CN107142135A - A kind of titanium maxter alloy lube oil additive and preparation method thereof - Google Patents
A kind of titanium maxter alloy lube oil additive and preparation method thereof Download PDFInfo
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- CN107142135A CN107142135A CN201710550951.XA CN201710550951A CN107142135A CN 107142135 A CN107142135 A CN 107142135A CN 201710550951 A CN201710550951 A CN 201710550951A CN 107142135 A CN107142135 A CN 107142135A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M163/00—Lubricating compositions characterised by the additive being a mixture of a compound of unknown or incompletely defined constitution and a non-macromolecular compound, each of these compounds being essential
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M159/00—Lubricating compositions characterised by the additive being of unknown or incompletely defined constitution
- C10M159/12—Reaction products
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M177/00—Special methods of preparation of lubricating compositions; Chemical modification by after-treatment of components or of the whole of a lubricating composition, not covered by other classes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/065—Organic compounds derived from inorganic acids or metal salts derived from Ti or Zr
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2227/00—Organic non-macromolecular compounds containing atoms of elements not provided for in groups C10M2203/00, C10M2207/00, C10M2211/00, C10M2215/00, C10M2219/00 or C10M2223/00 as ingredients in lubricant compositions
- C10M2227/06—Organic compounds derived from inorganic acids or metal salts
- C10M2227/066—Organic compounds derived from inorganic acids or metal salts derived from Mo or W
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/06—Oiliness; Film-strength; Anti-wear; Resistance to extreme pressure
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/10—Inhibition of oxidation, e.g. anti-oxidants
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/54—Fuel economy
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/56—Boundary lubrication or thin film lubrication
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/64—Environmental friendly compositions
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
- C10N2030/72—Extended drain
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/25—Internal-combustion engines
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- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Abstract
The invention discloses a kind of titanium maxter alloy lube oil additive and preparation method thereof, it is prepared from by organic-molybdenum amine blends, calcium titanate, methyl methacrylate, double dodecyl methyl tertiary amines；Wherein organic-molybdenum amine blends, calcium titanate, methyl methacrylate, the weight ratio of double dodecyl methyl tertiary amines are 1：5~8：15~20：15~20.Organic-molybdenum amine blends are made up of molybdenum oxide, orthanilic acid, alkylated diphenylamine, potassium permanganate reaction.Additive of the present invention is a kind of titanium maxter alloy lube oil additive, it is the lubricating oil particularly friction improver of I. C. engine lubricating oil, antiwear additive and antioxidant, significantly, due to not containing active sulfur, phosphorus, chlorine, the additive also has the advantages that energy-conserving and environment-protective to oil-saving effect.
Description
Technical field
The present invention relates to lubricant, more particularly to a kind of titanium maxter alloy lube oil additive and preparation method thereof.
Background technology
Organic-molybdenum is a kind of antifriction lubricant of function admirable high temperature resistance；, can be very big if molybdenum is applied in lubricating oil
Ground improves the antiwear and antifriction characteristic of lubricating oil, effectively protects engine, organic titanium is to apply antifriction most top in lubricating oil
Agent, it not only has excellent antifriction performance and fabulous high-temperature oxidation resistance, also with good oily molten and dispersive property；
Titanium and molybdenum are engaged, to be dissolved in the form of ion in lubricating oil, the wear-resistant of lubricating oil can be greatly improved, antifriction, anti-oxidant
Sexual function, can effectively extend the drain period, more effective lasting protection engine.
The content of the invention
The technical problems to be solved by the invention are to provide that a kind of production method is simple, cost is low, oil-soluble good, yield
High new titanium maxter alloy lube oil additive and preparation method thereof.
In order to solve the above-mentioned technical problem, the technical solution adopted by the present invention is：A kind of titanium maxter alloy lube oil additive
Preparation method, comprise the following steps：
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, in anti-under 140 DEG C~150 DEG C air-proof conditions
Answer 2~3 hours, then alkali cleaning, washing, between adjustment pH=6.5--7, add potassium permanganate, continue to react 3 at 90~100 DEG C
~4 hours, then vacuum filter, obtained sediment, is washed to neutrality, obtained brown thing for organic-molybdenum amine blends；Wherein oxygen
Change molybdenum, orthanilic acid, alkylated diphenylamine, potassium permanganate weight ratio=1：3~5：3~5：7~10；
2）The synthesis of titanium maxter alloy lube oil additive
The organic-molybdenum amine blends of above-mentioned preparation are mixed with calcium titanate, methyl methacrylate, after stirring, 90~100
DEG C, under the conditions of pressure 0.3MPa, react 4~5 hours；50~60 DEG C are cooled to, double dodecyl methyl tertiary amines is added, heightens temperature
Spend to 180~190 DEG C, continue to react 3~4 hours under pressure permanence condition, then cool to 100 DEG C, be evacuated to pressure and arrive
0.094MPa；Finally filter, obtain yellow oil-soluble titanium maxter alloy lube oil additive；Wherein organic-molybdenum amine blends, metatitanic acid
Calcium, methyl methacrylate, double dodecyl methyl tertiary amine weight ratio=1：5~8：15~20：15~20.
It is preferred that, the organic-molybdenum amine blends, calcium titanate, methyl methacrylate, double dodecyl methyl tertiary amine weights
Measure ratio=1：6：16：16；Molybdenum oxide, orthanilic acid, alkylated diphenylamine, potassium permanganate weight ratio=1：4：4：8.
Titanium maxter alloy lube oil additive made from the preparation method of above-mentioned new titanium maxter alloy lube oil additive.
The beneficial effects of the invention are as follows：
1st, it is dissolved in the form of an ion in various lubricating oil completely.
2nd, coefficient of friction is reduced：More than 50% can be reduced
3rd, fuel oil is saved：Can be with fuel-economizing more than 10%.
4th, the drain period is extended：It can extend for more than 30% drain period.
5th, it is substantially reduced wear scar diameter.
Embodiment
The present invention is described in further detail with reference to embodiment：
The preparation method of the titanium maxter alloy lube oil additive of the present invention, comprises the following steps：
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, in anti-under 140 DEG C~150 DEG C air-proof conditions
Answer 2~3 hours, then alkali cleaning, washing, between adjustment pH=6.5--7, add potassium permanganate, continue to react 3 at 90~100 DEG C
~4 hours, then vacuum filter, obtained sediment, is washed to neutrality, obtained brown thing for organic-molybdenum amine blends；Molybdenum oxide,
Orthanilic acid, alkylated diphenylamine, potassium permanganate weight ratio=1：4：4：8；
2）The synthesis of titanium maxter alloy lube oil additive
The organic-molybdenum amine blends of above-mentioned preparation are mixed with calcium titanate, methyl methacrylate, after stirring, 90~100
DEG C, under the conditions of pressure 0.3MPa, react 4~5 hours；50~60 DEG C are cooled to, double dodecyl methyl tertiary amines is added, heightens temperature
Spend to 180~190 DEG C, continue to react 3~4 hours under pressure permanence condition, then cool to 100 DEG C, be evacuated to pressure and arrive
0.094MPa；Finally filter, obtain yellow oil-soluble titanium maxter alloy lube oil additive；The organic-molybdenum amine blends, metatitanic acid
Calcium, methyl methacrylate, double dodecyl methyl tertiary amine weight ratio=1：6：16：16；
Titanium maxter alloy lube oil additive made from the preparation method of above-mentioned new titanium maxter alloy lube oil additive.
In the present invention, reacted first based on molybdenum oxide with orthanilic acid, alkylated diphenylamine, add Gao Meng
Sour potassium, using regulation pH value method, obtain being conducive to the organic-molybdenum amine blends of lower step sound response, then with calcium titanate,
Methyl methacrylate, double dodecyl methyl reactive tertiary amines, take two step pressure applications, thus be made with good lubricating properties and
The titanium maxter alloy lube oil additive of splendid wear resistence.
The titanium maxter alloy lube oil additive that the present invention is provided has the advantages that energy-saving, environment-friendly and high-efficiency.
Embodiment 1
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, in reaction 2 hours under 150 DEG C of air-proof conditions,
Then between alkali cleaning, washing, adjustment pH=6.5, potassium permanganate is added, being 100 DEG C in temperature continues to react 3 hours, then vacuum
Filtering, obtains sediment, is washed to neutrality, obtains brown thing for organic-molybdenum amine blends；
Molybdenum oxide:Orthanilic acid:Alkylated diphenylamine：Potassium permanganate=1：4：4：8（Weight ratio）；
2）The synthesis of titanium maxter alloy lube oil additive
5 grams of the organic-molybdenum amine blends of above-mentioned preparation are mixed with 25 grams of calcium titanate, 75 grams of methyl methacrylate, stirred
Afterwards under the conditions of 90 DEG C of temperature, pressure 0.3MPa, react 4 hours；50 DEG C are cooled to, double dodecyl methyl tertiary amines 75 are added
Gram, temperature is heightened to 180 DEG C, is continued to react 3 hours under pressure permanence condition, is then cooled to 100 DEG C, be evacuated to pressure and arrive
0.094MPa；Finally filter, obtain yellow titanium maxter alloy lube oil additive.
The antifriction antiwear of product and the investigation of bearing capacity：Determined using four-ball tester, set load（25 DEG C of temperature, bears
Lotus 392N, speed 1200R/min, time 60min）Under extreme pressure and anti-wear and wear-resistant performance, the steel ball used in four-ball test is straight
Footpath 12.7mm GCR steel balls, experiment shows that product has good extreme pressure and anti-wear and wear-resistant performance.By contrast, directly use
Lubricating oil, wear scar diameter reaches 0.7mm.1% is added in API SN0W/40 lubricating oil（Weight）The present embodiment prepares product, grinds spot
Diameter reaches 0.35mm, coefficient of friction 0.0289.
Embodiment 2
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, it is small in reaction 2.5 under 140 DEG C of air-proof conditions
When, then alkali cleaning, washing adjusts between pH=7, adds potassium permanganate, and being 90 DEG C in temperature continues to react 3.5 hours, Ran Houzhen
Sky filtering, obtains sediment, is washed to neutrality, obtains brown thing for organic-molybdenum amine blends；
Molybdenum oxide:Orthanilic acid:Alkylated diphenylamine：Potassium permanganate=1：5：5：10（Weight ratio）；
2）The synthesis of titanium maxter alloy lube oil additive
10 grams of the organic-molybdenum amine blends of above-mentioned preparation are mixed with 60 grams of calcium titanate, 160 grams of methyl methacrylate, stirring is equal
After even under the conditions of 100 DEG C of temperature, pressure 0.3MPa, react 5 hours；60 DEG C are cooled to, double dodecyl methyl tertiary amines are added
160 grams, temperature is heightened to 190 DEG C, is continued to react 4 hours under pressure permanence condition, is then cooled to 100 DEG C, be evacuated to pressure
Power is to 0.094MPa；Finally filter, obtain yellow titanium maxter alloy lube oil additive.
The antifriction antiwear of product and the investigation of bearing capacity：Determined using four-ball tester, set load（25 DEG C of temperature, bears
Lotus 392N, speed 1200R/min, time 60min）Under extreme pressure and anti-wear and wear-resistant performance, the steel ball used in four-ball test is straight
Footpath 12.7mm GCR steel balls, experiment shows that product has good extreme pressure and anti-wear and wear-resistant performance.By contrast, directly use
Lubricating oil, wear scar diameter reaches 0.7mm.1% is added in API SN0W/40 lubricating oil（Weight）The present embodiment prepares product, grinds spot
Diameter reaches 0.32mm, coefficient of friction 0.0271.
Embodiment 3
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, in reaction 3 hours under 145 DEG C of air-proof conditions,
Then between alkali cleaning, washing, adjustment pH=6.5, potassium permanganate is added, being 95 DEG C in temperature continues to react 4 hours, then vacuum
Filtering, obtains sediment, is washed to neutrality, obtains brown thing for organic-molybdenum amine blends；
Molybdenum oxide:Orthanilic acid:Alkylated diphenylamine：Potassium permanganate=1：3.5：3.5：9（Weight ratio）；
2）The synthesis of titanium maxter alloy lube oil additive
40 grams of the organic-molybdenum amine blends of above-mentioned preparation are mixed with 320 grams of calcium titanate, 800 grams of methyl methacrylate, stirred
After uniform under the conditions of 95 DEG C of temperature, pressure 0.3MPa, react 4.5 hours；50 DEG C are cooled to, double dodecyl methyl uncles are added
800 grams of amine, heightens temperature to 185 DEG C, continues to react 3.5 hours under pressure permanence condition, then cools to 100 DEG C, vacuumize
To pressure to 0.094MPa；Finally filter, obtain yellow titanium maxter alloy lube oil additive.
The antifriction antiwear of product and the investigation of bearing capacity：Determined using four-ball tester, set load（25 DEG C of temperature, bears
Lotus 392N, speed 1200R/min, time 60min）Under extreme pressure and anti-wear and wear-resistant performance, the steel ball used in four-ball test is straight
Footpath 12.7mm GCR steel balls, experiment shows that product has good extreme pressure and anti-wear and wear-resistant performance.By contrast, directly use
Lubricating oil, wear scar diameter reaches 0.7mm.1% is added in API SN0W/40 lubricating oil（Weight）The present embodiment prepares product, grinds spot
Diameter reaches 0.33mm, coefficient of friction 0.0285.
Embodiment 4
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, in reaction 3 hours under 150 DEG C of air-proof conditions,
Then between alkali cleaning, washing, adjustment pH=7, potassium permanganate is added, being 100 DEG C in temperature continues to react 3 hours, then vacuum mistake
Filter, obtains sediment, is washed to neutrality, obtains brown thing for organic-molybdenum amine blends；
Molybdenum oxide:Orthanilic acid:Alkylated diphenylamine：Potassium permanganate=1：4.5：4.5：8（Weight ratio）；
2）The synthesis of titanium maxter alloy lube oil additive
15 grams of the organic-molybdenum amine blends of above-mentioned preparation are mixed with 105 grams of calcium titanate, 285 grams of methyl methacrylate, stirred
After uniform under the conditions of 95 DEG C of temperature, pressure 0.3MPa, react 4 hours；60 DEG C are cooled to, double dodecyl methyl tertiary amines are added
285 grams, temperature is heightened to 190 DEG C, is continued to react 3 hours under pressure permanence condition, is then cooled to 100 DEG C, be evacuated to pressure
Power is to 0.094MPa；Finally filter, obtain yellow titanium maxter alloy lube oil additive.
The antifriction antiwear of product and the investigation of bearing capacity：Determined using four-ball tester, set load（25 DEG C of temperature, bears
Lotus 392N, speed 1200R/min, time 60min）Under extreme pressure and anti-wear and wear-resistant performance, the steel ball used in four-ball test is straight
Footpath 12.7mm GCR steel balls, experiment shows that product has good extreme pressure and anti-wear and wear-resistant performance.By contrast, directly use
Lubricating oil, wear scar diameter reaches 0.7mm.1% is added in API SN0W/40 lubricating oil（Weight）The present embodiment prepares product, grinds spot
Diameter reaches 0.31mm, coefficient of friction 0.0298.
The present invention is molybdenum oxide first to be carried out reaction generation organic-molybdenum amine blends and then and calcium titanate, methyl methacrylate
Ester, double dodecyl methyl tertiary amines etc. react, and generate a kind of new titanium maxter alloy lube oil additive molten with liquid ionic species
In various lubricating oil, minimized friction coefficient can be reduced to 0.0271;Wear scar diameter reaches 0.3 or so, can significantly improve profit
The film forming and bearing capacity of lubricating oil.Under lubricating component nominal situation, form a kind of with antifriction, wear-resistant effect in friction surface
Chemisorbed film；Under the harsh operating mode such as high speed, high temperature, high pressure, closer to one layer of protection engine.
Experimental data shows, this 1% this new titanium maxter alloy lube oil additive is added in engine oil, friction
Coefficient can be reduced to less than 0.027（The coefficient of friction of conventional engine oil is more than 0.08）, 60 points of 40 kgf of four-ball tester
Clock length is rubbed experiment, and wear scar diameter only has 0.31mm（The wear scar diameter of conventional engine oil is 0.50 or so）, temperature reaches 50 degree,
Rise is not continued to.It is the friction improver, antiwear additive and antioxidant of I. C. engine lubricating oil, oil-saving effect is notable.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art
Scholar can understand present disclosure and implement according to this, and it is not intended to limit the scope of the present invention.It is all according to the present invention
The equivalent change or modification that Spirit Essence is made, should all be included within the scope of the present invention.
Claims (3)
1. a kind of preparation method of titanium maxter alloy lube oil additive, it is characterised in that：Comprise the following steps：
1）The synthesis of organic-molybdenum amine blends
Molybdenum oxide and orthanilic acid, alkylated diphenylamine are placed in container, in anti-under 140 DEG C~150 DEG C air-proof conditions
Answer 2~3 hours, then alkali cleaning, washing, between adjustment pH=6.5--7, add potassium permanganate, continue to react 3 at 90~100 DEG C
~4 hours, then vacuum filter, obtained sediment, is washed to neutrality, obtained brown thing for organic-molybdenum amine blends；Wherein oxygen
Change molybdenum, orthanilic acid, alkylated diphenylamine, weight ratio=1 of potassium permanganate：3~5：3~5：7~10；
2）The synthesis of titanium maxter alloy lube oil additive
The organic-molybdenum amine blends of above-mentioned preparation are mixed with calcium titanate, methyl methacrylate, after stirring, 90~100
DEG C, under the conditions of pressure 0.3MPa, react 4~5 hours；50~60 DEG C are cooled to, double dodecyl methyl tertiary amines is added, heightens temperature
Spend to 180~190 DEG C, continue to react 3~4 hours under pressure permanence condition, then cool to 100 DEG C, be evacuated to pressure and arrive
0.094MPa；Finally filter, obtain yellow oil-soluble titanium maxter alloy lube oil additive；Wherein organic-molybdenum amine blends, metatitanic acid
Calcium, methyl methacrylate, weight ratio=1 of double dodecyl methyl tertiary amines：5~8：15~20：15~20.
2. a kind of preparation method of titanium maxter alloy lube oil additive according to claim 1, it is characterised in that described organic
Molybdenum amine blends, calcium titanate, methyl methacrylate, weight ratio=1 of double dodecyl methyl tertiary amines：6：16：16；Molybdenum oxide,
Orthanilic acid, alkylated diphenylamine, weight ratio=1 of potassium permanganate：4：4：8.
3. a kind of titanium maxter alloy lubricating oil made from the preparation method of titanium maxter alloy lube oil additive according to claim 1
Additive.
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111826223A (en) * | 2020-07-23 | 2020-10-27 | 滨州市坤厚工贸有限责任公司 | Multi-effect additive for lubricating oil and preparation method thereof |
| CN112920875A (en) * | 2021-02-05 | 2021-06-08 | 池素玲 | Vehicle lubricating oil additive with semi-solid high-strength membrane, synthetic method of vehicle lubricating oil additive and lubricating oil |
| CN113755226A (en) * | 2021-10-21 | 2021-12-07 | 华亿金卫(杭州)能源有限公司 | Oil-soluble organic zirconium friction reducer and preparation method thereof |
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| JP2011246684A (en) * | 2010-05-25 | 2011-12-08 | Nippon Parkerizing Co Ltd | Aqueous lubricant for plastic working of metallic material, having hardly crystallizable property, and excellent in hygroscopic resistance, corrosion resistance and workability, and metallic material having lubricating film thereof formed thereon |
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Application publication date: 20170908 |