CN107118626A - A kind of water-based exterior wall paint for exempting from priming paint - Google Patents

A kind of water-based exterior wall paint for exempting from priming paint Download PDF

Info

Publication number
CN107118626A
CN107118626A CN201710277463.6A CN201710277463A CN107118626A CN 107118626 A CN107118626 A CN 107118626A CN 201710277463 A CN201710277463 A CN 201710277463A CN 107118626 A CN107118626 A CN 107118626A
Authority
CN
China
Prior art keywords
parts
water
exterior wall
exempting
paint
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710277463.6A
Other languages
Chinese (zh)
Inventor
崔佳惠
赵娟
郑毅
陈向新
李青春
魏君
仝其超
刘赛
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hebei Chenyang Industry and Trade Group Co Ltd
Original Assignee
Hebei Chenyang Industry and Trade Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hebei Chenyang Industry and Trade Group Co Ltd filed Critical Hebei Chenyang Industry and Trade Group Co Ltd
Priority to CN201710277463.6A priority Critical patent/CN107118626A/en
Publication of CN107118626A publication Critical patent/CN107118626A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D125/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
    • C09D125/02Homopolymers or copolymers of hydrocarbons
    • C09D125/04Homopolymers or copolymers of styrene
    • C09D125/08Copolymers of styrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention relates to technical field of coatings, a kind of water-based exterior wall paint for exempting from priming paint is disclosed, meter includes raw material components by weight:20~30 parts of water, 0.1~0.15 part of bactericide, 0.2~0.3 part of cellulose, 0.5~0.7 part of dispersant, 0.15~0.2 part of wetting agent, 15~18 parts of antifreezing agent, 18~20 parts of coalescents, 15~18 parts of titanium dioxide, 7~8 parts of kaolin, 2~3 parts of diatomite, 2~3 parts of mica powder, 6~7 parts of coarse whiting, 35~40 parts of resin aqueous emulsion, 0.2~0.3 part of defoamer, 0.3~0.5 part of levelling agent, 0.05~0.1 part of thickener.Exterior coating of the present invention does not need brushing primer, can directly be coated on metope, while meeting the technical requirements of priming paint and finish paint, paint film effect is good, reduces the construction cost of exterior wall application, shortens the engineering time.

Description

A kind of water-based exterior wall paint for exempting from priming paint
Technical field
The present invention relates to technical field of coatings.
Background technology
Current outer surface of wall water paint is made up of supporting priming paint and finish paint more, it is necessary to which first priming is brushed again during construction Finish paint.Priming paint is directly applied to wall surface, as the basis of finish paint, therefore it is required that priming paint has excellent adhesive force, anti-corrosive properties Energy and saline-alkali tolerance, and finish paint is then required with good weatherability and necessary form and aspect and dicoration.
Prior art on exempt from priming paint wall covering study it is also less, if it is possible to develop it is a kind of exempt from priming paint it is aqueous outside Wall coating, only needs to carry out an application compared with prior art, it is clear that can save engineering time and coating cost.
The content of the invention
The technical problem to be solved in the present invention is to provide a kind of water-based exterior wall paint for exempting from priming paint, it is not necessary to brushing primer, Metope can be directly coated on, while meeting the technical requirements of priming paint and finish paint, paint film effect is good, can reduce exterior wall application Construction cost, shortens the engineering time.
In order to solve the above technical problems, the technical solution used in the present invention is:A kind of water-based exterior wall paint for exempting from priming paint, Its raw materials by weight portion meter, including following components:20~30 parts of water, 0.1~0.15 part of bactericide, 0.2~0.3 part Cellulose, 0.5~0.7 part of dispersant, 0.15~0.2 part of wetting agent, 15~18 parts of antifreezing agent, 18~20 parts into Film auxiliary agent, 15~18 parts of titanium dioxide, 7~8 parts of kaolin, 2~3 parts of diatomite, 2~3 parts of mica powder, 6~7 parts Coarse whiting, 35~40 parts of resin aqueous emulsion, 0.2~0.3 part of defoamer, 0.3~0.5 part of levelling agent, 0.05~0.1 part Thickener;
The resin aqueous emulsion is Styrene And Chloroalkyl Acrylates copolymer emulsion.
It is preferred that, the solid content of the resin aqueous emulsion is 54%~56%, and MFT is not higher than 0 DEG C.
Preferably, the water is deionized water, the wetting agent is polyoxyethylated alkyl phenol, polyoxyethylene fatty alcohol Any one in ether, polyoxyethylene polyoxypropylene block copolymer, the thickener is that alkali soluble rises class thickener, polyacrylic acid One kind in type thickener, the cellulose is hydroxyethyl cellulose, and the dispersant is ammonium polyacrylate salt dispersant, The defoamer is mineral oil defoaming agent, and the levelling agent is polyurethanes levelling agent, and the titanium dioxide is rutile type titanium White powder.
Present invention also offers a kind of preparation method for the water-based exterior wall paint for exempting from priming paint as previously described, including following step Suddenly:
1)Matched according to the raw material components, under stirring, successively by bactericide, cellulose, dispersant, wetting agent, antifreeze Agent, coalescents are added to the water, and are well mixed;
2)Again to step 1)Titanium dioxide, kaolin, diatomite, mica powder, coarse whiting are sequentially added in gained compound, mixing is equal It is even, make gained feed liquid Xi Du≤55um;
3)The resin aqueous emulsion, defoamer are added into step 2 successively)In gained feed liquid, it is well mixed, mill base is made;
4)To step 3)Levelling agent is added in gained mill base, is well mixed, thickener is added, regulation viscosity is made to qualified The described water-based exterior wall paint for exempting from priming paint.
It is using the beneficial effect produced by above-mentioned technical proposal:The water-based exterior wall paint that the present invention exempts from priming paint can not With brushing primer, metope is directly coated on, coating adhesion is strong after drying, both the sealing effect with priming paint, it is such as alkaline-resisting, resistance to Water, saline-alkali tolerance, while also possess the weatherability of finish paint, dicoration, can be significantly cost-effective, simplify construction procedure, shorten Engineering time.
Embodiment
Illustrate below and the present invention is described in further detail.
Embodiment 1
A kind of water-based exterior wall paint for exempting from priming paint, its raw materials by weight portion meter is made up of following components mixing:28 parts of water, 0.17 part of bactericide, 0.2 part of cellulose, 0.6 part of dispersant, 0.20 part of wetting agent, 18 parts of antifreezing agent, 20 parts Coalescents, 18 parts of titanium dioxide, 7 parts of kaolin, 3 parts of diatomite, 3 parts of mica powder, 7 parts of coarse whiting, 35 parts of water Property resin emulsion, 0.3 part of defoamer, 0.45 part of levelling agent, 0.05 part of thickener.
The water-based exterior wall paint that the present embodiment exempts from priming paint is prepared by following preparation method:
(1)Raw material components are weighed according to above-mentioned proportioning, deionized water is added in retort, are stirred with 150rpm speed, Bactericide, cellulose, dispersant, wetting agent, antifreezing agent are sequentially added, coalescents are slow added into, afterwards with 150rpm's Speed stirs 5min;
(2)Continue to be slowly added to titanium dioxide, kaolin, diatomite, mica powder, coarse whiting successively into retort A, 1200rpm's Speed stirs 30min to uniform, then with Hegman grind gage, and it is that 55um is qualified to scrape fineness, fineness requirement Wei≤55um;
(3)Resin aqueous emulsion, defoamer are added in retort A successively, 10 minutes are stirred extremely with 700rpm rate of dispersion Mill base is uniform;
(4)Levelling agent is slowly added in retort, is stirred 5 minutes with 900rpm speed, initial viscosity is surveyed, according to initial viscous Degree, adds thickener and is thickened, and to 25 DEG C, stormer viscosity meter 100KU, the water-based exterior wall paint for exempting from priming paint is made.
Resin aqueous emulsion used is styrene-ethylene copolymerization breast in the present embodiment, and solid content is 54~56%, such as Poly Good 818.
Wetting agent used is the alkyl polyoxyethylene ether wetting agent LCN407 of Clariant.
Dispersant used is the peaceful polyacrylic acid ammonia salt dispersant 963 of section.
Defoamer used is the A10 of BASF.
Titanium dioxide used is the rutile titanium white powder that chloridising is produced, the LR996 of such as imperial boa.
Kaolin used is the calcined kaolin DB80 of the golden space in Shanxi, and diatomite used is Celite 499, used Mica powder is the auspicious GA-4 of lattice, and powdered whiting used is the powdered whiting CC-700 of wide good fortune.
Thickener used is that alkali soluble rises class thickener.
Levelling agent used is the 2025 of no-solvent polyurethane class levelling agent, such as France Gao Tai.
Coalescents used are selected from the TEXANOL ester alcohols of the graceful extraordinary Chemical Co., Ltd. of neat Tracie Ruiz-Conforto.
Antifreezing agent used is the ethylene glycol of Zhong Hui Chemical Co., Ltd.s;
Bactericide used is Tao Shi RS.
Embodiment 2
A kind of water-based exterior wall paint for exempting from priming paint, its raw materials by weight portion meter is made up of following components mixing:25 parts of water, 0.15 part of bactericide, 0.3 part of cellulose, 0.7 part of dispersant, 0.2 part of wetting agent, 18 parts of antifreezing agent, 20 parts Coalescents, 18 parts of titanium dioxide, 8 parts of kaolin, 3 parts of diatomite, 3 parts of mica powder, 7 parts of coarse whiting, 40 parts of water Property resin emulsion, 0.3 part of defoamer, 0.5 part of levelling agent, 0.1 part of thickener.
Resin aqueous emulsion used is styrene-ethylene copolymerization breast in the present embodiment, and solid content is 54~56%, such as Poly Good 818.
Wetting agent used is polyoxyethylated alkyl phenol wetting agent.
Dispersant used is the peaceful polyacrylic acid ammonia salt dispersant 963 of section.
Defoamer used is the A10 of BASF.
Titanium dioxide used is the rutile titanium white powder that chloridising is produced, the LR996 of such as imperial boa.
Kaolin used is the calcined kaolin DB80 of the golden space in Shanxi, and diatomite used is Celite 499, used Mica powder is the auspicious GA-4 of lattice, and powdered whiting used is the powdered whiting CC-700 of wide good fortune.
Thickener used is polyacrylate-type thickeners.
Levelling agent used is the 2025 of no-solvent polyurethane class levelling agent, such as France Gao Tai.
Coalescents used are selected from the TEXANOL ester alcohols of the graceful extraordinary Chemical Co., Ltd. of neat Tracie Ruiz-Conforto.
Antifreezing agent used is the ethylene glycol of Zhong Hui Chemical Co., Ltd.s;
Bactericide used is Tao Shi RS.
The present embodiment exempts from the water-based exterior wall paint preparation method be the same as Example 1 of priming paint.
Embodiment 3
A kind of water-based exterior wall paint for exempting from priming paint, its raw materials by weight portion meter is made up of following components mixing:20 parts of water, 0.1 part of bactericide, 0.2 part of cellulose, 0.5 part of dispersant, 0.15 part of wetting agent, 15 parts of antifreezing agent, 18 parts Coalescents, 15 parts of titanium dioxide, 7 parts of kaolin, 2 parts of diatomite, 2 parts of mica powder, 6 parts of coarse whiting, 35 parts of water Property resin emulsion, 0.2 part of defoamer, 0.3 part of levelling agent, 0.05 part of thickener.
Resin aqueous emulsion used is styrene-ethylene copolymerization breast in the present embodiment, and solid content is 54~56%, such as Poly Good 818.
Wetting agent used is polyoxyethylene polyoxypropylene block copolymer.
Dispersant used is the peaceful polyacrylic acid ammonia salt dispersant 963 of section.
Defoamer used is the A10 of BASF.
Titanium dioxide used is the rutile titanium white powder that chloridising is produced, the LR996 of such as imperial boa.
Kaolin used is the calcined kaolin DB80 of the golden space in Shanxi, and diatomite used is Celite 499, used Mica powder is the auspicious GA-4 of lattice, and powdered whiting used is the powdered whiting CC-700 of wide good fortune.
Thickener used is polyacrylate-type thickeners.
Levelling agent used is the 2025 of no-solvent polyurethane class levelling agent, such as France Gao Tai.
Coalescents used are selected from the TEXANOL ester alcohols of the graceful extraordinary Chemical Co., Ltd. of neat Tracie Ruiz-Conforto.
Antifreezing agent used is the ethylene glycol of Zhong Hui Chemical Co., Ltd.s;
Bactericide used is Tao Shi RS.
The present embodiment exempts from the water-based exterior wall paint preparation method be the same as Example 1 of priming paint.
The obtained water-based exterior wall paints for exempting from priming paint of 1-3 of the embodiment of the present invention are detected, it is as a result as shown in the table.
As seen from the above table, water-based exterior wall paint of the embodiment of the present invention meets the basic property of conventional exterior coating, can be without Brushing primer, is directly coated on metope, and coating adhesion is strong after drying, and has the technique effect of priming paint and finish paint paint film concurrently, constructs Simply, saving of labor, material-saving, resistance to rainprint, stain resistant effect are good.
The present invention is described in detail above, embodiments of the present invention carried out using specific case in the present invention Illustrate, the explanation of above example is only intended to help and understands the present invention, it is noted that for the technology people of the art For member, under the premise without departing from the principles of the invention, some improvement can be also carried out to the present invention, these improvement also fall into this hair In bright scope of the claims.

Claims (10)

1. a kind of water-based exterior wall paint for exempting from priming paint, it is characterised in that:Its raw materials by weight portion meter, including following components: 20 ~30 parts of water, 0.1~0.15 part of bactericide, 0.2~0.3 part of cellulose, 0.5~0.7 part of dispersant, 0.15~ 0.2 part of wetting agent, 15~18 parts of antifreezing agent, 18~20 parts of coalescents, 15~18 parts of titanium dioxide, 7~8 parts of height Ridge soil, 2~3 parts of diatomite, 2~3 parts of mica powder, 6~7 parts of coarse whiting, 35~40 parts of resin aqueous emulsion, 0.2~ 0.3 part of defoamer, 0.3~0.5 part of levelling agent, 0.05~0.1 part of thickener;
The resin aqueous emulsion is Styrene And Chloroalkyl Acrylates copolymer emulsion.
2. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the resin aqueous emulsion is consolidated Content is 54%~56%, and MFT is not higher than 0 DEG C.
3. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the water is deionized water.
4. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the wetting agent is polyoxyethylene Any one in alkyl phenol ether, polyoxyethylene aliphatic alcohol ether, polyoxyethylene polyoxypropylene block copolymer.
5. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the thickener is that alkali soluble rises class One kind in thickener, polyacrylate-type thickeners.
6. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the cellulose is that ethoxy is fine Dimension element.
7. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the dispersant is polyacrylic acid Ammonium salt class dispersant.
8. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the defoamer is mineral oils Defoamer, the levelling agent is polyurethanes levelling agent.
9. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that the titanium dioxide is rutile-type Titanium dioxide.
10. the water-based exterior wall paint according to claim 1 for exempting from priming paint, it is characterised in that be by following preparation method system It is standby to obtain:
1)Matched according to the raw material components, under stirring, successively by bactericide, cellulose, dispersant, wetting agent, antifreeze Agent, coalescents are added to the water, and are well mixed;
2)Again to step 1)Titanium dioxide, kaolin, diatomite, mica powder, coarse whiting are sequentially added in gained compound, mixing is equal It is even, make gained feed liquid Xi Du≤55um;
3)The resin aqueous emulsion, defoamer are added into step 2 successively)In gained feed liquid, it is well mixed, mill base is made;
4)To step 3)Levelling agent is added in gained mill base, is well mixed, thickener is added, regulation viscosity is made to qualified The described water-based exterior wall paint for exempting from priming paint.
CN201710277463.6A 2017-04-25 2017-04-25 A kind of water-based exterior wall paint for exempting from priming paint Pending CN107118626A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710277463.6A CN107118626A (en) 2017-04-25 2017-04-25 A kind of water-based exterior wall paint for exempting from priming paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201710277463.6A CN107118626A (en) 2017-04-25 2017-04-25 A kind of water-based exterior wall paint for exempting from priming paint

Publications (1)

Publication Number Publication Date
CN107118626A true CN107118626A (en) 2017-09-01

Family

ID=59725506

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201710277463.6A Pending CN107118626A (en) 2017-04-25 2017-04-25 A kind of water-based exterior wall paint for exempting from priming paint

Country Status (1)

Country Link
CN (1) CN107118626A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903725A (en) * 2017-10-31 2018-04-13 河北晨阳工贸集团有限公司 Non-through constitution sense finish and its preparation method and application
CN109517456A (en) * 2018-11-09 2019-03-26 沪宝新材料科技(上海)股份有限公司 A kind of epoxy-modified acrylic acid bottom surface unification exterior wall latex paint and preparation method thereof
CN112898833A (en) * 2021-01-25 2021-06-04 三棵树(上海)新材料研究有限公司 High-performance primer-topcoat exterior wall coating for renovating old wall and preparation method thereof
CN116239916A (en) * 2022-09-05 2023-06-09 龙牌涂料(北京)有限公司 Ultraviolet-absorbing indoor coating and preparation method thereof
CN116355464A (en) * 2023-02-22 2023-06-30 卡本科技集团股份有限公司 Self-cleaning texture paint free of primer and finish coat and preparation method thereof

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102329545A (en) * 2011-10-17 2012-01-25 青岛爱尔家佳新材料有限公司 Waterborne external thermal insulation coating and preparation method thereof
CN102443324A (en) * 2010-10-07 2012-05-09 艾永平 Interior and exterior wall paint and production method thereof
CN106118293A (en) * 2016-07-01 2016-11-16 上海展辰涂料有限公司 A kind of door and window is with exempting from priming paint aqueous finish paint

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102443324A (en) * 2010-10-07 2012-05-09 艾永平 Interior and exterior wall paint and production method thereof
CN102329545A (en) * 2011-10-17 2012-01-25 青岛爱尔家佳新材料有限公司 Waterborne external thermal insulation coating and preparation method thereof
CN106118293A (en) * 2016-07-01 2016-11-16 上海展辰涂料有限公司 A kind of door and window is with exempting from priming paint aqueous finish paint

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107903725A (en) * 2017-10-31 2018-04-13 河北晨阳工贸集团有限公司 Non-through constitution sense finish and its preparation method and application
CN109517456A (en) * 2018-11-09 2019-03-26 沪宝新材料科技(上海)股份有限公司 A kind of epoxy-modified acrylic acid bottom surface unification exterior wall latex paint and preparation method thereof
CN112898833A (en) * 2021-01-25 2021-06-04 三棵树(上海)新材料研究有限公司 High-performance primer-topcoat exterior wall coating for renovating old wall and preparation method thereof
CN116239916A (en) * 2022-09-05 2023-06-09 龙牌涂料(北京)有限公司 Ultraviolet-absorbing indoor coating and preparation method thereof
CN116355464A (en) * 2023-02-22 2023-06-30 卡本科技集团股份有限公司 Self-cleaning texture paint free of primer and finish coat and preparation method thereof

Similar Documents

Publication Publication Date Title
CN107118626A (en) A kind of water-based exterior wall paint for exempting from priming paint
US10093821B2 (en) Aqueous coating composition and process of making the same
CN107001844B (en) Water-based paint compositions and its obtained method
EP3234047B1 (en) Aqueous coating composition and process thereof
US9796860B2 (en) Storage-stable urea preparations which are suitable as rheology control agents
CN103409002A (en) Environment-friendly anticorrosive acrylic acid water-based coating and preparation method thereof
CN110229573A (en) A kind of aqueous rusty anti-corrosive primer and preparation method thereof
CN104877526A (en) Paint containing water-based acrylic modified epoxy phosphate resin and preparation method thereof
CN105419603A (en) Easy-to-polish water-based woodware double-component white primer and preparation method thereof
WO2014201674A1 (en) An aqueous coating composition
CN107216761A (en) The preparation method of the water soluble acrylic resin of high solid
CN103602193A (en) Priming paint for water-borne heavy anti-corrosion coating and preparation method thereof
CN102643586A (en) High-solid-content quick-drying water-based white primer and preparation method thereof
CN110669422A (en) Double-component exterior wall coating and preparation method thereof
CN109337474A (en) A kind of woodenware sealing wax and preparation method thereof
CN110305564A (en) Two coating water-based anticorrosive paints of one kind and application
CN113840858B (en) Rheology control additives containing cyclic amides
CN109575776A (en) The aqueous clear highly resistance of height scrapes the clear face mian paint of five light splitting and preparation method and bi-component clear finish
CN113831792A (en) Water-based paint composition and preparation method thereof
CN113372768B (en) Bottom-surface-in-one water paint for container and preparation method thereof
CN107267003A (en) Vehicle bridge coating of waterborne organic silicon modified acroleic acid bottom surface unification and preparation method thereof
KR20130066925A (en) Thickener for aqueous paint and aqueous paint composition containing the same
CN104559601A (en) Metallic water-based paint
CN105131763A (en) Water paint for wood furniture and preparation method thereof
CN107903725A (en) Non-through constitution sense finish and its preparation method and application

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20170901