CN107141739A - A kind of plastics chimney filter and the composition for the plastics chimney filter - Google Patents

A kind of plastics chimney filter and the composition for the plastics chimney filter Download PDF

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Publication number
CN107141739A
CN107141739A CN201710412421.9A CN201710412421A CN107141739A CN 107141739 A CN107141739 A CN 107141739A CN 201710412421 A CN201710412421 A CN 201710412421A CN 107141739 A CN107141739 A CN 107141739A
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China
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degree
plastics
chimney filter
bracing piece
stirred
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Granted
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CN201710412421.9A
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CN107141739B (en
Inventor
彭代信
陈莹珍
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Taizhou Changli Resin Tube Co., Ltd.
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SUZHOU YIKETAI ELECTRONIC MATERIAL CO Ltd
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Priority to CN201710412421.9A priority Critical patent/CN107141739B/en
Priority to CN201810611125.6A priority patent/CN108822512A/en
Priority to CN201810611943.6A priority patent/CN109021514A/en
Priority to CN201810611941.7A priority patent/CN108822513A/en
Priority to CN201810611942.1A priority patent/CN109021513A/en
Publication of CN107141739A publication Critical patent/CN107141739A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0001Making filtering elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Filtering Materials (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)

Abstract

A kind of composition the invention discloses plastics chimney filter and for the plastics chimney filter, plastics composite is prepared into by 3 aminopropyltriethoxy dimethoxysilanes, Emulsifier EL-60, fatty acid ester, poly butyric ester, ethylene vinyl acetate copolymer, PPDO, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, end hydroxy butadiene;Plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin, is added into injection machine, prepares chimney filter.Plastics chimney filter disclosed by the invention, which belongs to clean again, uses environmentally friendly machine, can directly change traditional filter bag equipment, be not necessary to change existing dust-collecting equipment, while service life of equipment is long, service life can be more than traditional more than 10 times.

Description

A kind of plastics chimney filter and the composition for the plastics chimney filter
Technical field
The invention belongs to field of environment protection equipment, and in particular to a kind of plastics chimney filter and the composition for the plastics chimney filter.
Background technology
With the development of modern industry, dust is increasingly serious to the influence caused by the health of environment and the mankind, effectively Dust pollution is administered, Environmental protection pay attention to day by day and global warming phenomenon are serious in recent years, in order to advocate carbon reduction, Environmental protection industry flourishes, and purifies the living environment of the mankind, it has also become proprietary common recognition.Existing chimney filter is only flat, filter Pipe discounting end is divided into pointed and square, and existing plastics chimney filter pulse dust cleaning has dead angle, causes ash-removal effect difference and filter area small; Precipitron operation pressure is high;Conventional filter bag can not be replaced.
The content of the invention
It is an object of the invention to provide a kind of plastics chimney filter, for deduster dedusting, be conducive to environmentally friendly development.
To achieve the above object of the invention, the technical solution adopted by the present invention is:A kind of plastics chimney filter, by 3- aminopropyltriethoxies Dimethoxysilane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, poly butyric ester are added, 100 Degree stirring 20 minutes, adds ethylene vinyl acetate and PPDO, and 140 degree are stirred 2 hours, cold But compound is obtained to room temperature;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid Pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then will be mixed Compound is under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated Obtain plastics composite;Added after plastics composite is mixed with uramit, paraffin in injection machine, melted according to 150 degree, The technique of 245 degree of shapings prepares body, reinforcing ring and bracing piece integrated component crude product;Then by body, reinforcing ring and bracing piece Integrated component crude product is put into boiling water and handled 2 hours, takes out, heated-air drying, as body, reinforcing ring and bracing piece one portion Part;Body, reinforcing ring and bracing piece integrated component and base combination are obtained into plastics chimney filter.
The invention also discloses a kind of preparation method of plastics chimney filter, comprise the following steps:By 3- aminopropyltriethoxy diformazans TMOS, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, are added poly butyric ester, are stirred at 100 degree Mix 20 minutes, add ethylene vinyl acetate and PPDO, 140 degree are stirred 2 hours, are cooled to Room temperature obtains compound;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, Lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then mixture is existed 170 degree, under 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is moulded Feed composition;After plastics composite is mixed with uramit, paraffin add injection machine in, according to 150 degree melt, 245 degree into The technique of type prepares body, reinforcing ring and bracing piece integrated component crude product;Then by body, reinforcing ring and bracing piece integrated component Crude product is put into boiling water and handled 2 hours, takes out, heated-air drying, as body, reinforcing ring and bracing piece integrated component;By body, Reinforcing ring obtains plastics chimney filter with bracing piece integrated component and base combination.
In the present invention, chimney filter is hatch frame, and overall similar tubulose, bottom is arranged on housing, open top, for arteries and veins Rush in wind, tube wall filtration;The reinforcing ring is located in body, and is connected by bracing piece with body;The body Cross section is gear type structure;The tooth top and teeth groove of the gear type structure are all arcuate structure;The reinforcing ring is located at body One end;Circular platform type bulge-structure is provided with the middle of the base;The bracing piece is 4~8;The bracing piece and reinforcing ring connect Contact is evenly distributed on reinforcing ring;The bracing piece is flat structure;The contact point of the bracing piece and body is located at gear At the teeth groove of type structure;Each reinforcement pole length is consistent;The angle of the arcuate structure is 30~150 degree;The gear The height of the tooth of type structure is the 28~34% of reinforcement pole length.
The invention also discloses a kind of plastics chimney filter feedstock composition, by 3- aminopropyltriethoxies dimethoxysilane, gather Oxygen ethylene castor oil is stirred 1 hour with fatty acid ester at 90 degree, adds poly butyric ester, is stirred 20 minutes at 100 degree, then Ethylene vinyl acetate and PPDO are added, 140 degree are stirred 2 hours, are cooled to room temperature and are mixed Material;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, dodecyl sulphate Sodium, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture in 170 degree, 4MPa Under, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is obtained into plastics composite; The plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin.
The invention also discloses a kind of plastics chimney filter plastics composite, the plastics composite is prepared as, by 3- ammonia Hydroxypropyl methyl dimethoxysilane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, add poly butyric Ester, is stirred 20 minutes at 100 degree, adds ethylene vinyl acetate and PPDO, 140 degree of stirrings 2 Hour, it is cooled to room temperature and obtains compound;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl disulfides Mixed for phosphopyridine, lauryl sodium sulfate, end hydroxy butadiene with batch mixer, form finely dispersed mixture;So Afterwards by mixture under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture after heat treatment is extruded Machine granulation obtains plastics composite.
The invention also discloses a kind of preparation method of plastics chimney filter plastics composite, comprise the following steps, by 3- ammonia Hydroxypropyl methyl dimethoxysilane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, add poly butyric Ester, is stirred 20 minutes at 100 degree, adds ethylene vinyl acetate and PPDO, 140 degree of stirrings 2 Hour, it is cooled to room temperature and obtains compound;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl disulfides Mixed for phosphopyridine, lauryl sodium sulfate, end hydroxy butadiene with batch mixer, form finely dispersed mixture;So Afterwards by mixture under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture after heat treatment is extruded Machine granulation obtains plastics composite.
The invention also discloses a kind of plastics chimney filter body, the body is prepared as, by 3- aminopropyltriethoxy dimethoxies Base silane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, add poly butyric ester, in 100 degree of stirrings 20 minutes, ethylene vinyl acetate and PPDO are added, 140 degree are stirred 2 hours, are cooled to room Temperature obtains compound;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, ten Sodium dialkyl sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then mixture is existed 170 degree, under 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is moulded Feed composition;After plastics composite is mixed with uramit, paraffin add injection machine in, according to 150 degree melt, 245 degree into The technique of type prepares body crude product;Then body crude product is put into boiling water and handled 2 hours, taken out, heated-air drying is as managed Body.
The invention also discloses a kind of preparation method of plastics chimney filter body, comprise the following steps, by 3- aminopropyltriethoxies Dimethoxysilane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, poly butyric ester are added, 100 Degree stirring 20 minutes, adds ethylene vinyl acetate and PPDO, and 140 degree are stirred 2 hours, cold But compound is obtained to room temperature;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid Pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then will be mixed Compound is under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated Obtain plastics composite;Added after plastics composite is mixed with uramit, paraffin in injection machine, melted according to 150 degree, The technique of 245 degree of shapings prepares body crude product;Then body crude product is put into boiling water and handled 2 hours, taken out, heated-air drying, As body.
In the present invention, the 3- aminopropyltriethoxies dimethoxysilane, Emulsifier EL-60, fatty acid ester, poly- hydroxyl Butyrate, ethylene vinyl acetate, PPDO, polytetrafluoroethylparticle particle, methyl trimethoxy epoxide silicon Alkane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, the mass ratio of end hydroxy butadiene are 22: 11: 16: 32: 29 ∶14∶25∶32∶11∶8∶29;The mass ratio of the plastics composite and uramit, paraffin is 100: 19: 2.
The present invention coordinates using so that space is more uniform for paraffin, especially led to using uramit as major porogen Cross the heating of two steps, it is to avoid sky is prematurely formed, the uniformity in the hole also fully ensured that, and this does not see in prior art, especially It is follow-up hydrothermal processing, this is that the present invention is pioneering, substantially avoid the influence of impurity in hole, several combinations is produced obtained from Product filter effect is excellent, and combines plastics composite, effectively can produce suction with particulate pollutant, even organic pollution Attached effect.
The present invention is except mechanical property and the filtering designing discounting formula structure, improve product creative in structure Effect, it is main that fine efficient filtering and mechanical property, service life are realized by preparing raw material and preparation technology Greatly improve.Existing plastics chimney filter is all prepared by polypropylene or doping polypropylene injection, because polypropylene is easy to process, phase To cheap, but the problem of there is obvious poor mechanical property, poor filtration effect, short service life, the present invention reopens thinking, please Materialogy expert is taught, new preparing raw material and technique is designed, although be complicated compared with existing product in cost and preparation, but It is the filter effect with long useful life and high-precision, positive and negative calculating for the enterprise using chimney filter, is handled Same gas, cost of consumption is the 29% of existing product, can be calculated, in simple terms, and product price of the present invention is existing 3 times or so of product, but useful life of the present invention is at least 10 times of existing product, it is easy to calculate, after practical application, the present invention It is still low cost.
Chimney filter processing gas is, it is necessary to possess excellent anti-wear performance, strainability, heat resistance, in addition it is also necessary to excellent power Learn performance, fire resistance;Existing product typically all addition inorganic material are to improve some performances, but organic-inorganic product is natural Heterogeneity cause to be modified anyway and can not still avoid the defect between two-phase, the short time is not seen, but high in high temperature Under wet gas constantly washes away, defect point can constantly expand, and cause damage of product, and present invention, avoiding this problem, this is also this One of the reason for invention life of product is long, but by rational organic matter compatibility, obtained product still mechanical property, heat-resisting Performance, anti-wear performance are excellent, do not reduce quality.
In the present invention, synthesis compound is as high-strength, high-anti-friction material of main part, and polytetrafluoroethylene (PTFE) is mechanical strong to improve Degree and processing characteristics simultaneously reduce coefficient of friction;The self-lubricating of organo-silicon compound and organosulfur compound to improve product Property, while 3- aminopropyltriethoxies dimethoxysilane can also improve the affinity between product composition, polyoxyethylene caster Oil increase activity, improves the reactivity between product;The present invention is not to reach technique effect by a kind of or two or three kind of material, But gas chromatography is organically subjected to compatibility, synergy is played after reaction, excellent technique effect can be just obtained, such as The cooperation of silicon and sulphur not only improves product heat resistance and also gives good fire resistance, such as acid anhydrides, ester, the cooperation of ketone are main body Material provides excellent mechanical support;Etc..
The plastics composite of the present invention can have higher elasticity and intensity in wider hardness range, excellent wear-resisting Property, oil resistivity, fatigue durability and anti-vibration resistance, antiseptic property is good after end hydroxy butadiene and Emulsifier EL-60 reaction; Using resin combination as major ingredient, reactivity and stability are adjusted from reactive compound, by organosilicon, Organic fluoride characteristic, Degrees of fusion, mobility between the wear resistence of enhancing itself, small molecule guarantee each component so that performance reaches optimal state; Except with good adhesive property between each resin, also with enough intensity and good anti-wear performance.Usually, add Certain inorganic filler can improve the intensity of epoxyn, and can also improve other property of adhesive Can, after ethylene vinyl acetate reacts with lauryl sodium sulfate, end hydroxy butadiene, corrosion-resistant, wear-resisting, Thermal conductivity is good, thermal coefficient of expansion is low, can play skeleton and wear-resistant effect, and Emulsifier EL-60, fatty acid ester can be with Reduce coefficient of friction, product can be made to become smooth, coefficient of friction diminishes.
In the present invention, the plastics chimney filter also includes base, and body is arranged on base;It is preferred that, in the middle of the base It is interior using chimney filter inside, circular platform type projection is ecto-entad protrusion, i.e., from chimney filter bottom to convex provided with circular platform type bulge-structure Go out;The invention chimney filter bottom set circular platform type bulge-structure, when air pulse undershoot to circular platform type bulge-structure When, bounce-back is effectively formed, plays a part of distributing air-flow, increases pulse lavage effect.Circular platform type is raised, up-small and down-big, microcephaly One end is closed, major part one end open, is hollow from microcephaly to the one of major part section, chimney filter body is mitigated while pulsatile effect is lifted Weight.Using right-angled trapezium perpendicular to straight line where the waist on base as rotary shaft, what curved surface formed by remaining each side rotation was surrounded Solid is called round platform;Rotary shaft is called the axle of round platform, the upper and lower formed disc of bottom rotation of right-angled trapezium be referred to as round platform it is upper, Bottom surface, the waist that another formed curved surface of waist rotation is referred to as the right-angled trapezium of each position on the side of round platform, side is referred to as circle The bus of platform, the height of round platform is the distance between upper and lower bottom surface.
In the present invention, the bracing piece is a plurality of;The contact point of the bracing piece and reinforcing ring is evenly distributed on reinforcement On ring;The present invention sets reinforcing ring in chimney filter first, is circular configuration, it is to avoid the use of inner support frame, reduces chimney filter Component wear, and cost can be reduced, it is important to which chimney filter intensity can be ensured by being integrally formed with body, and the present invention's plus The strengthening part that strong bar is constituted with reinforcing ring is flow guiding type structure, does not increase air resistance, does not influence filtering accuracy and efficiency, is selected Select a plurality of bracing pieces be evenly distributed on reinforcing ring can provide stiffening effect while so that reinforcing ring is stablized in itself.
The present invention limits reinforcing ring and is located at body one end, rather than other positions, has both solved existing filter bag or chimney filter The problem of needing inner support frame, strengthens the mechanical strength of chimney filter, while avoiding the influence to pulse cleaning, it is important to be located at again One end can not influence gas filtration.
In the present invention, the bracing piece is flat structure;The bracing piece is 4~8;Flat structure refers to bracing piece Thickness is compared with length, and the ratio that thickness accounts for length is small, and preferably the thickness of bracing piece is the 2~3% of length, can so be formed Gas flow guiding, it is to avoid the interference flowed to gas, while limiting the quantity of bracing piece, on the one hand ensures enough stiffening effects, On the other hand cost is reduced, influence of the strengthening part to filter effect is also avoided.
In the present invention, the contact point of the bracing piece and body is located at the teeth groove of gear type structure;Each reinforcement Pole length is consistent so that reinforcing ring is located in the middle part of body.Body of the present invention and the cross-sectional area of outer tube are that tooth top is handed over teeth groove For the gear shape of setting, centered on symmetrical structure;Reinforcing ring is arranged in body, can effectively be played booster action, be prevented Stress-deviation, and at the teeth groove of gear structure set bracing piece tie point, it is possible to reduce prepare difficulty, more importantly keep away Exempt to interference in air flow.
In the present invention, the angle of the arcuate structure is 30~150 degree;The tooth top of gear type structure can be by one with teeth groove Section arc composition, can also be made up of several sections of arcuate structures of different radians;The top of all tooth tops and the bottom of all teeth groove Respectively on same circumference, the number of the angle corresponding teeth of arcuate structure, the number of teeth is too many, is difficult to be stripped in formed product, and And be easily deformed, and there may be filtering dead angle, can not preferably increase filtration contact area again very little;The present invention limits angle Degree, achieves and not only improves filtering accuracy but also increase the technique effect of filter efficiency, and prepared by product easy, and structure is steady It is fixed.
In the present invention, the height of the tooth of the gear type structure is the 28~34% of reinforcement pole length;Pass through the tune of height Section can change chimney filter filtration contact area, and chimney filter pipe diameter size can be changed by the length adjustment of bracing piece, limit both Ratio, on the basis of filtering accuracy, filter efficiency is ensured, it is ensured that stable intensity.
Because above-mentioned technical proposal is used, the present invention has following advantages compared with prior art:
The present invention creatively sets strengthening part in chimney filter, it is to avoid due under intensity caused by overall gear structure Drop, the problem of stability is poor, and by limiting strengthening part various parameters, reach and both stablize chimney filter, and do not influence gas to flow Effect;Tooth top structure is provided with the middle of chimney filter base first, by the inside tooth top in chimney filter bottom, when air pulse undershoot to tooth top During structure, bounce-back is effectively formed, plays a part of distributing air-flow, increases pulse lavage effect;Sintering of plastics chimney filter is not necessary to simultaneously There is inner support frame, it is not easy to wear, it is possible to decrease cost, mitigate chimney filter body weight while filter effect is lifted, overcome existing skill The problem that art chimney filter can be aggravated;Discounting area increases, and increases filter area;Other equipment reduces floor space, can also reduce and make Valency cost;By changing section number of teeth mesh, the height of gear teeth tips part adjust filtration contact area, using isostatic pressed into Type, can not only ensure that the deformation comparison of product is small, can also require according to product design, change the cross section parameters of chimney filter, So as to increase the filtration contact area of chimney filter to a certain extent, to improve the filter effect or cost-effective of chimney filter.In design In the case of identical filter area, identical filtering surface can be reached by reducing the consumption of chimney filter or reducing the caliber of chimney filter Product, and space shared by the screen pipe of more slim pipe diameter can be fewer, can thus reduce the volume of chimney filter, and saving steel is used Amount, so as to generally save the manufacturing cost of filter plant;Rationally, dismounting is easy for plastics chimney filter structure composition, is applicable a variety of mistakes Filter occasion;Material forms for sintering of plastics, and intensity is big, and sintering precision is high and wearability is strong;Filter type is absorption, surface filtration It is combined with in-depth filtration, work principle of filter is mainly inertial collision, diffusion and retained, and it is relative to cyclone dust removal, stratum granulosum mistake Filtering dust collecting, electrostatic precipitation, wet sprinkling dedusting etc., not only efficiency of dust collection is high, filtering accuracy is high, obvious heat of smoke utilization rate is high, and And using scope is wide, it is high temperature resistant, corrosion-resistant.
Plastics chimney filter disclosed by the invention, which belongs to clean again, uses environmentally friendly machine, and cleaning performance is optimal;Can be direct Traditional filter bag equipment is changed, is not necessary to change existing dust-collecting equipment, while service life of equipment is long, service life can be more than tradition More than 10 times of type, is not only summarized from actual motion, also can determine that from accelerating to damage to test, the wear life of product of the present invention is existing There are 12.5 times of product;Reduction operation operating cost, it is adaptable to high temperature, the dust removal process of acid-base property coal-fired flue-gas.
Embodiment
With reference to embodiment, the invention will be further described:
Embodiment one
3- aminopropyltriethoxies dimethoxysilane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, then Poly butyric ester is added, is stirred 20 minutes at 100 degree, ethylene vinyl acetate is added with poly- to dioxy ring Hexanone, 140 degree are stirred 2 hours, are cooled to room temperature and are obtained compound;By compound, polytetrafluoroethylparticle particle, methyl trimethoxy epoxide Silane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form scattered Uniform mixture;Then by mixture under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, at heat Mixture extruder granulation after reason obtains plastics composite, i.e. plastics chimney filter plastics composite;
Plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin, note is added into In molding machine, body, reinforcing ring and bracing piece integrated component crude product are prepared according to the technique of 150 degree of meltings, 245 degree of shapings;Then Body, reinforcing ring and bracing piece integrated component crude product are put into boiling water and handled 2 hours, is taken out, heated-air drying, as body, Reinforcing ring and bracing piece integrated component;Body, reinforcing ring and bracing piece integrated component and base combination are obtained into plastics chimney filter.
Above-mentioned 3- aminopropyltriethoxies dimethoxysilane, Emulsifier EL-60, fatty acid ester, poly butyric ester, second Alkene-vinyl acetate copolymers, PPDO, polytetrafluoroethylparticle particle, MTMS, dialkyl group two D2EHDTPA pyridine, lauryl sodium sulfate, the mass ratio of end hydroxy butadiene are 22: 11: 16: 32: 29: 14: 25: 32: 11∶8∶29;The mass ratio of plastics composite and uramit, paraffin is 100: 19: 2;To above-mentioned tubular body (without bracing piece with adding Qiang Huan, for testing) the index such as bending strength, tensile strength and wear rate detected that tensile strength is more than 260 MPas, Bending strength is more than 370 MPas, and 5000 dry grinding loss rates are less than 0.01%, 10,000 wet-milling loss rates and are less than 0.008%, and abrasion refers to Number is less than 21 (GB3960-83);Toughness of products is strong, wear-resistant, and coefficient of friction is small, reduces noise;Oxygen index (OI) is 49;10% hydrogen Sodium hydroxide solution soaks 30 minutes surfaces without influence:Regular hydrochloric acid soaks 15 minutes surfaces without influence.
Embodiment two
Using the preparation method of embodiment one, reinforcing ring is located in body, and is connected by bracing piece with body;Body Cross section is gear type structure;The tooth top and teeth groove of gear type structure are all arcuate structure;Reinforcing ring is located at body one end;Strengthen Bar is 8;The contact point of bracing piece and reinforcing ring is evenly distributed on reinforcing ring;Bracing piece is that (thickness is length to flat structure 3%);The contact point of bracing piece and body is located at the teeth groove of gear type structure;Each reinforcement pole length is consistent;Arcuate structure Angle be 150 degree;The height of the tooth of gear type structure is the 30% of reinforcement pole length;Said structure is all conventional geometry knot Structure.
Measured by repeatedly actual, the plastics chimney filter dust clearance of the present embodiment is reached under 99%, same size, is filtered Efficiency is more than under 2.3 times of existing product, same treatment conditions, and service life is at least 10 times of existing product, in existing product Damage on the basis of ten, product of the present invention is still continuing with.
By test, product of the invention:Also it can determine that from accelerating to damage to test, the wear life of product of the present invention is existing There are more than 12 times of product;Press perpendicular is to the 50% of external diameter, and off-load immediately, product does not rupture;150 DEG C of pressurize 2Kg, 8 hours It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Flexibility≤ 1.2%, ring stiffness >=21KN/m2
Embodiment three
Using the preparation method of embodiment one, reinforcing ring is located in body, and is connected by bracing piece with body;Body Cross section is gear type structure;The tooth top and teeth groove of gear type structure are all arcuate structure;Reinforcing ring is located at body one end;Strengthen Bar is 4;The contact point of bracing piece and reinforcing ring is evenly distributed on reinforcing ring;Bracing piece is that (thickness is length to flat structure 3%);The contact point of bracing piece and body is located at the teeth groove of gear type structure;Each reinforcement pole length is consistent;Arcuate structure Angle be 40 degree;The height of the tooth of gear type structure is the 33% of reinforcement pole length.
Measured by repeatedly actual, the plastics chimney filter dust clearance of the present embodiment is reached under 99%, same size, is filtered Efficiency is more than under 2.5 times of existing product, same treatment conditions, and service life is at least 10 times of existing product, in existing product Damage on the basis of ten, product of the present invention is still continuing with.
By test, product of the invention:Also it can determine that from accelerating to damage to test, the wear life of product of the present invention is existing There are more than 12 times of product;Press perpendicular is to the 50% of external diameter, and off-load immediately, product does not rupture;150 DEG C of pressurize 2Kg, 8 hours It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Flexibility≤ 1.2%, ring stiffness >=21KN/m2
Example IV
Using the preparation method of embodiment one, reinforcing ring is located in body, and is connected by bracing piece with body;Body Cross section is gear type structure;The tooth top and teeth groove of gear type structure are all arcuate structure;Reinforcing ring is located at body one end;Strengthen Bar is 6;The contact point of bracing piece and reinforcing ring is evenly distributed on reinforcing ring;Bracing piece is that (thickness is length to flat structure 3%);The contact point of bracing piece and body is located at the teeth groove of gear type structure;Each reinforcement pole length is consistent;Arcuate structure Angle be 90 degree;The height of the tooth of gear type structure is the 30% of reinforcement pole length;Provided with circular platform type projection knot in the middle of base Structure.
Measured by repeatedly actual, the plastics chimney filter dust clearance of the present embodiment is reached under 99%, same size, is filtered Efficiency is more than under 2.4 times of existing product, same treatment conditions, and service life is at least 10 times of existing product, in existing product Damage on the basis of ten, product of the present invention is still continuing with.
By test, product of the invention:Also it can determine that from accelerating to damage to test, the wear life of product of the present invention is existing There are more than 12 times of product;Press perpendicular is to the 50% of external diameter, and off-load immediately, product does not rupture;150 DEG C of pressurize 2Kg, 8 hours It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Flexibility≤ 1.2%, ring stiffness >=21KN/m2

Claims (10)

1. a kind of plastics chimney filter, it is characterised in that:By 3- aminopropyltriethoxies dimethoxysilane, Emulsifier EL-60 and fat Acid esters is stirred 1 hour at 90 degree, adds poly butyric ester, is stirred 20 minutes at 100 degree, is added ethane-acetic acid ethyenyl Base ester copolymer and PPDO, 140 degree are stirred 2 hours, are cooled to room temperature and are obtained compound;By compound, poly- four PVF particle, MTMS, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, terminal hydroxy group polybutadiene Alkene is mixed with batch mixer, forms finely dispersed mixture;Then by mixture under 170 degree, 4MPa, closed heat treatment 4 is small When;Then under 235 degree, the mixture extruder granulation after heat treatment is obtained into plastics composite;By plastics composite with gathering Ureaformaldehyde, paraffin mixing after add injection machine in, according to 150 degree melting, 245 degree be molded techniques prepare body, reinforcing ring and Bracing piece integrated component crude product;Then body, reinforcing ring and bracing piece integrated component crude product are put into boiling water and handled 2 hours, Take out, heated-air drying, as body, reinforcing ring and bracing piece integrated component;By body, reinforcing ring and bracing piece integrated component with Base combination obtains plastics chimney filter.
2. plastics chimney filter according to claim 1, it is characterised in that:The reinforcing ring is located in body, and passes through bracing piece It is connected with body;The cross section of the body is gear type structure;The tooth top and teeth groove of the gear type structure are all arc knot Structure;The reinforcing ring is located at body one end;Circular platform type bulge-structure is provided with the middle of the base;The bracing piece is 4~8; The contact point of the bracing piece and reinforcing ring is evenly distributed on reinforcing ring;The bracing piece is flat structure;The bracing piece It is located at the contact point of body at the teeth groove of gear type structure;Each reinforcement pole length is consistent;The angle of the arcuate structure Spend for 30~150 degree;The height of the tooth of the gear type structure is the 28~34% of reinforcement pole length.
3. plastics chimney filter according to claim 1, it is characterised in that:The 3- aminopropyltriethoxies dimethoxysilane, polyoxy Ethylene castor oil, fatty acid ester, poly butyric ester, ethylene vinyl acetate, PPDO, poly- four PVF particle, MTMS, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, terminal hydroxy group polybutadiene The mass ratio of alkene is 22: 11: 16: 32: 29: 14: 25: 32: 11: 8: 29;The plastics composite and uramit, the matter of paraffin Amount is than being 100: 19: 2.
4. a kind of preparation method of plastics chimney filter, it is characterised in that comprise the following steps:By 3- aminopropyltriethoxy dimethoxy silicon Alkane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, add poly butyric ester, and 20 points are stirred at 100 degree Clock, adds ethylene vinyl acetate and PPDO, and 140 degree are stirred 2 hours, are cooled to room temperature and are obtained To compound;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, dodecane Base sodium sulphate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture 170 degree, Under 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is obtained into plastic composition Thing;Added after plastics composite is mixed with uramit, paraffin in injection machine, the work being molded according to 150 degree of meltings, 245 degree Skill prepares body, reinforcing ring and bracing piece integrated component crude product;Then body, reinforcing ring and bracing piece integrated component crude product are put Enter in boiling water and handle 2 hours, take out, heated-air drying, as body, reinforcing ring and bracing piece integrated component;By body, reinforcing ring Plastics chimney filter is obtained with bracing piece integrated component and base combination.
5. the preparation method of plastics chimney filter according to claim 4, it is characterised in that:The reinforcing ring is located in body, and It is connected by bracing piece with body;The cross section of the body is gear type structure;The tooth top and teeth groove of the gear type structure All it is arcuate structure;The reinforcing ring is located at body one end;Circular platform type bulge-structure is provided with the middle of the base;The bracing piece For 4~8;The contact point of the bracing piece and reinforcing ring is evenly distributed on reinforcing ring;The bracing piece is flat structure;Institute The contact point for stating bracing piece and body is located at the teeth groove of gear type structure;Each reinforcement pole length is consistent;The arc The angle of structure is 30~150 degree;The height of the tooth of the gear type structure is the 28~34% of reinforcement pole length.
6. plastics chimney filter feedstock composition, it is characterised in that:By 3- aminopropyltriethoxies dimethoxysilane, polyoxyethylene caster Oil with fatty acid ester 90 degree stir 1 hour, add poly butyric ester, 100 degree stirring 20 minutes, add ethene- Vinyl acetate copolymers and PPDO, 140 degree are stirred 2 hours, are cooled to room temperature and are obtained compound;Will mixing Material, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, terminal hydroxy group Polybutadiene is mixed with batch mixer, forms finely dispersed mixture;Then by mixture under 170 degree, 4MPa, at closed heat Reason 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is obtained into plastics composite;By plastics composite The plastics chimney filter feedstock composition is obtained after being mixed with uramit, paraffin.
7. plastics chimney filter plastics composite, it is characterised in that:The plastics composite is prepared as, by 3- aminopropyltriethoxies two Methoxy silane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, poly butyric ester are added, at 100 degree Stirring 20 minutes, adds ethylene vinyl acetate and PPDO, and 140 degree are stirred 2 hours, cooling Compound is obtained to room temperature;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyrrole Pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then will mixing Thing is under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated To plastics composite.
8. the preparation method of plastics chimney filter plastics composite, it is characterised in that:Comprise the following steps, by 3- aminopropyltriethoxies two Methoxy silane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, poly butyric ester are added, at 100 degree Stirring 20 minutes, adds ethylene vinyl acetate and PPDO, and 140 degree are stirred 2 hours, cooling Compound is obtained to room temperature;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyrrole Pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then will mixing Thing is under 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated To plastics composite.
9. plastics chimney filter body, it is characterised in that:Being prepared as the body, by 3- aminopropyltriethoxies dimethoxysilane, gathers Oxygen ethylene castor oil is stirred 1 hour with fatty acid ester at 90 degree, adds poly butyric ester, is stirred 20 minutes at 100 degree, then Ethylene vinyl acetate and PPDO are added, 140 degree are stirred 2 hours, are cooled to room temperature and are mixed Material;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, dodecyl sulphate Sodium, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture in 170 degree, 4MPa Under, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is obtained into plastics composite; Added after plastics composite is mixed with uramit, paraffin in injection machine, the technique system being molded according to 150 degree of meltings, 245 degree Standby body crude product;Then body crude product is put into boiling water and handled 2 hours, taken out, heated-air drying, as body.
10. the preparation method of plastics chimney filter body, it is characterised in that comprise the following steps, by 3- aminopropyltriethoxy dimethoxys Silane, Emulsifier EL-60 and fatty acid ester are stirred 1 hour at 90 degree, add poly butyric ester, and 20 are stirred at 100 degree Minute, ethylene vinyl acetate and PPDO are added, 140 degree are stirred 2 hours, are cooled to room temperature Obtain compound;By compound, polytetrafluoroethylparticle particle, MTMS, dialkyl dithiophosphoric acid pyridine, 12 Sodium alkyl sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture 170 Under degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder granulation after heat treatment is obtained into plastics Composition;Added after plastics composite is mixed with uramit, paraffin in injection machine, according to 150 degree of meltings, 245 degree of shapings Technique prepare body crude product;Then body crude product is put into boiling water and handled 2 hours, taken out, heated-air drying, as body.
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CN201810611125.6A CN108822512A (en) 2017-05-24 2017-05-24 A kind of plastics chimney filter tube body and preparation method thereof
CN201810611943.6A CN109021514A (en) 2017-05-24 2017-05-24 A kind of plastics chimney filter plastics composite and preparation method thereof
CN201810611941.7A CN108822513A (en) 2017-05-24 2017-05-24 A kind of preparation method of plastics chimney filter
CN201810611942.1A CN109021513A (en) 2017-05-24 2017-05-24 A kind of plastics chimney filter feedstock composition and preparation method thereof

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CN201810611125.6A Division CN108822512A (en) 2017-05-24 2017-05-24 A kind of plastics chimney filter tube body and preparation method thereof
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CN105625042A (en) * 2014-11-04 2016-06-01 厦门三维丝环保股份有限公司 High temperature resistant filter cartridge substrate filter material stiffening finishing method
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CN105625042A (en) * 2014-11-04 2016-06-01 厦门三维丝环保股份有限公司 High temperature resistant filter cartridge substrate filter material stiffening finishing method
CN104945703A (en) * 2015-01-23 2015-09-30 湖北步洲环保科技有限公司 Preparation method of foamed polyethylene filter material
CN105860212A (en) * 2016-04-29 2016-08-17 秦诗发 3D plastic-sintered antistatic flame-retardant gas-liquid filter cartridge
CN106334375A (en) * 2016-10-17 2017-01-18 江苏工程职业技术学院 Chitosan ultra-fine fiber filter material and preparation method thereof

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