CN107129248A - One kind has ecological functions gypsum and preparation method thereof - Google Patents

One kind has ecological functions gypsum and preparation method thereof Download PDF

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Publication number
CN107129248A
CN107129248A CN201710210869.2A CN201710210869A CN107129248A CN 107129248 A CN107129248 A CN 107129248A CN 201710210869 A CN201710210869 A CN 201710210869A CN 107129248 A CN107129248 A CN 107129248A
Authority
CN
China
Prior art keywords
gypsum
ecological functions
water
nano silver
titanium dioxide
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710210869.2A
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Chinese (zh)
Inventor
刘训兵
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
HUNAN ANYADA BUILDING MATERIAL TECHNOLOGY Co Ltd
Original Assignee
HUNAN ANYADA BUILDING MATERIAL TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by HUNAN ANYADA BUILDING MATERIAL TECHNOLOGY Co Ltd filed Critical HUNAN ANYADA BUILDING MATERIAL TECHNOLOGY Co Ltd
Priority to CN201710210869.2A priority Critical patent/CN107129248A/en
Publication of CN107129248A publication Critical patent/CN107129248A/en
Pending legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/14Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00017Aspects relating to the protection of the environment
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00025Aspects relating to the protection of the health, e.g. materials containing special additives to afford skin protection

Abstract

One kind has ecological functions gypsum and preparation method thereof, should have ecological functions gypsum to be made up of the raw material of following weight:Land plaster, Nano titanium dioxide 1.2 1.8%, Nano Silver 0.4 0.6%, water 60 70%, the Nano titanium dioxide, Nano Silver, the percentage of water are using land plaster weight as radix.Present invention additionally comprises the preparation method with ecological functions gypsum.There is ecological functions gypsum obtained by the present invention, can on one's own initiative, effectively purify indoor environment, it is to avoid noxious material is detrimental to health, and health, comfortable work and living environment can be built for people.

Description

One kind has ecological functions gypsum and preparation method thereof
Technical field
The present invention relates to a kind of gypsum and preparation method thereof, and in particular to one kind has ecological functions gypsum and its preparation side Method.
Background technology
It is well known that environmental problem turns into the matter of severe problem, particularly living environment that human development must be faced Amount increasingly obtains the concern of people.It is a large amount of in due to decorating indoors to use the poor quality containing harmful substances such as formaldehyde, toluene Material, brings great harm to the physical and mental health of people, and the incidence of disease such as cancer is constantly raised, so constantly releasing healthy ring The ecotecture ornament materials of guarantor is building material industry obligation one can't decline.
The content of the invention
The technical problems to be solved by the invention be to provide one kind can on one's own initiative, effectively purify indoor environment, it is to avoid have Noxious material is detrimental to health, and a health, comfortable work and living environment can be built for people has ecological functions stone Cream and preparation method thereof.
The technical solution adopted for the present invention to solve the technical problems is:
The present invention's has ecological functions gypsum, is made up of the raw material of following weight:Land plaster, nanoscale dioxy Change titanium 1.2-1.8%, Nano Silver 0.4-0.6%, water 60-70%, the Nano titanium dioxide, Nano Silver, the percentage of water Using land plaster weight as radix.
Further, the preferred 1.4-1.6% of the Nano titanium dioxide, more preferably 1.5%.
Further, the preferred 0.45-0.55% of the Nano Silver, more preferably 0.5%.
Further, the preferred 62-68% of the water, more preferably 65%.
The Nano titanium dioxide is a kind of nontoxic, and catalytic activity is high, and oxidability is strong, corrosion-resistant good excellent light Catalyst.
The Nano Silver is that particle diameter is accomplished nano level argent simple substance by one kind, puts it into carrier, and a kind of height is made The bactericide of effect.
The water can be the domestic water without objectionable impurities, such as running water.
The preparation method with ecological functions gypsum of the present invention, comprises the following steps:
(1) first nanoscale TiO is weighed by preset blending ratio2, Nano Silver, water;
(2) material weighed is put into bucket and be stirred, obtain mixed solution;
(3) land plaster is weighed by preset blending ratio again, poured into the bucket equipped with mixed solution, stirred, obtain gypsum slurry;
(4) gained gypsum slurry is poured into mould mould, shakes, strikes off, rejecting clout, stood, is stripped, dried.
The mechanism of action of the additive of the present invention:
(1)TiO2The mechanism of action:TiO2High, the stable chemical performance with catalytic activity, oxidation-reduction quality is strong, most of Organic pollution can be under benign environment in TiO2Surface permineralization is CO2And H2O, irradiates in the ultraviolet of certain wavelength Under, TiO2Absorb luminous energy, the electronics (e of its out orbit-) will be excited and cross forbidden band and enter conduction band, while in original track On leave a space (h+), this space has very strong oxidisability, can be by TiO2The hydrone of surrounding is oxidized to hydroxyl free Base (.OH), and excite generation electronics (e-) there is very strong reducing power, by TiO2Neighbouring O2It is reduced into (.O2 -).Hydroxyl is certainly By base (.OH) and (.O2 -) all it is the group with very Strong oxdiative ability, can be by TiO2Neighbouring organic matter or bacterium effectively divides Solution, such as formaldehyde, toluene, so as to reach the effect of purification air.
(2) mechanism of action of Nano Silver:The haptoreaction of silver ion causes microorganism to have component damage or produces function Obstacle.When micro silver ion reaches microbial cell film, because the latter is negatively charged, by Coulomb attraction, make both firm Absorption, silver ion penetration cell wall enters intracellular, makes protein coagulating, destroys the activity of cell synzyme, cell loss division Multiplication capacity and it is dead.Silver ion can also destroy microorganism electric transmission system, respiratory system and substance delivery system, and division is thin Bacterium, the cell membrane of virus, can effectively kill 12 kinds of Gram-negative bacterias and 8 kinds of Gram-negative bacterias, Escherichia coli, golden yellow The extremely sick bacterium such as coccus.Meanwhile, in the presence of ultraviolet, sodium rice silver and water or air effect, generation active oxygen O2 -And freedom Base .OH, its redox, the active oxygen O when harmful bacteria is close to nanometer silver surface2 -With free radical .OH by attack bacteria After birth, is killed.
The ecological functions added material system that the present invention is used uses the raw material that can be used on food additives and cosmetics, Do not have to have admixed 5 Nano titanium dioxides, Nano Silver, pure water, shape in any toxic action, ecological series additive to human body Into a kind of responsive to visible light type photocatalyst, it can just be worked under common illumination, even same under low-light occur light Catalytic action, produces active oxygen and hydroxyl free radical, persistently induces a large amount of negative oxygen ions, to harmful in product itself and air The harmful substance such as chemical substance, especially PARA FORMALDEHYDE PRILLS(91,95), toluene, ammonia and TVOC (volatile organic matter) has stronger degradation capability, All also there is extremely strong killing ability to harmful bacteria simultaneously.
Gypsum hardenite used of the invention has natural microcellular structure, and with good respiratory function, itself can be preferable Ground adjusts indoor temperature and humidity.It is sustainable to induce a large amount of negative oxygen ions, sustaining degradation harmful chemicals thing after the ecological additive of addition Matter, sustained anti-microbial is mould proof, comprehensive decontamination room air, lifts IAQ, improves indoor environment, is really achieved green life Effect of state.
Obtained by the present invention have ecological functions gypsum, can on one's own initiative, effectively purify indoor environment, it is to avoid Toxic Matter is detrimental to health, and a health, comfortable work and living environment can be built for people.
Embodiment
The invention will be further described with reference to embodiments.
Embodiment
The present invention's has ecological functions gypsum, is made up of the raw material of following weight:2500 grams of land plaster;Nanometer 38 grams of grade titanium dioxide;12.5 grams of Nano Silver;1600 grams of pure water.
Preparation method, comprises the following steps:
(1) nanoscale TiO is weighed238 grams, 12.5 grams of Nano Silver, 1600 grams of pure water;
(2) material weighed is put into bucket and be stirred, obtain mixed solution;
(3) 2500 grams of land plaster is weighed, is poured into the bucket equipped with mixed solution, stirs 25 seconds, obtains gypsum slurry;
(4) gained gypsum slurry is poured into mould mould, shakes, strikes off, rejecting clout, be stripped after standing 30 minutes, weight Multiple aforesaid operations, are made 9 identical samples, dry.
Through entrusting Building Materials Industry Technology Supervision Research Center according to JC/T1074-2008《Function of purifying indoor air Coating material purifying property》Standard detection, its every green technology index such as table.
Sequence number Inspection project Standard requirement Testing result Individual event conclusion
1 Purifying formaldehyde efficiency (%) ≧75 92.3 It is qualified
2 Purifying formaldehyde effect persistence (%) ≧60 85.2 It is qualified
3 Toluene purification efficiency (%) ≧35 64.4 It is qualified
4 Toluene clean-up effect persistence (%) ≧20 51.2 It is qualified
5 The anion amount of inducing 2.41×10 It is qualified
6 Bacteria resistance energy > 90% > 99% It is qualified
7 Anti-mildew energy Meet 0 grade It is qualified
From upper table, indices exceed relevant national standard, are worthy of the name to have green ecological function Gypsum material.

Claims (8)

1. one kind has ecological functions gypsum, it is characterised in that be made up of the raw material of following weight:Land plaster, nanometer Grade titanium dioxide 1.2-1.8%, Nano Silver 0.4-0.6%, water 60-70%, the Nano titanium dioxide, Nano Silver, water Percentage is using land plaster weight as radix.
2. according to claim 1 have ecological functions gypsum, it is characterised in that the Nano titanium dioxide is 1.4- 1.6%.
3. according to claim 2 have ecological functions gypsum, it is characterised in that the Nano titanium dioxide is 1.5%.
4. there is ecological functions gypsum according to claim 1 or 2 or 3, it is characterised in that the Nano Silver is 0.45- 0.55%.
5. according to claim 4 have ecological functions gypsum, it is characterised in that the Nano Silver is 0.5%.
6. according to claim 5 have ecological functions gypsum, it is characterised in that the water is 62-68%.
7. according to claim 6 have ecological functions gypsum, it is characterised in that the water is 65%.
8. a kind of preparation method as claimed in claim 1 with ecological functions gypsum, it is characterised in that including following step Suddenly:
(1) first nanoscale TiO is weighed by preset blending ratio2, Nano Silver, water;
(2) material weighed is put into bucket and be stirred, obtain mixed solution;
(3) land plaster is weighed by preset blending ratio again, poured into the bucket equipped with mixed solution, stirred, obtain gypsum slurry;
(4) gained gypsum slurry is poured into mould mould, shakes, strikes off, rejecting clout, stood, is stripped, dried.
CN201710210869.2A 2017-03-31 2017-03-31 One kind has ecological functions gypsum and preparation method thereof Pending CN107129248A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710210869.2A CN107129248A (en) 2017-03-31 2017-03-31 One kind has ecological functions gypsum and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201710210869.2A CN107129248A (en) 2017-03-31 2017-03-31 One kind has ecological functions gypsum and preparation method thereof

Publications (1)

Publication Number Publication Date
CN107129248A true CN107129248A (en) 2017-09-05

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047705A (en) * 2020-09-02 2020-12-08 广东美穗建材科技有限公司 Titanium-calcium plate and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102838338A (en) * 2012-09-27 2012-12-26 杨四海 Multifunctional ecological environmental-friendly architectural decoration material and production method thereof
CN104529349A (en) * 2014-11-28 2015-04-22 陕西省建筑科学研究院 Passive composite humidity adjusting particles and application thereof
CN105000857A (en) * 2015-08-03 2015-10-28 湖南安雅达建材科技有限公司 Gypsum binding agent and preparation method thereof
EP2978721A1 (en) * 2013-03-29 2016-02-03 Siniat International SAS High-porosity facing paper for plasterboards

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102838338A (en) * 2012-09-27 2012-12-26 杨四海 Multifunctional ecological environmental-friendly architectural decoration material and production method thereof
EP2978721A1 (en) * 2013-03-29 2016-02-03 Siniat International SAS High-porosity facing paper for plasterboards
CN104529349A (en) * 2014-11-28 2015-04-22 陕西省建筑科学研究院 Passive composite humidity adjusting particles and application thereof
CN105000857A (en) * 2015-08-03 2015-10-28 湖南安雅达建材科技有限公司 Gypsum binding agent and preparation method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
唐春红等: "《天然防腐剂与抗氧化剂》", 31 May 2010 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112047705A (en) * 2020-09-02 2020-12-08 广东美穗建材科技有限公司 Titanium-calcium plate and preparation method thereof

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Application publication date: 20170905