absorber.
3. according to claim 2 fire-retardant and ageing-resistant CABLE MATERIALS, it is characterised in that by below according to the original of parts by weight
Material composition：4 third 113 parts of fluorubber, 25 parts of maleic anhydride grafted ethene-acetate copolymer, 43 parts of ethylene propylene diene rubber,
12 parts of gas-phase silica, 15 parts of mica powder, 11 parts of APP, 7 parts of boric acid melamine, 6 parts of nano zine oxide, thio dipropyl
Sour 3 parts of dilauryl, 4.5 parts of age resistor, 7 parts of antioxidant 1010,12 parts of stearic acid monoglyceride, 0.8 part of silane coupler,
1.5 parts of trioctyl trimellitate (TOTM), 4 parts of tetrabutyl titanate, 4.5 parts of turpentine oil, 2.6 parts of ultra-violet absorber.
4. according to claim 1 fire-retardant and ageing-resistant CABLE MATERIALS, it is characterised in that the age resistor is age resistor
NBC。
5. according to claim 1 fire-retardant and ageing-resistant CABLE MATERIALS, it is characterised in that the ultra-violet absorber is
UV531。
6. a kind of preparation method of fire-retardant and ageing-resistant CABLE MATERIALS as described in claim 1-5 is any, it is characterised in that step
It is rapid as follows：
1）Mica powder and nano zine oxide are weighed, after being well mixed, 450-500 DEG C is heated to, is incubated 2-3h, first is obtained and mixes
Material；
2）APP, boric acid melamine and stearic acid monoglyceride are weighed, adds into the first compound, is put into sand mill
In, in 800-1000 revs/min of lower sanded treatment 40-50min, obtain the second compound；
3）Weigh 4 third fluorubber, maleic anhydride grafted ethene-acetate copolymer, ethylene propylene diene rubber and gas phase hard charcoal
It is black, open banbury and be preheated to 65-70 DEG C, by 4 third fluorubber and maleic anhydride grafted ethene-acetate copolymer throwing
Enter banburying 3-4min in banbury, banbury is warming up to 73-78 DEG C, and put into ethylene propylene diene rubber and gas-phase silica, after
Continuous banburying 5-6min, obtains compound A；
4）Weigh dilauryl thiodipropionate, age resistor, antioxidant 1010, silane coupler, trioctyl trimellitate (TOTM), titanic
Sour four butyl esters, turpentine oil and ultra-violet absorber, put into compound A, continue mixing process 4-5min, obtain compound B；
5）Second compound is put into compound B, continues mixing process 6-8min, compound C is obtained；
6）Compound C is put into extruding pelletization in double screw extruder, dried, you can.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710284764.1A CN107151409A (en) | 2017-04-27 | 2017-04-27 | Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710284764.1A CN107151409A (en) | 2017-04-27 | 2017-04-27 | Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107151409A true CN107151409A (en) | 2017-09-12 |
Family
ID=59793569
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710284764.1A Pending CN107151409A (en) | 2017-04-27 | 2017-04-27 | Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107151409A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652596A (en) * | 2017-10-27 | 2018-02-02 | 安徽嘉中金属材料有限公司 | A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof |
| CN108219505A (en) * | 2017-12-15 | 2018-06-29 | 安徽嘉中金属材料有限公司 | A kind of building cable material of heat-resisting ageing-resisting and preparation method thereof |
| CN108822351A (en) * | 2018-07-02 | 2018-11-16 | 芜湖航天特种电缆厂股份有限公司 | Wear-resisting water-proof cable gum cover and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280151A (en) * | 2016-08-30 | 2017-01-04 | 安徽蓝德集团股份有限公司 | A kind of power cable ageing-resistant waterproof protective cover material |
| CN106380759A (en) * | 2016-08-30 | 2017-02-08 | 安徽蓝德集团股份有限公司 | Waterproof sheath material for control cable |
| CN106432992A (en) * | 2016-08-30 | 2017-02-22 | 安徽蓝德集团股份有限公司 | Waterproof control cable sheathing material with good elasticity |
| CN106519521A (en) * | 2016-11-18 | 2017-03-22 | 广西大学 | Waterproof flame-retardant cable material and preparation method thereof |
-
2017
- 2017-04-27 CN CN201710284764.1A patent/CN107151409A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106280151A (en) * | 2016-08-30 | 2017-01-04 | 安徽蓝德集团股份有限公司 | A kind of power cable ageing-resistant waterproof protective cover material |
| CN106380759A (en) * | 2016-08-30 | 2017-02-08 | 安徽蓝德集团股份有限公司 | Waterproof sheath material for control cable |
| CN106432992A (en) * | 2016-08-30 | 2017-02-22 | 安徽蓝德集团股份有限公司 | Waterproof control cable sheathing material with good elasticity |
| CN106519521A (en) * | 2016-11-18 | 2017-03-22 | 广西大学 | Waterproof flame-retardant cable material and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107652596A (en) * | 2017-10-27 | 2018-02-02 | 安徽嘉中金属材料有限公司 | A kind of fire-resistant cable material of high temperature resistant cracking resistance and preparation method thereof |
| CN108219505A (en) * | 2017-12-15 | 2018-06-29 | 安徽嘉中金属材料有限公司 | A kind of building cable material of heat-resisting ageing-resisting and preparation method thereof |
| CN108822351A (en) * | 2018-07-02 | 2018-11-16 | 芜湖航天特种电缆厂股份有限公司 | Wear-resisting water-proof cable gum cover and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN107151409A (en) | Fire-retardant and ageing-resistant a kind of CABLE MATERIALS and preparation method thereof | |
| CN101885873B (en) | Semi-conductive ethylene vinyl acetate (EVA) plastic for shielding and production method thereof | |
| CN105330990B (en) | Insulating materials for new-energy automobile charging pile cable and preparation method thereof | |
| WO2021114756A1 (en) | Color polyethylene cable material cross-linked by led ultraviolet light, and preparation method therefor | |
| CN105131413B (en) | High-strength high temperature-resistant silanes crosslinked cable semiconductive shieldin material and preparation method thereof | |
| CN105139939A (en) | High-strength ageing-resistant cable | |
| CN104629135A (en) | Modified chlorosulfonated polyethylene cable sheath material | |
| CN107698906A (en) | Undersea detection steady phase high-strength composite cable and preparation method thereof | |
| CN110256956B (en) | Primer for silicon rubber and preparation method thereof | |
| CN106280137A (en) | A kind of cracking resistance heatproof composite cable material and preparation method thereof | |
| CN105367869B (en) | A kind of antifouling work super-pressure insulating materials and preparation method thereof | |
| CN107057244A (en) | Ageing-resistant and fire-retardant a kind of CABLE MATERIALS and preparation method thereof | |
| CN112280303A (en) | External insulation curing material for live working robot and preparation method thereof | |
| CN107857959A (en) | Undersea detection high-strength composite cable and preparation method thereof | |
| CN106398221A (en) | Silicon rubber cable sheath | |
| CN105348617A (en) | Polyolefin cable material for low-smoke halogen-free middle-high-voltage direct current cable and preparation method | |
| CN107383713A (en) | Undersea detection high-strength composite rubber and preparation method thereof | |
| CN109762216A (en) | A kind of fire-resistant corrosion-resistant rubber | |
| CN104311917A (en) | Impact-resistant anti-aging cable material and preparation method thereof | |
| CN104844894A (en) | Shell powder-containing silicone crosslinked polyethylene cable material and manufacturing method thereof | |
| CN107513241A (en) | Undersea detection high-strength composite cable seal sheath and preparation method thereof | |
| CN108976546A (en) | A kind of cable general shield layer material | |
| CN112521675B (en) | Insulating cold-resistant cable material and preparation method and application thereof | |
| CN104829909A (en) | High-temperature-resistant high-strength silane crosslinked polyethylene cable material and preparation method therefor | |
| CN107652685A (en) | A kind of heat-resisting age inhibiting cable protective case and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20170912 |
|
| WD01 | Invention patent application deemed withdrawn after publication |