CN105040444A - Novel nano water-borne epoxy resin sizing agent for carbon fibers and preparation method thereof - Google Patents
Novel nano water-borne epoxy resin sizing agent for carbon fibers and preparation method thereof Download PDFInfo
- Publication number
- CN105040444A CN105040444A CN201510565786.6A CN201510565786A CN105040444A CN 105040444 A CN105040444 A CN 105040444A CN 201510565786 A CN201510565786 A CN 201510565786A CN 105040444 A CN105040444 A CN 105040444A
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- CN
- China
- Prior art keywords
- epoxy resin
- epoxy resins
- sizing agent
- aqueous epoxy
- carbon fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003822 epoxy resin Substances 0.000 title claims abstract description 150
- 229920000647 polyepoxide Polymers 0.000 title claims abstract description 150
- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 63
- 238000004513 sizing Methods 0.000 title claims abstract description 57
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 50
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 50
- 238000002360 preparation method Methods 0.000 title claims abstract description 23
- 238000003756 stirring Methods 0.000 claims abstract description 47
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 44
- 150000004982 aromatic amines Chemical class 0.000 claims abstract description 27
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims abstract description 20
- 238000006243 chemical reaction Methods 0.000 claims abstract description 19
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 14
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 229960000583 acetic acid Drugs 0.000 claims abstract description 10
- 239000012362 glacial acetic acid Substances 0.000 claims abstract description 10
- 239000003960 organic solvent Substances 0.000 claims abstract description 10
- GIAFURWZWWWBQT-UHFFFAOYSA-N 2-(2-aminoethoxy)ethanol Chemical compound NCCOCCO GIAFURWZWWWBQT-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012153 distilled water Substances 0.000 claims abstract description 9
- 239000002904 solvent Substances 0.000 claims abstract description 9
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 claims description 65
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 62
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 47
- 239000005543 nano-size silicon particle Substances 0.000 claims description 41
- 235000012239 silicon dioxide Nutrition 0.000 claims description 26
- 230000004048 modification Effects 0.000 claims description 17
- 238000012986 modification Methods 0.000 claims description 17
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 claims description 16
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 12
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 12
- 238000013019 agitation Methods 0.000 claims description 10
- BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical compound CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 8
- 238000007865 diluting Methods 0.000 claims description 8
- IDGUHHHQCWSQLU-UHFFFAOYSA-N ethanol;hydrate Chemical compound O.CCO IDGUHHHQCWSQLU-UHFFFAOYSA-N 0.000 claims description 8
- 239000008367 deionised water Substances 0.000 claims description 4
- 229910021641 deionized water Inorganic materials 0.000 claims description 4
- 239000002245 particle Substances 0.000 claims description 2
- 239000000243 solution Substances 0.000 abstract description 15
- 238000005516 engineering process Methods 0.000 abstract description 7
- 238000010790 dilution Methods 0.000 abstract description 2
- 239000012895 dilution Substances 0.000 abstract description 2
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 abstract 2
- 238000000034 method Methods 0.000 description 14
- 239000000463 material Substances 0.000 description 7
- 229920000642 polymer Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 241001502050 Acis Species 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 229920002292 Nylon 6 Polymers 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- 239000002114 nanocomposite Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 238000009955 starching Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- 229920001187 thermosetting polymer Polymers 0.000 description 2
- 239000004677 Nylon Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 230000002421 anti-septic effect Effects 0.000 description 1
- 239000003125 aqueous solvent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 239000000805 composite resin Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000011065 in-situ storage Methods 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052755 nonmetal Inorganic materials 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- -1 titanate ester Chemical class 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000004846 water-soluble epoxy resin Substances 0.000 description 1
Landscapes
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Description
Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Comparative example |
The rate of sizing (%) | 5.4 | 7.1 | 6.5 | 7.0 | 5.9 | 6.7 | 3.1 |
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510565786.6A CN105040444B (en) | 2015-09-08 | 2015-09-08 | A kind of preparation method of nanometer waterborne epoxy resin sizing agent for carbon fiber |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201510565786.6A CN105040444B (en) | 2015-09-08 | 2015-09-08 | A kind of preparation method of nanometer waterborne epoxy resin sizing agent for carbon fiber |
Publications (2)
Publication Number | Publication Date |
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CN105040444A true CN105040444A (en) | 2015-11-11 |
CN105040444B CN105040444B (en) | 2018-04-20 |
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CN (1) | CN105040444B (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105297448A (en) * | 2015-11-30 | 2016-02-03 | 山东大学 | Interface-enhanced nano silicon dioxide-modified epoxy resin sizing agent for carbon fiber |
CN109972397A (en) * | 2019-03-25 | 2019-07-05 | 吉林乾仁新材料有限公司 | The preparation and application of fabricated in situ nano-oxide enhancing carbon fiber sizing agent and basalt fibre size |
CN110158317A (en) * | 2019-05-30 | 2019-08-23 | 叶小文 | A kind of preparation method of high mating type carbon fiber epoxy sizing agent |
CN115341392A (en) * | 2022-09-23 | 2022-11-15 | 哈尔滨工业大学 | Preparation method of high-temperature-resistant epoxy resin emulsion carbon fiber sizing agent |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002327374A (en) * | 2001-02-28 | 2002-11-15 | Toray Ind Inc | Carbon fiber for fiber reinforced plastic and fiber reinforced plastic |
CN1632217A (en) * | 2004-12-07 | 2005-06-29 | 中国科学院山西煤炭化学研究所 | Process for preparing nano SiO2 modified carbon fiber emulsion pasting agent |
CN101982602A (en) * | 2010-10-22 | 2011-03-02 | 北京化工大学 | Sizing agent for carbon fiber |
CN104389175A (en) * | 2014-11-03 | 2015-03-04 | 哈尔滨工业大学 | Nano SiO2 modified emulsion type carbon fiber sizing agent and preparation method thereof |
CN104420204A (en) * | 2013-09-10 | 2015-03-18 | 济南大学 | Carbon fiber water-soluble epoxy resin sizing agent |
-
2015
- 2015-09-08 CN CN201510565786.6A patent/CN105040444B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2002327374A (en) * | 2001-02-28 | 2002-11-15 | Toray Ind Inc | Carbon fiber for fiber reinforced plastic and fiber reinforced plastic |
CN1632217A (en) * | 2004-12-07 | 2005-06-29 | 中国科学院山西煤炭化学研究所 | Process for preparing nano SiO2 modified carbon fiber emulsion pasting agent |
CN101982602A (en) * | 2010-10-22 | 2011-03-02 | 北京化工大学 | Sizing agent for carbon fiber |
CN104420204A (en) * | 2013-09-10 | 2015-03-18 | 济南大学 | Carbon fiber water-soluble epoxy resin sizing agent |
CN104389175A (en) * | 2014-11-03 | 2015-03-04 | 哈尔滨工业大学 | Nano SiO2 modified emulsion type carbon fiber sizing agent and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
王成忠等: "T-800碳纤维缠绕用环氧树脂基体研究", 《2004年中国材料研讨会论文摘要集》 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105297448A (en) * | 2015-11-30 | 2016-02-03 | 山东大学 | Interface-enhanced nano silicon dioxide-modified epoxy resin sizing agent for carbon fiber |
CN109972397A (en) * | 2019-03-25 | 2019-07-05 | 吉林乾仁新材料有限公司 | The preparation and application of fabricated in situ nano-oxide enhancing carbon fiber sizing agent and basalt fibre size |
CN110158317A (en) * | 2019-05-30 | 2019-08-23 | 叶小文 | A kind of preparation method of high mating type carbon fiber epoxy sizing agent |
CN115341392A (en) * | 2022-09-23 | 2022-11-15 | 哈尔滨工业大学 | Preparation method of high-temperature-resistant epoxy resin emulsion carbon fiber sizing agent |
CN115341392B (en) * | 2022-09-23 | 2023-03-10 | 哈尔滨工业大学 | Preparation method of high-temperature-resistant epoxy resin emulsion carbon fiber sizing agent |
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Publication number | Publication date |
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CN105040444B (en) | 2018-04-20 |
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CB03 | Change of inventor or designer information |
Inventor after: Shi Xianfeng Inventor after: Lin Jian Inventor after: Li Yueqiang Inventor after: Li Daqing Inventor after: Chen Xiaoru Inventor before: Wu Guoqing |
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CB03 | Change of inventor or designer information | ||
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Effective date of registration: 20180314 Address after: 264202 Penglai Road, Huancui District, Weihai, Shandong Province, No. 365 Applicant after: WEIHAI NUOWEI XINHE NEW MATERIAL CO.,LTD. Address before: 313026 Zhejiang Province, Huzhou city Nanxun district and Fu Zhen Bai Wan Dou Applicant before: HUZHOU HONGXIN SILK FACTORY |
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Denomination of invention: A preparation method of nano waterborne epoxy resin sizing agent for carbon fiber Effective date of registration: 20220128 Granted publication date: 20180420 Pledgee: Shandong Weihai Rural Commercial Bank Co.,Ltd. sunjiatuan sub branch Pledgor: WEIHAI NUOWEI XINHE NEW MATERIAL CO.,LTD. Registration number: Y2022980001225 |
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Date of cancellation: 20230131 Granted publication date: 20180420 Pledgee: Shandong Weihai Rural Commercial Bank Co.,Ltd. sunjiatuan sub branch Pledgor: WEIHAI NUOWEI XINHE NEW MATERIAL CO.,LTD. Registration number: Y2022980001225 |
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PC01 | Cancellation of the registration of the contract for pledge of patent right | ||
PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A preparation method of nano waterborne epoxy resin sizing agent for carbon fiber Effective date of registration: 20230201 Granted publication date: 20180420 Pledgee: Shandong Weihai Rural Commercial Bank Co.,Ltd. sunjiatuan sub branch Pledgor: WEIHAI NUOWEI XINHE NEW MATERIAL CO.,LTD. Registration number: Y2023110000043 |
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