CN107117913A - A kind of facing mortar of low contract with dry rate - Google Patents
A kind of facing mortar of low contract with dry rate Download PDFInfo
- Publication number
- CN107117913A CN107117913A CN201710320264.9A CN201710320264A CN107117913A CN 107117913 A CN107117913 A CN 107117913A CN 201710320264 A CN201710320264 A CN 201710320264A CN 107117913 A CN107117913 A CN 107117913A
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- China
- Prior art keywords
- bentonite
- facing mortar
- nano
- quality
- dry rate
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
- C04B28/06—Aluminous cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00017—Aspects relating to the protection of the environment
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00474—Uses not provided for elsewhere in C04B2111/00
- C04B2111/00482—Coating or impregnation materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/2092—Resistance against biological degradation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/27—Water resistance, i.e. waterproof or water-repellent materials
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
Abstract
The invention discloses a kind of facing mortar of low contract with dry rate, it is made up of following component:Aluminate cement, portland cement, gypsum, quartz sand, acrylic emulsion, hydroxymethyl cellulose, treated basalt fiber, active attapulgite, pigment, defoamer, water, facing mortar cost prepared by the present invention is relatively low, with good weatherability, impervious, waterproof, mould proof, energy-conserving and environment-protective, dry powder easy to maintain, convenient transportation, long shelf-life, the low feature of shrinkage factor, the building inside and outside wall being suitable under various environmental weather conditions are applied.
Description
Technical field
The invention belongs to facing mortar technical field, and in particular to a kind of facing mortar of low contract with dry rate.
Background technology
With economic development, people require more and more higher and variation, traditional emulsion paint for architecture inside and outside decoration
People's demand can not be fully met with ceramic tile, facing mortar is because its color change range is big, molding surface abundant, weather-proof
Property good more and more welcomed by the people, facing mortar is made up of inorganic coagulation material, filler, additive and aggregate, uses
In building wall material and the material of ceiling decoration.The exterior wall of Most current building all does external thermal insulation, and facing mortar is with showing
Finish coat prepared by the organic materials such as some coating is compared, and facing mortar has more preferable matching and compatible with outer heat preservation system
Property.In addition, facing mortar is compared with tile decorative surface, facing mortar thickness degree is only 1-3mm, and light weight is adornd as skyscraper
During surface layer, the problems such as will not be because of negative blast there is brick phenomenon, it is to avoid the potential safety hazard of tile decorative surface, but existing facing
Mortar contract with dry rate problem still more substantially, it is dry-shrinkage deformed but be cause mortar ftracture one of the main reasons.
The content of the invention
The purpose of the present invention is that there is provided a kind of facing mortar of low contract with dry rate the problem of being directed to existing.
The present invention is achieved by the following technical solutions:
A kind of facing mortar of low contract with dry rate, is made up of following component by weight:Aluminate cement 45-60, silicate cement
Mud 9-12, gypsum 20-30, quartz sand 300-330, acrylic emulsion 3-8, hydroxymethyl cellulose 0.8-1.2, modified basalt are fine
Tie up 5.5-5.8, active attapulgite 3.6-4.5, pigment 1.2-1.6, defoamer 0.5-0.8, water 30-60;
The preparation method of the treated basalt fiber is:
(1)Granularity is scattered in deionized water for 70nm nano-bentonite particle, deionized water pH is adjusted to 5.5-
5.8, the KH550 of nano-bentonite quality 10% is then added, 88 DEG C are adjusted the temperature to, it is small with the stirring 2.5 of 2500r/min rotating speeds
When, separation of solid and liquid is then carried out under high speed centrifugation, then washed, dry, it is stand-by;;
(2)After 200 times of deionized water of nano-bentonite particle by above-mentioned processing and its quality is uniformly mixed, received
Rice bentonite solution, 1 is pressed by the nano-bentonite aqueous solution:2 mass ratios are equal for 2.2% acrylic acid solution with mass fraction
It is even admixed together, 78 DEG C are adjusted the temperature to, after being stirred 2 hours with 2000r/min rotating speeds, then nano-bentonite quality is added
15% lauroylamidopropyl betaine, after stirring, obtains modified solution;
(3)Basalt fibre precursor is made in basaltic broken stone, basalt fibre precursor and above-mentioned modified solution are pressed 1:10 matter
Measure after ratio uniform mixing, be heated to 80 DEG C, after being incubated 2 hours, it is at 25kHz ultrasonic wave for 300W, frequency to use power
5min is managed, insulation 2 hours is then proceeded to, then filters, dries, produces.
Further, the aluminate cement and portland cement mass ratio are 5:1.
Further, the active attapulgite preparation method is:Attapulgite is calcined into 40min at 450 DEG C, then
100 DEG C are cooled to, is added in high-speed mixer, then is added under the diethyl phosphate of its quality 1.2%, then 2000r/min rotating speeds
Mixed processing 30min is carried out, then takes out, is cleaned using deionized water, drying to constant weight, you can.
Further, the pigment is azo pigment.
Further, the defoamer uses dimethyl silicone polymer.
The present invention has advantages below compared with prior art:Facing mortar cost prepared by the present invention is relatively low, with weather-proof
Property good, impervious, waterproof, mould proof, energy-conserving and environment-protective, dry powder easy to maintain, convenient transportation, long shelf-life, the low feature of shrinkage factor, be adapted to
Applied in the building inside and outside wall under various environmental weather conditions, by using 5:Aluminate cement, the silicate, Neng Gouyi of 1 proportioning
Determine to reduce the shrinkage factor of facing mortar in degree, by adding the synergy of active attapulgite, this hair can be significantly reduced
The shrinkage factor of bright facing mortar, facing mortar shrinkage factor prepared by the present invention is low, can reduce when mortar condenses in different pacts
Under pencil state because of caused by contraction tension, while by being modified to basalt fibre, facing can greatly be strengthened
The tensile strength of mortar so that the tensile strength of facing mortar of the present invention is noticeably greater than because of the tension that contraction is got up, so as to keep away
Exempt from the generation in mortar crackle or crack, it is ensured that the durability performance of mortar.
Embodiment
Embodiment 1
A kind of facing mortar of low contract with dry rate, is made up of following component by weight:Aluminate cement 45, portland cement 9,
Gypsum 20, quartz sand 300, acrylic emulsion 3, hydroxymethyl cellulose 0.8, treated basalt fiber 5.5, active attapulgite
3.6th, pigment 1.2, defoamer 0.5, water 30;
The preparation method of the treated basalt fiber is:
(1)Granularity is scattered in deionized water for 70nm nano-bentonite particle, deionized water pH is adjusted to 5.5-
5.8, the KH550 of nano-bentonite quality 10% is then added, 88 DEG C are adjusted the temperature to, it is small with the stirring 2.5 of 2500r/min rotating speeds
When, separation of solid and liquid is then carried out under high speed centrifugation, then washed, dry, it is stand-by;;
(2)After 200 times of deionized water of nano-bentonite particle by above-mentioned processing and its quality is uniformly mixed, received
Rice bentonite solution, 1 is pressed by the nano-bentonite aqueous solution:2 mass ratios are equal for 2.2% acrylic acid solution with mass fraction
It is even admixed together, 78 DEG C are adjusted the temperature to, after being stirred 2 hours with 2000r/min rotating speeds, then nano-bentonite quality is added
15% lauroylamidopropyl betaine, after stirring, obtains modified solution;
(3)Basalt fibre precursor is made in basaltic broken stone, basalt fibre precursor and above-mentioned modified solution are pressed 1:10 matter
Measure after ratio uniform mixing, be heated to 80 DEG C, after being incubated 2 hours, it is at 25kHz ultrasonic wave for 300W, frequency to use power
5min is managed, insulation 2 hours is then proceeded to, then filters, dries, produces.
The aluminate cement is 5 with portland cement mass ratio:1.
The active attapulgite preparation method is:Attapulgite is calcined into 40min at 450 DEG C, 100 are subsequently cooled to
DEG C, it is added in high-speed mixer, then add and mixed under the diethyl phosphate of its quality 1.2%, then 2000r/min rotating speeds
30min is handled, then takes out, is cleaned using deionized water, drying to constant weight, you can.
The pigment is azo pigment.
The defoamer uses dimethyl silicone polymer.
Embodiment 2
A kind of facing mortar of low contract with dry rate, is made up of following component by weight:Aluminate cement 60, portland cement
12nd, gypsum 30, quartz sand 330, acrylic emulsion 8, hydroxymethyl cellulose 1.2, treated basalt fiber 5.8, active attapulgite
Soil 4.5, pigment 1.6, defoamer 0.8, water 60;
The preparation method of the treated basalt fiber is:
(1)Granularity is scattered in deionized water for 70nm nano-bentonite particle, deionized water pH is adjusted to 5.5-
5.8, the KH550 of nano-bentonite quality 10% is then added, 88 DEG C are adjusted the temperature to, it is small with the stirring 2.5 of 2500r/min rotating speeds
When, separation of solid and liquid is then carried out under high speed centrifugation, then washed, dry, it is stand-by;;
(2)After 200 times of deionized water of nano-bentonite particle by above-mentioned processing and its quality is uniformly mixed, received
Rice bentonite solution, 1 is pressed by the nano-bentonite aqueous solution:2 mass ratios are equal for 2.2% acrylic acid solution with mass fraction
It is even admixed together, 78 DEG C are adjusted the temperature to, after being stirred 2 hours with 2000r/min rotating speeds, then nano-bentonite quality is added
15% lauroylamidopropyl betaine, after stirring, obtains modified solution;
(3)Basalt fibre precursor is made in basaltic broken stone, basalt fibre precursor and above-mentioned modified solution are pressed 1:10 matter
Measure after ratio uniform mixing, be heated to 80 DEG C, after being incubated 2 hours, it is at 25kHz ultrasonic wave for 300W, frequency to use power
5min is managed, insulation 2 hours is then proceeded to, then filters, dries, produces.
The aluminate cement is 5 with portland cement mass ratio:1.
The active attapulgite preparation method is:Attapulgite is calcined into 40min at 450 DEG C, 100 are subsequently cooled to
DEG C, it is added in high-speed mixer, then add and mixed under the diethyl phosphate of its quality 1.2%, then 2000r/min rotating speeds
30min is handled, then takes out, is cleaned using deionized water, drying to constant weight, you can.
The pigment is azo pigment.
The defoamer uses dimethyl silicone polymer.
Embodiment 3
A kind of facing mortar of low contract with dry rate, is made up of following component by weight:Aluminate cement 50, portland cement
10th, gypsum 25, quartz sand 320, acrylic emulsion 5, hydroxymethyl cellulose 1.0, treated basalt fiber 5.6, active attapulgite
Soil 3.8, pigment 1.4, defoamer 0.7, water 40;
The preparation method of the treated basalt fiber is:
(1)Granularity is scattered in deionized water for 70nm nano-bentonite particle, deionized water pH is adjusted to 5.5-
5.8, the KH550 of nano-bentonite quality 10% is then added, 88 DEG C are adjusted the temperature to, it is small with the stirring 2.5 of 2500r/min rotating speeds
When, separation of solid and liquid is then carried out under high speed centrifugation, then washed, dry, it is stand-by;;
(2)After 200 times of deionized water of nano-bentonite particle by above-mentioned processing and its quality is uniformly mixed, received
Rice bentonite solution, 1 is pressed by the nano-bentonite aqueous solution:2 mass ratios are equal for 2.2% acrylic acid solution with mass fraction
It is even admixed together, 78 DEG C are adjusted the temperature to, after being stirred 2 hours with 2000r/min rotating speeds, then nano-bentonite quality is added
15% lauroylamidopropyl betaine, after stirring, obtains modified solution;
(3)Basalt fibre precursor is made in basaltic broken stone, basalt fibre precursor and above-mentioned modified solution are pressed 1:10 matter
Measure after ratio uniform mixing, be heated to 80 DEG C, after being incubated 2 hours, it is at 25kHz ultrasonic wave for 300W, frequency to use power
5min is managed, insulation 2 hours is then proceeded to, then filters, dries, produces.
The aluminate cement is 5 with portland cement mass ratio:1.
The active attapulgite preparation method is:Attapulgite is calcined into 40min at 450 DEG C, 100 are subsequently cooled to
DEG C, it is added in high-speed mixer, then add and mixed under the diethyl phosphate of its quality 1.2%, then 2000r/min rotating speeds
30min is handled, then takes out, is cleaned using deionized water, drying to constant weight, you can.
The pigment is azo pigment.
The defoamer uses dimethyl silicone polymer.
Experiment:Formula mould, middle shaping by embodiment mortar in 25 × 25mm × 280mm, after shaping temperature be 20 DEG C,
Relative humidity is conserved under conditions of being more than 90%RH, form removal after 24 hours, and test specimen is conserved as temperature for continuation in 20 DEG C of water
Taken out after 2d, after the first length for determining style, move into constant-temp. and-moisture maintenance(Curing temperature control is at 20 ± 3 DEG C, and relative humidity is
50±4%);The shrinkage performance of the length measurment mortar of different larval instar test specimen is measured with comparator, contract with dry rate is calculated(Embodiment 1,
2nd, 3 results take average, and using aluminate cement and portland cement mass ratio as variable, wherein portland cement amount is constant);
Mortar drying shrinkage is determined, with reference to JC/T603-1995(Cement mortar dry shrinkage test method)With Australian National standard
AS2350.13-1995/Amdt 1-1997(Portland and mixing water earth rubber sand dry shrinkage test method):
Table 1
As can be seen from Table 1, the present invention uses 5:1 aluminate cement and portland cement mass ratio, can substantially reduce decorations
The contract with dry rate of facing sand slurry.
Experiment:Formula mould, middle shaping by embodiment mortar in 25 × 25mm × 280mm, after shaping temperature be 20 DEG C,
Relative humidity is conserved under conditions of being more than 90%RH, form removal after 24 hours, and test specimen is conserved as temperature for continuation in 20 DEG C of water
Taken out after 2d, after the first length for determining style, move into constant-temp. and-moisture maintenance(Curing temperature control is at 20 ± 3 DEG C, and relative humidity is
50±4%);Determine the tensile strength of different times(Whether the result of embodiment 1,2,3 takes average, be modified as becoming with basalt fibre
Amount, wherein addition is constant)
Table 2
As can be seen from Table 2, the tensile strength of facing mortar of the present invention can be significantly improved using treated basalt fiber.
Experiment:Formula mould, middle shaping by embodiment mortar in 25 × 25mm × 280mm, after shaping temperature be 20 DEG C,
Relative humidity is conserved under conditions of being more than 90%RH, form removal after 24 hours, and test specimen is conserved as temperature for continuation in 20 DEG C of water
Taken out after 2d, after the first length for determining style, move into constant-temp. and-moisture maintenance(Curing temperature control is at 20 ± 3 DEG C, and relative humidity is
50±4%);Determine the rupture strength of different times(The result of embodiment 1,2,3 takes average, and with attapulgite, whether activity is processed as
Variable, wherein addition are constant)
Table 3
As can be seen from Table 3, by activity processing after attapulgite can significantly improve facing mortar of the present invention anti-folding it is strong
Degree.
Claims (5)
1. a kind of facing mortar of low contract with dry rate, it is characterised in that be made up by weight of following component:Aluminate cement
45-60, portland cement 9-12, gypsum 20-30, quartz sand 300-330, acrylic emulsion 3-8, hydroxymethyl cellulose 0.8-
1.2nd, treated basalt fiber 5.5-5.8, active attapulgite 3.6-4.5, pigment 1.2-1.6, defoamer 0.5-0.8, water 30-
60;
The preparation method of the treated basalt fiber is:
(1)Granularity is scattered in deionized water for 70nm nano-bentonite particle, deionized water pH is adjusted to 5.5-
5.8, the KH550 of nano-bentonite quality 10% is then added, 88 DEG C are adjusted the temperature to, it is small with the stirring 2.5 of 2500r/min rotating speeds
When, separation of solid and liquid is then carried out under high speed centrifugation, then washed, dry, it is stand-by;;
(2)After 200 times of deionized water of nano-bentonite particle by above-mentioned processing and its quality is uniformly mixed, received
Rice bentonite solution, 1 is pressed by the nano-bentonite aqueous solution:2 mass ratios are equal for 2.2% acrylic acid solution with mass fraction
It is even admixed together, 78 DEG C are adjusted the temperature to, after being stirred 2 hours with 2000r/min rotating speeds, then nano-bentonite quality is added
15% lauroylamidopropyl betaine, after stirring, obtains modified solution;
(3)Basalt fibre precursor is made in basaltic broken stone, basalt fibre precursor and above-mentioned modified solution are pressed 1:10 matter
Measure after ratio uniform mixing, be heated to 80 DEG C, after being incubated 2 hours, it is at 25kHz ultrasonic wave for 300W, frequency to use power
5min is managed, insulation 2 hours is then proceeded to, then filters, dries, produces.
2. a kind of facing mortar of low contract with dry rate as claimed in claim 1, it is characterised in that the aluminate cement and silicate
Cement quality ratio is 5:1.
3. a kind of facing mortar of low contract with dry rate as claimed in claim 1, it is characterised in that the active attapulgite preparation side
Method is:Attapulgite is calcined into 40min at 450 DEG C, 100 DEG C is subsequently cooled to, is added in high-speed mixer, then add it
Mixed processing 30min is carried out under the diethyl phosphate of quality 1.2%, then 2000r/min rotating speeds, is then taken out, using deionized water
Cleaned, drying to constant weight, you can.
4. a kind of facing mortar of low contract with dry rate as claimed in claim 1, it is characterised in that the pigment is azo pigment.
5. a kind of facing mortar of low contract with dry rate as claimed in claim 1, it is characterised in that the defoamer uses poly dimethyl
Siloxanes.
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112456927A (en) * | 2020-11-16 | 2021-03-09 | 辽宁省交通高等专科学校 | Graphene oxide/polymer modified cement-based repair mortar and preparation method thereof |
CN112456869A (en) * | 2020-11-16 | 2021-03-09 | 辽宁省交通高等专科学校 | High-fracture-resistance graphene oxide cement mortar and preparation method thereof |
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CN104045307A (en) * | 2014-07-09 | 2014-09-17 | 四川省建筑科学研究院 | Surface-decorative mortar and preparation method thereof |
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2017
- 2017-05-09 CN CN201710320264.9A patent/CN107117913A/en active Pending
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CN104045307A (en) * | 2014-07-09 | 2014-09-17 | 四川省建筑科学研究院 | Surface-decorative mortar and preparation method thereof |
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何建新: "《新型纤维材料学》", 31 July 2014, 东华大学出版社 * |
刘小兵等: "硅酸盐水泥和铝酸盐水泥复合性能研究", 《粉煤灰》 * |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN112456927A (en) * | 2020-11-16 | 2021-03-09 | 辽宁省交通高等专科学校 | Graphene oxide/polymer modified cement-based repair mortar and preparation method thereof |
CN112456869A (en) * | 2020-11-16 | 2021-03-09 | 辽宁省交通高等专科学校 | High-fracture-resistance graphene oxide cement mortar and preparation method thereof |
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Application publication date: 20170901 |