CN107119453A - A kind of fabric antimicrobial finishing agent and preparation method thereof - Google Patents
A kind of fabric antimicrobial finishing agent and preparation method thereof Download PDFInfo
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- CN107119453A CN107119453A CN201710504798.7A CN201710504798A CN107119453A CN 107119453 A CN107119453 A CN 107119453A CN 201710504798 A CN201710504798 A CN 201710504798A CN 107119453 A CN107119453 A CN 107119453A
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- finishing agent
- fabric
- antimicrobial finishing
- fabric antimicrobial
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/07—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof
- D06M11/11—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with halogens; with halogen acids or salts thereof; with oxides or oxyacids of halogens or salts thereof with halogen acids or salts thereof
- D06M11/17—Halides of elements of Groups 3 or 13 of the Periodic System
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/12—Aldehydes; Ketones
- D06M13/13—Unsaturated aldehydes, e.g. acrolein; Unsaturated ketones; Ketenes ; Diketenes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/165—Ethers
- D06M13/17—Polyoxyalkyleneglycol ethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/03—Polysaccharides or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/53—Polyethers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M16/00—Biochemical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. enzymatic
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Life Sciences & Earth Sciences (AREA)
- Biochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Microbiology (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to a kind of fabric antimicrobial finishing agent, according to parts by weight, the fabric antimicrobial finishing agent includes following component：5~8 parts of alkyl-glucoside, 2~3 parts of ytterbium salt, 3~5 parts of clore basil essential oil, 3~6 parts of polyethylene glycol, 50~70 parts of water.The present invention is by selecting suitable rare earth element --- ytterbium, coordinate specific bactericide, obtain the finishing agent with broad spectrum antibiotic activity for textile finishing；Using fabric antimicrobial finishing agent finish fabric of the present invention, the fabric after arrangement is washed to the antibiotic property of staphylococcus aureus and Escherichia coli more than 95%, and by 50 times, and its antibiotic property is still more than 90%.
Description
Technical field
The invention belongs to technical field of textile auxiliary agent, and in particular to a kind of fabric antimicrobial finishing agent and preparation method thereof.
Background technology
With the improvement of living standards, people increasingly pay attention to the quality of life, it would be desirable to obtain the clothing for having comfort
And the living environment of hygiene and health, so people require more and more higher, particularly safety, peace for various textiles
The formation of " green " idea such as the heart, comfortable, health, health, cleaning, makes the antibacterial of textile, mould proof, deodorization Final finishing process more
Plus be valued by people.
In life, people inevitably touch the microorganisms such as various bacteriums, fungi, and these microorganisms exist
It under suitable external condition, can rapidly breed, and be spread disease by modes such as contacts, influence people's is healthy and normal
Work, studying and living.Fiber belongs to porous material, can form the polylayer forest in countless spaces again after superposition braiding, therefore
Fabric is easier to adsorb mushroom.Antibiotic finish is exactly fabric is had the function of suppressing fungus grown, maintains the clothing life of health
Environment living, it is ensured that health.
Rare earth element has the bioactivity such as relatively good antibacterial, antitumor, anti-AIDS.Due to rare earth ion have compared with
High charge number (+3) and larger ionic radius (85~106pm), thus in the antibiotic finish process Rare Earth Ion of fabric
, while forming complex or chelate with bacteriostatic agent again, it may make antibacterial with the coordination atom such as oxygen, nitrogen formation chelate in fabric
Agent is combined with fabric securely；At the same time, between different bacteriostatic agents, using rare earth ion as tie-point, the antibacterial work of collaboration is produced
With, cause fabric again have spectrum fungistatic effect.
This area needs to develop a kind of fabric antimicrobial finishing agent, and it can play the effect of rare earth ion, improves fabric
Antibacterial activity.
The content of the invention
It is an object of the invention to provide a kind of fabric antimicrobial finishing agent, according to parts by weight, the antibiotic finish of the fabric
Agent includes following component：
5~8 parts of alkyl-glucoside
8~12 parts of chitin
2~3 parts of ytterbium salt
3~5 parts of clore basil essential oil
3~6 parts of polyethylene glycol
50~70 parts of water.
Preferably, the HLB value of the alkyl-glucoside is 13~14.
Preferably, the average degree of polymerization of the alkyl-glucoside is 1.3~1.6.
Preferably, the alkyl-glucoside is selected from lauryl glucosyl.
Preferably, the deacetylation of the chitin is more than 60~80%, preferably 70%.
Preferably, the ytterbium salt is selected from ytterbium chloride, ytterbium nitrate or ytterbium oxide, preferably ytterbium chloride.
Preferably, the clore basil essential oil contains eugenol, linalool, terpinol, ocimenum and firpene.
Preferably, the polyethylene glycol is selected from polyethylene glycol 200, polyethylene glycol 400, polyethylene glycol 2000 or polyethylene glycol
Any a kind or at least two kinds of of combination in 6000.
Preferably, the fabric antimicrobial finishing agent includes following component：
6 parts of alkyl-glucoside
10 parts of chitin
2.5 parts of ytterbium salt
4 parts of clore basil essential oil
5 parts of polyethylene glycol
60 parts of water.
The two of the object of the invention are to provide a kind of preparation method of the fabric antimicrobial finishing agent as described in the first purpose, described
Method is adds the alkyl-glucoside of formula ratio, ytterbium salt and polyethylene glycol in the water of formula ratio together, and high-speed stirred is to mixed
Close uniform, then add clore basil essential oil, stirring at low speed produces the fabric antimicrobial finishing agent to well mixed.
Preferably, the mixing speed of the high-speed stirred is 1700~2000r/min.
Preferably, the mixing speed of the stirring at low speed is 60~80r/min.
Compared with prior art, the invention has the advantages that：
The present invention is by selecting suitable rare earth element --- ytterbium, coordinate specific bactericide, obtained whole for fabric
The finishing agent with broad spectrum antibiotic activity of reason；Using fabric antimicrobial finishing agent finish fabric of the present invention, after arrangement
Fabric is washed to the antibiotic property of staphylococcus aureus and Escherichia coli more than 95%, and by 50 times, and its antibiotic property is still
More than 90%.
Embodiment
Technical scheme is further illustrated below by embodiment.
Those skilled in the art it will be clearly understood that the embodiment be only to aid in understand the present invention, be not construed as to this hair
Bright concrete restriction.
Embodiment 1
A kind of fabric antimicrobial finishing agent, by weight including following component：
6 parts of alkyl-glucoside
10 parts of chitin
2.5 parts of ytterbium salt
4 parts of clore basil essential oil
5 parts of polyethylene glycol
60 parts of water；
The clore basil essential oil contains 35wt% citronellal, 20wt% citronellol, 15wt% geraniol.
Preparation method is：Methods described be by the alkyl-glucoside of formula ratio, chitin, ytterbium salt and polyethylene glycol together
In the water for adding formula ratio, then 1800r/min high-speed stirreds add clore basil essential oil, 70r/min is low to well mixed
Speed stirring produces the fabric antimicrobial finishing agent to well mixed.
Embodiment 2
A kind of fabric antimicrobial finishing agent, by weight including following component：
5 parts of alkyl-glucoside
8 parts of chitin
3 parts of ytterbium salt
3 parts of clore basil essential oil
6 parts of polyethylene glycol
50 parts of water；
The clore basil essential oil contains 35wt% citronellal, 10wt% citronellol, 30wt% geraniol.
Preparation method is：Methods described be by the alkyl-glucoside of formula ratio, chitin, ytterbium salt and polyethylene glycol together
In the water for adding formula ratio, then 1700r/min high-speed stirreds add clore basil essential oil, 60r/min is low to well mixed
Speed stirring produces the fabric antimicrobial finishing agent to well mixed.
Embodiment 3
A kind of fabric antimicrobial finishing agent, by weight including following component：
8 parts of alkyl-glucoside
8~12 parts of chitin
2.5 parts of ytterbium salt
5 parts of clore basil essential oil
3 parts of polyethylene glycol
70 parts of water；
The clore basil essential oil contains 30wt% citronellal, 20wt% citronellol, 10wt% geraniol.
Preparation method is：Methods described be by the alkyl-glucoside of formula ratio, chitin, ytterbium salt and polyethylene glycol together
In the water for adding formula ratio, then 2000r/min high-speed stirreds add clore basil essential oil, 80r/min is low to well mixed
Speed stirring produces the fabric antimicrobial finishing agent to well mixed.
Comparative example
A kind of fabric antimicrobial finishing agent, by weight including following component：
6 parts of alkyl-glucoside
10 parts of chitin
6 parts of clore basil essential oil
5 parts of polyethylene glycol
60 parts of water；
The clore basil essential oil contains 35wt% citronellal, 20wt% citronellol, 15wt% geraniol.
Preparation method is：Methods described is to add the alkyl-glucoside, chitin and polyethylene glycol of formula ratio together
In the water of formula ratio, then 1800r/min high-speed stirreds add clore basil essential oil, 70r/min low speed is stirred to well mixed
Mix to well mixed, produce the fabric antimicrobial finishing agent.
Performance test
Wool fabric is immersed in the fabric antimicrobial finishing agent that embodiment and comparative example are provided, adjusts pH value to 3~4,
1.5h is soaked at 60~70 DEG C, wool fabric is taken out afterwards, water washing is distilled, obtains what is arranged by fabric antimicrobial finishing agent
Wool fabric, is tested.
Antibiotic property：By the wool fabric and control sample 1 that are arranged by fabric antimicrobial finishing agent (without antibiotic finish of the fabric
The wool fabric that agent is arranged) it is placed in triangular flask, it is inoculated with test organisms, it is incubated, determine clump count；The clump count of control sample 1
For 100；
Washing fastness：The wool fabric and control sample 2 that are arranged by fabric antimicrobial finishing agent is (whole without antibacterial fabric
Manage the wool fabric that agent is arranged) wash 50 times, it is subsequently placed in triangular flask, is inoculated with test organisms, it is incubated, determine bacterium colony
Number；The clump count of control sample 2 is 105；.
The performance test results：
| Embodiment clump count is not washed | Wash 50 embodiment clump counts | |
| Embodiment 1 | 98 | 96 |
| Embodiment 2 | 96 | 93 |
| Embodiment 3 | 96 | 93 |
| Comparative example | 70 | 30 |
Applicant states that the present invention illustrates the process of the present invention, but not office of the invention by above-described embodiment
It is limited to above-mentioned processing step, that is, does not mean that the present invention has to rely on above-mentioned processing step and could implemented.Art
Technical staff it will be clearly understood that any improvement in the present invention, equivalence replacement and auxiliary element to raw material selected by the present invention
Addition, selection of concrete mode etc., within the scope of all falling within protection scope of the present invention and being open.
Claims (10)
1. a kind of fabric antimicrobial finishing agent, it is characterised in that according to parts by weight, the fabric antimicrobial finishing agent includes such as the following group
Point：
5~8 parts of alkyl-glucoside
8~12 parts of chitin
2~3 parts of ytterbium salt
3~5 parts of clore basil essential oil
3~6 parts of polyethylene glycol
50~70 parts of water.
2. fabric antimicrobial finishing agent as claimed in claim 1, it is characterised in that the HLB value of the alkyl-glucoside is 13
~14；
Preferably, the average degree of polymerization of the alkyl-glucoside is 1.3~1.6；
Preferably, the alkyl-glucoside is selected from lauryl glucosyl.
3. fabric antimicrobial finishing agent as claimed in claim 1 or 2, it is characterised in that the deacetylation of the chitin is 60
More than~80%, preferably 70%.
4. the fabric antimicrobial finishing agent as described in one of claims 1 to 3, it is characterised in that the ytterbium salt is selected from ytterbium chloride, nitre
Sour ytterbium or ytterbium oxide, preferably ytterbium chloride.
5. the fabric antimicrobial finishing agent as described in one of Claims 1 to 4, it is characterised in that the clore basil essential oil contains
Eugenol, linalool, terpinol, ocimenum and firpene.
6. the fabric antimicrobial finishing agent as described in one of Claims 1 to 5, it is characterised in that the polyethylene glycol is selected from poly- second
Any a kind or at least two kinds of of combination in glycol 200, polyethylene glycol 400, polyethylene glycol 2000 or Macrogol 6000.
7. the fabric antimicrobial finishing agent as described in one of claim 1~6, it is characterised in that the fabric antimicrobial finishing agent bag
Include following component：
6 parts of alkyl-glucoside
10 parts of chitin
2.5 parts of ytterbium salt
4 parts of clore basil essential oil
5 parts of polyethylene glycol
60 parts of water.
8. a kind of preparation method of fabric antimicrobial finishing agent as described in one of claim 1~6, it is characterised in that the side
Method is adds the alkyl-glucoside of formula ratio, chitin, ytterbium salt and polyethylene glycol in the water of formula ratio together, high-speed stirred
To well mixed, clore basil essential oil is then added, stirring at low speed produces the fabric antimicrobial finishing agent to well mixed.
9. preparation method as claimed in claim 8, it is characterised in that the mixing speed of the high-speed stirred is 1700~
2000r/min。
10. preparation method as claimed in claim 8 or 9, it is characterised in that the mixing speed of the stirring at low speed is 60~
80r/min。
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710504798.7A CN107119453A (en) | 2017-06-28 | 2017-06-28 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710504798.7A CN107119453A (en) | 2017-06-28 | 2017-06-28 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107119453A true CN107119453A (en) | 2017-09-01 |
Family
ID=59718937
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710504798.7A Pending CN107119453A (en) | 2017-06-28 | 2017-06-28 | A kind of fabric antimicrobial finishing agent and preparation method thereof |
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| Country | Link |
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| CN (1) | CN107119453A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105272377A (en) * | 2015-11-03 | 2016-01-27 | 昆明理工大学 | Preparation method of antibacterial ceramic |
| CN105755809A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Antibacterial finishing agent for textile fabric and preparation method of antibacterial finishing agent |
| CN105755818A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Antibacterial finishing agent for textile fabric and preparation method of antibacterial finishing agent |
| CN105926270A (en) * | 2016-05-05 | 2016-09-07 | 无锡市长安曙光手套厂 | Fabric antibacterial finishing agent and preparing method thereof |
| CN106049043A (en) * | 2016-06-23 | 2016-10-26 | 无锡市金五星针纺有限公司 | Fabric antibacterial finishing agent and preparation method thereof |
-
2017
- 2017-06-28 CN CN201710504798.7A patent/CN107119453A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105272377A (en) * | 2015-11-03 | 2016-01-27 | 昆明理工大学 | Preparation method of antibacterial ceramic |
| CN105755809A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Antibacterial finishing agent for textile fabric and preparation method of antibacterial finishing agent |
| CN105755818A (en) * | 2016-05-05 | 2016-07-13 | 无锡市长安曙光手套厂 | Antibacterial finishing agent for textile fabric and preparation method of antibacterial finishing agent |
| CN105926270A (en) * | 2016-05-05 | 2016-09-07 | 无锡市长安曙光手套厂 | Fabric antibacterial finishing agent and preparing method thereof |
| CN106049043A (en) * | 2016-06-23 | 2016-10-26 | 无锡市金五星针纺有限公司 | Fabric antibacterial finishing agent and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 张卫明: "《芳香疗法和芳疗植物》", 31 August 2009, 南京：东南大学出版社 * |
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Application publication date: 20170901 |
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