CN108822512A - A kind of plastics chimney filter tube body and preparation method thereof - Google Patents

A kind of plastics chimney filter tube body and preparation method thereof Download PDF

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Publication number
CN108822512A
CN108822512A CN201810611125.6A CN201810611125A CN108822512A CN 108822512 A CN108822512 A CN 108822512A CN 201810611125 A CN201810611125 A CN 201810611125A CN 108822512 A CN108822512 A CN 108822512A
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tube body
degree
chimney filter
plastics
mixture
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彭代信
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SUZHOU YIKETAI ELECTRONIC MATERIAL CO Ltd
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SUZHOU YIKETAI ELECTRONIC MATERIAL CO Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/04Polyesters derived from hydroxycarboxylic acids, e.g. lactones
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/0001Making filtering elements
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D46/00Filters or filtering processes specially modified for separating dispersed particles from gases or vapours
    • B01D46/24Particle separators, e.g. dust precipitators, using rigid hollow filter bodies
    • B01D46/2403Particle separators, e.g. dust precipitators, using rigid hollow filter bodies characterised by the physical shape or structure of the filtering element
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/18Applications used for pipes
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/02Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Geometry (AREA)
  • Filtering Materials (AREA)
  • Filtering Of Dispersed Particles In Gases (AREA)

Abstract

The invention discloses a kind of plastics chimney filter tube bodies and preparation method thereof, and 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, aliphatic ester, poly butyric ester, ethylene vinyl acetate, polydioxanone, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, end hydroxy butadiene are prepared into plastics composite;Plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin, is added into injection molding machine, is prepared chimney filter.Plastics chimney filter disclosed by the invention, which belongs to, to be cleaned again using environmentally friendly machine, and traditional filter bag equipment can be directly replaced, and be not necessary to modify existing dust-collecting equipment, while service life of equipment is long, and service life can be greater than traditional 10 times or more.

Description

A kind of plastics chimney filter tube body and preparation method thereof
The present invention is a kind of entitled plastics chimney filter and the composition for the plastics chimney filter, the applying date are 2017 May 24, application No. is the divisional applications of 2017104124219 patent applications, belong to product preparation method part.
Technical field
The invention belongs to field of environment protection equipment, and in particular to a kind of plastics chimney filter tube body and preparation method thereof.
Background technique
With the development of modern industry, influence caused by health of the dust to environment and the mankind is got worse, effectively Dust pollution is administered, Environmental protection pay attention to day by day and global warming phenomenon are serious in recent years, in order to advocate carbon reduction, Environmental protection industry flourishes, and purifies the living environment of the mankind, it has also become proprietary common recognition.Existing chimney filter is only flat, filter Pipe discounting end is divided into pointed and rectangular, and existing plastics chimney filter pulse dust cleaning has dead angle, causes ash-removal effect difference and filter area small; Precipitron operation pressure is high;Conventional filter bag can not be replaced.
Summary of the invention
The object of the present invention is to provide a kind of plastics chimney filters, are used for deduster dedusting, are good for the environment development.
To achieve the above object of the invention, the technical solution adopted by the present invention is that:A kind of plastics chimney filter, by 3- aminopropyltriethoxy Dimethoxysilane, Emulsifier EL-60 and aliphatic ester stir 1 hour at 90 degree, poly butyric ester are added, 100 Degree stirring 20 minutes adds ethylene vinyl acetate and polydioxanone, and 140 degree are stirred 2 hours, cold But mixture is obtained to room temperature;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid Pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then it will mix Object is closed at 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated Obtain plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, melted according to 150 degree, 245 degree of molding techniques prepare tube body, reinforcing ring and reinforcing rod integrated component crude product;Then by tube body, reinforcing ring and reinforcing rod Integrated component crude product is put into boiling water and handles 2 hours, takes out, heated-air drying, as tube body, reinforcing ring and reinforcing rod one portion Part;Tube body, reinforcing ring and reinforcing rod integrated component and base combination are obtained into plastics chimney filter.
The invention also discloses a kind of preparation methods of plastics chimney filter, include the following steps:By 3- aminopropyltriethoxy diformazan Oxysilane, Emulsifier EL-60 and aliphatic ester stir 1 hour at 90 degree, add poly butyric ester, stir at 100 degree It mixes 20 minutes, adds ethylene vinyl acetate and polydioxanone, 140 degree are stirred 2 hours, are cooled to Room temperature obtains mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, Lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then mixture is existed 170 degree, under 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated and is moulded Feed composition;After plastics composite is mixed with uramit, paraffin be added injection molding machine in, according to 150 degree melt, 245 degree at The technique of type prepares tube body, reinforcing ring and reinforcing rod integrated component crude product;Then by tube body, reinforcing ring and reinforcing rod integrated component Crude product is put into boiling water and handles 2 hours, takes out, heated-air drying, as tube body, reinforcing ring and reinforcing rod integrated component;By tube body, Reinforcing ring and reinforcing rod integrated component and base combination obtain plastics chimney filter.
In the present invention, chimney filter is hatch frame, and whole similar tubulose, bottom is mounted on shell, and top opening is used for arteries and veins Rush in wind, tube wall filtration;The reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;The tube body Cross section is gear type structure;The tooth top and tooth socket of the gear type structure are all arcuate structure;The reinforcing ring is located at tube body One end;Circular platform type bulge-structure is equipped among the pedestal;The reinforcing rod is 4~8;The reinforcing rod and reinforcing ring connect Contact is evenly distributed on reinforcing ring;The reinforcing rod is flat structure;The contact point of the reinforcing rod and tube body is located at gear At the tooth socket of type structure;Each reinforcement pole length is consistent;The angle of the arcuate structure is 30~150 degree;The gear The height of the tooth of type structure is reinforce pole length 28~34%.
The invention also discloses a kind of plastics chimney filter tube body, the tube body is prepared as, by 3- aminopropyltriethoxy dimethoxy Base silane, Emulsifier EL-60 and aliphatic ester stir 1 hour at 90 degree, add poly butyric ester, stir at 100 degree 20 minutes, ethylene vinyl acetate and polydioxanone are added, 140 degree are stirred 2 hours, and room is cooled to Temperature obtains mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, ten Sodium dialkyl sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then mixture is existed 170 degree, under 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated and is moulded Feed composition;After plastics composite is mixed with uramit, paraffin be added injection molding machine in, according to 150 degree melt, 245 degree at The technique of type prepares tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying is as managed Body.
The invention also discloses a kind of preparation methods of plastics chimney filter tube body, include the following steps, by 3- aminopropyltriethoxy Dimethoxysilane, Emulsifier EL-60 and aliphatic ester stir 1 hour at 90 degree, poly butyric ester are added, 100 Degree stirring 20 minutes adds ethylene vinyl acetate and polydioxanone, and 140 degree are stirred 2 hours, cold But mixture is obtained to room temperature;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid Pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then it will mix Object is closed at 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated Obtain plastics composite;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, melted according to 150 degree, 245 degree of molding techniques prepare tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying, As tube body.
In the present invention, the 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, aliphatic ester, poly- hydroxyl Butyrate, ethylene vinyl acetate, polydioxanone, polytetrafluoroethylparticle particle, methyl trimethoxy oxygroup silicon Alkane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, end hydroxy butadiene mass ratio be 22: 11: 16: 32: 29 :14:25:32:11:8:29;The mass ratio of the plastics composite and uramit, paraffin is 100: 19: 2.
The present invention cooperates using so that gap is more uniform for paraffin using uramit as major porogen, especially logical The heating of two steps is crossed, sky is avoided and is prematurely formed, the uniformity in the hole also fully ensured that, this does not see in the prior art, especially It is follow-up hydrothermal processing, this is that the present invention is pioneering, substantially avoids the influence of impurity in hole, and several combinations produce obtained from Product filter effect is excellent, and combines plastics composite, effectively can generate suction with particulate pollutant, even organic pollutant Attached effect.
The present invention designs discounting formula structure in addition to creative in structure, improves the mechanical property and filtering of product Effect mainly realizes fine efficient filtering and mechanical property, service life by preparing raw material and preparation process Greatly improve.Existing plastics chimney filter is all polypropylene or doping polypropylene injection molding preparation, because polypropylene is easy to process, phase To cheap, but there is a problem of that apparent poor mechanical property, poor filtration effect, service life are short, the present invention reopens thinking, asks Teach materialogy expert, design it is new prepare raw material and technique, although upper complicated compared with existing product in cost and preparation, It is the filter effect with long service life and high-precision, positive and negative calculating is handled for the enterprise for using chimney filter Same gas, cost of consumption are the 29% of existing product, can be calculated, and in simple terms, product of the present invention price is existing 3 times of product or so, but service life of the present invention is at least 10 times of existing product, it is easy to it calculates, after practical application, the present invention It is still low cost.
Chimney filter processing gas needs to have excellent wear-resisting property, strainability, heat resistance, it is also necessary to excellent power Learn performance, flame retardant property;Existing product generally all addition inorganic material are to improve some performances, but organic-inorganic product is natural Heterogeneity cause to be modified the defect that not can avoid still between two-phase anyway, the short time is not seen, but in high temperature height Under wet gas constantly washes away, defect point can constantly expand, and lead to damage of product, and the invention avoids this problems, this is also this Long one of the reason of invention life of product, but by reasonable organic matter compatibility, obtained product still mechanical property, heat-resisting Performance, wear-resisting property are excellent, do not reduce quality.
In the present invention, for synthesis mixture as high-strength, high-anti-friction material of main part, polytetrafluoroethylene (PTFE) is mechanical strong to improve Degree and processing performance simultaneously reduce coefficient of friction;The self-lubricating of organo-silicon compound and organosulfur compound to improve product Property, while 3- aminopropyltriethoxy dimethoxysilane can also improve the affinity between product composition, polyoxyethylene caster Oil increases activity, improves the reactivity between product;The present invention is not to reach technical effect by a kind of or two or three kind of substance, But gas chromatography is organically subjected to compatibility, synergistic effect is played after reaction, can just obtain excellent technical effect, such as The cooperation of silicon and sulphur not only improves product heat resistance and also gives good flame retardant property, such as based on the cooperation of acid anhydrides, ester, ketone Material provides excellent mechanical support;Etc..
Plastics composite of the invention can be in wider hardness range elasticity with higher and intensity, excellent wear-resisting Property, oil resistivity, fatigue durability and anti-vibration resistance, antiseptic property is good after end hydroxy butadiene is reacted with Emulsifier EL-60; Using resin combination as major ingredient, reactive compound is selected to adjust reactivity and stability, by organosilicon, Organic fluoride characteristic, Enhance the wear resistence of itself, degrees of fusion, mobility between small molecule guarantee each component, so that performance reaches optimal state; In addition to good adhesive property, also there is enough intensity and good wear-resisting property between each resin.Generally, it is added The intensity of epoxyn can be improved in certain inorganic filler, and can also improve other property of adhesive Can, after ethylene vinyl acetate is reacted with lauryl sodium sulfate, end hydroxy butadiene, corrosion-resistant, wear-resisting, Thermal conductivity is good, thermal expansion coefficient is low, can play skeleton and wear-resistant effect, and Emulsifier EL-60, aliphatic ester can be with Reduce coefficient of friction, product can be made to become smooth, coefficient of friction becomes smaller.
In the present invention, the plastics chimney filter further includes pedestal, and tube body is mounted on the base;Preferably, among the pedestal Equipped with circular platform type bulge-structure, be with chimney filter inside it is interior, circular platform type protrusion is ecto-entad protrusion, i.e., from chimney filter bottom to convex Out;Circular platform type bulge-structure is arranged in chimney filter bottom in the invention, when air pulse undershoot to circular platform type bulge-structure When, it is effectively formed rebound, plays the role of distributing air-flow, increases pulse lavage effect.Circular platform type protrusion, up-small and down-big, microcephaly Closed at one end, major part is open at one end, is hollow, mitigation chimney filter body while promoting pulsatile effect from microcephaly to the one of major part section Weight.Using right-angled trapezium perpendicular to straight line where the waist on bottom edge as rotary shaft, remaining each side rotation and what the curved surface that is formed was surrounded Solid is called rotary table;Rotary shaft is called the axis of rotary table, the upper and lower bottom of right-angled trapezium rotate formed disc be known as rotary table it is upper, Bottom surface, another waist rotate the side that formed curved surface is known as rotary table, and the waist of the right-angled trapezium of each position is known as justifying on side The bus of platform, the height of rotary table are the distances between upper and lower bottom surface.
In the present invention, the reinforcing rod is a plurality of;The contact point of the reinforcing rod and reinforcing ring is evenly distributed on reinforcement On ring;Reinforcing ring is arranged in the present invention in chimney filter for the first time, is circular configuration, avoids the use of inner support frame, reduce chimney filter Component wear, and cost can be reduced, it is important to can guarantee chimney filter intensity with tube body integrated molding, and it is of the invention plus The strengthening part of strong bar and reinforcing ring composition is flow guiding type structure, does not increase air resistance, does not influence filtering accuracy and efficiency, selects Selecting that a plurality of reinforcing rods are evenly distributed on reinforcing ring can be while providing reinforcing effect, so that reinforcing ring itself is stable.
The present invention limits reinforcing ring and is located at tube body one end, rather than other positions, has both solved existing filter bag or chimney filter The problem of needing inner support frame, and enhance the mechanical strength of chimney filter, while avoiding the influence to pulse cleaning, it is important to it is located at One end can not influence gas filtration.
In the present invention, the reinforcing rod is flat structure;The reinforcing rod is 4~8;Flat structure refers to reinforcing rod For thickness compared with length, the ratio that thickness accounts for length is small, preferably reinforcing rod with a thickness of the 2~3% of length, can so be formed Gas flow guiding avoids the interference flowed to gas, while limiting the quantity of reinforcing rod, on the one hand guarantees enough reinforcing effects, On the other hand cost is reduced, influence of the strengthening part to filter effect is also avoided.
In the present invention, the contact point of the reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement Pole length is consistent, so that reinforcing ring is located in the middle part of tube body.Tube body of the present invention and the cross-sectional area of outer tube are that tooth top and tooth socket are handed over It is center symmetrical structure for the gear shape of setting;Reinforcing ring is arranged in tube body, can effectively play booster action, prevent Stress-deviation, and at the tooth socket of gear structure be arranged reinforcing rod tie point, it is possible to reduce preparation difficulty, more important is keep away Exempt to interference in air flow.
In the present invention, the angle of the arcuate structure is 30~150 degree;The tooth top and tooth socket of gear type structure can be by one Section arc composition, can also be made of several sections of arcuate structures of different radians;The bottom at the top of all tooth tops and all tooth sockets Respectively on the same circumference, the number of the angle corresponding teeth of arcuate structure, the number of teeth is too many, is difficult to demould in formed product, and And be easily deformed, and there may be filtering dead angle, it is very little preferably to increase filtration contact area again;The present invention limits angle Degree achieves the technical effect for not only improving filtering accuracy but also increasing filter efficiency, and product preparation is easy, and structure is steady It is fixed.
In the present invention, the height of the tooth of the gear type structure is reinforce pole length 28~34%;Pass through the tune of height Both section can change chimney filter filtration contact area, can change chimney filter pipe diameter size by the length adjustment of reinforcing rod, limit Ratio guarantees stable intensity on the basis of guaranteeing filtering accuracy, filter efficiency.
Since above-mentioned technical proposal is used, the present invention has following advantages compared with prior art:
Strengthening part is creatively arranged in the present invention in chimney filter, avoids under the intensity as caused by overall gear structure Drop, the problem of stability difference, and by limiting strengthening part various parameters, reach not only stable chimney filter, but also do not influence gas flowing Effect;Tooth top structure is equipped among chimney filter pedestal for the first time, by the inside tooth top in chimney filter bottom, when air pulse undershoot to tooth top When structure, it is effectively formed rebound, plays the role of distributing air-flow, increases pulse lavage effect;Sintering of plastics chimney filter is not necessary to simultaneously There is inner support frame, it is not easy to wear, cost can be reduced, mitigates chimney filter weight while promoting filter effect, overcomes existing skill The problem that art chimney filter can aggravate;Discounting area increases, and increases filter area;In addition equipment reduces occupied area, can also reduce and make Valence cost;Height by changing section number of teeth mesh, gear teeth tips part adjusts filtration contact area, using etc. static pressure at Type can not only guarantee that the deformation comparison of product is small, can also require according to product design, change the cross section parameters of chimney filter, To increase the filtration contact area of chimney filter to a certain extent, to improve the filter effect or save the cost of chimney filter.It is designing In the case where identical filter area, identical filtering surface can be reached by reducing the dosage of chimney filter or reducing the caliber of chimney filter Product, and space occupied by the screen pipe of more slim pipe diameter can be fewer, can thus reduce the volume of chimney filter, and saving steel is used Amount, to generally save the manufacturing cost of filter plant;Plastics chimney filter structure composition is reasonable, and disassembly is easy, and is applicable in a variety of mistakes Filter occasion;Material forms for sintering of plastics, and intensity is big, and sintering precision is high and wearability is strong;Filter type is absorption, surface filtration It is combined with in-depth filtration, work principle of filter is mainly inertial collision, diffusion and retention, relative to cyclone dust removal, stratum granulosum mistake Filtering dust collecting, electrostatic precipitation, wet sprinkling dedusting etc., not only high dust collection efficiency, filtering accuracy are high, obvious heat of smoke utilization rate is high, and And use scope is wide, high temperature resistant, corrosion-resistant.
Plastics chimney filter disclosed by the invention, which belongs to, can clean again using environmentally friendly machine, and cleaning effect is best;It can be direct Traditional filter bag equipment is replaced, is not necessary to modify existing dust-collecting equipment, while service life of equipment is long, service life can be greater than tradition It 10 times of type or more, not only summarizes, also can determine from accelerating damage to test, the wear life of product of the present invention is existing from actual motion There are 12.5 times of product;Reduce operation operating cost, the dust removal process suitable for high temperature, acid-base property coal-fired flue-gas.
Specific embodiment
The present invention will be further described below with reference to examples:
Embodiment one
3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60 and aliphatic ester are stirred 1 hour at 90 degree, then Poly butyric ester is added, is stirred 20 minutes at 100 degree, adds ethylene vinyl acetate and poly- to dioxy ring Hexanone, 140 degree are stirred 2 hours, are cooled to room temperature to obtain mixture;By mixture, polytetrafluoroethylparticle particle, methyl trimethoxy oxygroup Silane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, end hydroxy butadiene are mixed with batch mixer, form dispersion Uniform mixture;Then by mixture at 170 degree, 4MPa, closed heat treatment 4 hours;Then under 235 degree, at heat Mixture extruder after reason is granulated to obtain plastics composite, i.e. plastics chimney filter plastics composite;
Plastics chimney filter feedstock composition is obtained after plastics composite is mixed with uramit, paraffin, is added into note In molding machine, tube body, reinforcing ring and reinforcing rod integrated component crude product are prepared according to 150 degree of meltings, 245 degree of molding techniques;Then Tube body, reinforcing ring and reinforcing rod integrated component crude product are put into boiling water and handled 2 hours, is taken out, heated-air drying, as tube body, Reinforcing ring and reinforcing rod integrated component;Tube body, reinforcing ring and reinforcing rod integrated component and base combination are obtained into plastics chimney filter.
Above-mentioned 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, aliphatic ester, poly butyric ester, second Alkene-vinyl acetate copolymers, polydioxanone, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl group two Thiophosphoric acid pyridine, lauryl sodium sulfate, end hydroxy butadiene mass ratio be 22: 11: 16: 32: 29: 14: 25: 32: 11:8:29;The mass ratio of plastics composite and uramit, paraffin is 100: 19: 2;Above-mentioned tubular body (without reinforcing rod and is added Qiang Huan, for testing) the indexs such as bending strength, tensile strength and wear rate detected, tensile strength is greater than 260 megapascal, Bending strength is greater than 370 megapascal, and less than 0.008%, abrasion refers to less than 0.01%, 10,000 time wet-milling loss rate of 5000 dry grinding loss rates Number is less than 21 (GB3960-83);Toughness of products is strong, wear-resistant, and coefficient of friction is small, reduces noise;Oxygen index (OI) is 49;10% hydrogen Sodium hydroxide solution impregnates 30 minutes surfaces without influence;Regular hydrochloric acid impregnates 15 minutes surfaces without influence.
Embodiment two
Using the preparation method of embodiment one, reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;Tube body Cross section is gear type structure;The tooth top and tooth socket of gear type structure are all arcuate structure;Reinforcing ring is located at tube body one end;Reinforce Bar is 8;The contact point of reinforcing rod and reinforcing ring is evenly distributed on reinforcing ring;Reinforcing rod is flat structure (with a thickness of length 3%);The contact point of reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement pole length is consistent;Arcuate structure Angle be 150 degree;The height of the tooth of gear type structure is reinforce pole length 30%;Above structure is all conventional geometry knot Structure.
By multiple actual measurement, the plastics chimney filter dust removal rate of the present embodiment reaches 99%, under same size, filtering Efficiency is greater than 2.3 times of existing product, and under same treatment conditions, service life is at least 10 times of existing product, in existing product On the basis of damage ten, product of the present invention is still continued to use.
By test, product of the invention:It also can determine from accelerating damage to test, the wear life of product of the present invention is existing There are 12 times or more of product;To the 50% of outer diameter, off-load immediately, product does not rupture press perpendicular;150 DEG C of pressurization 2Kg, 8 hours It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Curvature≤ 1.2%, ring stiffness >=21KN/m2
Embodiment three
Using the preparation method of embodiment one, reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;Tube body Cross section is gear type structure;The tooth top and tooth socket of gear type structure are all arcuate structure;Reinforcing ring is located at tube body one end;Reinforce Bar is 4;The contact point of reinforcing rod and reinforcing ring is evenly distributed on reinforcing ring;Reinforcing rod is flat structure (with a thickness of length 3%);The contact point of reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement pole length is consistent;Arcuate structure Angle be 40 degree;The height of the tooth of gear type structure is reinforce pole length 33%.
By multiple actual measurement, the plastics chimney filter dust removal rate of the present embodiment reaches 99%, under same size, filtering Efficiency is greater than 2.5 times of existing product, and under same treatment conditions, service life is at least 10 times of existing product, in existing product On the basis of damage ten, product of the present invention is still continued to use.
By test, product of the invention:It also can determine from accelerating damage to test, the wear life of product of the present invention is existing There are 12 times or more of product;To the 50% of outer diameter, off-load immediately, product does not rupture press perpendicular;150 DEG C of pressurization 2Kg, 8 hours It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Curvature≤ 1.2%, ring stiffness >=21KN/m2
Example IV
Using the preparation method of embodiment one, reinforcing ring is located in tube body, and is connect by reinforcing rod with tube body;Tube body Cross section is gear type structure;The tooth top and tooth socket of gear type structure are all arcuate structure;Reinforcing ring is located at tube body one end;Reinforce Bar is 6;The contact point of reinforcing rod and reinforcing ring is evenly distributed on reinforcing ring;Reinforcing rod is flat structure (with a thickness of length 3%);The contact point of reinforcing rod and tube body is located at the tooth socket of gear type structure;Each reinforcement pole length is consistent;Arcuate structure Angle be 90 degree;The height of the tooth of gear type structure is reinforce pole length 30%;Circular platform type protrusion knot is equipped among pedestal Structure.
By multiple actual measurement, the plastics chimney filter dust removal rate of the present embodiment reaches 99%, under same size, filtering Efficiency is greater than 2.4 times of existing product, and under same treatment conditions, service life is at least 10 times of existing product, in existing product On the basis of damage ten, product of the present invention is still continued to use.
By test, product of the invention:It also can determine from accelerating damage to test, the wear life of product of the present invention is existing There are 12 times or more of product;To the 50% of outer diameter, off-load immediately, product does not rupture press perpendicular;150 DEG C of pressurization 2Kg, 8 hours It is indeformable;Temperature is under conditions of 0 DEG C, height 1M, the weight for being 3Kg with weight, impacts 20 times, no cracking;Curvature≤ 1.2%, ring stiffness >=21KN/m2

Claims (6)

1. a kind of plastics chimney filter tube body, it is characterised in that:The tube body is prepared as, by 3- aminopropyltriethoxy dimethoxy silicon Alkane, Emulsifier EL-60 and aliphatic ester stir 1 hour at 90 degree, add poly butyric ester, stir 20 points at 100 degree Clock adds ethylene vinyl acetate and polydioxanone, and 140 degree are stirred 2 hours, is cooled to room temperature To mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, dodecane Base sodium sulphate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then by mixture 170 degree, Under 4MPa, closed heat treatment 4 hours;Then it under 235 degree, is granulated the mixture extruder after heat treatment to obtain plastic composition Object;It is added in injection molding machine after plastics composite is mixed with uramit, paraffin, according to 150 degree of meltings, 245 degree of molding works Skill prepares tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying, as tube body.
2. plastics chimney filter tube body according to claim 1, it is characterised in that:The cross section of the tube body is gear type structure; The tooth top and tooth socket of the gear type structure are all arcuate structure;The angle of the arcuate structure is 30~150 degree;The gear The height of the tooth of type structure is reinforce pole length 28~34%.
3. plastics chimney filter tube body according to claim 1, it is characterised in that:The 3- aminopropyltriethoxy dimethoxysilane, Emulsifier EL-60, aliphatic ester, poly butyric ester, ethylene vinyl acetate, polydioxanone, Polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, terminal hydroxy group are poly- The mass ratio of butadiene is 22: 11: 16: 32: 29: 14: 25: 32: 11: 8: 29;The plastics composite and uramit, paraffin Mass ratio be 100: 19: 2.
4. a kind of preparation method of plastics chimney filter tube body, which is characterized in that include the following steps, by 3- aminopropyltriethoxy dimethoxy Base silane, Emulsifier EL-60 and aliphatic ester stir 1 hour at 90 degree, add poly butyric ester, stir at 100 degree 20 minutes, ethylene vinyl acetate and polydioxanone are added, 140 degree are stirred 2 hours, and room is cooled to Temperature obtains mixture;By mixture, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, ten Sodium dialkyl sulfate, end hydroxy butadiene are mixed with batch mixer, form finely dispersed mixture;Then mixture is existed 170 degree, under 4MPa, closed heat treatment 4 hours;Then under 235 degree, the mixture extruder after heat treatment is granulated and is moulded Feed composition;After plastics composite is mixed with uramit, paraffin be added injection molding machine in, according to 150 degree melt, 245 degree at The technique of type prepares tube body crude product;Then tube body crude product is put into boiling water and is handled 2 hours, taken out, heated-air drying is as managed Body.
5. the preparation method of plastics chimney filter tube body according to claim 4, it is characterised in that:The cross section of the tube body is tooth Wheel-type structure;The tooth top and tooth socket of the gear type structure are all arcuate structure;The angle of the arcuate structure is 30~150 Degree;The height of the tooth of the gear type structure is reinforce pole length 28~34%.
6. the preparation method of plastics chimney filter tube body according to claim 4, it is characterised in that:The 3- aminopropyltriethoxy diformazan Oxysilane, aliphatic ester, poly butyric ester, ethylene vinyl acetate, is gathered to two Emulsifier EL-60 Oxygen cyclohexanone, polytetrafluoroethylparticle particle, methyltrimethoxysilane, dialkyl dithiophosphoric acid pyridine, lauryl sodium sulfate, The mass ratio of end hydroxy butadiene is 22: 11: 16: 32: 29: 14: 25: 32: 11: 8: 29;The plastics composite and polyureas Formaldehyde, paraffin mass ratio be 100: 19: 2.
CN201810611125.6A 2017-05-24 2017-05-24 A kind of plastics chimney filter tube body and preparation method thereof Pending CN108822512A (en)

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WO2013155420A2 (en) * 2012-04-13 2013-10-17 Ticona Llc Polyarylene sulfide composition including a silane coupling agent and a silicone elastomer
CN104877282A (en) * 2015-05-19 2015-09-02 广西众昌树脂有限公司 Thermoplastic flame-retardant plastic pipe
CN104906885A (en) * 2015-06-12 2015-09-16 上海铵培化工装备有限公司 Elastomer corrugated filter tube

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Application publication date: 20181116