CN107141896A - A kind of fluoro coatings of environmental protection - Google Patents
A kind of fluoro coatings of environmental protection Download PDFInfo
- Publication number
- CN107141896A CN107141896A CN201710347352.8A CN201710347352A CN107141896A CN 107141896 A CN107141896 A CN 107141896A CN 201710347352 A CN201710347352 A CN 201710347352A CN 107141896 A CN107141896 A CN 107141896A
- Authority
- CN
- China
- Prior art keywords
- parts
- urea
- stirring
- environmental protection
- add
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D123/00—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers
- C09D123/02—Coating compositions based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D123/04—Homopolymers or copolymers of ethene
- C09D123/08—Copolymers of ethene
- C09D123/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C09D123/0892—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms containing monomers with other atoms than carbon, hydrogen or oxygen atoms
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/18—Fireproof paints including high temperature resistant paints
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2237—Oxides; Hydroxides of metals of titanium
- C08K2003/2241—Titanium dioxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Abstract
The present invention discloses a kind of fluoro coatings of environmental protection, and its raw material includes by weight：30 40 parts of epoxy phenolics, 60 70 parts of ethylene tetrafluoroethylene copolymer, 80 90 parts of inserts, 1.5 2.5 parts of dibutyl tin laurate, 0.6 1 parts of triethylamine, 24 parts of zinc oxide, 46 parts of cetomacrogol 1000,24 parts of waterproofing agent, 46 parts of age resistor.Urea complex is prepared using following technique：By formaldehyde, microcrystalline wax, ammoniacal liquor, water stirring, add urea, heating stirring, is 7.8 8.4 with sodium hydroxide regulation system pH value, adds tossa, disproportionation starch, borax, heating stirring, add methylvinyldichlorosilane, aminomethyl phenyl dimethoxysilane to be well mixed, add tetramethyl-ring tetrasiloxane, heating stirring, room temperature is cooled to, urea complex is dried to obtain.Adhesive force of the present invention is good, and cost is low, and free formaldehyde is few, environmental protection.
Description
Technical field
The present invention relates to fluoro coatings technical field, more particularly to a kind of fluoro coatings of environmental protection.
Background technology
In coatings industry, solvent based coating contains substantial amounts of volatile organic solvent (VOC), arranges in use
Enter air, not only break up atmospheric environment, while causing the wasting of resources.Fluoro coatings refer to all kinds of paintings by base-material of fluorine resin
Material, also adds appropriate pigment, filler etc..
Fluoro coatings can have resistance to chemical reagents, water resistance, solvent resistance, stain resistance, hardness, weatherability, durability etc. excellent
Point.But, with the environmental requirement more and more higher to coating, the height of VOC content turns into a certain extent weighs a kind of apply
Material whether be green environmental friendly coatingses standard.Therefore a kind of not only adhesive force how is developed strong, and the fluoro coatings of low VOC content
As the task of top priority.
The content of the invention
The technical problem existed based on background technology, the present invention proposes a kind of fluoro coatings of environmental protection, with excellent
Resistance to ag(e)ing, resistance to extensive chemical corrosive nature is excellent, and adhesive force is good, and cost is low, and free formaldehyde is few, environmental protection.
A kind of fluoro coatings of environmental protection proposed by the present invention, its raw material includes by weight：Epoxy phenolics 30-40
Part, 60-70 parts of ethylene-tetrafluoroethylene copolymer, 80-90 parts of inserts, 1.5-2.5 parts of dibutyl tin laurate, triethylamine
0.6-1 parts, 2-4 parts of zinc oxide, 4-6 parts of cetomacrogol 1000,2-4 parts of waterproofing agent, 4-6 parts of age resistor.
Preferably, inserts includes by weight：40-50 parts of urea complex, 8-16 parts of glass microballoon, calcined kaolin
6-12 parts, 8-16 parts of CNT, 4-8 parts of nano titanium oxide.
Preferably, urea complex is prepared using following technique：By formaldehyde, microcrystalline wax, ammoniacal liquor, water stirring, urine is added
Element, heating stirring, is 7.8-8.4 with sodium hydroxide regulation system pH value, adds tossa, disproportionation starch, borax, and heating is stirred
Mix, add methylvinyldichlorosilane, aminomethyl phenyl dimethoxysilane and be well mixed, add tetramethyl-ring tetrasiloxane,
Heating stirring, is cooled to room temperature, is dried to obtain urea complex.
Preferably, urea complex is prepared using following technique：By weight by 90-100 parts of formaldehyde, 2-4 parts of microlites
Wax, 2-4 part ammoniacal liquor, 90-110 parts of water stirrings, add 35-45 parts of urea, and heating stirring is with sodium hydroxide regulation system pH value
7.8-8.4, adds 15-25 parts of tossas, 3-5 parts of disproportionation starch, 2-4 parts of boraxs, and heating stirring adds 12-15 parts of methyl
Hydridovinyldichlorosilane, 2-4 parts of aminomethyl phenyl dimethoxysilanes are well mixed, and add 0.5-0.9 parts of tetramethyl cyclotetrasiloxane silica
Alkane, heating stirring, is cooled to room temperature, is dried to obtain urea complex.
Preferably, urea complex is prepared using following technique：By weight by 90-100 parts of formaldehyde, 2-4 parts of microlites
Wax, 2-4 part ammoniacal liquor, 90-110 parts of water stirring 4-8h, add 35-45 parts of urea, are warming up to 140-150 DEG C of stirring 1-2h, use hydrogen
Sodium oxide molybdena regulation system pH value is 7.8-8.4, adds 15-25 parts of tossas, 3-5 parts of disproportionation starch, 2-4 parts of boraxs, heating
To 80-90 DEG C of stirring 30-50min, 12-15 parts of methylvinyldichlorosilanes, 2-4 parts of aminomethyl phenyl dimethoxysilanes are added
It is well mixed, 0.5-0.9 parts of tetramethyl-ring tetrasiloxanes are added, 145-155 DEG C of stirring 4-8h is warming up to, is cooled to room temperature, does
It is dry to obtain urea complex.
The present invention is compounded using ethylene-tetrafluoroethylene copolymer, epoxy phenolics, with triethylamine, the fourth of tin dilaurate two
Ji Xi is acted on, and the crosslinking curing that intersects forms highly cross-linked network structure, with excellent resistance to ag(e)ing, and adhesive force
It is good.
In urea complex, carboxyl, phenolic hydroxyl group and formaldehyde carry out hydroxymethylation, hydroxyl in tossa molecular structure
Methylate is crosslinked with active group in disproportionation starch, in the case where borax is complexed to methylolation product, the molecule of tossa
Between between uniformly insert firm chemical bond, the entrance of hydrone can be effectively prevented, gumminess is good, with methyl ethylene dichloro silicon
Alkane, the effect of aminomethyl phenyl dimethoxysilane, water-fast under the cooperation of tetramethyl-ring tetrasiloxane, radiation hardness, high-low temperature resistant,
Storage stability is excellent, can prevent precipitation and layering, and cost is low, and free formaldehyde is few, environmental protection；Urea complex is micro- with glass
Pearl, calcined kaolin, CNT coordinate, can be fully dispersed in ethylene-tetrafluoroethylene copolymer, attached after the solidification of coating film forming
Put forth effort strong, resistance to extensive chemical corrosive nature is excellent, and mechanical property is good, even if under the adverse circumstances of pole, will not also produce bulge, come off now
As increasing the service life.
VOC content of the present invention is low, and it can reach GB18582-2008 standards, meets paint development trend, its production cost
Less than the aqueous fluorine-carbon paint of same performance, high financial profit of the present invention.
Embodiment
Below, technical scheme is described in detail by specific embodiment.
Embodiment 1
A kind of fluoro coatings of environmental protection proposed by the present invention, its raw material includes by weight：30 parts of epoxy phenolics,
70 parts of ethylene-tetrafluoroethylene copolymer, 80 parts of inserts, 2.5 parts of dibutyl tin laurate, 0.6 part of triethylamine, zinc oxide 4
Part, 4 parts of cetomacrogol 1000,4 parts of waterproofing agent, 4 parts of age resistor.
Embodiment 2
A kind of fluoro coatings of environmental protection proposed by the present invention, its raw material includes by weight：40 parts of epoxy phenolics,
60 parts of ethylene-tetrafluoroethylene copolymer, 90 parts of inserts, 1.5 parts of dibutyl tin laurate, 1 part of triethylamine, 2 parts of zinc oxide,
6 parts of cetomacrogol 1000,2 parts of waterproofing agent, 6 parts of age resistor.
Inserts includes by weight：40 parts of urea complex, 16 parts of glass microballoon, 6 parts of calcined kaolin, CNT
16 parts, 4 parts of nano titanium oxide.
Urea complex is prepared using following technique：By formaldehyde, microcrystalline wax, ammoniacal liquor, water stirring, urea, heating are added
Stirring, is 7.8-8.4 with sodium hydroxide regulation system pH value, adds tossa, disproportionation starch, borax, and heating stirring is added
Methylvinyldichlorosilane, aminomethyl phenyl dimethoxysilane are well mixed, and add tetramethyl-ring tetrasiloxane, and heating is stirred
Mix, be cooled to room temperature, be dried to obtain urea complex.
Embodiment 3
A kind of fluoro coatings of environmental protection proposed by the present invention, its raw material includes by weight：32 parts of epoxy phenolics,
67 parts of ethylene-tetrafluoroethylene copolymer, 84 parts of inserts, 2.2 parts of dibutyl tin laurate, 0.7 part of triethylamine, zinc oxide
3.5 parts, 4.5 parts of cetomacrogol 1000,3.5 parts of waterproofing agent, 4.5 parts of age resistor.
Inserts includes by weight：50 parts of urea complex, 8 parts of glass microballoon, 12 parts of calcined kaolin, CNT
8 parts, 8 parts of nano titanium oxide.
Urea complex is prepared using following technique：By weight by 95 parts of formaldehyde, 3 parts of microcrystalline waxes, 3 parts of ammoniacal liquor, 100
Part water stirring, adds 40 parts of urea, heating stirring, is 7.8-8.4 with sodium hydroxide regulation system pH value, 20 parts of jute fibres of addition
Dimension, 4 parts of disproportionation starch, 3 parts of boraxs, heating stirring add 13.5 parts of methylvinyldichlorosilanes, 3 parts of aminomethyl phenyl diformazans
TMOS is well mixed, and adds 0.7 part of tetramethyl-ring tetrasiloxane, and heating stirring is cooled to room temperature, is dried to obtain urea and answers
Compound.
Embodiment 4
A kind of fluoro coatings of environmental protection proposed by the present invention, its raw material includes by weight：38 parts of epoxy phenolics,
63 parts of ethylene-tetrafluoroethylene copolymer, 88 parts of inserts, 1.8 parts of dibutyl tin laurate, 0.9 part of triethylamine, zinc oxide
2.5 parts, 5.5 parts of cetomacrogol 1000,2.5 parts of waterproofing agent, 5.5 parts of age resistor.
Inserts includes by weight：43 parts of urea complex, 14 parts of glass microballoon, 8 parts of calcined kaolin, CNT
14 parts, 5 parts of nano titanium oxide.
Urea complex is prepared using following technique：By weight by 90 parts of formaldehyde, 4 parts of microcrystalline waxes, 2 parts of ammoniacal liquor, 110
Part water stirring 4h, adds 45 parts of urea, is warming up to 140 DEG C of stirring 2h, is 7.8-8.4 with sodium hydroxide regulation system pH value, plus
Enter 15 parts of tossas, 5 parts of disproportionation starch, 2 parts of boraxs, be warming up to 90 DEG C of stirring 30min, add 15 parts of methyl ethylene dichloros
Silane, 2 parts of aminomethyl phenyl dimethoxysilanes are well mixed, and are added 0.9 part of tetramethyl-ring tetrasiloxane, are warming up to 145 DEG C and stir
8h is mixed, room temperature is cooled to, urea complex is dried to obtain.
Embodiment 5
A kind of fluoro coatings of environmental protection proposed by the present invention, its raw material includes by weight：35 parts of epoxy phenolics,
65 parts of ethylene-tetrafluoroethylene copolymer, 86 parts of inserts, 2 parts of dibutyl tin laurate, 0.8 part of triethylamine, 3 parts of zinc oxide,
5 parts of cetomacrogol 1000,3 parts of waterproofing agent, 5 parts of age resistor.
Inserts includes by weight：45 parts of urea complex, 10 parts of glass microballoon, 10 parts of calcined kaolin, carbon nanometer
10 parts of pipe, 7 parts of nano titanium oxide.
Urea complex is prepared using following technique：By weight by 100 parts of formaldehyde, 2 parts of microcrystalline waxes, 4 parts of ammoniacal liquor, 90
Part water stirring 8h, adds 35 parts of urea, is warming up to 150 DEG C of stirring 1h, is 7.8-8.4 with sodium hydroxide regulation system pH value, plus
Enter 25 parts of tossas, 3 parts of disproportionation starch, 4 parts of boraxs, be warming up to 80 DEG C of stirring 50min, add 12 parts of methyl ethylene dichloros
Silane, 4 parts of aminomethyl phenyl dimethoxysilanes are well mixed, and are added 0.5 part of tetramethyl-ring tetrasiloxane, are warming up to 155 DEG C and stir
4h is mixed, room temperature is cooled to, urea complex is dried to obtain.
The foregoing is only a preferred embodiment of the present invention, but protection scope of the present invention be not limited thereto,
Any one skilled in the art the invention discloses technical scope in, technique according to the invention scheme and its
Inventive concept is subject to equivalent substitution or change, should all be included within the scope of the present invention.
Claims (5)
1. a kind of fluoro coatings of environmental protection, it is characterised in that its raw material includes by weight：30-40 parts of epoxy phenolics,
60-70 parts of ethylene-tetrafluoroethylene copolymer, 80-90 parts of inserts, 1.5-2.5 parts of dibutyl tin laurate, triethylamine 0.6-
1 part, 2-4 parts of zinc oxide, 4-6 parts of cetomacrogol 1000,2-4 parts of waterproofing agent, 4-6 parts of age resistor.
2. fluoro coatings of environmental protection according to claim 1, it is characterised in that inserts includes by weight：Urea is answered
40-50 parts of compound, 8-16 parts of glass microballoon, 6-12 parts of calcined kaolin, 8-16 parts of CNT, 4-8 parts of nano titanium oxide.
3. fluoro coatings of environmental protection according to claim 2, it is characterised in that urea complex uses following technique system
It is standby：By formaldehyde, microcrystalline wax, ammoniacal liquor, water stirring, urea is added, heating stirring, is 7.8- with sodium hydroxide regulation system pH value
8.4, tossa, disproportionation starch, borax are added, heating stirring adds methylvinyldichlorosilane, aminomethyl phenyl dimethoxy
Base silane is well mixed, and adds tetramethyl-ring tetrasiloxane, and heating stirring is cooled to room temperature, is dried to obtain urea complex.
4. the fluoro coatings of environmental protection according to Claims 2 or 3, it is characterised in that urea complex uses following technique
Prepare：90-100 parts of formaldehyde, 2-4 parts of microcrystalline waxes, 2-4 parts of ammoniacal liquor, 90-110 parts of water are stirred by weight, 35-45 is added
Part urea, heating stirring, is 7.8-8.4 with sodium hydroxide regulation system pH value, adds 15-25 parts of tossas, 3-5 parts of disproportionations
Starch, 2-4 part borax, heating stirring, add 12-15 parts of methylvinyldichlorosilanes, 2-4 parts of aminomethyl phenyl dimethoxy silicon
Alkane is well mixed, and adds 0.5-0.9 parts of tetramethyl-ring tetrasiloxanes, and heating stirring is cooled to room temperature, is dried to obtain urea and is combined
Thing.
5. according to the fluoro coatings of any one of the claim 2-4 environmental protections, it is characterised in that urea complex is using as follows
It is prepared by technique：90-100 parts of formaldehyde, 2-4 parts of microcrystalline waxes, 2-4 parts of ammoniacal liquor, 90-110 parts of water are stirred into 4-8h by weight, plus
Enter 35-45 parts of urea, be warming up to 140-150 DEG C of stirring 1-2h, be 7.8-8.4 with sodium hydroxide regulation system pH value, add 15-
25 parts of tossas, 3-5 parts of disproportionation starch, 2-4 parts of boraxs, are warming up to 80-90 DEG C of stirring 30-50min, add 12-15 parts of first
Base hydridovinyldichlorosilane, 2-4 parts of aminomethyl phenyl dimethoxysilanes are well mixed, and add 0.5-0.9 parts of tetramethyl cyclotetrasiloxane silicon
Oxygen alkane, is warming up to 145-155 DEG C of stirring 4-8h, is cooled to room temperature, is dried to obtain urea complex.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710347352.8A CN107141896A (en) | 2017-05-17 | 2017-05-17 | A kind of fluoro coatings of environmental protection |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710347352.8A CN107141896A (en) | 2017-05-17 | 2017-05-17 | A kind of fluoro coatings of environmental protection |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107141896A true CN107141896A (en) | 2017-09-08 |
Family
ID=59777828
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710347352.8A Pending CN107141896A (en) | 2017-05-17 | 2017-05-17 | A kind of fluoro coatings of environmental protection |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107141896A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1777655A (en) * | 2003-03-26 | 2006-05-24 | 阿托特希德国有限公司 | Powder coating and process for the preparation of thin layers in the manufacture of printed circuit boards |
| CN101575487A (en) * | 2009-05-05 | 2009-11-11 | 浙江林学院 | Alkali lignin oxidized starch modified urea-formaldehyde glue and production method thereof |
| CN105153834A (en) * | 2015-08-21 | 2015-12-16 | 无锡乐华自动化科技有限公司 | Anticorrosive coating for hub |
| CN105400395A (en) * | 2015-11-27 | 2016-03-16 | 安徽锦洋氟化学有限公司 | High-performance PVDF fluorocarbon powder coating |
| CN105400394A (en) * | 2015-11-27 | 2016-03-16 | 安徽锦洋氟化学有限公司 | Waterproof fluorocarbon powder coating |
-
2017
- 2017-05-17 CN CN201710347352.8A patent/CN107141896A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1777655A (en) * | 2003-03-26 | 2006-05-24 | 阿托特希德国有限公司 | Powder coating and process for the preparation of thin layers in the manufacture of printed circuit boards |
| CN101575487A (en) * | 2009-05-05 | 2009-11-11 | 浙江林学院 | Alkali lignin oxidized starch modified urea-formaldehyde glue and production method thereof |
| CN105153834A (en) * | 2015-08-21 | 2015-12-16 | 无锡乐华自动化科技有限公司 | Anticorrosive coating for hub |
| CN105400395A (en) * | 2015-11-27 | 2016-03-16 | 安徽锦洋氟化学有限公司 | High-performance PVDF fluorocarbon powder coating |
| CN105400394A (en) * | 2015-11-27 | 2016-03-16 | 安徽锦洋氟化学有限公司 | Waterproof fluorocarbon powder coating |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102190936A (en) | Swelling-preventing polyacrylate dispersion/SiO2 hybrid aqueous wood coating | |
| CN102787529A (en) | Preparation method of starch adhesive for papermaking coating, its product, and application of product | |
| CN108250411B (en) | Organosilicon modified epoxy resin aqueous curing agent and preparation method thereof | |
| CN107858078B (en) | Epoxy woodware sealing agent and preparation method and application thereof | |
| CN105175687B (en) | The preparation method of Diamond Search high-flexibility aqueous epoxy resin curing agent | |
| US20130331483A1 (en) | Organic-inorganic hybrid paint composition | |
| CN104073185A (en) | Silicone oil release film with sticky surface and production process of silicone oil release film | |
| CN102272228A (en) | Metal stabilizers for epoxy resins | |
| CN104389237A (en) | Papermaking coating biomass adhesive, preparation method and applications thereof | |
| CN106978019A (en) | A kind of good fluorocarbon coating of adhesive force | |
| TWI594947B (en) | Inorganic polymer material, method for forming the same, and inorganic polymer coatingproduced therefrom | |
| CN108841344A (en) | A kind of weather-proof primary coat coating of high-adhesion and purposes | |
| CN102898624A (en) | Epoxy resin curing agent and preparation method thereof | |
| CN102041721B (en) | Surface coating paint for wine label paper as well as preparation method and application thereof | |
| CN108503814B (en) | Epoxidized polyester resin and preparation method and application thereof | |
| CN102391763A (en) | Solvent-borne two-component electroplating primer for chromium-plated plastic and preparation method of solvent-borne two-component electroplating primer | |
| JP2012201858A5 (en) | ||
| CN107141896A (en) | A kind of fluoro coatings of environmental protection | |
| JP5069737B2 (en) | imitation leather | |
| CN105040444A (en) | Novel nano water-borne epoxy resin sizing agent for carbon fibers and preparation method thereof | |
| CN112876986A (en) | Organic silicon transparent flexible hard coating material and preparation method thereof | |
| CN110746804A (en) | Water-based paint for furniture production, preparation method and application thereof, and furniture preparation process | |
| CN103044657B (en) | Nano-modified epoxy resin and preparation method thereof | |
| KR101666052B1 (en) | Organic-inorganic composite coating composition for hard coating and method for producing the same | |
| CN105860029A (en) | Preparation method of high temperature resistant waterborne epoxy resin |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20170908 |