CN107142725A - A kind of fabric antimicrobial finishing agent and preparation method thereof - Google Patents
A kind of fabric antimicrobial finishing agent and preparation method thereof Download PDFInfo
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- CN107142725A CN107142725A CN201710504864.0A CN201710504864A CN107142725A CN 107142725 A CN107142725 A CN 107142725A CN 201710504864 A CN201710504864 A CN 201710504864A CN 107142725 A CN107142725 A CN 107142725A
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- antimicrobial finishing
- fabric antimicrobial
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- 239000004744 fabric Substances 0.000 title claims abstract description 57
- 230000000845 anti-microbial effect Effects 0.000 title claims abstract description 35
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 40
- 240000002505 Pogostemon cablin Species 0.000 claims abstract description 27
- 235000011751 Pogostemon cablin Nutrition 0.000 claims abstract description 27
- 239000002202 Polyethylene glycol Substances 0.000 claims abstract description 20
- 229920001223 polyethylene glycol Polymers 0.000 claims abstract description 20
- 229920001661 Chitosan Polymers 0.000 claims abstract description 19
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 16
- 150000002603 lanthanum Chemical class 0.000 claims abstract description 11
- 229910052746 lanthanum Inorganic materials 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims description 8
- RRAFCDWBNXTKKO-UHFFFAOYSA-N eugenol Chemical compound COC1=CC(CC=C)=CC=C1O RRAFCDWBNXTKKO-UHFFFAOYSA-N 0.000 claims description 4
- MRELNEQAGSRDBK-UHFFFAOYSA-N lanthanum(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[La+3].[La+3] MRELNEQAGSRDBK-UHFFFAOYSA-N 0.000 claims description 4
- ICAKDTKJOYSXGC-UHFFFAOYSA-K lanthanum(iii) chloride Chemical group Cl[La](Cl)Cl ICAKDTKJOYSXGC-UHFFFAOYSA-K 0.000 claims description 4
- 238000003756 stirring Methods 0.000 claims description 4
- NPBVQXIMTZKSBA-UHFFFAOYSA-N Chavibetol Natural products COC1=CC=C(CC=C)C=C1O NPBVQXIMTZKSBA-UHFFFAOYSA-N 0.000 claims description 2
- 239000005770 Eugenol Substances 0.000 claims description 2
- UVMRYBDEERADNV-UHFFFAOYSA-N Pseudoeugenol Natural products COC1=CC(C(C)=C)=CC=C1O UVMRYBDEERADNV-UHFFFAOYSA-N 0.000 claims description 2
- 230000006196 deacetylation Effects 0.000 claims description 2
- 238000003381 deacetylation reaction Methods 0.000 claims description 2
- 229960002217 eugenol Drugs 0.000 claims description 2
- CSKINCSXMLCMAR-ZETOZRRWSA-N patchoulene Chemical compound C1[C@@H](C2(C)C)CC[C@@]2(C)C2=C1[C@H](C)CC2 CSKINCSXMLCMAR-ZETOZRRWSA-N 0.000 claims description 2
- 229940068918 polyethylene glycol 400 Drugs 0.000 claims description 2
- USDOQCCMRDNVAH-UHFFFAOYSA-N sigma-cadinene Natural products C1C=C(C)CC2C(C(C)C)CC=C(C)C21 USDOQCCMRDNVAH-UHFFFAOYSA-N 0.000 claims description 2
- USDOQCCMRDNVAH-KKUMJFAQSA-N β-cadinene Chemical compound C1C=C(C)C[C@H]2[C@H](C(C)C)CC=C(C)[C@@H]21 USDOQCCMRDNVAH-KKUMJFAQSA-N 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 3
- 241000196324 Embryophyta Species 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims 1
- 229960003511 macrogol Drugs 0.000 claims 1
- FGIUAXJPYTZDNR-UHFFFAOYSA-N potassium nitrate Chemical compound [K+].[O-][N+]([O-])=O FGIUAXJPYTZDNR-UHFFFAOYSA-N 0.000 claims 1
- 230000003115 biocidal effect Effects 0.000 abstract description 11
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 8
- 229910052761 rare earth metal Inorganic materials 0.000 abstract description 7
- 241000588724 Escherichia coli Species 0.000 abstract description 2
- 241000191967 Staphylococcus aureus Species 0.000 abstract description 2
- 239000003899 bactericide agent Substances 0.000 abstract description 2
- 238000009988 textile finishing Methods 0.000 abstract 1
- 150000002628 limonene derivativess Chemical class 0.000 description 9
- -1 rare earth ion Chemical class 0.000 description 9
- 210000002268 wool Anatomy 0.000 description 7
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 5
- 210000004556 brain Anatomy 0.000 description 5
- 239000008159 sesame oil Substances 0.000 description 5
- 235000011803 sesame oil Nutrition 0.000 description 5
- 244000166124 Eucalyptus globulus Species 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000013068 control sample Substances 0.000 description 4
- 235000001510 limonene Nutrition 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 239000004753 textile Substances 0.000 description 3
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- 241000233866 Fungi Species 0.000 description 2
- 239000000022 bacteriostatic agent Substances 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000011056 performance test Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 208000030507 AIDS Diseases 0.000 description 1
- 235000001674 Agaricus brunnescens Nutrition 0.000 description 1
- 240000004510 Agastache rugosa Species 0.000 description 1
- 244000131522 Citrus pyriformis Species 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000000259 anti-tumor effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 238000009954 braiding Methods 0.000 description 1
- 229930007050 cineol Natural products 0.000 description 1
- 150000001849 cineol derivatives Chemical class 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 201000010099 disease Diseases 0.000 description 1
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 230000001408 fungistatic effect Effects 0.000 description 1
- 210000004209 hair Anatomy 0.000 description 1
- FYDKNKUEBJQCCN-UHFFFAOYSA-N lanthanum(3+);trinitrate Chemical compound [La+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O FYDKNKUEBJQCCN-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 229940113115 polyethylene glycol 200 Drugs 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/45—Oxides or hydroxides of elements of Groups 3 or 13 of the Periodic Table; Aluminates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The present invention relates to a kind of fabric antimicrobial finishing agent, according to parts by weight, the fabric antimicrobial finishing agent includes following component：5~8 parts of chitosan, 2~3 parts of lanthanum salt, 3~5 parts of Pogostemon cablin essential, 3~6 parts of polyethylene glycol, 50~70 parts of water.The present invention is by selecting suitable rare earth element --- lanthanum, coordinate specific bactericide, obtain the finishing agent with broad spectrum antibiotic activity for textile finishing；Using fabric antimicrobial finishing agent finish fabric of the present invention, the fabric after arrangement is washed to the antibiotic property of staphylococcus aureus and Escherichia coli more than 95%, and by 50 times, and its antibiotic property is still more than 92%.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, and in particular to a kind of fabric antimicrobial finishing agent and preparation method thereof.
Background technology
With the improvement of living standards, people increasingly pay attention to the quality of life, it would be desirable to obtain the clothing for having comfort
And the living environment of hygiene and health, so people require more and more higher, particularly safety, peace for various textiles
The formation of " green " idea such as the heart, comfortable, health, health, cleaning, makes the antibacterial of textile, mould proof, deodorization Final finishing process more
Plus be valued by people.
In life, people inevitably touch the microorganisms such as various bacteriums, fungi, and these microorganisms exist
It under suitable external condition, can rapidly breed, and be spread disease by modes such as contacts, influence people's is healthy and normal
Work, studying and living.Fiber belongs to porous material, can form the polylayer forest in countless spaces again after superposition braiding, therefore
Fabric is easier to adsorb mushroom.Antibiotic finish is exactly fabric is had the function of suppressing fungus grown, maintains the clothing life of health
Environment living, it is ensured that health.
Rare earth element has the bioactivity such as relatively good antibacterial, antitumor, anti-AIDS.Due to rare earth ion have compared with
High charge number (+3) and larger ionic radius (85~106pm), thus in the antibiotic finish process Rare Earth Ion of fabric
, while forming complex or chelate with bacteriostatic agent again, it may make antibacterial with the coordination atom such as oxygen, nitrogen formation chelate in fabric
Agent is combined with fabric securely；At the same time, between different bacteriostatic agents, using rare earth ion as tie-point, the antibacterial work of collaboration is produced
With, cause fabric again have spectrum fungistatic effect.
This area needs to develop a kind of fabric antimicrobial finishing agent, and it can play the effect of rare earth ion, improves fabric
Antibacterial activity.
The content of the invention
It is an object of the invention to provide a kind of fabric antimicrobial finishing agent, according to parts by weight, the antibiotic finish of the fabric
Agent includes following component：
5~8 parts of chitosan
2~3 parts of lanthanum salt
3~5 parts of Pogostemon cablin essential
3~6 parts of polyethylene glycol
50~70 parts of water.
Preferably, the chitosan molecule amount is 60,000~70,000.
Preferably, the deacetylation of the chitosan is more than 95%, preferably 95~97%.
Preferably, the lanthanum salt is selected from lanthanum chloride, lanthanum nitrate or lanthana, preferably lanthanum chloride.
Preferably, the Pogostemon cablin essential contains wrinkled giant hyssop alcohol, patchoulene, eugenol and cadinene.
The Pogostemon cablin essential it is typical but non-limiting containing 10wt% to Meng's ethene, 3wt% dipentenes, 6wt% lemons
Lemon olein, 2wt% cineols, 5wt% sesame oil brain, 1wt% anisoxides.
Preferably, the polyethylene glycol is selected from polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 2000 or polyethylene glycol
Any a kind or at least two kinds of of combination in 6000.
Preferably, the fabric antimicrobial finishing agent includes following component：
6 parts of chitosan
2 parts of lanthanum salt
4 parts of Pogostemon cablin essential
5 parts of polyethylene glycol
60 parts of water.
The two of the object of the invention are to provide a kind of preparation method of the fabric antimicrobial finishing agent as described in the first purpose, described
Method is adds the chitosan of formula ratio, lanthanum salt, Pogostemon cablin essential and polyethylene glycol in the water of formula ratio together, high-speed stirred
To well mixed, Pogostemon cablin essential is then added, stirring at low speed produces the fabric antimicrobial finishing agent to well mixed.
Preferably, the mixing speed of the high-speed stirred is 1700~2000r/min.
Preferably, the mixing speed of the stirring at low speed is 60~80r/min.
Compared with prior art, the invention has the advantages that：
The present invention is by selecting suitable rare earth element --- lanthanum, coordinate specific bactericide, obtained whole for fabric
The finishing agent with broad spectrum antibiotic activity of reason；Using fabric antimicrobial finishing agent finish fabric of the present invention, after arrangement
Fabric is washed to the antibiotic property of staphylococcus aureus and Escherichia coli more than 95%, and by 50 times, and its antibiotic property is still
More than 92%.
Embodiment
Technical scheme is further illustrated below by embodiment.
Those skilled in the art it will be clearly understood that the embodiment be only to aid in understand the present invention, be not construed as to this hair
Bright concrete restriction.
Embodiment 1
A kind of fabric antimicrobial finishing agent, by weight including following component：
6 parts of chitosan
2 parts of lanthanum salt
4 parts of Pogostemon cablin essential
5 parts of polyethylene glycol
60 parts of water；
The Pogostemon cablin essential contains 30wt% to Meng's ethene, 3wt% dipentenes, 2wt% limonenes, 2wt% volatile oil extracted from eucalyptus' leaves or twigs
Phenol, 5wt% sesame oil brain, 1wt% anisoxides；
Preparation method is：Methods described is to add the chitosan of formula ratio, lanthanum salt, Pogostemon cablin essential and polyethylene glycol together
In the water for entering formula ratio, then 1800r/min high-speed stirreds add Pogostemon cablin essential, 70r/min low speed is stirred to well mixed
Mix to well mixed, produce the fabric antimicrobial finishing agent.
Embodiment 2
A kind of fabric antimicrobial finishing agent, by weight including following component：
5 parts of chitosan
3 parts of lanthanum salt
3 parts of Pogostemon cablin essential
6 parts of polyethylene glycol
50 parts of water；
The Pogostemon cablin essential contains 40wt% to Meng's ethene, 15wt% dipentenes, 2wt% limonenes, 2wt% volatile oil extracted from eucalyptus' leaves or twigs
Phenol, 5wt% sesame oil brain, 1wt% anisoxides；
Preparation method is：Methods described is to add the chitosan of formula ratio, lanthanum salt, Pogostemon cablin essential and polyethylene glycol together
In the water for entering formula ratio, then 1700r/min high-speed stirreds add Pogostemon cablin essential, 60r/min low speed is stirred to well mixed
Mix to well mixed, produce the fabric antimicrobial finishing agent.
Embodiment 3
A kind of fabric antimicrobial finishing agent, by weight including following component：
8 parts of chitosan
2.5 parts of lanthanum salt
5 parts of Pogostemon cablin essential
3 parts of polyethylene glycol
70 parts of water；
The Pogostemon cablin essential contains 10wt% to Meng's ethene, 3wt% dipentenes, 2wt% limonenes, 2wt% volatile oil extracted from eucalyptus' leaves or twigs
Phenol, 15wt% sesame oil brain, 1wt% anisoxides；
Preparation method is：Methods described is to add the chitosan of formula ratio, lanthanum salt, Pogostemon cablin essential and polyethylene glycol together
In the water for entering formula ratio, then 2000r/min high-speed stirreds add Pogostemon cablin essential, 80r/min low speed is stirred to well mixed
Mix to well mixed, produce the fabric antimicrobial finishing agent.
Comparative example
A kind of fabric antimicrobial finishing agent, by weight including following component：
6 parts of chitosan
6 parts of Pogostemon cablin essential
5 parts of polyethylene glycol
60 parts of water；
The Pogostemon cablin essential contains 30wt% to Meng's ethene, 3wt% dipentenes, 2wt% limonenes, 2wt% volatile oil extracted from eucalyptus' leaves or twigs
Phenol, 5wt% sesame oil brain, 1wt% anisoxides；
Preparation method is：Methods described is to add the chitosan of formula ratio, lanthanum salt, Pogostemon cablin essential and polyethylene glycol together
In the water for entering formula ratio, then 1800r/min high-speed stirreds add Pogostemon cablin essential, 70r/min low speed is stirred to well mixed
Mix to well mixed, produce the fabric antimicrobial finishing agent.
Performance test
Wool fabric is immersed in the fabric antimicrobial finishing agent that embodiment and comparative example are provided, adjusts pH value to 3~4,
1.5h is soaked at 60~70 DEG C, wool fabric is taken out afterwards, water washing is distilled, obtains what is arranged by fabric antimicrobial finishing agent
Wool fabric, is tested.
Antibiotic property：By the wool fabric and control sample 1 that are arranged by fabric antimicrobial finishing agent (without antibiotic finish of the fabric
The wool fabric that agent is arranged) it is placed in triangular flask, it is inoculated with test organisms, it is incubated, determine clump count；The clump count of control sample 1
For 100；
Washing fastness：The wool fabric and control sample 2 that are arranged by fabric antimicrobial finishing agent is (whole without antibacterial fabric
Manage the wool fabric that agent is arranged) wash 50 times, it is subsequently placed in triangular flask, is inoculated with test organisms, it is incubated, determine bacterium colony
Number；The clump count of control sample 2 is 105；.
The performance test results：
| Embodiment clump count is not washed | Wash 50 embodiment clump counts | |
| Embodiment 1 | 98 | 96 |
| Embodiment 2 | 95 | 93 |
| Embodiment 3 | 95 | 93 |
| Comparative example | 70 | 30 |
Applicant states that the present invention illustrates the process of the present invention, but not office of the invention by above-described embodiment
It is limited to above-mentioned processing step, that is, does not mean that the present invention has to rely on above-mentioned processing step and could implemented.Art
Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to raw material selected by the present invention
Addition, selection of concrete mode etc., within the scope of all falling within protection scope of the present invention and being open.
Claims (10)
1. a kind of fabric antimicrobial finishing agent, it is characterised in that according to parts by weight, the fabric antimicrobial finishing agent includes such as the following group
Point：
5~8 parts of chitosan
2~3 parts of lanthanum salt
3~5 parts of Pogostemon cablin essential
3~6 parts of polyethylene glycol
50~70 parts of water.
2. fabric antimicrobial finishing agent as claimed in claim 1, it is characterised in that the chitosan molecule amount is 60,000~70,000.
3. fabric antimicrobial finishing agent as claimed in claim 1 or 2, it is characterised in that the deacetylation of the chitosan is
More than 95%, preferably 95~97%.
4. the fabric antimicrobial finishing agent as described in one of claims 1 to 3, it is characterised in that the lanthanum salt is selected from lanthanum chloride, nitre
Sour lanthanum or lanthana, preferably lanthanum chloride.
5. the fabric antimicrobial finishing agent as described in one of Claims 1 to 4, it is characterised in that the Pogostemon cablin essential contains the leaves of pulse plants
Aromatic, patchoulene, eugenol and cadinene.
6. the fabric antimicrobial finishing agent as described in one of Claims 1 to 5, it is characterised in that the polyethylene glycol is selected from poly- second
Any a kind or at least two kinds of of combination in glycol 200, polyethylene glycol 400, polyethylene glycol 2000 or Macrogol 6000.
7. the fabric antimicrobial finishing agent as described in one of claim 1~6, it is characterised in that the fabric antimicrobial finishing agent bag
Include following component：
6 parts of chitosan
2 parts of lanthanum salt
4 parts of Pogostemon cablin essential
5 parts of polyethylene glycol
60 parts of water.
8. a kind of preparation method of fabric antimicrobial finishing agent as described in one of claim 1~6, it is characterised in that the side
Method is adds the chitosan of formula ratio, lanthanum salt and polyethylene glycol in the water of formula ratio together, and high-speed stirred is to being well mixed, so
After add Pogostemon cablin essential, stirring at low speed produces the fabric antimicrobial finishing agent to well mixed.
9. preparation method as claimed in claim 8, it is characterised in that the mixing speed of the high-speed stirred is 1700~
2000r/min。
10. preparation method as claimed in claim 8 or 9, it is characterised in that the mixing speed of the stirring at low speed is 60~
80r/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710504864.0A CN107142725A (en) | 2017-06-28 | 2017-06-28 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710504864.0A CN107142725A (en) | 2017-06-28 | 2017-06-28 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN107142725A true CN107142725A (en) | 2017-09-08 |
Family
ID=59785784
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|---|---|---|---|
| CN201710504864.0A Pending CN107142725A (en) | 2017-06-28 | 2017-06-28 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108411634A (en) * | 2018-04-02 | 2018-08-17 | 东莞市佳乾新材料科技有限公司 | A kind of preparation method of universal fabric antimicrobial finishing agent |
| CN109090765A (en) * | 2018-10-30 | 2018-12-28 | 温州薪然鞋业有限公司 | A kind of deodorizing sole and preparation method thereof |
| CN109288196A (en) * | 2018-10-30 | 2019-02-01 | 浙江巨圣鞋业有限公司 | A kind of deodorizing sole and preparation method thereof |
| CN112442898A (en) * | 2020-11-25 | 2021-03-05 | 浙江天天向上无纺布科技有限公司 | Antibacterial cleaning cloth and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN108411634A (en) * | 2018-04-02 | 2018-08-17 | 东莞市佳乾新材料科技有限公司 | A kind of preparation method of universal fabric antimicrobial finishing agent |
| CN109090765A (en) * | 2018-10-30 | 2018-12-28 | 温州薪然鞋业有限公司 | A kind of deodorizing sole and preparation method thereof |
| CN109288196A (en) * | 2018-10-30 | 2019-02-01 | 浙江巨圣鞋业有限公司 | A kind of deodorizing sole and preparation method thereof |
| CN109090765B (en) * | 2018-10-30 | 2021-04-16 | 温州薪然鞋业有限公司 | Deodorant sole and preparation method thereof |
| CN112442898A (en) * | 2020-11-25 | 2021-03-05 | 浙江天天向上无纺布科技有限公司 | Antibacterial cleaning cloth and preparation method thereof |
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