CN107117984A - A kind of low-cost high-toughness wear resistance lining, preparation method and gas-solid separation equipment - Google Patents

A kind of low-cost high-toughness wear resistance lining, preparation method and gas-solid separation equipment Download PDF

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Publication number
CN107117984A
CN107117984A CN201710495336.3A CN201710495336A CN107117984A CN 107117984 A CN107117984 A CN 107117984A CN 201710495336 A CN201710495336 A CN 201710495336A CN 107117984 A CN107117984 A CN 107117984A
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Prior art keywords
gas
wear resistance
parts
resistance lining
solid
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Inventor
张晨曦
魏飞
骞伟中
付晓添
钱成伟
魏广权
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Liaoning Gem Chemical Equipment Co Ltd
Tsinghua University
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Liaoning Gem Chemical Equipment Co Ltd
Tsinghua University
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Priority to CN201710495336.3A priority Critical patent/CN107117984A/en
Publication of CN107117984A publication Critical patent/CN107117984A/en
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Abstract

The invention provides a kind of low-cost high-toughness wear resistance lining, preparation method and gas-solid separation equipment, the raw material of the wear resistance lining includes the material of following parts by weight:2~5 parts of 65~75 parts of aggregate, 20~32 parts of flyash, 2~5 parts of binding agent and additive.The wear resistance lining that this programme is provided is using the inexpensive raw material of industry and with high tenacity, it is easy to anchor in the cyclone body of gas-solid separation equipment and thermal shock resistance is good.

Description

A kind of low-cost high-toughness wear resistance lining, preparation method and gas-solid separation equipment
Technical field
The present invention relates to chemical technology field, more particularly to a kind of low-cost high-toughness wear resistance lining, preparation method and gas Gu separation equipment.
Background technology
Gas-solid separation equipment is a kind of utilization centrifugal force by setting that solid particle is separated from the current-carrying medium of gas phase It is standby, such as cyclone single tube and cyclone separator.In separation process, solid particle can be with gas-solid separation equipment due to centrifugal force Cyclone body inwall collides, in order to avoid the damage of cyclone body, typically in cyclone body Inwall on anchoring have wear resistance lining, to be protected to cyclone body.
Make wear resistance lining when, generally using white fused alumina as wear resistance lining powder, due to white fused alumina density compared with Greatly (>3900kg/m3), make the wear resistance lining weight being made larger, be difficult to be anchored with cyclone body.
The content of the invention
The embodiments of the invention provide a kind of low-cost high-toughness wear resistance lining, preparation method and gas-solid separation equipment, make Wear resistance lining is easy to anchoring with cyclone body.
In a first aspect, the embodiments of the invention provide a kind of low-cost high-toughness wear resistance lining, its raw material includes following weight Measure the material of part:
2~5 parts of 65~75 parts of aggregate, 20~32 parts of flyash, 2~5 parts of binding agent and additive.
Preferably,
The aggregate includes:White fused alumina and any one in ceramics or two kinds.
Preferably,
When the aggregate includes described ceramic,
The ceramic particle diameter is:100~300 μm.
Preferably,
When the aggregate includes the white fused alumina,
The particle diameter of the white fused alumina is 100~300 μm.
Preferably,
The particle diameter of the flyash is 0.5~100 μm.
Preferably,
The binding agent includes:Any one in aluminate cement and portland cement or two kinds;
Preferably,
The additive includes:It is any in one-dimensional carbon fiber, one dimension fibre shape carborundum and one dimension fibre shape silicon nitride It is one or more.
Second aspect, the embodiments of the invention provide the low-cost high-toughness provided in a kind of any of the above-described embodiment is wear-resisting The preparation method of lining, including:
The material of following parts by weight is weighed respectively:
2~5 parts of 65~75 parts of aggregate, 20~32 parts of flyash, 2~5 parts of binding agent and additive;
The aggregate weighed, the flyash, the binding agent and the additive are mixed with water, form solid Liquid mixture;
The solidliquid mixture is put into mould, and controls the solidliquid mixture to be uniformly distributed in institute by mode of vibration State mould;
After solidliquid mixture progress natural curing, it is stripped;
The water in the solidliquid mixture after the demoulding is removed by drying mode, the wear resistance lining is formed.
Preferably,
It is described to weigh 65~75 parts of the aggregate, including:
Weigh 32.5~37.5 parts of 32.5~37.5 parts of white fused alumina and ceramics.
The third aspect, the embodiments of the invention provide a kind of gas-solid separation equipment, including:Cyclone body, necking The low-cost high-toughness wear resistance lining that device and any of the above-described embodiment of the invention are provided;Wherein,
The wear resistance lining is anchored on the inwall of the cyclone body;
The reducing device is connected with the first end of the cyclone body;
The reducing device, for receiving gas-solid material to be separated, and by gas-solid material to be separated by the whirlwind The first end of separator main body is delivered in the cyclone body;
The cyclone body, for driving gas-solid material to be separated to produce eddy flow, is made by centrifugal action Solid particle in the gas-solid material to be separated is got rid of to side wall, collided with the wear resistance lining, and from bottom Dipleg is discharged, and the gas in the gas-solid material to be separated is discharged from the riser on top.
Preferably,
The gas-solid separation equipment is applied to cyclone separator;
The first end of the reducing device is connected with external fluidized bed reactor, the second end of the reducing device with it is described The first end of cyclone body is connected;
In the reducing device, the gas-solid material to be separated for filtering out the external fluidized bed reactor output Part I solid particle, and remaining gas-solid material to be separated after filtering out the Part I solid particle is tangentially entered Enter the cyclone body.
Preferably,
The gas-solid separation equipment is applied to tornadotron;
The cyclone body includes:Tornadotron main body;
The first end of the tornadotron main body is provided with guide vane;
The reducing device, for making gas-solid material to be separated axially into the first of the cyclone body End;
The guide vane, for being rotated under outside dynamic action, is treated with the gas-solid that driving axial enters Separation of material produces eddy flow.
The embodiments of the invention provide a kind of wear resistance lining, preparation method and gas-solid separation equipment, from flyash conduct The powder of wear resistance lining, because the density of flyash is only 0.2~0.3kg/m3, much smaller than white fused alumina density (>3900kg/ m3) so that when raw material weight than it is close when, the weight of the wear resistance lining being made reduces, so that wear resistance lining and gas-solid point Cyclone body from equipment is easy to anchoring.
Brief description of the drawings
In order to illustrate more clearly about the embodiment of the present invention or technical scheme of the prior art, below will be to embodiment or existing There is the accompanying drawing used required in technology description to be briefly described, it should be apparent that, drawings in the following description are the present invention Some embodiments, for those of ordinary skill in the art, on the premise of not paying creative work, can also basis These accompanying drawings obtain other accompanying drawings.
Fig. 1 is a kind of flow chart for low-cost high-toughness wear resistance lining preparation method that one embodiment of the invention is provided;
Fig. 2 is a kind of structural representation for gas-solid separation equipment that one embodiment of the invention is provided;
Fig. 3 is a kind of structural representation for gas-solid separation equipment that another embodiment of the present invention is provided;
Fig. 4 is a kind of structural representation for gas-solid separation equipment that another embodiment of the invention is provided.
Embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention In accompanying drawing, the technical scheme in the embodiment of the present invention is clearly and completely described, it is clear that described embodiment is A part of embodiment of the present invention, rather than whole embodiments, based on the embodiment in the present invention, those of ordinary skill in the art The every other embodiment obtained on the premise of creative work is not made, belongs to the scope of protection of the invention.
The embodiments of the invention provide a kind of low-cost high-toughness wear resistance lining, its raw material includes the thing of following parts by weight Matter:
2~5 parts of 65~75 parts of aggregate, 20~32 parts of flyash, 2~5 parts of binding agent and additive.
The above embodiment of the present invention provides a kind of wear resistance lining, from powder of the flyash as wear resistance lining, due to The density of flyash is only 0.2~0.3kg/m3, much smaller than white fused alumina density (>3900kg/m3) so that when the weight of raw material Than it is close when, the weight of the wear resistance lining being made reduces and toughness strengthens, so that wear resistance lining is easy with cyclone body In anchoring.
Specifically, in one embodiment of the invention, the aggregate includes:Any one in white fused alumina and ceramics or two Plant, preferably the mixture of white fused alumina and ceramics.
Because the density of ceramics is 2380kg/m3Left and right, compared with white fused alumina density (>3900kg/m3) small, therefore from pottery Porcelain can further reduce the weight of wear resistance lining as the aggregate of wear resistance lining, so that wear resistance lining and cyclone separator master Body is easier to anchoring.
In addition, waste ceramic is as a kind of solid waste in Ceramic production, because it have passed through high-temperature firing, firmly Degree is high, it is impossible to reuses, can not also digest naturally as ceramic raw material, can only carry out landfill disposal as industrial refuse. And the main raw material(s) for producing ceramics is the non-renewable resources such as natural earth, ore deposit, directly landfill waste ceramic is very big to resource Waste, and environment can be damaged.Therefore, waste ceramic is realized into discarded object recycling as the aggregate of wear resistance lining, The cost of wear resistance lining has not only been saved, environmental protection is also helped.
Specifically, in one embodiment of the invention, from waste ceramic as wear resistance lining aggregate when, selection it is ceramic Particle diameter is:100~300 μm, the particle diameter for the white fused alumina that aggregate includes also is 100~300 μm.This causes ceramics and white fused alumina tool There are good skeleton and supporting role.
In addition, the particle diameter of flyash is 0.5~100 μm so that flyash has good filling effect.In practical application When, flyash as thermal power plant discarded object, be it is a kind of by differing in size, the high dispersive that particle in irregular shape is constituted Aggregate, its particle diameter is general at 0.5~300 μm., can be by while save production cost in order that discarded object is well utilized Flyash in the μ m of particle diameter 0.5~300 as the raw material of wear resistance lining, wherein, in the μ m of particle diameter 100~300 The actual skeleton for serving as aggregate of flyash and the flyash being made in effect, the μ m of particle diameter 0.5~100 have the filling of powder Effect.In order to ensure filling effect that powder is good, so that it is guaranteed that the intensity of wear resistance lining, by the powder in 0.5~300 μ m Coal ash as wear resistance lining raw material when, need to ensure that the fly ash content in the μ m of particle diameter 0.5~100 accounts for flyash total content More than 50%.
In one embodiment of the invention, binding agent selects aluminate cement.Due to containing three more oxidations in flyash Two aluminium, it can be reacted with the calcium oxide in aluminate cement and a calcium aluminate in middle thermophase, and a calcium aluminate is generated respectively And Calcium dialuminate, 20% and 13% volumetric expansion can be produced respectively in course of reaction, made so as to avoid in wear resistance lining During, because of the contraction that hydrated product is dehydrated and produces, and then improve the intensity of wear resistance lining.In addition, bonding agent is also optional With portland cement or the mixture of aluminate cement and portland cement.
In order to improve in the heat-conducting effect of wear resistance lining, one embodiment of the invention, the additive includes:One-dimensional carbon is fine Any one or more in dimension, one dimension fibre shape carborundum and one dimension fibre shape silicon nitride.
Because the toughness of fine and close ceramic-like lining is poor, cause heat resistanceheat resistant poor-performing of the lining during driving and parking. Therefore in the present embodiment, one-dimensional carbon fiber, one dimension fibre shape carborundum and one dimension fibre shape are increased in wear resistance lining raw material The one dimension fibre shape material such as silicon nitride does additive, can further enhance the toughness of wear resistance lining, so as to improve wear resistance lining Thermal shock resistance.Simultaneously as these materials have good thermal conductivity, therefore thermal stress suffered by wear resistance lining can be made evenly, So as to improve the heat-conducting effect of wear resistance lining.
As shown in figure 1, the embodiments of the invention provide the low-cost high-toughness provided in a kind of any of the above-described embodiment is resistance to Preparation method in mill lining, this method may comprise steps of:
Step 101, the material of following parts by weight is weighed respectively:65~75 parts of aggregate, 20~32 parts of flyash, binding agent 2 ~5 parts and 2~5 parts of additive;
Step 102, the aggregate weighed, the flyash, the binding agent and the additive and water are mixed Close, form solidliquid mixture;
Step 103, the solidliquid mixture is put into mould, and controls the solidliquid mixture uniform by mode of vibration It is distributed in the mould;
Step 104, by after solidliquid mixture progress natural curing, it is stripped;
Step 105, the water in the solidliquid mixture after the demoulding is removed by drying mode, the wear-resisting lining is formed In.
In above-described embodiment, from raw material of the flyash as wear resistance lining, wear resistance lining is prepared, it is close due to flyash Degree is only 0.2~0.3kg/m3, much smaller than white fused alumina density (>3900kg/m3) so that when raw material weight than it is close when, system Into wear resistance lining weight reduce so that the cyclone body of wear resistance lining and separation equipment be easy to anchoring.
Specifically, in one embodiment of the invention, the embodiment of step 101 can include:
Weigh 32.5~37.5 parts of 32.5~37.5 parts of white fused alumina and ceramics.
Herein, it is 1 by the ratio setting of white fused alumina and ceramics:1, good skeleton and supporting role can be made it have. In actual use, the ratio of white fused alumina and ceramics can be adjusted according to actual needs, wherein, the content of white fused alumina accounts for white firm The beautiful total content 0~100% with the mixture of ceramics composition.
Specific embodiment 1:Weigh 35 parts of white fused alumina, 35 parts of ceramics, 20 parts of flyash, 5 parts of aluminous cement and carbon fiber 5 Part, the white fused alumina weighed, ceramics, flyash, aluminous cement and carbon fiber are mixed with water, solidliquid mixture is formed, Solidliquid mixture is put into mould, and vibration moulding is 160mm × 40mm × 40mm sample, and 48h is conserved under ambient temperature and moisture, 24h is dried at 110 DEG C after the demoulding, to remove the water in solidliquid mixture, wear resistance lining is formed.
Specific embodiment 2:3 parts of 70 parts of ceramics, 25 parts of flyash, 2 parts of portland cement and carbon fiber are weighed, by what is weighed Ceramics, flyash, aluminous cement and carbon fiber are mixed with water, form solidliquid mixture, solidliquid mixture is put into mould Tool, and vibration moulding is 160mm × 40mm × 40mm sample, and 48h is conserved under ambient temperature and moisture, in 110 DEG C of drying after the demoulding 24h, to remove the water in solidliquid mixture, forms wear resistance lining.
Specific embodiment 3:Weigh 32 parts of white fused alumina, 33 parts of ceramics, 30 parts of flyash, 2 parts of aluminous cement and carbon fiber 3 Part, the white fused alumina weighed, ceramics, flyash, aluminous cement and carbon fiber are mixed with water, solidliquid mixture is formed, Solidliquid mixture is put into mould, and vibration moulding is 160mm × 40mm × 40mm sample, and 48h is conserved under ambient temperature and moisture, 24h is dried at 110 DEG C after the demoulding, to remove the water in solidliquid mixture, wear resistance lining is formed.
Further, by the wear resistance lining being prepared from using the method provided in above-mentioned 3 specific embodiments at 815 DEG C After calcining 3 hours, materialization test is carried out, including bulk density, cold crushing strength, strength at normal temperature, heating permanent line become Rate and normal temperature abrasion resistance, the data drawn are as shown in table 1, where it can be seen that utilizing the method that 3 specific embodiments are provided The wear resistance lining being prepared from, is respectively provided with higher intensity, and rate of change is small after heating, while having good anti-wear performance.
Table 1
Wear resistance lining can be used in gas-solid separation equipment, as shown in Fig. 2 being set the embodiments of the invention provide one kind separation It is standby, including:The low-cost high-toughness that cyclone body 201, reducing device 202 and any of the above-described embodiment of the invention are provided Wear resistance lining 203;Wherein,
The wear resistance lining 203 is anchored on the inwall of the cyclone body 201;
The reducing device 202 is connected with the first end of the cyclone body 201;
The reducing device 202, for receiving gas-solid material to be separated, and by gas-solid material to be separated by the rotation The first end of wind separator main body 201 is delivered in the cyclone body 201;
The cyclone body 201, for controlling gas-solid material to be separated to produce eddy flow, passes through centrifugal action So that the solid particle in the gas-solid material to be separated is got rid of to side wall, collided with the wear resistance lining 203, and the bottom of from Gas in the dipleg discharge at end, the gas-solid material to be separated is discharged from the riser on top.
In above-described embodiment, on the inwall that wear resistance lining is anchored to the cyclone body of gas-solid separation equipment, when When gas-solid material to be separated carries out helical rotation in cyclone body, solid particle in gas-solid material to be separated due to Centrifugal force is got rid of to side wall, is collided with wear resistance lining, then along wear resistance lining from the dipleg of cyclone body bottom Discharge, while the gas in gas-solid material to be separated is discharged from the riser on cyclone body top, realizes gas-solid and treats The separation of solid and gas in separation of material.Because the powder of wear resistance lining selects flyash, the density of flyash is smaller, makes resistance to Weight in mill lining is smaller and toughness is higher, so that wear resistance lining is easy to be anchored on the inwall of cyclone body.Together When, wear resistance lining is anchored on cyclone body inwall, cyclone body is played a protective role, gas can be improved Gu the service life of separation equipment.
Specifically, when separation equipment be high-temperature systems (>1000 DEG C) when, can be in cyclone body inwall and wear-resisting lining In between increase by one layer of heat-barrier material, it is to avoid the temperature of cyclone body outer wall is too high.Heat-barrier material also can select fine coal Ash, because flyash particle diameter is smaller, and particle is in hollow spheres, makes its effect of heat insulation preferable.Flyash is a kind of solid simultaneously Body discarded object, cost is relatively low, utilizes it as heat-barrier material, has ensured good effect of heat insulation cost-effective while.
When separation equipment is middle cryogenic system, wear resistance lining can be directly anchored in the inwall of cyclone body On, and metal hexsteel can be increased in wear resistance lining, to further enhance the anchoring of wear resistance lining and cyclone body Fastness, so that wear resistance lining is difficult to come off from cyclone body inwall, and then increases the service life of wear resistance lining.
In order to further improve in the separative efficiency of separation equipment, one embodiment of the invention, when gas-solid material to be separated It is tangential when entering cyclone body, such as in cyclone separator, the first end of the reducing device 202 with it is external fluidized Bed reactor is connected, and the second end of the reducing device 202 is connected with the first end of the cyclone body 201;
The reducing device 202, the gas-solid material to be separated for filtering out the external fluidized bed reactor output In Part I solid particle, and cut remaining gas-solid material to be separated after filtering out the Part I solid particle To the entrance cyclone body 201.
In above-described embodiment, the two ends of the reducing device of gas-solid separation equipment are connected to fluidized-bed reactor and whirlwind respectively Separator main body, reducing device can filter out a part of solid particle in the gas-solid material to be separated of fluidized-bed reactor output, So as to reduce the concentration that the solid particle into the material to be separated of cyclone body is transmitted by reducing device, whirlwind point From device main body when carrying out gas solid separation for the relatively low material to be separated of concentration, gas-solid disngaging efficiency is higher, so as to improve The separative efficiency of separation equipment.
Specifically, in order to realize filtered out by reducing device in the gas-solid material to be separated that fluidized-bed reactor is exported the A part of solid particle, while ensure reducing device when filtering out Part I solid particle, larger pressure drop will not be produced and So that solid particle enters cyclone body with fast state, as shown in figure 3, in one embodiment of the invention, the contracting The first pod apertures 301 and the second pod apertures 302 are provided with mouth device 202;Wherein,
First pod apertures 301 and second pod apertures 302 are frustum structure, first pod apertures 301 Butt end mouthful perforated area it is identical with the perforated area of the reducing device 202;
The butt end mouthful of first pod apertures 301 is connected with the external fluidized bed reactor, first pod apertures The connection corresponding with the taper end mouthful of second pod apertures 302 of 301 taper end mouthful;
The butt end mouthful of second pod apertures 302 is connected with the first end of the reducing device 202;
In first pod apertures 301, the gas-solid material to be separated for filtering out the external fluidized bed reactor output Part I solid particle, and the Part I solid particle is back to the fluidized-bed reactor;And, it will filter out Remaining gas-solid material to be separated accelerates to transmit to second pod apertures 302 after the Part I solid particle;
Second pod apertures 302, the material to be separated material for first pod apertures 301 to be transmitted slow down transmit to The reducing device 202.
The gas-solid material to be separated of external fluidized bed reactor output is by the butt end mouthful of the first pod apertures towards the first water conservancy diversion During the taper end mouthful motion in hole:Gas in gas-solid mixture is incompressible continuous media so that the gas in gas-solid mixture Fraction solids Particle Acceleration is carried by the first pod apertures to enter the second pod apertures;Solid particle in gas-solid mixture is can Discrete media is compressed, choke plug phenomenon, i.e., a part of solid particle in gas-solid mixture occur in the pod apertures of frustum first It can be deposited in the first pod apertures, realize the Part I solid particle filtered out in gas-solid mixture.
As shown in figure 4, in one embodiment of the invention, when gas-solid material to be separated is axially into cyclone body When 201, such as in tornadotron, the cyclone body 201 is tornadotron main body 201, the tornadotron main body 201 First end be provided with guide vane 401;
The reducing device 202, for making the material to be separated axially into the first of the tornadotron main body 201 End;
The guide vane 401, for being rotated under outside dynamic action, is treated point with driving axially into described in Helical rotation is carried out from material.
When material to be separated is axially into tornadotron main body, relies primarily on the drive of the guide vane in tornadotron main body and treat Separation of material produces eddy flow, so as to realize the gas solid separation of material to be separated, and improves separative efficiency.
In summary, each embodiment of the invention at least has the advantages that:
1st, in embodiments of the present invention, from powder of the flyash as wear resistance lining, because the density of flyash is only 0.2~0.3kg/m3, much smaller than white fused alumina density (>3900kg/m3) so that when raw material weight than it is close when, what is be made is resistance to Weight in mill lining reduces and toughness strengthens, so that wear resistance lining is easy to anchoring with cyclone body.
2nd, in embodiments of the present invention, aggregate includes any one in white fused alumina and ceramics or two kinds, preferably in vain just Beautiful and ceramics mixtures.Because the density of ceramics is 2380kg/m3Left and right, compared with white fused alumina density (>3900kg/m3) small, because This Ceramics can further reduce the weight of wear resistance lining as the aggregate of wear resistance lining, so that wear resistance lining and whirlwind Separator main body is easier to anchoring.In addition, as the aggregate of wear resistance lining waste ceramic is realized into discarded object recycling, not only The cost of wear resistance lining has been saved, environmental protection is also helped.
3rd, in embodiments of the present invention, it is 1 by the ratio setting of white fused alumina and ceramics:1, making the aggregate of wear resistance lining has Good skeleton and supporting role, so as to increase the intensity of wear resistance lining.
4th, in embodiments of the present invention, the ceramic particle diameter of selection is:100~300 μm, the particle diameter of white fused alumina for 100~ 300 μm, this causes aggregate to have good skeleton and supporting role.In addition, the particle diameter from flyash is 0.5~100 μm, make Obtaining flyash has good filling effect.
5th, in embodiments of the present invention, binding agent selects any one in aluminate cement and portland cement or two Kind, it can avoid in wear resistance lining manufacturing process, because of the contraction that hydrated product is dehydrated and produces, and then improve the strong of wear resistance lining Degree.
6th, in embodiments of the present invention, additive selects one-dimensional carbon fiber, one dimension fibre shape carborundum and one dimension fibre shape Any one or more in silicon nitride, can further improve the toughness of wear resistance lining, so as to improve the anti-thermal shock of wear resistance lining Property.And because these materials have good thermal conductivity, therefore thermal stress suffered by wear resistance lining can be made evenly, so as to improve The heat-conducting effect of wear resistance lining.
7th, in embodiments of the present invention, wear resistance lining is anchored to the inwall of the cyclone body of gas-solid separation equipment On, when gas-solid material to be separated carries out helical rotation in cyclone body, the solid in gas-solid material to be separated Grain is got rid of to side wall due to centrifugal force, is collided with wear resistance lining, then along wear resistance lining from cyclone body bottom Dipleg discharge, while gas in gas-solid material to be separated is discharged from the riser on cyclone body top, realize The separation of solid and gas in gas-solid material to be separated.Because the powder of wear resistance lining selects flyash, the density of flyash compared with It is small, make that the weight of wear resistance lining is smaller and toughness is higher, so that wear resistance lining is easy to be anchored at the interior of cyclone body On wall.Meanwhile, wear resistance lining is anchored on cyclone body inwall, cyclone body is played a protective role, The service life of separation equipment can be improved.
8th, in embodiments of the present invention, when separation equipment be high-temperature systems when, cyclone body inwall with it is wear-resisting Between lining increase by one layer by coal ash for manufacturing into heat-barrier material, it is to avoid the temperature of cyclone body outer wall is too high, improve The performance of separation equipment.When separation equipment is middle cryogenic system, increases metal hexsteel in wear resistance lining, strengthen resistance to With the anchoring fastness of cyclone body in mill lining, so as to increase the service life of wear resistance lining.
9th, in embodiments of the present invention, when gas-solid material to be separated tangentially enters cyclone body, reducing device The fraction solids particle in gas-solid material to be separated can be filtered out, is transmitted so as to reduce by reducing device to cyclone separator master The concentration of solid particle in the material to be separated of body, cyclone body is carrying out gas for the relatively low material to be separated of concentration Admittedly separate, gas-solid disngaging efficiency is higher, so as to improve the separative efficiency of separation equipment.
10th, in embodiments of the present invention, when gas-solid material to be separated is axially into cyclone body, in whirlwind point From guide vane is set in device main body, so that guide vane drives material to be separated to produce eddy flow, so as to realize gas to be separated Gu separation, and improve separative efficiency.
It should be noted that herein, such as first and second etc relational terms are used merely to an entity Or operation makes a distinction with another entity or operation, and not necessarily require or imply exist between these entities or operation Any this actual relation or order.Moreover, term " comprising ", "comprising" or its any other variant be intended to it is non- It is exclusive to include, so that process, method, article or equipment including a series of key elements not only include those key elements, But also other key elements including being not expressly set out, or also include solid by this process, method, article or equipment Some key elements.In the absence of more restrictions, the key element limited by sentence " including one ", is not arranged Except also there is other identical factor in the process including the key element, method, article or equipment.
It is last it should be noted that:Presently preferred embodiments of the present invention is the foregoing is only, the skill of the present invention is merely to illustrate Art scheme, is not intended to limit the scope of the present invention.Any modification for being made within the spirit and principles of the invention, Equivalent substitution, improvement etc., are all contained in protection scope of the present invention.

Claims (10)

1. a kind of low-cost high-toughness wear resistance lining, it is characterised in that its raw material includes the material of following parts by weight:
2~5 parts of 65~75 parts of aggregate, 20~32 parts of flyash, 2~5 parts of binding agent and additive.
2. wear resistance lining according to claim 1, it is characterised in that the aggregate includes:Appointing in white fused alumina and ceramics Meaning is one or two kinds of.
3. wear resistance lining according to claim 2, it is characterised in that
When the aggregate includes described ceramic,
The ceramic particle diameter is:100~300 μm.
And/or,
When the aggregate includes the white fused alumina,
The particle diameter of the white fused alumina is 100~300 μm.
4. according to any described wear resistance lining of claims 1 to 3, it is characterised in that
The particle diameter of the flyash is 0.5~100 μm.
5. according to any described wear resistance lining in Claims 1-4, it is characterised in that
The binding agent includes:Any one in aluminate cement and portland cement or two kinds;
And/or,
The additive includes:Any one in one-dimensional carbon fiber, one dimension fibre shape carborundum and one dimension fibre shape silicon nitride Or it is a variety of.
6. the preparation method of any described low-cost high-toughness wear resistance lining in a kind of claim 1 to 5, it is characterised in that Including:
The material of following parts by weight is weighed respectively:
2~5 parts of 65~75 parts of aggregate, 20~32 parts of flyash, 2~5 parts of binding agent and additive;
The aggregate weighed, the flyash, the binding agent and the additive are mixed with water, solid-liquid is formed and mixes Compound;
The solidliquid mixture is put into mould, and controls the solidliquid mixture to be uniformly distributed in the mould by mode of vibration Tool;
After solidliquid mixture progress natural curing, it is stripped;
The water in the solidliquid mixture after the demoulding is removed by drying mode, the wear resistance lining is formed.
7. method according to claim 6, it is characterised in that
It is described to weigh 65~75 parts of the aggregate, including:
Weigh 32.5~37.5 parts of 32.5~37.5 parts of white fused alumina and ceramics.
8. a kind of gas-solid separation equipment, it is characterised in that including:Cyclone body, reducing device and claim 1 to 5 In any described low-cost high-toughness wear resistance lining;Wherein,
The wear resistance lining is anchored on the inwall of the cyclone body;
The reducing device is connected with the first end of the cyclone body;
The reducing device, for receiving gas-solid material to be separated, and by gas-solid material to be separated by the cyclonic separation The first end of device main body is delivered in the cyclone body;
The cyclone body, for driving gas-solid material to be separated to produce eddy flow, by centrifugal action so that institute The solid particle stated in gas-solid material to be separated is got rid of to side wall, is collided with the wear resistance lining, and from the dipleg of bottom Gas in discharge, the gas-solid material to be separated is discharged from the riser on top.
9. gas-solid separation equipment according to claim 8, it is characterised in that applied to cyclone separator;
The first end of the reducing device is connected with external fluidized bed reactor, the second end and the whirlwind of the reducing device The first end of separator main body is connected;
The reducing device, first in gas-solid material to be separated for filtering out the external fluidized bed reactor output Fraction solids particle, and remaining gas-solid material to be separated after filtering out the Part I solid particle is tangentially entered institute State cyclone body.
10. gas-solid separation equipment according to claim 8, it is characterised in that applied to tornadotron;
The cyclone body includes:Tornadotron main body;
The first end of the tornadotron main body is provided with guide vane;
The reducing device, for making gas-solid material to be separated axially into the first end of the tornadotron main body;
The guide vane, it is to be separated with the gas-solid that driving axial enters for being rotated under outside dynamic action Material produces eddy flow.
CN201710495336.3A 2017-06-26 2017-06-26 A kind of low-cost high-toughness wear resistance lining, preparation method and gas-solid separation equipment Pending CN107117984A (en)

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1070390A (en) * 1991-09-07 1993-03-31 武进县横山桥镇五一节能材料厂 Two-pack heat resistant and wear resistant lining material
CN202078978U (en) * 2011-05-10 2011-12-21 天津格威莱德科技发展有限公司 Cyclone separator
CN103398375A (en) * 2013-07-01 2013-11-20 中国华能集团清洁能源技术研究院有限公司 Cyclone separator with wear-resistant target section and guiding device for circulating fluidized bed boiler
CN205413384U (en) * 2016-03-08 2016-08-03 山东科技大学 Inside shape of intake pipe is cyclone of convergent flaring type
CN106631054A (en) * 2016-10-11 2017-05-10 洛阳万基炭素有限公司 High-strength wearproof corundum casting material and construction process thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1070390A (en) * 1991-09-07 1993-03-31 武进县横山桥镇五一节能材料厂 Two-pack heat resistant and wear resistant lining material
CN202078978U (en) * 2011-05-10 2011-12-21 天津格威莱德科技发展有限公司 Cyclone separator
CN103398375A (en) * 2013-07-01 2013-11-20 中国华能集团清洁能源技术研究院有限公司 Cyclone separator with wear-resistant target section and guiding device for circulating fluidized bed boiler
CN205413384U (en) * 2016-03-08 2016-08-03 山东科技大学 Inside shape of intake pipe is cyclone of convergent flaring type
CN106631054A (en) * 2016-10-11 2017-05-10 洛阳万基炭素有限公司 High-strength wearproof corundum casting material and construction process thereof

Non-Patent Citations (6)

* Cited by examiner, † Cited by third party
Title
包生重等: "ρ-Al2O3对刚玉尖晶石浇注料性能的影响研究", 《陶瓷学报》 *
周春山: "《新编实用化工小商品配方与生产》", 30 June 1994, 中南工业大学出版社 *
夏征农: "《大辞海 化工轻工纺织卷》", 31 August 2009 *
许佩瑶: "《火电厂应用化学》", 31 August 2007, 中国电力出版社 *
贺中央等: "加入纳米碳酸钙对铬刚玉浇注料力学性能的影响", 《耐火材料》 *
陆庆云: "《流化催化裂化 第2版》", 31 August 1989 *

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Application publication date: 20170901