Summary of the invention
Technical problem to be solved by this invention is to overcome the deficiencies in the prior art, and a kind of polyurethane resin frosted coating and preparation method thereof is provided.
The present invention adopts following technical scheme to achieve these goals:
A kind of polyurethane resin frosted coating, is characterized in that the weight portion of its constitutive material is: polyurethane resin 50-65, ethylene polyamine class curing agent 1.4-1.8, glass dust 15-20, polyurethane levelling thickener pu-80800.15-0.25, rosin acid polyoxyethylene ester 1.0-2.0, polyisobutene 3.8-4.5, magnesium carbonate 10-15, polyvinyl acetate emulsion 5.0-7.0, vinyl three ('beta '-methoxy ethyoxyl) silane 2.3-2.5 and diatomite 30-35.
Described polyurethane resin frosted coating, is characterized in that the weight portion of its constitutive material is: polyurethane resin 58, ethylene polyamine class curing agent 1.6, glass dust 18, polyurethane levelling thickener pu-80800.2, rosin acid polyoxyethylene ester 1.5, polyisobutene 4.2, magnesium carbonate 12, polyvinyl acetate emulsion 6.0, vinyl three ('beta '-methoxy ethyoxyl) silane 2.4 and diatomite 32.
The preparation method of described polyurethane resin frosted coating, is characterized in that comprising the following steps:
(1) glass dust, magnesium carbonate, diatomite are mixed, then add rosin acid polyoxyethylene ester, polyisobutene, stir 30-40 minute, then, add vinyl three ('beta '-methoxy ethyoxyl) silane, at temperature 120-130 DEG C, stir 20-30 minute, cooling;
(2) take polyurethane resin and other residue constitutive material and step (1) mixing of materials by the weight portion of constitutive material, then mixing and stirring, sends into extruder extruding pelletization, and extruder temperature is 130-140 DEG C, while being ground to 200-300 order after cooling; Stop grinding packaging.
Beneficial effect of the present invention:
As long as the present invention is direct on glass that the coating direct spraying of producing by the present invention is cleaned up in process, toast 180 DEG C and get final product to obtain imitative frosted finish effect, film performance excellence, the persistence of film, water-fast, moisture-proof, good corrosion resistance, adhesion property is splendid, and after the glass of film falls on the ground and breaks into pieces, glass dregs can not scatter everywhere, but be broken into one, improve the safety in utilization of glass.
Embodiment 1: polyurethane resin frosted coating, the weight portion (kg) of its constitutive material is: polyurethane resin 58, ethylene polyamine class curing agent 1.6, glass dust 18, polyurethane levelling thickener pu-80800.2, rosin acid polyoxyethylene ester 1.5, polyisobutene 4.2, magnesium carbonate 12, polyvinyl acetate emulsion 6.0, vinyl three ('beta '-methoxy ethyoxyl) silane 2.4 and diatomite 32.
The preparation method of described polyurethane resin frosted coating, is characterized in that comprising the following steps:
(1) glass dust, magnesium carbonate, diatomite are mixed, then add rosin acid polyoxyethylene ester, polyisobutene, stir 30-40 minute, then, add vinyl three ('beta '-methoxy ethyoxyl) silane, at temperature 120-130 DEG C, stir 20-30 minute, cooling;
(2) take polyurethane resin and other residue constitutive material and step (1) mixing of materials by the weight portion of constitutive material, then mixing and stirring, sends into extruder extruding pelletization, and extruder temperature is 130-140 DEG C, while being ground to 200-300 order after cooling; Stop grinding packaging.
The dull polished coating material in environmental protection direct spraying making by production method of the present invention is on the process glass lamp cleaning up, and heatproof is tested: after 180 DEG C/5h of baking oven baking, baking oven toasts glass lamp after 130 DEG C/15 days and coats color and luster without significant change; 3h is irradiated in ultraviolet ray, and not shedding of coating is non-yellowing, has good imitative frosted finish effect.