CN107129321A - A kind of hacking pottery combines glaze with sky blue - Google Patents
A kind of hacking pottery combines glaze with sky blue Download PDFInfo
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- CN107129321A CN107129321A CN201710413618.4A CN201710413618A CN107129321A CN 107129321 A CN107129321 A CN 107129321A CN 201710413618 A CN201710413618 A CN 201710413618A CN 107129321 A CN107129321 A CN 107129321A
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/80—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
- C04B41/81—Coating or impregnation
- C04B41/89—Coating or impregnation for obtaining at least two superposed coatings having different compositions
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
- C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
- C04B41/52—Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
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Abstract
A kind of hacking pottery combines glaze with sky blue, and the combination glaze is made up of internal layer glaze, middle level glaze and outer layer glaze；Internal layer glaze has the of a relatively high coefficient of expansion for middle level glaze and outer layer glaze, so that glaze produces larger tensile stress in high temperature sintering, glaze is formed many crackles, obtains the decorative effect of hacking；Middle level glaze has good mobility, so as to be repaired to a certain extent to the crackle of generation, improves toughness during pottery sintering, improves the rate of burning till；Outer layer glaze has the coefficient of expansion of very little, and its sintering temperature is relatively low, liquefaction sinter layer can be quickly formed in sintering process and envelopes middle level glaze and internal layer glaze, so that the air that middle level glaze and internal layer glaze are produced in sintering process is unable to emersion glaze, and many minute bubbles are formed in glaze, glaze layer is become milkiness and opaque, after expanding with heat and contract with cold, glaze layer ftractures with regard to fish scale-shaped and is superimposed, so as to further form glaze layer hacking effect.
Description
Technical field
The present invention relates to the pottery in ceramic field, specifically a kind of hacking pottery combines glaze with sky blue.
Background technology
Ceramics development and the mankind progress have it is close and remote contact, it be human civilization epoch mark.Pottery
Pottery in porcelain, has handled Tang, Song, member, bright, clear years baptism, has formd the artistic expression of uniqueness, an ancient unit of weight kiln has pole
Beautiful color, glaze changes all the time in kiln, and with nature aesthetic feeling, is still inherited and imitated by various regions porcelain kiln today, and constantly
Innovation, makes this gorgeous flower of an ancient unit of weight kiln reset extraordinary splendor.
An ancient unit of weight kiln is northern celadon kiln system, still there is very big achievement at present, is typically burnt using bavin, coal, charcoal and natural gas
System, the glaze color change that different burning process is produced is also different.Outside is that glaze produces gorgeous color when by high-temperature fusion
Variegation bright-coloured changes, and reason is mainly in the formula of glaze, and this is to influence the key factor of pottery finished product exogenic color, while being also to cause an ancient unit of weight
Porcelain enters that kiln is of the same colour, the color key factor of kiln discharge ten thousand.
Pottery is in sintering procedure, because of reasons such as glaze thickness and firing temperatures, a variety of flow liners occurs, further enhancing glaze
Face decoration effect, it is relatively common and for people appreciate be that earthworm walks mud line, borneol line, mian silkings etc..
Earthworm walks a kind of natural transmutation decorative pattern that mud line is pottery.In the glaze layer of pottery, a rule continuously emerges and does not advise
Then walk the vestige of mud such as earthworm, it is cranky, afford food for thought.Its Crack cause, has different versions in the past, passes through the practice of craftsman teacher
Learnt with archaeological discovery, pottery system burns till twice, a thickness glaze is applied after biscuiting, is burnt till initial stage, some glaze layer crackings, glaze occurs
Irregular cracks, then through high temperature, glaze layer melting, the relatively low part of glaze viscosity flows into crack, made up, because by temperature after burning till
Degree influences and is formed and walk mud line.This flow liner is generally present in the relatively low position of glaze layer temperature, and color and luster is deep mixed, there is kermesinus,
Also there is cyan etc..
Borneol line is also named " opening first ", i.e., occur the irregular splitting as borneol on glaze.Glaze ftractures, daily
Originally it is a kind of fatal defect on pottery, and it has the honor to appear on decorative ceramics, is a kind of artistic beauty.An ancient unit of weight kiln ware glaze is opened
Split, the hacking that adds decoration, set off implements are quaint interesting.The reason for glaze ftractures is silicon amount too high in glaze and tire glaze
The coefficient of expansion is different, cracking when being cooled down after kiln discharge.
mian silkings are the elements such as copper, iron in the hot stage in sintering procedure, glaze, because of the atmosphere shadow in high temperature and kiln
Sound and moulding fluctuating and glaze juice cleverly trickle and occurred.Its such as lifelike rabbit hair, has very strong third dimension and dynamic
Glaze decorating, is obtained exceptionally fine and smooth soft by sense.
It follows that " hacking crack ceramic product " is all liked that it has dense by vast consumption from ancient times to the present
Sense of history, line piece is original, simple and unsophisticated, pure, elegance, fish scale-shaped cracking superposition, and the defect such as incomplete, rough is incorporated pottery art system by it
The Aesthetic Category of product, is not difficult to find out, the appearance of the development history of crack glaze to Contemporary Ceramics has the influence power of uniqueness.Meanwhile, when
Also different artistic effect and enjoying value have been createed for pottery art for ceramic art.
The content of the invention
Glaze is combined with sky blue it is an object of the invention to provide a kind of hacking pottery, the combination glaze is by three kinds of heterogeneities
Glaze respectively as internal layer glaze, middle level glaze and outer layer glaze, wherein, internal layer glaze has relative for middle level glaze and outer layer glaze
The higher coefficient of expansion, so that glaze produces larger tensile stress in high temperature sintering, makes glaze form many crackles, is opened
The decorative effect of piece；Middle level glaze has good mobility, so as to be repaired to a certain extent to the crackle of generation,
Toughness during pottery sintering is improved, the rate of burning till is improved；Outer layer glaze has the coefficient of expansion of very little, and its sintering temperature phase
To relatively low, liquefaction sinter layer can be quickly formed in sintering process and envelopes middle level glaze and internal layer glaze so that middle level glaze and
The air that internal layer glaze is produced in sintering process is unable to emersion glaze, and many minute bubbles are formed in glaze, due to firing temperature
Control makes a number of non-fused quartz particle of remaining in glaze at 1280~1310 DEG C, and forms substantial amounts of anorthite crystallization, this
The light that a little minute bubbles, quartz particles and anorthite crystallizations enter glaze layer is scattered, thus glaze layer is become milkiness and impermeable
Bright, after expanding with heat and contract with cold, glaze layer ftractures with regard to fish scale-shaped and is superimposed, so as to further form glaze layer hacking effect.
The technical scheme that is used for achieving the above object of the present invention for：A kind of hacking pottery is combined with sky blue
Glaze, the combination glaze is made up of internal layer glaze, middle level glaze and outer layer glaze, according to weight ratio, potassium feldspar, 21- of the internal layer glaze by 24-26 parts
23 parts of calcite, 16-18 parts of quartz, 6-7 parts of lime stone, 3-5 parts Datong District soil, 0.6-0.8 parts of zinc oxide and
1.2-1.6 parts of zirconium dioxide composition, middle level glaze is by 28-30 parts of albite, 22-24 parts of calcite, 11-13 parts of stone
English, 4-5 parts of elemental silicon, 0.5-0.7 parts of cupric phosphate composition, outer layer glaze are solved by 30-32 parts of potassium feldspar, 25-27 parts of side
Stone, 8-10 parts of quartz, 3-5 parts of dolomite, 4-6 parts of talcum powder and 0.6-0.8 parts of zirconium dioxide composition.
The also magnesia containing 0.4-0.6 parts of iron oxide and 0.5-0.7 part in the internal layer glaze.
The also bentonite containing 0.8-1.2 parts of talcum powder and 0.4-0.8 part in the middle level glaze.
Also containing 0.8-1.2 parts of Fluorspar Powder in the outer layer glaze.
The glazing thickness of the middle level glaze is the 150-170% of internal layer glaze thickness, and the glazing thickness of outer layer glaze is thick for internal layer glaze
The 80-120% of degree.
The internal layer glaze is drying after glazing is finished and 10min is sintered under the conditions of 300 DEG C, the after-applied middle level of natural cooling
Glaze, middle level glaze is drying after glazing is finished and 15min is sintered under the conditions of 280 DEG C, the after-applied outer layer glaze of natural cooling, outer layer glaze
Drying after glazing is finished and completing glazing operation after sintering 10min under the conditions of 350 DEG C normally sinter.
In the present invention, the firing temperature of the combination glaze is 1200-1300 DEG C.
Compared with prior art, the invention has the advantages that：
1）The present invention combines glaze by the glaze of three kinds of heterogeneities respectively as internal layer glaze, middle level glaze and outer layer glaze, wherein, internal layer
Glaze has the of a relatively high coefficient of expansion for middle level glaze and outer layer glaze, so that glaze generation is larger in high temperature sintering
Tensile stress, glaze is formed many crackles, obtain the decorative effect of hacking；Middle level glaze has good mobility, so as to
It is enough that the crackle of generation is repaired to a certain extent, toughness during pottery sintering is improved, the rate of burning till is improved；Outer layer glaze
The coefficient of expansion with very little, and its sintering temperature is relatively low, and liquefaction sinter layer can be quickly formed in sintering process
Middle level glaze and internal layer glaze are enveloped, so that the air that middle level glaze and internal layer glaze are produced in sintering process is unable to emersion glaze,
And many minute bubbles are formed in glaze, because firing temperature control is at 1280~1310 DEG C, make remaining in glaze a number of not
Fused quartz particle, and substantial amounts of anorthite crystallization is formed, these minute bubbles, quartz particles and anorthite crystallization enter the light of glaze layer
Line is scattered, thus glaze layer is become milkiness and opaque, after expanding with heat and contract with cold, and glaze layer ftractures with regard to fish scale-shaped and is superimposed, from
And further form glaze layer hacking effect；
2）It is monoclinic system to contain in internal layer glaze and outer layer glaze of the present invention under zirconium dioxide, zirconium dioxide normal temperature, at 1170 DEG C
When, it is changed into metastable state tetragonal structure, and it is changed into list after temperature is reduced to below 1170 DEG C, and from metastable state tetragonal structure
Oblique system, then 3-5% volumetric expansion is produced during this, due to being the volumetric expansion of little crystal grain, whole ceramics will not be caused
Cracking, only can trigger some micro-cracks in crystal grain surrounding, due to the presence of these micro-cracks, change the stress around crystal grain
, when outside Crack Extension passes through this crystal grain, will occur crack skew effect, so as to improve fracture toughness；Middle level
Contain elemental silicon in glaze, when elemental silicon is sintered in reducing atmosphere at high temperature, some can keep the elemental stage of melting, from
And the mobility of middle level glaze is improved, so as to carry out certain reparation to the fine crack that internal layer glaze is produced；
3）The talcum powder and bentonite contained in middle level glaze of the present invention, can not only reduce the coefficient of expansion of middle level glaze, reduction and burn
Junction temperature, raising mobility, but also glaze-body interface generation, the opaque of increase chun glaze can be promoted；Added in outer layer glaze
Fluorspar Powder, can not only make the color and luster for burning till rear enamel more beautiful, and can further reduce the sintering temperature of outer layer glaze
Degree.
Embodiment
With reference to specific embodiment, the present invention is further elaborated.It is each used in the following embodiment of the present invention
Raw material is this area conventional material.
Embodiment 1
A kind of hacking pottery combines glaze with sky blue, and the combination glaze is made up of internal layer glaze, middle level glaze and outer layer glaze, according to weight
Than, internal layer glaze by 24 parts of potassium feldspar, 21 parts of calcite, 16 parts of quartz, 6 parts of lime stone, 3 parts Datong District soil, 0.6 part
Zinc oxide and 1.2 parts zirconium dioxide composition, middle level glaze by 28 parts of albite, 22 parts of calcite, 11 parts quartz, 4
Part elemental silicon, 0.5 part cupric phosphate composition, outer layer glaze by 30 parts of potassium feldspar, 25 parts of calcite, 8 parts quartz, 3 parts
Dolomite, the zirconium dioxide composition of 4 parts of talcum powder and 0.6 part.
Above be the present embodiment basic embodiment, can more than on the basis of further improved, optimized and limited：
Such as, the magnesia in the internal layer glaze also containing 0.4 part of iron oxide and 0.5 part；
And for example, the bentonite in the middle level glaze also containing 0.8 part of talcum powder and 0.4 part；
For another example, also containing 0.8 part of Fluorspar Powder in the outer layer glaze；
Again for another example, the glazing thickness of the middle level glaze is the 150% of internal layer glaze thickness, and the glazing thickness of outer layer glaze is thick for internal layer glaze
The 80% of degree；
Finally, the internal layer glaze is drying after glazing is finished and is sintering 10min under the conditions of 300 DEG C, during natural cooling is after-applied
Layer glaze, middle level glaze is drying after glazing is finished and 15min is sintered under the conditions of 280 DEG C, the after-applied outer layer glaze of natural cooling, outer layer
Glaze is drying after glazing is finished and glazing operation progress normally sintering is completed after sintering 10min under the conditions of 350 DEG C.
Embodiment 2
A kind of hacking pottery combines glaze with sky blue, and the combination glaze is made up of internal layer glaze, middle level glaze and outer layer glaze, according to weight
Than, internal layer glaze by 26 parts of potassium feldspar, 23 parts of calcite, 18 parts of quartz, 7 parts of lime stone, 5 parts Datong District soil, 0.8 part
Zinc oxide and 1.6 parts zirconium dioxide composition, middle level glaze by 30 parts of albite, 24 parts of calcite, 13 parts quartz, 5
Part elemental silicon, 0.7 part cupric phosphate composition, outer layer glaze by 32 parts of potassium feldspar, 27 parts of calcite, 10 parts quartz, 5 parts
Dolomite, the zirconium dioxide composition of 6 parts of talcum powder and 0.8 part.
Above be the present embodiment basic embodiment, can more than on the basis of further improved, optimized and limited：
Such as, the magnesia in the internal layer glaze also containing 0.6 part of iron oxide and 0.7 part；
And for example, the bentonite in the middle level glaze also containing 1.2 parts of talcum powder and 0.8 part；
For another example, also containing 1.2 parts of Fluorspar Powder in the outer layer glaze；
Again for another example, the glazing thickness of the middle level glaze is the 170% of internal layer glaze thickness, and the glazing thickness of outer layer glaze is thick for internal layer glaze
The 120% of degree；
Finally, the internal layer glaze is drying after glazing is finished and is sintering 10min under the conditions of 300 DEG C, during natural cooling is after-applied
Layer glaze, middle level glaze is drying after glazing is finished and 15min is sintered under the conditions of 280 DEG C, the after-applied outer layer glaze of natural cooling, outer layer
Glaze is drying after glazing is finished and glazing operation progress normally sintering is completed after sintering 10min under the conditions of 350 DEG C.
Embodiment 3
A kind of hacking pottery combines glaze with sky blue, and the combination glaze is made up of internal layer glaze, middle level glaze and outer layer glaze, according to weight
Than internal layer glaze is by 25 parts of potassium feldspar, 22 parts of calcite, 17 parts of quartz, 6.5 parts of lime stone, 4 parts Datong District soil, 0.7
Part zinc oxide and 1.4 parts zirconium dioxide composition, middle level glaze by 29 parts of albite, 23 parts of calcite, 12 parts quartz,
4.5 parts of elemental silicon, 0.6 part of cupric phosphate composition, outer layer glaze is by 31 parts of potassium feldspar, 26 parts of calcite, 9 parts of quartz, 4
The dolomite, 5 parts of talcum powder and 0.7 part of zirconium dioxide composition of part.
Above be the present embodiment basic embodiment, can more than on the basis of further improved, optimized and limited：
Such as, the magnesia in the internal layer glaze also containing 0.5 part of iron oxide and 0.6 part；
And for example, the bentonite in the middle level glaze also containing 1 part of talcum powder and 0.6 part；
For another example, also containing 1 part of Fluorspar Powder in the outer layer glaze；
Again for another example, the glazing thickness of the middle level glaze is the 160% of internal layer glaze thickness, and the glazing thickness of outer layer glaze is thick for internal layer glaze
The 100% of degree；
Finally, the internal layer glaze is drying after glazing is finished and is sintering 10min under the conditions of 300 DEG C, during natural cooling is after-applied
Layer glaze, middle level glaze is drying after glazing is finished and 15min is sintered under the conditions of 280 DEG C, the after-applied outer layer glaze of natural cooling, outer layer
Glaze is drying after glazing is finished and glazing operation progress normally sintering is completed after sintering 10min under the conditions of 350 DEG C.
The sintering method of combination glaze when in use do not mentioned in various embodiments above, is this area normal sintering side
Method, such as can be fired using following methods：
（1）Glazing：Become glaze slip with compressed air to nebulize, be then uniformly sprayed on base substrate, by the water imbibition of base substrate make
Glaze is adsorbed on base substrate；Or will for a moment be taken out in the glaze slip of base substrate immersion celeste glaze, using the water imbibition of base substrate, make glaze slip equal
Even is attached to billet surface；
（2）The glaze firing oxidizing flame stage：Base substrate is loaded saggar by glazing after finishing, by saggar loading of kiln, then by kiln temperature from 0 DEG C by
Edge up to 1040 DEG C, the chimney casket plate of control ventilation is opened, and kiln top skylight is opened, be in oxidizing atmosphere, saggar, base substrate and kiln in kiln
Organic matter in interior moisture and glaze etc. is discharged, and glaze layer starts fusing, and glaze surface is in unsintered fine granularity；
（3）The glaze firing reducing flame stage：Kiln temperature is at 1040 DEG C -1150 DEG C, and this stage skylight is closed, flue casket door closing or half
Open, coal can not fully be burnt, and carbon monoxide increases, and be in reducing atmosphere in kiln, and glaze layer fusing, glaze is gradually closed by porous
Close, form rough state；
（4）The neutral flame stage：It is in weakly reducing atmosphere that kiln temperature, which is raised to by 1150 DEG C in 1270 DEG C, kiln, with kiln temperature liter
High glaze layer is fused into thick liquid nano and from top to bottom flowed, and the melting of glaze layer makes glaze flatten, glaze layer formation vitreous；
（5）Aoxidize cooling stage：When kiln temperature is raised to 1250 DEG C -1300 DEG C, soaking is ceased fire after being incubated 1-2 hours, is opened
Wicket, a large amount of oxygen enter in kiln, are in oxidizing atmosphere in kiln, and oxygen is aoxidized to glaze, and cooling, glaze colours is formed.
Claims (6)
1. a kind of hacking pottery combines glaze with sky blue, it is characterised in that：The combination glaze is by internal layer glaze, middle level glaze and outer layer glaze group
Into according to weight ratio, internal layer glaze is by 24-26 parts of potassium feldspar, 21-23 parts of calcite, 16-18 parts of quartz, 6-7 parts of stone
Lime stone, 3-5 parts of Datong District's soil, 0.6-0.8 parts of zinc oxide and 1.2-1.6 parts of zirconium dioxide composition, middle level glaze is by 28-30 parts
Albite, 22-24 parts of calcite, 11-13 parts of quartz, 4-5 parts of elemental silicon, 0.5-0.7 parts cupric phosphate composition, outside
Layer glaze is by 30-32 parts of potassium feldspar, 25-27 parts of calcite, 8-10 parts of quartz, 3-5 parts of dolomite, 4-6 parts of talcum
Powder and 0.6-0.8 parts of zirconium dioxide composition.
2. a kind of hacking pottery according to claim 1 combines glaze with sky blue, it is characterised in that：In the internal layer glaze also
Magnesia containing 0.4-0.6 parts of iron oxide and 0.5-0.7 parts.
3. a kind of hacking pottery according to claim 1 combines glaze with sky blue, it is characterised in that：In the middle level glaze also
Bentonite containing 0.8-1.2 parts of talcum powder and 0.4-0.8 parts.
4. a kind of hacking pottery according to claim 1 combines glaze with sky blue, it is characterised in that：In the outer layer glaze also
Contain 0.8-1.2 parts of Fluorspar Powder.
5. a kind of hacking pottery according to claim 1 combines glaze with sky blue, it is characterised in that：The middle level glaze is applied
Glaze thickness is the 150-170% of internal layer glaze thickness, and the glazing thickness of outer layer glaze is the 80-120% of internal layer glaze thickness.
6. a kind of hacking pottery according to claim 1 combines glaze with sky blue, it is characterised in that：The internal layer glaze is being applied
Glaze dries after finishing and 10min is sintered under the conditions of 300 DEG C, the after-applied middle level glaze of natural cooling, and middle level glaze is after glazing is finished
Dry and 15min sintered under the conditions of 280 DEG C, the after-applied outer layer glaze of natural cooling, outer layer glaze dried after glazing is finished and
Sintered under the conditions of 350 DEG C and glazing operation progress normally sintering is completed after 10min.
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107572803A (en) * | 2017-09-28 | 2018-01-12 | 禹州市正玉钧窑有限公司 | A kind of enameling method for preventing pottery from ftractureing |
| CN107602068A (en) * | 2017-09-28 | 2018-01-19 | 禹州市正玉钧窑有限公司 | A kind of crack resistence pottery and its preparation technology |
| CN107777887A (en) * | 2017-09-28 | 2018-03-09 | 禹州市正玉钧窑有限公司 | A kind of crack resistence pottery glaze and preparation method thereof |
| CN109052948A (en) * | 2018-09-29 | 2018-12-21 | 河南省钧艺照明灯具有限公司 | A kind of hacking pottery kermesinus combination glaze |
| CN114163129A (en) * | 2021-12-31 | 2022-03-11 | 德化县京隆堂陶瓷有限责任公司 | Metal-texture in-glaze-pattern glazed ceramic and preparation method thereof |
| CN114890821A (en) * | 2022-05-11 | 2022-08-12 | 福建省德化县恒利陶瓷有限公司 | Gradient color glaze ceramic and preparation method thereof |
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| CN105339319A (en) * | 2013-07-17 | 2016-02-17 | 费罗公司 | Method of forming durable glass enamel |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107572803A (en) * | 2017-09-28 | 2018-01-12 | 禹州市正玉钧窑有限公司 | A kind of enameling method for preventing pottery from ftractureing |
| CN107602068A (en) * | 2017-09-28 | 2018-01-19 | 禹州市正玉钧窑有限公司 | A kind of crack resistence pottery and its preparation technology |
| CN107777887A (en) * | 2017-09-28 | 2018-03-09 | 禹州市正玉钧窑有限公司 | A kind of crack resistence pottery glaze and preparation method thereof |
| CN109052948A (en) * | 2018-09-29 | 2018-12-21 | 河南省钧艺照明灯具有限公司 | A kind of hacking pottery kermesinus combination glaze |
| CN114163129A (en) * | 2021-12-31 | 2022-03-11 | 德化县京隆堂陶瓷有限责任公司 | Metal-texture in-glaze-pattern glazed ceramic and preparation method thereof |
| CN114163129B (en) * | 2021-12-31 | 2023-11-28 | 德化县京隆堂陶瓷有限责任公司 | Glaze ceramic with metallic texture and preparation method thereof |
| CN114890821A (en) * | 2022-05-11 | 2022-08-12 | 福建省德化县恒利陶瓷有限公司 | Gradient color glaze ceramic and preparation method thereof |
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