CN107124812A - Atmosphere pressure glow discharge plasma producing apparatus and textile material processing unit - Google Patents

Atmosphere pressure glow discharge plasma producing apparatus and textile material processing unit Download PDF

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Publication number
CN107124812A
CN107124812A CN201710492001.6A CN201710492001A CN107124812A CN 107124812 A CN107124812 A CN 107124812A CN 201710492001 A CN201710492001 A CN 201710492001A CN 107124812 A CN107124812 A CN 107124812A
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CN
China
Prior art keywords
glow discharge
atmosphere pressure
pressure glow
producing apparatus
wire electrode
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CN201710492001.6A
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Chinese (zh)
Inventor
胡波
胡一波
冯程
杨佳奇
诸葛兰剑
吴雪梅
王文利
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Suzhou University
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Suzhou University
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Priority to CN201710492001.6A priority Critical patent/CN107124812A/en
Publication of CN107124812A publication Critical patent/CN107124812A/en
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    • HELECTRICITY
    • H05ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
    • H05HPLASMA TECHNIQUE; PRODUCTION OF ACCELERATED ELECTRICALLY-CHARGED PARTICLES OR OF NEUTRONS; PRODUCTION OR ACCELERATION OF NEUTRAL MOLECULAR OR ATOMIC BEAMS
    • H05H1/00Generating plasma; Handling plasma
    • H05H1/24Generating plasma
    • H05H1/2406Generating plasma using dielectric barrier discharges, i.e. with a dielectric interposed between the electrodes
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M10/00Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements
    • D06M10/02Physical treatment of fibres, threads, yarns, fabrics, or fibrous goods made from such materials, e.g. ultrasonic, corona discharge, irradiation, electric currents, or magnetic fields; Physical treatment combined with treatment with chemical compounds or elements ultrasonic or sonic; Corona discharge
    • D06M10/025Corona discharge or low temperature plasma

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  • Engineering & Computer Science (AREA)
  • Physics & Mathematics (AREA)
  • Plasma & Fusion (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)

Abstract

The present invention relates to a kind of atmosphere pressure glow discharge plasma producing apparatus, including multiple quartz ampoules horizontally arranged in parallel, adjacent quartz ampoule is in close contact, inserted with wire electrode in each quartz ampoule, wire electrode is in close contact with quartz ampoule, two neighboring wire electrode respectively with high-voltage ac power, be connected, two in most edge wire electrode is connected to the ground.The invention further relates to a kind of textile material processing unit.The invention has the advantages that:Using Atomospheric pressure glow discharge pattern, the plasma of generation is more uniform, and treatment effect is better than the plasma of filament-like discharges;Double medium DBD sparking electrodes design of special construction, suppresses arc discharge effect significantly, even if being not easy to puncture under high voltages;Discharging gap is small, and thread DBD electric discharges are also not easily formed under low-voltage, the maintenance voltage produced needed for glow discharge is effectively reduced;Success produces rice magnitude homogeneous atmosphere pressure glow discharge plasma.

Description

Atmosphere pressure glow discharge plasma producing apparatus and textile material processing unit
Technical field
The present invention relates to a kind of plasma producing apparatus, more particularly to a kind of atmosphere pressure glow discharge plasma producing apparatus And textile material processing unit.
Background technology
At present, although atmospheric pressure plasma has extensive prospect in commercial Application, not on a large scale Applied to industry.Most important of which be exactly the plasma that produces under atmospheric pressure because air pressure is high, the grain being ionized Son is that collision is complex as neutral particle in a short period of time.Therefore the plasma produced by has high unstability, And it is difficult to produce the uniform plasma of large area.The application of current atmospheric pressure plasma is still within miniaturization, local In the stage of change, this can not meet the industrial extensive, process demand of high speed, high efficiency.
The mode of operation of atmospheric pressure plasma can substantially be divided into three kinds:Corona discharge, glow discharge and arc discharge. Discharge medium is all punctured by applying sufficiently high voltage on electrode and produced by these three patterns.When electrode voltage by It is smaller in radius of curvature due to point effect when edging up high(It is needle-like, thread)Electrode near electric-field intensity it is most strong, these The discharge gas in place ionizes to produce corona discharge at first.This is a kind of local, faint discharge mode.And work as voltage When continuing to raise, the region being ionized gradually increases, and finally diffuses to whole discharge space, forms glow discharge.When voltage liter It is high to a certain extent when, discharge gas is then breakdown to form strong without uniform discharge channel, and electric discharge now is that electric arc is put Electricity.Therefore, in these three patterns, only glow discharge mode can produce the uniform plasma of large area, be suitable for The processing of textile material.Therefore producing glow discharge under atmospheric pressure turns into the key of technique.
However, in the conventional technology, it is difficult to produce glow discharge in the environment of atmospheric pressure, that is, allow to produce, Strict its discharge voltage of control is wanted, otherwise electric discharge is easy to convert to damage processed material to arc discharge.With The development of plasma source technology, people are exploring the method for producing Atomospheric pressure glow discharge always.Current most efficient method It is by dielectric barrier discharge(DBD)Mode.DBD electric discharges refer to dielectric inserting discharge space, enough by applying Alternating voltage and produce a kind of nonequilibrium state gas discharge of plasma.The why unstable original of Atomospheric pressure glow discharge Because be because voltage it is sufficiently high when be easy to discharge space gas breakdown produce avalanche effect form strong discharge channel, Arc discharge is converted into so as to discharge.And when there is dielectric to insert discharge space, can effectively obstruct discharge channel Formed, suppress the generation of arc discharge.Kanazawa in 1988 et al. obtains atmosphere pressure glow discharge using helium DBD electric discharges first Discharge plasma.And summarize three conditions for producing Atomospheric pressure glow discharge:1st, driving source frequency need 1kHz with On;2nd, double medium DBD are needed;3rd, helium must be used as discharge gas.But helium is high due to use cost, also simply exist Used in laboratory.Arrive now, helium is not the necessary condition for producing Atomospheric pressure glow discharge, and high-frequency ac power drives Dynamic DBD electric discharges turn into the most effectual way for obtaining atmosphere pressure glow discharge plasma.
DBD electric discharges, which are equally utilized on electrode, to be applied sufficiently high voltage and carrys out disruptive discharge gas to produce plasma Body.Because of the effect of dielectric, the gas punctured will not form strong discharge channel, but produce many filament shapes Micro-discharge.When discharging weaker, these filaments are randomly distributed on whole discharge space, with the increasing of discharge voltage Plus, filament is more and more to form fixed pattern, referred to as spot figure with starting self-organizing.Continue to raise voltage, electric discharge becomes strong Thread discharge channel starts diffusion, ultimately forms equably glow discharge.Even DBD is put it can be seen from above-mentioned analysis Electricity wants to realize that Atomospheric pressure glow discharge condition is also very harsh.If discharge voltage is low, what is formed is thread electric discharge, If discharge voltage is too high, arc discharge still can be converted into.And due to the general non-refractory of textile material, unsuitable temperature during electric discharge Spend height.It is obvious that this 2 points requirements are contradiction, the only sufficiently high electric discharge that just can guarantee that generation of voltage is glow discharge, And it is the rise of temperature that high voltage band, which is come,.Therefore, can only in order to reduce temperature on the premise of glow discharge mode is ensured By way of reducing discharging gap.The breakdown voltage of gas can be reduced by reducing discharging gap, so as to be produced when reducing electric discharge Heat.But this brings new problem again, reduce glow discharge behind gap and be just more prone to convert to arc discharge.
Just because of these harsh requirements, although Atomospheric pressure glow discharge has good treatment effect, but does not exist yet Industrially have a wide range of applications.Existing DBD discharge technologies are used in laboratory, it is impossible to realize that the large area of technical grade is equal Even Atomospheric pressure glow discharge plasma.
The content of the invention
Instant invention overcomes the deficiencies in the prior art, there is provided a kind of atmosphere pressure glow discharge plasma weaving material simple in construction Material processing device.
To reach above-mentioned purpose, the technical solution adopted by the present invention is:A kind of atmosphere pressure glow discharge plasma producing apparatus, Including multiple quartz ampoules horizontally arranged in parallel, the adjacent quartz ampoule is in close contact, and is inserted in each quartz ampoule Entering has wire electrode, and the wire electrode and the quartz ampoule are in close contact, the two neighboring wire electrode respectively with high pressure AC power, be connected, two in the most edge wire electrode is connected to the ground.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises the quartz ampoule Length be more than the wire electrode length.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises the thread electricity Extremely copper wire.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises the quartz ampoule Internal diameter be that 1mm, external diameter are 2mm.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises the thread electricity A diameter of 1mm of pole, length are 1m.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises that the high pressure is handed over Stream power supply uses frequency to be the adjustable high frequency and high voltage power supplies of 0-30kV for 20kHz, voltage magnitude.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises also including two Insulation clamping seat, the two ends of each quartz ampoule are each passed through two insulation clamping seats.
In a preferred embodiment of the present invention, atmosphere pressure glow discharge plasma producing apparatus further comprises each described exhausted Edge deck includes setting fluted in deck body, the clamp on the deck body, the deck body, and the groove runs through The deck body.
A kind of textile material processing unit, including atmosphere pressure glow discharge plasma producing apparatus, in addition to textile material are passed Dynamic device, the textile material transmission device includes let off roll, wind-up roll and is connected between the let off roll and wind-up roll Textile material, the textile material be located at multiple quartz ampoules upper end.
In a preferred embodiment of the present invention, textile material processing unit further comprises also including two series cylinders, every group Roller includes two rollers being oppositely arranged up and down, and the direction of rotation of two rollers is opposite.
The present invention solves defect present in background technology, the invention has the advantages that:
(1)Using Atomospheric pressure glow discharge pattern, the plasma of generation is more uniform, treatment effect better than filament-like discharges etc. Gas ions;
(2)Double medium DBD sparking electrodes design of special construction, suppresses arc discharge effect significantly, even if under high voltages It is difficult to puncture, is to produce glow discharge plasma under atmospheric pressure to create condition;
(3)Discharging gap is small, and thread DBD electric discharges are also not easily formed under low-voltage, generation glow discharge is effectively reduced Required maintenance voltage, has been greatly reduced operating temperature, solves the contradiction between voltage, temperature, uniformity, gap;
(4)Success produces rice magnitude homogeneous atmosphere pressure glow discharge plasma, and plasma producing apparatus can pass through In parallel, cascade mode is optionally combined to realize bigger area, is that industrial-scale mass is applied there is provided mentality of designing;
(5)The present invention can obtain Atomospheric pressure glow discharge plasma in larger voltage range, to this kind of processing of textile The higher material of uniformity requirement is significant, and meets the demand of extensive textile processing, works well, significantly The discharge of textile industry pollution is reduced, is the new technology of a green cleaning.
Brief description of the drawings
The present invention is further described with reference to the accompanying drawings and examples.
Fig. 1 is the structural representation of the atmosphere pressure glow discharge plasma producing apparatus of the preferred embodiments of the present invention;
Fig. 2 is that the two neighboring quartz ampoule of the preferred embodiments of the present invention produces the structural representation of plasma;
Fig. 3 is the structural representation of the setting insulation clamping seat of the preferred embodiment of the present invention;
Fig. 4 is the structural representation of the textile material processing unit of the preferred embodiments of the present invention;
Fig. 5 is the electron energy distribution functions figure of the preferred embodiments of the present invention;
Fig. 6 is the shape appearance figure of the generation plasma of the preferred embodiments of the present invention.
Embodiment
Presently in connection with drawings and examples, the present invention is further detailed explanation, and these accompanying drawings are simplified signal Figure, only illustrates the basic structure of the present invention in a schematic way, therefore it only shows the composition relevant with the present invention.
As shown in figure 1, a kind of atmosphere pressure glow discharge plasma producing apparatus 1, including it is horizontally arranged in parallel multiple Quartz ampoule 2, adjacent quartz ampoule 2 is in close contact, inserted with wire electrode 4, wire electrode 4 and quartz ampoule 2 in each quartz ampoule 2 Be in close contact, the tight of quartz ampoule 2 on wire electrode 4, two neighboring wire electrode 4 respectively with high-voltage ac power 6, It is connected, two in most edge wire electrode 4 is connected to the ground, improves security.
The length of preferably quartz ampoule 2 of the invention is more than the length of wire electrode 4.Preferably wire electrode 4 of the invention is copper wire. The internal diameter of preferably quartz ampoule 2 of the invention is that 1mm, external diameter are 2mm, and a diameter of 1mm of wire electrode 4, length are 1m, certainly, stone The internal diameter of English pipe 2 and the diameter of wire electrode 4 can be adjusted accordingly, as long as meeting the tight wire electrode 4 of quartz ampoule 2, The length of quartz ampoule 2 and the length of wire electrode 4 can also be adjusted accordingly, and the external diameter of quartz ampoule 2 can also be adjusted, and be set External diameter is less than 2mm.On the one hand, quartz ampoule 2 is very thin so that apart from very little between adjacent wire electrode 4, reduces and realizes that aura is put The minimum voltage of electricity, on the other hand, tight between wire electrode 4 and quartz ampoule 2 have blocked the formation of arc discharge to lead to Road, adds the breakdown voltage of discharging gap, so that air glow plasma is generated in the gap 5 of adjacent quartz ampoule 2, As shown in Fig. 2 what the arrow in figure represented is discharging gap, outwards, discharging gap is increasing for dotted line position along in Fig. 2, Even if discharging gap becomes big, do not allow to be also easy to produce thread electric discharge yet, can be steady because discharging gap is small near dotted line position Fixed maintenance glow discharge, electric current preferentially flows through from this region, even if so the big region electric discharge of discharging gap faint is also Uniformly, filament-like discharges passage will not be formed.
Preferably high-voltage ac power 6 of the invention uses frequency to be the adjustable high-frequency and high-voltages of 0-30kV for 20kHz, voltage magnitude AC power.
As shown in figure 3, for the ease of the close contact between adjacent quartz ampoule 2, present invention additionally comprises two insulation clamping seats 8, the two ends of each quartz ampoule 2 are each passed through two insulation clamping seats 8, and the present invention preferably insulation clamping seat 8 uses polytetrafluoroethylene (PTFE) material Material is made.Each insulation clamping seat 8 includes being provided with deck body 10, the clamp 12 on deck body 10, deck body 10 recessed Groove 14, groove 14 runs through deck body 10, and the two ends of quartz ampoule 2 pass through groove 14, and clamp 12 can push down quartz ampoule 2, clamp 12 It can be fixed on by two screws 16 on deck body 10.
As shown in figure 4, a kind of textile material processing unit, including atmosphere pressure glow discharge plasma producing apparatus 1, in addition to Textile material transmission device, textile material transmission device includes let off roll 18, wind-up roll 20 and is connected to let off roll 18 and receipts Textile material 22 between winding up roller 20, textile material 22 be located at multiple quartz ampoules 2 upper end, the direction of transfer of textile material 22 with The orientation of multiple quartz ampoules 2 is parallel.Also include two series cylinders, with respect to two rollers 24, two up and down are included per series cylinder The direction of rotation of roller 24 is on the contrary, each roller 24 is by a motor(Not shown in figure)Driving, is easy to the biography of textile material 22 Send.
Containing abundant ion, high energy electron, excited state molecule isoreactivity particle and various rays in low temperature plasma, When plasma is contacted with textile material, these particles will interact with textile material surface.Due to weaving material Material typically is made up of macromolecule polyalcohol, can be by when the active particle in plasma and the interaction of textile material surface Energy transmission in plasma, when the energy of active particle is higher than the bond energy of polymer, is spun into surface polymer molecule Knitting material surface macromolecular chain can be broken, and understand " coarse " state that out-of-flatness is showed on microcosmic.The depth of interaction of this process Often there was only several microns, be very microcosmic processing, fabric this body structure will not be damaged, and can reach that conventional method is difficult With the modified effect reached, this causes textile surfaces to be activated, to be processed further providing condition.And the pass of this process Key is exactly the bond energy that active particle energy in plasma is higher than textile surfaces macromolecule polyalcohol.Common macromolecular Chemical bond energy is respectively less than 10eV and [the beautiful atmospheric pressure intermediate frequency glow discharge plasma characteristic research of Cheng Man and its changed in polymer Property textile fabric:[Master's thesis] Shanghai:Donghua University, 2008.].Because atmospheric pressure plasma electron energy is difficult to directly Measurement, and atmospheric pressure plasma is that a kind of energy is high, ion energy is close to the plasma of normal temperature, electron energy and low pressure Plasma is close, therefore we can be with electron energy distribution functions [Huang F, the Ye C, He of low pressure plasma H, et al. Effect of driving frequency on plasma property in radio frequency and very high frequency magnetron sputtering discharges[J]. Plasma Sources Science & Technology, 2014, 23(1):184-195.] as reference, Fig. 5 is specifically shown in, as can be seen from Figure 5 The highest energy of electronics can reach more than 20eV, so the active particle in plasma has enough energy to allow weaving The fracture of thing surface macromolecular, so reconnect, be grafted, the series of chemical such as copolymerization or the new functional group of introducing(This A little reactions are relevant with discharge gas species), so as to reach the effect that surface is modified.
60 × 1000mm large area glow discharge plasma can be produced by opening high-voltage ac power 6, realize rice amount The atmosphere pressure glow discharge plasma of level is significant, it was confirmed that the feasibility of industrial large-scale application.Plasma during work Pattern is as shown in fig. 6, wherein white portion is exactly plasma.Through measurement, produced plasma temperature is about during work 50 DEG C, the processing of the relatively low suitable textile material 22 of temperature, and the plasma uniformity produced is good, without the thread of part Electric discharge is formed, and will not cause topical burn to textile material 22.By taking fleece material as an example, it is only necessary to handle two minutes, you can be allowed to Surface chemistry key breaks to form micro-rough state.Test water imbibition raising about ten after result display processing after its water imbibition Times, good surface state can be provided for follow-up dyeing processing, greatly reduce the use of dyeing assistant, and after treating Material surface is without calcination point, it was demonstrated that the uniform low-temperature of plasma.
Therefore experiment shows that hydrophily, the permeability on the textile material surface after plasma treated are carried Height, and can reach good effect without the auxiliary of a large amount of auxiliary agents when dyeing.
The desirable embodiment according to the present invention is enlightenment above, by above-mentioned description, and related personnel completely can be with Without departing from the scope of the technological thought of the present invention', various changes and amendments are carried out.The technical scope of this invention It is not limited to the content on specification, it is necessary to determine the technical scope according to the scope of the claims.

Claims (10)

1. a kind of atmosphere pressure glow discharge plasma producing apparatus, it is characterised in that:Including multiple stones horizontally arranged in parallel Ying Guan, the adjacent quartz ampoule is in close contact, inserted with wire electrode in each quartz ampoule, the wire electrode and institute State quartz ampoule close contact, the two neighboring wire electrode respectively with high-voltage ac power, be connected, in most edge Two wire electrodes are connected to the ground.
2. atmosphere pressure glow discharge plasma producing apparatus according to claim 1, it is characterised in that:The length of the quartz ampoule Length of the degree more than the wire electrode.
3. atmosphere pressure glow discharge plasma producing apparatus according to claim 2, it is characterised in that:The wire electrode is Copper wire.
4. atmosphere pressure glow discharge plasma producing apparatus according to claim 3, it is characterised in that:The quartz ampoule it is interior Footpath is that 1mm, external diameter are 2mm.
5. atmosphere pressure glow discharge plasma producing apparatus according to claim 4, it is characterised in that:The wire electrode A diameter of 1mm, length are 1m.
6. atmosphere pressure glow discharge plasma producing apparatus according to claim 1, it is characterised in that:The High Level AC Voltage Source uses frequency to be the adjustable high frequency and high voltage power supplies of 0-30kV for 20kHz, voltage magnitude.
7. atmosphere pressure glow discharge plasma producing apparatus according to claim 1, it is characterised in that:Also include two insulation Deck, the two ends of each quartz ampoule are each passed through two insulation clamping seats.
8. atmosphere pressure glow discharge plasma producing apparatus according to claim 7, it is characterised in that:Each edge insulator Seat includes setting fluted in deck body, the clamp on the deck body, the deck body, and the groove is through described Deck body.
9. a kind of textile material processing unit, it is characterised in that:Including the atmospheric pressure brightness as any one of claim 1-8 Light plasma generating means, in addition to textile material transmission device, the textile material transmission device include let off roll, winding Roller and the textile material being connected between the let off roll and wind-up roll, the textile material are located at multiple quartz ampoules Upper end.
10. textile material processing unit according to claim 9, it is characterised in that:Also include two series cylinders, per series cylinder Two rollers being oppositely arranged including above and below, the direction of rotation of two rollers is opposite.
CN201710492001.6A 2017-06-26 2017-06-26 Atmosphere pressure glow discharge plasma producing apparatus and textile material processing unit Pending CN107124812A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110468580A (en) * 2019-08-30 2019-11-19 重庆中涪科瑞工业技术研究院有限公司 A kind of glow discharge plasma surface treatment method and device
CN112509907A (en) * 2020-11-30 2021-03-16 中船重工安谱(湖北)仪器有限公司 Dielectric barrier glow discharge ion source structure
CN113194592A (en) * 2021-04-16 2021-07-30 清华大学 Plasma device, device and method for quality inspection of children's toys
CN114269059A (en) * 2021-12-06 2022-04-01 北京天恒盛通科技发展有限公司 Unilateral rainbow bar type plasma generator
CN114745839A (en) * 2022-05-13 2022-07-12 大连理工大学 Surface-body coupling discharge plasma device based on seed electron generation

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110468580A (en) * 2019-08-30 2019-11-19 重庆中涪科瑞工业技术研究院有限公司 A kind of glow discharge plasma surface treatment method and device
CN110468580B (en) * 2019-08-30 2022-07-26 重庆中涪科瑞工业技术研究院有限公司 Glow discharge plasma surface treatment method and device
CN112509907A (en) * 2020-11-30 2021-03-16 中船重工安谱(湖北)仪器有限公司 Dielectric barrier glow discharge ion source structure
CN113194592A (en) * 2021-04-16 2021-07-30 清华大学 Plasma device, device and method for quality inspection of children's toys
CN114269059A (en) * 2021-12-06 2022-04-01 北京天恒盛通科技发展有限公司 Unilateral rainbow bar type plasma generator
CN114745839A (en) * 2022-05-13 2022-07-12 大连理工大学 Surface-body coupling discharge plasma device based on seed electron generation
CN114745839B (en) * 2022-05-13 2023-02-28 大连理工大学 Surface-body coupling discharge plasma device based on seed electron generation

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