CN107136661A - A kind of button and preparation method thereof - Google Patents
A kind of button and preparation method thereof Download PDFInfo
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- CN107136661A CN107136661A CN201710523804.3A CN201710523804A CN107136661A CN 107136661 A CN107136661 A CN 107136661A CN 201710523804 A CN201710523804 A CN 201710523804A CN 107136661 A CN107136661 A CN 107136661A
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Classifications
-
- A—HUMAN NECESSITIES
- A44—HABERDASHERY; JEWELLERY
- A44B—BUTTONS, PINS, BUCKLES, SLIDE FASTENERS, OR THE LIKE
- A44B1/00—Buttons
- A44B1/02—Buttons characterised by their material
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/042—Coating with two or more layers, where at least one layer of a composition contains a polymer binder
- C08J7/0423—Coating with two or more layers, where at least one layer of a composition contains a polymer binder with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
- C08J7/04—Coating
- C08J7/06—Coating with compositions not containing macromolecular substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09G—POLISHING COMPOSITIONS; SKI WAXES
- C09G1/00—Polishing compositions
- C09G1/02—Polishing compositions containing abrasives or grinding agents
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2300/00—Characterised by the use of unspecified polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2463/00—Characterised by the use of epoxy resins; Derivatives of epoxy resins
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Inorganic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention provides a kind of preparation method of button, including：A button blank) is prepared using resin material；B shaping button) is made in the button blank；C) the shaping button is polished, the button after being polished；D the button after the polishing) is subjected to pretreatment fluid spraying, the button after being sprayed；E the button after the spraying) is subjected to electric rifle coating, finished product button is obtained；The material that the electric rifle coating is used is oxide.The present invention prepares button blank using resin material, without high calcining heat, resin button covering surface last layer oxide is caused to imitate ceramic material by electric rifle coating, so that resin button surface produces the enamel effect the same with ceramic button, the characteristics of resin button density is small is also maintained.Thus, obtained button is while with ceramic texture, with relatively low density, meets the characteristics of clothes is light.And whole production process is simple and easy to apply, and energy consumption is relatively low, and cost is smaller.
Description
Technical field
The present invention relates to garment production technical field, more particularly to a kind of button and preparation method thereof.
Background technology
Button is to be used for the fastener that the both sides hem are connected on clothes, and current button is largely resin or metal system
Into.However, the button quality being formed from a resin is too light, the button being made of metal then lacks reflecting feel, and both are in texture
Also there is certain deficiency, thus, design a kind of existing certain mass and glossy, and texture preferably ceramic button is pole
Have market prospects.
Ceramic button of the prior art is that embryo is sintered at a high temperature of 2000 DEG C using zirconium oxide and ceramic powder, cooling
Afterwards, continuation is melted down after preliminary polishing to calcine and shape, this process energy consumption is big, and cost is high, and obtained ceramic button
Density is larger, comparatively, and the ceramic button quality of same specification is much larger than common resin button, does not meet spring and summer clothes light
The characteristics of.Thus, how while button surface ceramic effect is kept, mitigate button quality as far as possible, and reduce life
Energy consumption during production, is the technical problem that those skilled in the art are badly in need of solving at present.
The content of the invention
In view of this, the technical problem to be solved in the present invention is to provide a kind of button and preparation method thereof, using this hair
Button made from bright preparation method is while with ceramic texture, with relatively low density；Meanwhile, production process is simply easy
OK, energy consumption is smaller.
The invention provides a kind of preparation method of button, including：
A button blank) is prepared using resin material；
B shaping button) is made in the button blank；
C) the shaping button is polished, the button after being polished；
D the button after the polishing) is subjected to pretreatment fluid spraying, the button after being sprayed；
E the button after the spraying) is subjected to electric rifle coating, finished product button is obtained；The material that the electric rifle coating is used
For oxide.
It is preferred that, step C) in, it is described to be finished to water roll cast light.
It is preferred that, the formula number meter of the water roll cast light includes：
1000 parts of water
1000~5000 parts of aluminum oxide rotten-stone
20~100 parts of polishing powder.
It is preferred that, the polishing powder is 500~1500 mesh polishing powders.
It is preferred that, step D) in, the pretreatment fluid count by weight including：
100 parts of matrix resin
100~150 parts of diluent.
It is preferred that, the matrix resin is acrylate-functional mixture.
It is preferred that, step E) in, the electron beam heating that the electric rifle coating is used is straight gun shaped electron gun, circulating electron
Rifle or e type electron evaporation rifles.
It is preferred that, the oxide is titanium monoxide, titanium dioxide, zirconium dioxide, alundum (Al2O3) or silica.
It is preferred that, the vacuum of the electric rifle coating is 1.2 × 10-5~1.2 × 10-2Pa。
Present invention also offers button made from a kind of preparation method described above.
The invention provides a kind of preparation method of button, including：A button blank) is prepared using resin material；B) by institute
State button blank and shaping button is made；C) the shaping button is polished, the button after being polished；D) by the polishing
Button afterwards carries out pretreatment fluid spraying, the button after being sprayed；E the button after the spraying) is subjected to electric rifle coating, obtained
To finished product button；The material that the electric rifle coating is used is oxide.The present invention prepares button blank using resin material, without
High calcining heat, causes resin button covering surface last layer oxide to imitate ceramic material by electric rifle coating, so that
Obtain resin button surface and produce the enamel effect the same with ceramic button, meanwhile, also maintain the characteristics of resin button density is small.
Thus, obtained button is while with ceramic texture, with relatively low density, meets the characteristics of clothes is light.Meanwhile, it is whole
Individual production process is simple and easy to apply, and energy consumption is relatively low, and cost is smaller.
Brief description of the drawings
Fig. 1 is the outside drawing of button prepared by the embodiment of the present invention 1；
Fig. 2 is the outside drawing of button prepared by the embodiment of the present invention 2.
Embodiment
Below in conjunction with the embodiment of the present invention, technical scheme is clearly and completely described, it is clear that institute
The embodiment of description is only a part of embodiment of the invention, rather than whole embodiments.Based on the embodiment in the present invention,
The every other embodiment that those of ordinary skill in the art are obtained under the premise of creative work is not made, belongs to this hair
The scope of bright protection.
The invention provides a kind of preparation method of button, including：
A button blank) is prepared using resin material；
B shaping button) is made in the button blank；
C) the shaping button is polished, the button after being polished；
D the button after the polishing) is subjected to pretreatment fluid spraying, the button after being sprayed；
E the button after the spraying) is subjected to electric rifle coating, finished product button is obtained；The material that the electric rifle coating is used
For oxide.
The present invention first prepares button blank using resin material.During button blank is prepared with resin material, first
Prepare base slurry.I.e.：Resin material, solvent, accelerator and initiator are mixed, base slurry is obtained.It is preferred that, specifically
For：Resin material and solvent are mixed, mixed solution is obtained；In the mixed solution, first add accelerator and mix, add
Initiator is mixed, and obtains base slurry.
In the present invention, the resin material is preferably unsaturated polyester resin；More preferably adjacent benzene-type unsaturated polyester (UP)
Resin and/or metaphenylene unsaturated polyester resin；Most preferably m-phthalate unsaturated polyester resin.In some implementations of the present invention
In example, the unsaturated-resin is 858 unsaturated-resins.The solvent is preferably styrene, butyl acetate or dimethylbenzene；More
Preferably styrene.The accelerator is preferably cobalt naphthenate and/or cobalt iso-octoate；More preferably cobalt naphthenate.It is described to trigger
Agent is preferably methyl ethyl ketone peroxide and/or cyclohexanone peroxide；More preferably methyl ethyl ketone peroxide.The resin material, solvent,
The weight ratio of accelerator and initiator is preferably 500~800：100~500：3~50：3~50；More preferably 550~750：
150~350：5~15：5~17；Most preferably 600~700：200~300：8~12：7~15.In some implementations of the present invention
In example, the resin material, solvent, the weight ratio of accelerator and initiator are 700：400：9：11、800：300：9：11 or
700：300：8：10.
Obtain after base slurry, carry out base.In the present invention, sheet material can be made in the base slurry, then punching
Obtain button blank；Bar can also be made, then section obtains button blank.The present invention, without special limitation, is adopted to this
With the method for sheet material base well known to those skilled in the art or bar base.
It is preferred that, it is specially：
A1 base slurry) is warming up to 28~32 DEG C, is then centrifuged for, sheet material is obtained after solidification；
B1 the sheet material) is punched into disk；
C1) disk toast obtaining button blank.
Above-mentioned centrifugation is carried out preferably in centrifuge, and the rotating speed of the centrifugation is preferably 150~175r/min.The present invention is right
The time of the centrifugation can stop after having no special limitation, the base slurry curing.The punching is preferably in blanking machine
It is middle to carry out.The present invention has no special limitation to the diameter of the disk, determines as required.In certain embodiments of the present invention
In, a diameter of 2.5cm of the disk.The baking is preferably carried out in an oven；The temperature of the baking is preferably 70~95
℃；In certain embodiments of the present invention, the temperature of the baking is 90 DEG C.The time of the baking is preferably 20~50min；
In certain embodiments of the present invention, the time of the baking is 40min.The disk is complete through overbaking solidify afterwards, and
The hardness of system button is reached.
Or
A2 base slurry) is warming up to 28~32 DEG C, bar is obtained after being subsequently poured into the aluminum pipe for being coated with paraffin, solidification；
B2 the bar) is cut into disk；
C2) disk toast obtaining button blank.
In the present invention, the step b2) carried out preferably in bar slicer.Thickness of the invention to the disk is simultaneously
Without special limitation, determine as required.In certain embodiments of the present invention, the thickness of the disk is 4mm.The baking
It is preferred that carrying out in an oven；The temperature of the baking is preferably 70~95 DEG C；In certain embodiments of the present invention, the baking
Temperature be 90 DEG C.The time of the baking is preferably 20~50min；In certain embodiments of the present invention, the baking
Time is 30min.The disk is complete through overbaking solidify afterwards, and has reached the hardness of system button.
Obtain after button blank, shaping button is made in the button blank.Specifically, being preferably：Will using deduction processed
Shaping button is made in the button blank.The present invention is to the size and dimension for shaping button and has no special requirements, according to need
It is prepared by the size and dimension wanted.
Then, the shaping button is polished, the button after being polished.The polishing is preferably entered in polishing machine
OK.Button after polishing has got rid of the burr left when system is buckled and knife pin is uneven.
The polishing is preferably water roll cast light.The formula number meter of the water roll cast light is preferably included：
1000 parts of water
1000~5000 parts of aluminum oxide rotten-stone
20~100 parts of polishing powder.
In the present invention, the mass fraction of the aluminum oxide rotten-stone is preferably 1000~5000 parts；More preferably 2500
~3000 parts.In certain embodiments of the present invention, the mass fraction of the aluminum oxide rotten-stone is 2500 parts or 3000 parts.Institute
State aluminum oxide rotten-stone and preferably include 0.6 × 0.6cm aluminum oxide rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone.It is described
The weight ratio preferably 3 of 0.6 × 0.6cm aluminum oxide rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone：1.
The mass fraction of the polishing powder is preferably 20~100 parts by weight；More preferably 50~100 parts by weight.It is described to throw
Light powder is preferably 500~1500 mesh polishing powders；More preferably 800~1000 mesh.In certain embodiments of the present invention, it is described to throw
Light powder is 800 mesh or 1000 mesh.The polishing powder preferably includes cerium rouge and aluminum oxide polishing powder；The cerium oxide is thrown
The weight ratio of light powder and aluminum oxide polishing powder is preferably 10：1.
The time of the water roll cast light is preferably 2~24h；In certain embodiments of the present invention, the water roll cast light
Time is 2h.
After the completion of the polishing, the button after the polishing is subjected to pretreatment fluid spraying, the button after being sprayed.Tool
Body, be preferably：Pretreatment fluid is sprayed on the button after the polishing using spray gun, the button after being sprayed.
The present invention has no special limitation to the spray gun, using spray gun well known to those skilled in the art, this hair
Bright is preferably rock field W-101 spray guns.The pretreatment fluid is counted by weight to be preferably included：
100 parts of matrix resin
100~150 parts of diluent.
In the present invention, it is preferably 100 parts that the matrix resin is counted by weight.The matrix resin is preferably function
Property acrylate mixture；More preferably photocuring acrylate-functional mixture M ST-509, this photocuring feature third
Olefin(e) acid ester admixture MST-509 solidification hardness is 5-6H, and viscosity is 25 DEG C of 800~1000mPa.s@.The diluent is by weight
Amount number meter preferably includes 100~150 parts；More preferably 150 parts.The diluent is preferably organic solvent；More preferably second
Acetoacetic ester or isopropanol.In certain embodiments of the present invention, the diluent is ethyl acetate.
After the pretreatment fluid spraying, preferably also include solidifying on the button after spraying.The present invention is to the curing mode
Special limitation is had no, using curing mode well known to those skilled in the art, the present invention is preferably heat cure or UV solid
Change.
Afterwards, the button that the present invention obtains above-mentioned steps carries out electric rifle coating, obtains finished product button.The electric rifle coating
Process be：The material for being used electric rifle coating using electron beam heating is gasified, and is coated in the surface of another material.
In the present invention, the electron beam heating that the electric rifle coating is used is preferably straight gun shaped electron gun, ring-type electron gun or e type electronics
Evaporate rifle；More preferably e types electron evaporation rifle.The material that the electric rifle coating is used is oxide；Preferably titanium monoxide, two
Titanium oxide, zirconium dioxide, alundum (Al2O3) or silica；More preferably titanium dioxide, zirconium dioxide or silica.It is described
The vacuum of electric rifle coating is preferably 1.2 × 10-5~1.2 × 10-2Pa；More preferably 1.2 × 10-5~1.3 × 10-5Pa.At this
In some embodiments of invention, the vacuum of the electric rifle coating is 1.2 × 10-5Or 1.3 × 10-5.By the knob of electric rifle coating
Button, one layer of oxide imitates ceramic material on covering surface so that resin button surface produce it is the same with ceramic button
Enamel effect.
After the electric rifle coating, the button surface spraying diaphragm after the electric rifle coating is preferably also included in, so that
To finished product button.The present invention has no special limitation to the mode of the spraying, using spraying well known to those skilled in the art
Mode, the present invention is preferably to be sprayed using rock field W-101 spray guns.The material of the diaphragm is preferably epoxy resin
Varnish, the epoxy resin varnish is counted by weight to be preferably included：
50~200 parts of epoxy resin；
10~100 parts of curing agent；
100~2000 parts of diluent.
In the present invention, the epoxy resin is calculated by weight as 50~200 parts；Preferably 80~150 parts；More preferably
For 100 parts.The present invention has no special limitation, preferably bisphenol A type epoxy resin or Bisphenol F to the species of the epoxy resin
Type epoxy resin.In certain embodiments of the present invention, the epoxy resin is 3610 bisphenol A type epoxy resins.The solidification
Agent is calculated by weight as 10~100 parts；Preferably 20~80 parts；More preferably 33 parts.The curing agent is preferably divinyl
One or more in triamine, trimethylhexamethylenediamine or trimethylhexane diamine.The diluent is calculated by weight as
100~2000 parts；Preferably 500~1500 parts；More preferably 800~1000 parts.In certain embodiments of the present invention, it is described
Diluent is calculated by weight as 800 parts or 1000 parts.During the diluent is preferably dimethylbenzene, butyl acetate or ethyl acetate
One or more.
The present invention has no special limitation to the source of above-mentioned used raw material components, can be general commercially available.
Present invention also offers button made from a kind of preparation method described above.The button surface has pottery
Sense, the density of the button is not more than 1.3g/cm3.In certain embodiments of the present invention, the density of the button is 1.2g/
cm3Or 1.3g/cm3.Therefore, the button that the present invention is provided, with relatively low density, meets clothing while with ceramic texture
The characteristics of taking light.
The invention provides a kind of preparation method of button, including：A button blank) is prepared using resin material；B) by institute
State button blank and shaping button is made；C) the shaping button is polished, the button after being polished；D) by the polishing
Button afterwards carries out pretreatment fluid spraying, the button after being sprayed；E the button after the spraying) is subjected to electric rifle coating, obtained
To finished product button；The material that the electric rifle coating is used is oxide.The present invention prepares button blank using resin material, without
High calcining heat, causes resin button covering surface last layer oxide to imitate ceramic material by electric rifle coating, so that
Obtain resin button surface and produce the enamel effect the same with ceramic button, meanwhile, also maintain the characteristics of resin button density is small.
Thus, obtained button is while with ceramic texture, with relatively low density, meets the characteristics of clothes is light.Meanwhile, it is whole
Individual production process is simple and easy to apply, and energy consumption is relatively low, and cost is smaller.
In order to further illustrate the present invention, a kind of button provided with reference to embodiments the present invention and preparation method thereof
It is described in detail, but limiting the scope of the present invention can not be understood as.
Embodiment 1
Mixed solution is obtained after 700g 858 unsaturated-resins are mixed with 400g styrene, then adds 10ml thereto
Cobalt naphthenate and stir, then add 10ml methyl ethyl ketone peroxides, after stirring, obtain base slurry.Its
In, 858 unsaturated-resins, styrene, the weight ratio of cobalt naphthenate and methyl ethyl ketone peroxide are 700：400：9：11.
The base slurry that above-mentioned steps are obtained is warming up to 30 DEG C, pours into centrifuge, and centrifuge speed is 150r/min, Gu
Sheet material is made after change.Blanking machine is reused, sheet material is punched into diameter 2.5cm disk.Afterwards, the disk cut is put into 90
40min is toasted in DEG C baking oven, disk completion of cure simultaneously reaches system button hardness, so as to obtain button blank.Button blank is passed through
Deduction processed makes side thickness 2.5mm, pocket knife 2.4mm, depth 1.3mm, pitch-row 4.4mm and aperture 2.0mm button shape, obtains
Shape button.
Shaping button is poured into polishing machine, enters water-filling roll cast light 2 hours.Water roll cast light is formulated：The parts by weight of water 1000, oxygen
Change the parts by weight of aluminium rotten-stone 3000, the parts by weight of 800 mesh polishing powder 50.Wherein, aluminum oxide rotten-stone is aoxidized from 0.6 × 0.6cm
Aluminium rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone press 3：1 weight is than proportioning；Polishing powder selects cerium rouge and aluminum oxide
Polishing powder presses 10：1 weight is than proportioning.
Using pretreatment fluid is sprayed on the button of rock field W-101 spray guns after a polish, the pretreatment fluid includes 100 weight
The photocuring acrylate-functional mixture M ST-509 of part and the ethyl acetate of 150 parts by weight, afterwards will using UV curing
It fully solidifies.
It is 1.2 × 10 that button after solidification is placed in into vacuum-5Vacuum condition under, then using e type electron evaporation rifles
Titanium dioxide is gasified, and it is coated in button surface.Afterwards, then in surface spraying epoxy resin varnish, lacquer formulation：
The parts by weight of 3610 bisphenol A type epoxy resin 100, the parts by weight of trimethylhexane diamine 33, the parts by weight of butyl acetate 1000.So as to be made
Required button.
Button made from the present embodiment is observed, as shown in Figure 1.Fig. 1 is button prepared by the embodiment of the present invention 1
Outside drawing.From figure 1 it appears that button made from the present embodiment has the enamel effect the same with ceramic button.
With AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, GB/T 5711,
ISO 105-X11, AATCC 133 are examination criteria, and performance test, experimental result table are carried out to button made from the present embodiment
It is bright, AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, all standards of GB/T 5711
The color fastness of detection is at 4 grades, and the color fastness of 133 two standard detections of ISO105-X11, AATCC is at 4.5 grades.
Using ASTM D5171-09a as impact resistance examination criteria, impact resistance test is carried out to button manufactured in the present embodiment,
Test result indicates that, 0.84kg balls are highly subjected to frontal impact in 44mm, impact resistance meets standard.
Density Detection is carried out to imitative ceramic button prepared by the present invention, testing result is 1.2g/cm3, far below very ceramic
Button 2.7g/cm3, meet the light demand of clothes.
Embodiment 2
Mixed solution is obtained after 800g 858 unsaturated-resins are mixed with 300g styrene, then adds 10ml thereto
Cobalt naphthenate and stir, then add 10ml methyl ethyl ketone peroxides, after stirring, obtain base slurry.Its
In, 858 unsaturated-resins, styrene, the weight ratio of cobalt naphthenate and methyl ethyl ketone peroxide are 800：300：9：11.
The base slurry that above-mentioned steps are obtained is warming up to 30 DEG C, and rod is obtained after pouring into the aluminum pipe for being coated with paraffin, solidification
Material.Bar slicer is reused, bar is cut into the disk that thickness is 4mm.Afterwards, the disk cut is put into 90 DEG C of baking ovens
30min is toasted, disk completion of cure simultaneously reaches system button hardness, so as to obtain button blank.Button blank is done by deduction processed
Into button thickness 1.6mm, basal diameter is 3.3mm coniform button, obtains shaping button.
Shaping button is poured into polishing machine, enters water-filling roll cast light 2 hours.Water roll cast light is formulated：The parts by weight of water 1000, oxygen
Change the parts by weight of aluminium rotten-stone 2500, the parts by weight of 1000 mesh polishing powder 100.Wherein, aluminum oxide rotten-stone selects 0.6 × 0.6cm oxygen
Change aluminium rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone presses 3：1 weight is than proportioning；Polishing powder selects cerium rouge and oxidation
Aluminium polishing powder presses 10：1 weight is than proportioning.
Using pretreatment fluid is sprayed on the button of rock field W-101 spray guns after a polish, the pretreatment fluid includes 100 weight
The photocuring acrylate-functional mixture M ST-509 of part and the ethyl acetate of 150 parts by weight, afterwards will using UV curing
It fully solidifies.
It is 1.3 × 10 that button after solidification is placed in into vacuum-5Vacuum condition under, then using e type electron evaporation rifles
Titanium dioxide is gasified, and it is coated in button surface.Afterwards, then in surface spraying epoxy resin varnish, lacquer formulation：
The parts by weight of 3610 bisphenol A type epoxy resin 100, the parts by weight of trimethylhexane diamine 33, the parts by weight of butyl acetate 1000.So as to be made
Required button.
Button made from the present embodiment is observed, as shown in Figure 2.Fig. 2 is button prepared by the embodiment of the present invention 2
Outside drawing.From figure 2 it can be seen that button made from the present embodiment has the enamel effect the same with ceramic button.
With AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, GB/T 5711,
ISO 105-X11, AATCC 133 are examination criteria, and performance test, experimental result table are carried out to button made from the present embodiment
It is bright, AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, all standards of GB/T 5711
The color fastness of detection is at 4 grades, and the color fastness of ISO105-X11, AATCC 133 is at 4.5 grades.
Using ASTMD5171-09a as impact resistance examination criteria, impact resistance test is carried out to button manufactured in the present embodiment, it is real
Test result to show, 0.84kg balls are highly subjected to frontal impact in 44mm, impact resistance meets standard.
Density Detection is carried out to imitative ceramic button prepared by the present invention, testing result is 1.3g/cm3, far below very ceramic
Button 2.7g/cm3, meet the light demand of clothes.
Embodiment 3
Mixed solution is obtained after 700g 858 unsaturated-resins are mixed with 300g styrene, then adds 9ml's thereto
Cobalt naphthenate is simultaneously stirred, and is then added 9ml methyl ethyl ketone peroxides, after stirring, is obtained base slurry.Wherein,
858 unsaturated-resins, styrene, the weight ratio of cobalt naphthenate and methyl ethyl ketone peroxide are 700：300：8：10.
The base slurry that above-mentioned steps are obtained is warming up to 30 DEG C, pours into centrifuge, and centrifuge speed is 150r/min, Gu
Sheet material is made after change.Blanking machine is reused, sheet material is punched into diameter 2.5cm disk.Afterwards, the disk cut is put into 90
40min is toasted in DEG C baking oven, disk completion of cure simultaneously reaches system button hardness, so as to obtain button blank.Button blank is passed through
Deduction processed makes side thickness 1.8mm, pocket knife 3mm, depth 1.4mm, pitch-row 4.4mm and aperture 2.0mm button shape, obtains into
Shape button.
Shaping button is poured into polishing machine, enters water-filling roll cast light 2 hours.Water roll cast light is formulated：The parts by weight of water 1000, oxygen
Change the parts by weight of aluminium rotten-stone 3000, the parts by weight of 800 mesh polishing powder 50.Wherein, aluminum oxide rotten-stone is aoxidized from 0.6 × 0.6cm
Aluminium rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone press 3：1 weight is than proportioning；Polishing powder selects cerium rouge and aluminum oxide
Polishing powder presses 10：1 weight is than proportioning.
Using pretreatment fluid is sprayed on the button of rock field W-101 spray guns after a polish, the pretreatment fluid includes 100 weight
The photocuring acrylate-functional mixture M ST-509 of part and the ethyl acetate of 150 parts by weight, afterwards will using UV curing
It fully solidifies.
It is 1.2 × 10 that button after solidification is placed in into vacuum-5Vacuum condition under, then using e type electron evaporation rifles
Titanium dioxide is gasified, and it is coated in button surface.Afterwards, then in surface spraying epoxy resin varnish, lacquer formulation：
The parts by weight of 3610 bisphenol A type epoxy resin 100, the parts by weight of trimethylhexane diamine 33, the parts by weight of butyl acetate 800.So as to be made
Required button.
Button made from the present embodiment is observed, it can be seen that button made from the present embodiment has with ceramic knob
The same enamel effect of button.
With AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, GB/T 5711,
ISO 105-X11, AATCC 133 are examination criteria, and performance test, experimental result table are carried out to button made from the present embodiment
Bright, the color fastness of all standard detection is more than 4.5 grades.
Using ASTM D5171-09a as impact resistance examination criteria, impact resistance test is carried out to button manufactured in the present embodiment,
Test result indicates that, 0.84kg balls are highly subjected to frontal impact in 67mm, impact resistance meets standard.
Density Detection is carried out to imitative ceramic button prepared by the present invention, testing result is 1.2g/cm3, far below very ceramic
Button 2.7g/cm3, meet the light demand of clothes.
Embodiment 4
Mixed solution is obtained after 700g 858 unsaturated-resins are mixed with 300g styrene, then adds 9ml's thereto
Cobalt naphthenate is simultaneously stirred, and is then added 9ml methyl ethyl ketone peroxides, after stirring, is obtained base slurry.Wherein,
858 unsaturated-resins, styrene, the weight ratio of cobalt naphthenate and methyl ethyl ketone peroxide are 700：300：8：10.
The base slurry that above-mentioned steps are obtained is warming up to 30 DEG C, pours into centrifuge, and centrifuge speed is 150r/min, Gu
Sheet material is made after change.Blanking machine is reused, sheet material is punched into diameter 2.5cm disk.Afterwards, the disk cut is put into 90
40min is toasted in DEG C baking oven, disk completion of cure simultaneously reaches system button hardness, so as to obtain button blank.Button blank is passed through
Deduction processed makes side thickness 1.8mm, pocket knife 3mm, depth 1.4mm, pitch-row 4.4mm and aperture 2.0mm button shape, obtains into
Shape button.
Shaping button is poured into polishing machine, enters water-filling roll cast light 2 hours.Water roll cast light is formulated：The parts by weight of water 1000, oxygen
Change the parts by weight of aluminium rotten-stone 3000, the parts by weight of 800 mesh polishing powder 50.Wherein, aluminum oxide rotten-stone is aoxidized from 0.6 × 0.6cm
Aluminium rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone press 3：1 weight is than proportioning；Polishing powder selects cerium rouge and aluminum oxide
Polishing powder presses 10：1 weight is than proportioning.
Using pretreatment fluid is sprayed on the button of rock field W-101 spray guns after a polish, the pretreatment fluid includes 100 weight
The photocuring acrylate-functional mixture M ST-509 of part and the ethyl acetate of 150 parts by weight, afterwards will using UV curing
It fully solidifies.
It is 1.2 × 10 that button after solidification is placed in into vacuum-5Vacuum condition under, then using e type electron evaporation rifles
Silica is gasified, and it is coated in button surface.Afterwards, then in surface spraying epoxy resin varnish, lacquer formulation：
The parts by weight of 3610 bisphenol A type epoxy resin 100, the parts by weight of trimethylhexane diamine 33, the parts by weight of butyl acetate 800.So as to be made
Required button.
Button made from the present embodiment is observed, it can be seen that button made from the present embodiment has with ceramic knob
The same enamel effect of button.
With AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, GB/T 5711,
ISO 105-X11, AATCC 133 are examination criteria, and performance test, experimental result table are carried out to button made from the present embodiment
Bright, the color fastness of all standard detection is more than 4.5 grades.
Using ASTMD5171-09a as impact resistance examination criteria, impact resistance test is carried out to button manufactured in the present embodiment, it is real
Test result to show, 0.84kg balls are highly subjected to frontal impact in 67mm, impact resistance meets standard.
Density Detection is carried out to imitative ceramic button prepared by the present invention, testing result is 1.2g/cm3, far below very ceramic
Button 2.7g/cm3, meet the light demand of clothes.
Embodiment 5
Mixed solution is obtained after 700g 858 unsaturated-resins are mixed with 300g styrene, then adds 9ml's thereto
Cobalt naphthenate is simultaneously stirred, and is then added 9ml methyl ethyl ketone peroxides, after stirring, is obtained base slurry.Wherein,
858 unsaturated-resins, styrene, the weight ratio of cobalt naphthenate and methyl ethyl ketone peroxide are 700：300：8：10.
The base slurry that above-mentioned steps are obtained is warming up to 30 DEG C, pours into centrifuge, and centrifuge speed is 150r/min, Gu
Sheet material is made after change.Blanking machine is reused, sheet material is punched into diameter 2.5cm disk.Afterwards, the disk cut is put into 90
40min is toasted in DEG C baking oven, disk completion of cure simultaneously reaches system button hardness, so as to obtain button blank.Button blank is passed through
Deduction processed makes side thickness 8mm, top 5mm, and following 10mm trapezoidal button shape obtains shaping button.
Shaping button is poured into polishing machine, enters water-filling roll cast light 2 hours.Water roll cast light is formulated：The parts by weight of water 1000, oxygen
Change the parts by weight of aluminium rotten-stone 3000, the parts by weight of 800 mesh polishing powder 50.Wherein, aluminum oxide rotten-stone is aoxidized from 0.6 × 0.6cm
Aluminium rotten-stone and 0.5 × 1cm aluminum oxide rotten-stone press 3：1 weight is than proportioning；Polishing powder selects cerium rouge and aluminum oxide
Polishing powder presses 10：1 weight is than proportioning.
Using pretreatment fluid is sprayed on the button of rock field W-101 spray guns after a polish, the pretreatment fluid includes 100 weight
The photocuring acrylate-functional mixture M ST-509 of part and the ethyl acetate of 100 parts by weight, afterwards will using UV curing
It fully solidifies.
It is 1.2 × 10 that button after solidification is placed in into vacuum-5Vacuum condition under, then using e type electron evaporation rifles
Zirconium dioxide is gasified, and it is coated in button surface.Afterwards, then in surface spraying epoxy resin varnish, lacquer formulation：
The parts by weight of 3610 bisphenol A type epoxy resin 100, the parts by weight of trimethylhexane diamine 33, the parts by weight of butyl acetate 800.So as to be made
Required button.
Button made from the present embodiment is observed, it can be seen that button made from the present embodiment has with ceramic knob
The same enamel effect of button.
With AATCC 61, ISO 105C06, GB/T 3921, ISO 105D01, AATCC 132-2013, GB/T 5711,
ISO 105-X11, AATCC 133 are examination criteria, and performance test, experimental result table are carried out to button made from the present embodiment
Bright, the color fastness of all standard detection is more than 4.5 grades.
Using ASTM D5171-09a as impact resistance examination criteria, impact resistance test is carried out to button manufactured in the present embodiment,
Test result indicates that, 0.84kg balls are highly subjected to frontal impact in 67mm, impact resistance meets standard.
Density Detection is carried out to imitative ceramic button prepared by the present invention, testing result is 1.2g/cm3, far below very ceramic
Button 2.7g/cm3, meet the light demand of clothes.
The foregoing description of the disclosed embodiments, enables professional and technical personnel in the field to realize or using the present invention.
A variety of modifications to these embodiments will be apparent for those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, it is of the invention
The embodiments shown herein is not intended to be limited to, and is to fit to and principles disclosed herein and features of novelty phase one
The most wide scope caused.
Claims (10)
1. a kind of preparation method of button, it is characterised in that including：
A button blank) is prepared using resin material；
B shaping button) is made in the button blank；
C) the shaping button is polished, the button after being polished；
D the button after the polishing) is subjected to pretreatment fluid spraying, the button after being sprayed；
E the button after the spraying) is subjected to electric rifle coating, finished product button is obtained；The material that the electric rifle coating is used is oxygen
Compound.
2. preparation method according to claim 1, it is characterised in that step C) in, it is described to be finished to water roll cast light.
3. preparation method according to claim 2, it is characterised in that the formula number meter bag of the water roll cast light
Include：
1000 parts of water
1000~5000 parts of aluminum oxide rotten-stone
20~100 parts of polishing powder.
4. preparation method according to claim 3, it is characterised in that the polishing powder is 500~1500 mesh polishing powders.
5. preparation method according to claim 1, it is characterised in that step D) in, the pretreatment fluid is by weight
Meter includes：
100 parts of matrix resin
100~150 parts of diluent.
6. preparation method according to claim 5, it is characterised in that the matrix resin mixes for acrylate-functional
Thing.
7. preparation method according to claim 1, it is characterised in that step E) in, the electronics that the electric rifle coating is used
Beam heating source is straight gun shaped electron gun, ring-type electron gun or e type electron evaporation rifles.
8. preparation method according to claim 1, it is characterised in that the oxide is titanium monoxide, titanium dioxide, two
Zirconium oxide, alundum (Al2O3) or silica.
9. preparation method according to claim 1, it is characterised in that the vacuum of the electric rifle coating is 1.2 × 10-5~
1.2×10-2Pa。
10. button made from a kind of preparation method according to any one of claims 1 to 9.
Priority Applications (1)
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| CN201710523804.3A CN107136661A (en) | 2017-06-30 | 2017-06-30 | A kind of button and preparation method thereof |
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| CN201710523804.3A CN107136661A (en) | 2017-06-30 | 2017-06-30 | A kind of button and preparation method thereof |
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| CN107136661A true CN107136661A (en) | 2017-09-08 |
Family
ID=59784803
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| CN201710523804.3A Pending CN107136661A (en) | 2017-06-30 | 2017-06-30 | A kind of button and preparation method thereof |
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Cited By (3)
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| CN108857728A (en) * | 2018-08-01 | 2018-11-23 | 广东溢达纺织有限公司 | The polishing method of button |
| CN109054421A (en) * | 2018-07-20 | 2018-12-21 | 陈明南 | A kind of resin button and its production method |
| CN109401316A (en) * | 2018-09-27 | 2019-03-01 | 嘉善舜创服饰辅料有限公司 | A kind of processing method of heat-resistant fireproof four-part button |
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Application publication date: 20170908 |