CN107140302A - Water proof type sealing shroud - Google Patents

Water proof type sealing shroud Download PDF

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Publication number
CN107140302A
CN107140302A CN201710312146.3A CN201710312146A CN107140302A CN 107140302 A CN107140302 A CN 107140302A CN 201710312146 A CN201710312146 A CN 201710312146A CN 107140302 A CN107140302 A CN 107140302A
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CN
China
Prior art keywords
envelope
water proof
proof type
sealing shroud
deck
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201710312146.3A
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Chinese (zh)
Other versions
CN107140302B (en
Inventor
吴德斌
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHANGZHOU RONGHE POLYMER MATERIAL TECHNOLOGY CO LTD
Original Assignee
Jiangsu Hok Seal Material Co Ltd
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Priority to CN201710312146.3A priority Critical patent/CN107140302B/en
Publication of CN107140302A publication Critical patent/CN107140302A/en
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Publication of CN107140302B publication Critical patent/CN107140302B/en
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Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D31/00Bags or like containers made of paper and having structural provision for thickness of contents
    • B65D31/02Bags or like containers made of paper and having structural provision for thickness of contents with laminated walls
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/08Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/14Layered products comprising a layer of natural or synthetic rubber comprising synthetic rubber copolymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00Layered products comprising a layer of synthetic resin
    • B32B27/40Layered products comprising a layer of synthetic resin comprising polyurethanes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B65CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
    • B65DCONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
    • B65D33/00Details of, or accessories for, sacks or bags

Abstract

The present invention discloses a kind of water proof type sealing shroud, including upper envelope and lower big envelope, the lower edge of the upper envelope and the upper edge of the lower big envelope are by sealing shackle member one spherical enclosures of formation, the upper envelope and the lower big envelope are made up of composite, and the composite is the composite layer of sealant, hot sealing layer and antistatic backing composition.Compared with prior art, snap-arms using the sealing structure of cassette type up and down, up and down on deck of water proof type sealing shroud that the present invention is provided and strengthen that the Multiple Protective Structure and high performance envelope material with cutting means enclosure are connected and sealed between neck, so that the big envelope being prepared into have good rational in infrastructure, air-tightness, resistance to puncture, tear-proof, antistatic, high-barrier, it is lightweight, seal up for safekeeping and dismantle the good characteristic such as convenient, non-maintaining, durable, the problem of making moist during goods and materials are sealed up for safekeeping for a long time can be effectively solved, goods and materials is favorably improved and seals accumulating quality up for safekeeping.

Description

Water proof type sealing shroud
Technical field
The present invention relates to the outer wrapper for sealing article up for safekeeping, more particularly to a kind of water proof type sealing shroud.
Background technology
At present, most of electronic product does not typically possess the function of having waterproof against pressure, cause people swimming, diving or Outgoing drifts of spending holidays, bath in hot spring etc. water activity when entrained mobile phone, wrist-watch, the use of digital camera bring it is very big not Just.Entrained electronic product, which has accidentally got wet, to be just broken;Some are easily by the temperature of environment, humidity, illumination and electricity Magnetic etc. influences larger apparatus, article in storage and transport process, and especially in adverse circumstances, the property of article can occur in various degree Change, have in addition can go bad or fail therefore, certain safeguard procedures are taken in storage or transport, to ensure goods and materials Safe storage and transport.Means of defence is more, and wherein conventional method is that coating butter is connect with completely cutting off goods and materials with air on apparatus Touch, with moistureproof antirust;Other also useful vapor phase inhibitor technology prevents the apparatus from making moist corrosion, though these means of defences can be in short-term In play certain protection effect, but can not ensure in prolonged storage from environmental attack, and this protection side There is many defects such as operation inconvenience in high-volume accumulating in method;In addition, also there is part thereof to use plastic-aluminum vacuum envelope bag Dress, the packaging can be allowed to thoroughly completely cut off with external environment, also can effectively prevent influence of the illumination to goods and materials.
The defect of prior art:Electronic product is fitted into the waterproof bag with valve port and fastener, passes through multiple winding Sack is buckled on bag, and the air in bag is discharged by valve port, such waterproof bag, not tight enough due to sealing, easily Infiltration, waterproof function against pressure;Seal sleeve structure is unreasonable, and sealing is poor, cause goods and materials in long-term storage and transport process still can corrosion, Damage, go bad etc.;Secondly, there is many drawbacks in the material for preparing big envelope, and such as resistance to property exposed, tear resistance are poor, especially in the wild In low temperature environment, envelope material pliability is poor, easily damaged after soft folding, and it is rotten that this not only causes military hardware or goods and materials to lose envelope, Storing and transporting security is poor, and in the case of electromagnetic interference, part equips easily failure and loses use value;Overall hermetic seal Although deposit equipment store apparatus and during goods and materials with it is certain moistureproof, sun-proof, dust-proof and anti-oxidation the effects such as, should Equipment air-tightness is poor, and parts are more, and structure is more complicated, tedious process when using and dismounting every time.
The content of the invention
To solve above technical problem, the present invention provides a kind of water proof type sealing shroud, with solve existing encapsulation it is cumbersome, The problem of sealing difference and poor barrier.
The technical solution adopted by the present invention is as follows:A kind of water proof type sealing shroud, including upper envelope and lower big envelope, key exist In:The lower edge of the upper envelope and the upper edge of the lower big envelope form a spherical enclosures by sealing shackle member, clamping, The upper envelope and the lower big envelope are made up of composite, and the composite is sealant, hot sealing layer and antistatic backing group Into composite layer;
The sealant is made up of the raw material of following mass fraction:30~45 parts of macromolecule polyol, polyisocyanates 35 ~55 parts, 0.1~1.0 part of catalyst, 2~8 parts of plasticizer, 2~6 parts of antioxidant, 30~50 parts of modified epoxy, modified life 10~30 parts of material.
It is preferred that, the modified epoxy is obtained using following methods:By linseed oil and phthalic anhydride input reaction In kettle, 80~110 DEG C are warming up to, 300~600r/min of mixing speed is controlled, after question response is uniform, system temperature is down to 70 ~90 DEG C, add epoxy resin and stir, system temperature is down to 30~40 DEG C, then by trimethylolpropane tris (2- piperazines Piperazine base ethyl) aminocrotonate is dissolved in ethyl acetate, then be added dropwise in reactor, stirred when being added dropwise, after dripping Insulation reaction 15-30min, obtains the modified epoxy.
The effect of the program is that modified epoxy contains more aromatic ring and heterocycle, and solidfied material crosslink density is high, is used Come after modified polyurethane glue, in addition to retaining original characteristic, its solidfied material compact structure, crosslink density are high.
It is preferred that, the modification biological material is obtained using following methods:First by biological material drying to moisture content For less than 16%, 100~400 mesh powders are ground into, then powder is placed in 80 DEG C of 1mol/L hydrochloric acid stirred, are soaked 1~3h, filtering, the filter residue of collection dries 24h in 110 DEG C of baking ovens, then at 650 DEG C of Muffle kiln roasting 4h, obtains the life of ashing Material;Then the biological material of ashing is used into N- β-(aminoethyl)-γ-aminopropyltrimethoxysilane coupling agent pair It is surface-treated, and coupling agent is configured to the ethanol solution of mass percent 5%;By solution and the biological material of ashing It is well mixed in mass ratio for 1: 2,2h, discharging is stirred at 50~60 DEG C;The vacuum removal ethanol in 60 DEG C of vacuum drying ovens again, With mortar grinder to without caking, the modification biological material is obtained.
The effect of the program is that modified biological material passes through the surface-treated agricultural of addition amino silane coupler Biomaterial, effectively improves the combination properties such as tensile strength, elongation at break and the tearing strength of polyurethane sealant.
It is preferred that, the epoxy resin is diglycidyl ether type epoxy resin or phenolic resin varnish type epoxy resin;Described Macromolecule polyol is propylene oxide polyol or polyoxyethylated polyols;Described biological material is stalk or shell; Described polyisocyanates is hexamethylene diisocyanate or IPDI;The catalyst is the Malaysia of dialkyl tin two Acid esters or two mercaptan tin alkyls;The antioxidant is four [methylene -3- (3,5- di-t-butyl -4- hydroxy phenyls) propionic acid Ester] methane or dilauryl -3,3 '-thiodipropionate;The plasticizer is dioctyl phthalate or diethylene glycol (DEG) hexichol Formic acid esters.
It is preferred that, the hot sealing layer is low density polyethylene (LDPE) or hydrogenated styrene analog synthetic rubber.
It is preferred that, the antistatic backing is polyurethane electrostatic resistance agent coating.
It is preferred that, the thickness ratio of the sealant, hot sealing layer and antistatic backing is 1:(1-3):(0.5-1.5).
It is preferred that, the sealing shackle member includes the upper blocking seat and lower deck of mutual clamping, the upper surface of the upper blocking seat It is fixedly connected with the lower edge of the upper envelope, the lower surface of the lower deck is fixedly connected with the upper edge of the lower big envelope, The medial surface of the lateral surface of upper blocking seat and the lower deck described in the lower deck is respectively connected with snap-arms, the upper blocking seat it is interior The lateral surface of side and the lower deck is respectively connected with reinforcement deck, and the reinforcement deck is provided with to be adapted with the snap-arms Reinforcement neck, clamping in the reinforcement neck is stretched into the free ends of the snap-arms.
It is preferred that, the upper blocking seat includes the upper raised line that is vertically arranged of upper bed-plate and three, three upper raised lines it is upper Surface is fixedly connected with the upper bed-plate, neck is formed between two adjacent upper raised lines, under the lower deck includes The lower raised line that base and two are vertically arranged, the lower raised line is adapted with the neck, the lower surface of two lower raised lines Upper surface with the lower bottom base is fixedly connected, two lower raised lines respectively with the corresponding mutual clamping of neck, institute The upper surface for stating upper bed-plate is fixedly connected with the lower edge of the upper envelope, the lower surface of the lower bottom base and the lower big envelope Upper edge is fixedly connected.
It is preferred that, around the outside of the upper envelope provided with a circle cutting means enclosure, the top of the cutting means enclosure and the upper envelope Outer surface be fixedly connected, the bottom of the cutting means enclosure is bent to the lower big envelope, and blocks the sealing shackle member.
Beneficial effect:Compared with prior art, the water proof type sealing shroud that the present invention is provided, it is simple in construction, it is practical, fit It is wide with scope, using the sealing structure of cassette type up and down to being connected and sealed between big envelope up and down, play one and protect again, up and down It is connected and sealed between snap-arms and reinforcement neck on deck, can further improve airtight quality, play double protection, on Cutting means enclosure on big envelope can further block the wet gas outside big envelope to enter big envelope, play triple protection, make upper and lower big envelope Junction keeps higher air-tightness for a long time, and the condition of storage of long-term safety is provided for the article in big envelope.In addition, of the invention Big envelope made of composite, the composite is composited by sealant, hot sealing layer and antistatic backing, and sealant is by height Based on molecular polylol, polyisocyanates, catalyst, plasticizer, antioxidant, modification biological material, modified epoxy etc. Composition is wanted, modified epoxy and modification biological material is introduced, the tensile strength of fluid sealant, elongation at break is improved and tears The combination properties such as resistance to spalling;Present invention employs multi-sealing structure and high performance envelope material, so that the envelope being prepared into Set has that rational in infrastructure, air-tightness is good, resistance to puncture, tear-proof, antistatic, high-barrier, it is lightweight, seal up for safekeeping and dismantle it is convenient, exempt from The good characteristics such as maintenance, durable, can effectively solve the problem of making moist during goods and materials are sealed up for safekeeping for a long time, be favorably improved goods and materials Seal accumulating quality up for safekeeping.
Brief description of the drawings
Fig. 1 is structural representation of the invention;
Fig. 2 is Fig. 1 A-A sectional views;
Fig. 3 is the structural representation of sealing shackle member 3 in Fig. 2;
Fig. 4 is enlarged drawing at the A in Fig. 2.
Embodiment
To make those skilled in the art be better understood from technical scheme, below in conjunction with the accompanying drawings and specific embodiment party Formula elaborates to the present invention.
Embodiment 1
As Figure 1-3, a kind of water proof type sealing shroud, including upper envelope 1 and lower big envelope 2, the lower edge of the upper envelope 1 Upper edge with the lower big envelope 2 is by sealing the clamping of shackle member 3 one spherical enclosures of formation, around the outer of the upper envelope 1 Side is provided with a circle cutting means enclosure 4, and the top of the cutting means enclosure 4 is fixedly connected with the outer surface of the upper envelope 1, under the cutting means enclosure 4 Portion is bent to the lower big envelope 2, and blocks the sealing shackle member 3;The upper envelope 1 and the lower big envelope 2 are by composite It is made, the composite is sealant a, low density polyethylene (LDPE) and the coat composed composite layer of polyurethane electrostatic resistance agent, The sealant a, low density polyethylene (LDPE) and polyurethane electrostatic resistance agent coating thickness ratio are 1:1:0.5;
The sealing shackle member 3 includes the upper blocking seat 31 and lower deck 32 of mutual clamping, the upper surface of the upper blocking seat 31 It is fixedly connected with the lower edge of the upper envelope 1, the upper edge of the lower surface of the lower deck 32 and the lower big envelope 2, which is fixed, to be connected Connect, the lateral surface of upper blocking seat 31 described in the lower deck 32 and the medial surface of the lower deck 32 are respectively connected with snap-arms 3c, institute The lateral surface of the medial surface and the lower deck 32 of stating upper blocking seat 31 is respectively connected with reinforcement deck 3d, the reinforcement deck 3d and set The free end having with the snap-arms 3c reinforcement neck 3e, the snap-arms 3c being adapted is stretched into blocks in the reinforcement neck 3e Connect;The upper blocking seat 31 includes the upper raised line 31b that upper bed-plate 31a and three are vertically arranged, three upper raised line 31b upper table Face is fixedly connected with the upper bed-plate 31a, and neck, the lower deck 32 are formed between two adjacent upper raised line 31b The lower raised line 32b being vertically arranged including lower bottom base 32a and two, the lower raised line is adapted with the neck, under two described Upper surface of the raised line 32b lower surface with the lower bottom base 32a is fixedly connected, two lower raised line 32b respectively with it is corresponding The mutual clamping of the neck, the upper surface of the upper bed-plate 31a is fixedly connected with the lower edge of the upper envelope 1, it is described under Base 32a lower surface is fixedly connected with the upper edge of the lower big envelope 2.
The sealant a is made up of the raw material of following mass fraction:30 parts of propylene oxide polyol, hexamethylene diisocyanate 35 Part, 0.1 part of dialkyl tin dimaleate, 2 parts of dioctyl phthalate, four [methylene -3- (3,5- di-t-butyl -4- Hydroxy phenyl) propionic ester] 2 parts of methane, 30 parts of modified epoxy, 10 parts of modification biological material.
The modified epoxy is obtained using following methods:By in linseed oil and phthalic anhydride input reactor, rise Temperature controls 300~600r/min of mixing speed, after question response is uniform, system temperature is down into 70~90 DEG C to 80~110 DEG C, Plus diglycidyl ether type epoxy resin agitating is uniform, system temperature is down into 30~40 DEG C, then by trimethylolpropane tris 2- Piperazinyl aminocrotonate is dissolved in ethyl acetate, then is added dropwise in reactor, is stirred when being added dropwise, after dripping Insulation reaction 15-30min, obtains the modified epoxy.
The modification biological material is obtained using following methods:It is first less than 16%, powder by stalk drying to moisture content 100~400 mesh powders are broken into, then powder is placed in 80 DEG C of 1mol/L hydrochloric acid stirred, 1~3h is soaked, filtered, are received The filter residue collected dries 24h in 110 DEG C of baking ovens, then at 650 DEG C of Muffle kiln roasting 4h, obtains straw ash;Then straw ash is adopted It is surface-treated with N- β-aminoethyl-γ-aminopropyltrimethoxysilane coupling agents, coupling agent is configured to quality hundred Divide the ethanol solution than 5%;Solution is well mixed for 1: 2 in mass ratio with straw ash, 2h is stirred at 50~60 DEG C, is gone out Material;The vacuum removal ethanol in 60 DEG C of vacuum drying ovens, with mortar grinder to without caking, obtains the modification biological material again.
The epoxy resin is or phenolic resin varnish type epoxy resin;Described macromolecule polyol is or polyethylene glycol oxide is more First alcohol;Described biological material is stalk or shell;Described polyisocyanates is hexamethylene diisocyanate or isophorone two Isocyanates;The catalyst is dialkyl tin dimaleate or two mercaptan tin alkyls;The antioxidant is or two bays Base -3,3 '-thiodipropionate;The plasticizer is or diethylene glycol dibenzoate.
The elongation for being tightly connected layer in the embodiment is 523%, and tensile strength reaches 14.1MPa, and shear strength is 6.8MPa, tearing strength reaches 47.3N/mm.
Embodiment 2
As Figure 1-3, a kind of water proof type sealing shroud, including upper envelope 1 and lower big envelope 2, the lower edge of the upper envelope 1 Upper edge with the lower big envelope 2 is by sealing the clamping of shackle member 3 one spherical enclosures of formation, around the outer of the upper envelope 1 Side is provided with a circle cutting means enclosure 4, and the top of the cutting means enclosure 4 is fixedly connected with the outer surface of the upper envelope 1, under the cutting means enclosure 4 Portion is bent to the lower big envelope 2, and blocks the sealing shackle member 3;The upper envelope 1 and the lower big envelope 2 are by composite It is made, the composite is that sealant a, hydrogenated styrene analog synthetic rubber and polyurethane electrostatic resistance agent are coat composed compound Material layer, the sealant a, hydrogenated styrene analog synthetic rubber and polyurethane electrostatic resistance agent coating thickness ratio are 1:3:1.5;
The sealing shackle member 3 includes the upper blocking seat 31 and lower deck 32 of mutual clamping, the upper surface of the upper blocking seat 31 It is fixedly connected with the lower edge of the upper envelope 1, the upper edge of the lower surface of the lower deck 32 and the lower big envelope 2, which is fixed, to be connected Connect, the lateral surface of upper blocking seat 31 described in the lower deck 32 and the medial surface of the lower deck 32 are respectively connected with snap-arms 3c, institute The lateral surface of the medial surface and the lower deck 32 of stating upper blocking seat 31 is respectively connected with reinforcement deck 3d, the reinforcement deck 3d and set The free end having with the snap-arms 3c reinforcement neck 3e, the snap-arms 3c being adapted is stretched into blocks in the reinforcement neck 3e Connect;The upper blocking seat 31 includes the upper raised line 31b that upper bed-plate 31a and three are vertically arranged, three upper raised line 31b upper table Face is fixedly connected with the upper bed-plate 31a, and neck, the lower deck 32 are formed between two adjacent upper raised line 31b The lower raised line 32b being vertically arranged including lower bottom base 32a and two, the lower raised line is adapted with the neck, under two described Upper surface of the raised line 32b lower surface with the lower bottom base 32a is fixedly connected, two lower raised line 32b respectively with it is corresponding The mutual clamping of the neck, the upper surface of the upper bed-plate 31a is fixedly connected with the lower edge of the upper envelope 1, it is described under Base 32a lower surface is fixedly connected with the upper edge of the lower big envelope 2.
The sealant a is made up of the raw material of following mass fraction:45 parts of polyoxyethylated polyols, isophorone two are different 55 parts of cyanate, 1.0 parts of two mercaptan tin alkyl, 8 parts of diethylene glycol dibenzoate, dilauryl -3,3 '-thiodipropionate 6 Part, 30~50 parts of modified epoxy, 10~30 parts of modification biological material.
The modified epoxy is obtained using following methods:By in linseed oil and phthalic anhydride input reactor, rise Temperature controls 300~600r/min of mixing speed, after question response is uniform, system temperature is down into 70~90 DEG C to 80~110 DEG C, Plus phenolic resin varnish type epoxy resin stirs, system temperature is down to 30~40 DEG C, then by trimethylolpropane tris 2- piperazines Piperazine base ethylamino crotonates is dissolved in ethyl acetate, then is added dropwise in reactor, is stirred, is protected after dripping when being added dropwise Temperature reaction 15-30min, obtains the modified epoxy.
The modification biological material is obtained using following methods:It is first less than 16%, powder by shell drying to moisture content 100~400 mesh powders are broken into, then powder is placed in 80 DEG C of 1mol/L hydrochloric acid stirred, 1~3h is soaked, filtered, are received The filter residue collected dries 24h in 110 DEG C of baking ovens, then at 650 DEG C of Muffle kiln roasting 4h, obtains shell ash;Then shell ash is adopted It is surface-treated with N- β-aminoethyl-γ-aminopropyltrimethoxysilane coupling agents, coupling agent is configured to quality hundred Divide the ethanol solution than 5%;Solution is well mixed for 1: 2 in mass ratio with shell ash, 2h is stirred at 50~60 DEG C, is gone out Material;The vacuum removal ethanol in 60 DEG C of vacuum drying ovens, with mortar grinder to without caking, obtains the modification biological material again.
The elongation for being tightly connected layer in the embodiment is 438%, and tensile strength reaches 12.9MPa, and shear strength is 7.3MPa, tearing strength reaches 38.8N/mm.
In use, article is placed in lower big envelope 2, then upper envelope 1 is buckled, by between raised line 31b in lower raised line 32b insertions Formed in neck, then clamping in reinforcement neck 3e is stretched into snap-arms 3c free end, puts down cutting means enclosure 4 and shelters from sealing clamping Operation is sealed in part 3, completion up for safekeeping;When dismantling big envelope, cutting means enclosure 4 is dug, reinforcement neck 3e is left into snap-arms 3c free ends, then Upper blocking seat 31 and lower deck 32 are separated, upper envelope 1 is raised, you can the goods and materials sealed up for safekeeping or equipment are taken out, upper and lower big envelope is deposited Put.
Finally it is to be appreciated that foregoing description is only the preferred embodiments of the present invention, those skilled in the art is in the present invention Enlightenment under, on the premise of without prejudice to present inventive concept and claim, expression as multiple types can be made, it is such to become Change and each fall within protection scope of the present invention.

Claims (10)

1. a kind of water proof type sealing shroud, including upper envelope (1) and lower big envelope (2), it is characterised in that:Under the upper envelope (1) The upper edge of edge and the lower big envelope (2) forms a spherical enclosures, the upper envelope by sealing shackle member (3) clamping (1) it is made up with the lower big envelope (2) of composite, the composite is sealant (a), hot sealing layer (b) and antistatic backing (c) composite layer of composition;
The sealant (a) is made up of the raw material of following mass fraction:30~45 parts of macromolecule polyol, polyisocyanates 35~ 55 parts, 0.1~1.0 part of catalyst, 2~8 parts of plasticizer, 2~6 parts of antioxidant, 30~50 parts of modified epoxy, modification biological 10~30 parts of material.
2. water proof type sealing shroud according to claim 1, it is characterised in that the modified epoxy is obtained using following methods: By in linseed oil and phthalic anhydride input reactor, 80~110 DEG C are warming up to, 300~600r/min of mixing speed is controlled, After question response is uniform, system temperature is down to 70~90 DEG C, epoxy resin is added and stirs, system temperature is down to 30~40 DEG C, then trimethylolpropane tris (2- piperazinyls) aminocrotonate is dissolved in ethyl acetate, then is added dropwise to anti- Answer in kettle, stirred when being added dropwise, drip rear insulation reaction 15-30min, obtain the modified epoxy.
3. water proof type sealing shroud according to claim 2, it is characterised in that:The modification biological material uses following methods Obtain:It is first less than 16% by biological material drying to moisture content, is ground into 100~400 mesh powders, then powder is placed in Stirred in 80 DEG C of 1mol/L hydrochloric acid, soak 1~3h, filtering, the filter residue of collection dries 24h in 110 DEG C of baking ovens, then at 650 DEG C of Muffle kiln roasting 4h, obtain the biological material of ashing;Then the biological material of ashing is used into N- β-(ammonia second Base)-γ-aminopropyltrimethoxysilane coupling agent is surface-treated to it, and coupling agent is configured into mass percent 5% Ethanol solution;Solution is well mixed for 1: 2 in mass ratio with the biological material being ashed, 2h is stirred at 50~60 DEG C, is gone out Material;The vacuum removal ethanol in 60 DEG C of vacuum drying ovens, with mortar grinder to without caking, obtains the modification biological material again.
4. water proof type sealing shroud according to claim 3, it is characterised in that:The epoxy resin is diglycidyl ether type epoxy Resin or phenolic resin varnish type epoxy resin;Described macromolecule polyol is that propylene oxide polyol or polyethylene glycol oxide are polynary Alcohol;Described biological material is stalk or shell;Described polyisocyanates is that hexamethylene diisocyanate or isophorone two are different Cyanate;The catalyst is dialkyl tin dimaleate or two mercaptan tin alkyls;The antioxidant be four [methylene- 3- (3,5- di-t-butyl -4- hydroxy phenyls) propionic ester] methane or dilauryl -3,3 '-thiodipropionate;The plasticising Agent is dioctyl phthalate or diethylene glycol dibenzoate.
5. water proof type sealing shroud according to claim 1, it is characterised in that:The hot sealing layer is low density polyethylene (LDPE) or hydrogenation Phenylethylene synthetic rubber.
6. water proof type sealing shroud according to claim 1, it is characterised in that:The antistatic backing (c) is polyurethane electrostatic resistance Agent coating.
7. according to any one of claim 1, the 5 or 6 water proof type sealing shroud, it is characterised in that:The sealant (a), heat-sealing The thickness ratio of layer (b) and antistatic backing (c) is 1:(1-3):(0.5-1.5).
8. water proof type sealing shroud according to claim 7, it is characterised in that:The sealing shackle member (3) includes mutual clamping Upper blocking seat (31) and lower deck (32), the lower edge of the upper surface of the upper blocking seat (31) and the upper envelope (1), which is fixed, to be connected Connect, the lower surface of the lower deck (32) is fixedly connected with the upper edge of the lower big envelope (2), on the lower deck (32) is described The medial surface of the lateral surface of deck (31) and the lower deck (32) is respectively connected with snap-arms (3c), the upper blocking seat (31) it is interior Side and the lower deck (32) lateral surface be respectively connected with reinforcement deck (3d), it is described reinforcement deck (3d) be provided with it is described The adaptable reinforcement neck (3e) of snap-arms (3c), the free end of the snap-arms (3c) is stretched into blocks in the reinforcement neck (3e) Connect.
9. water proof type sealing shroud according to claim 8, it is characterised in that:The upper blocking seat (31) includes upper bed-plate (31a) With three upper raised lines being vertically arranged (31b), the upper surface of three upper raised lines (31b) is consolidated with the upper bed-plate (31a) Form neck between fixed connection, two adjacent upper raised lines (31b), the lower deck (32) include lower bottom base (32a) and Two lower raised lines (32b) for being vertically arranged, the lower raised line is adapted with the neck, under two lower raised lines (32b) Upper surface of the surface with the lower bottom base (32a) is fixedly connected, two lower raised lines (32b) respectively with the corresponding card The mutual clamping of groove, the upper surface of the upper bed-plate (31a) is fixedly connected with the lower edge of the upper envelope (1), the lower bottom base The lower surface of (32a) is fixedly connected with the upper edge of the lower big envelope (2).
10. the water proof type sealing shroud according to claim 1 or 9, it is characterised in that:Set on the outside of the upper envelope (1) There is a circle cutting means enclosure (4), the top of the cutting means enclosure (4) is fixedly connected with the outer surface of the upper envelope (1), the cutting means enclosure (4) Bottom bent to the lower big envelope (2), and block the sealing shackle member (3).
CN201710312146.3A 2017-05-05 2017-05-05 Waterproof sealing sleeve Active CN107140302B (en)

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CN201710312146.3A CN107140302B (en) 2017-05-05 2017-05-05 Waterproof sealing sleeve

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CN1888003A (en) * 2006-07-12 2007-01-03 山东恒冠化工科技有限公司 Waterproof sealing agent for wires, cables and terminals and its prepn
CN202132740U (en) * 2011-05-30 2012-02-01 徐培鑫 Waterproof LED (Light-emitting Diode) covered with sealing material
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CN110964339B (en) * 2019-12-24 2022-03-29 黑龙江幸福人生态农业开发股份有限公司 Preparation method of bio-based composite material film with good air tightness

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