CN107286722B - A kind of water-fast crack resistence wall putty - Google Patents
A kind of water-fast crack resistence wall putty Download PDFInfo
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- CN107286722B CN107286722B CN201710704675.8A CN201710704675A CN107286722B CN 107286722 B CN107286722 B CN 107286722B CN 201710704675 A CN201710704675 A CN 201710704675A CN 107286722 B CN107286722 B CN 107286722B
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- crack resistence
- fly ash
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- 239000000835 fiber Substances 0.000 claims abstract description 40
- 239000000843 powder Substances 0.000 claims abstract description 25
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 22
- 239000000919 ceramic Substances 0.000 claims abstract description 14
- 239000010881 fly ash Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- 239000011398 Portland cement Substances 0.000 claims abstract description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000013530 defoamer Substances 0.000 claims abstract description 6
- 239000003112 inhibitor Substances 0.000 claims abstract description 6
- 239000006210 lotion Substances 0.000 claims abstract description 6
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 6
- 239000010703 silicon Substances 0.000 claims abstract description 6
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 239000002270 dispersing agent Substances 0.000 claims abstract description 5
- 239000006004 Quartz sand Substances 0.000 claims abstract description 3
- 239000005543 nano-size silicon particle Substances 0.000 claims description 15
- 229910052814 silicon oxide Inorganic materials 0.000 claims description 15
- 239000004743 Polypropylene Substances 0.000 claims description 11
- 229920001155 polypropylene Polymers 0.000 claims description 11
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 10
- 239000002245 particle Substances 0.000 claims description 6
- -1 polypropylene Polymers 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 5
- 238000006243 chemical reaction Methods 0.000 claims description 5
- 239000002131 composite material Substances 0.000 claims description 5
- 239000008367 deionised water Substances 0.000 claims description 5
- 229910021641 deionized water Inorganic materials 0.000 claims description 5
- 230000008021 deposition Effects 0.000 claims description 5
- 238000001035 drying Methods 0.000 claims description 5
- 239000000706 filtrate Substances 0.000 claims description 5
- 239000008236 heating water Substances 0.000 claims description 5
- 238000006703 hydration reaction Methods 0.000 claims description 5
- 239000007791 liquid phase Substances 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 229920000642 polymer Polymers 0.000 claims description 5
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 5
- 229940068984 polyvinyl alcohol Drugs 0.000 claims description 5
- 235000019422 polyvinyl alcohol Nutrition 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000003860 storage Methods 0.000 claims description 5
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 5
- 238000005491 wire drawing Methods 0.000 claims description 5
- 238000010422 painting Methods 0.000 claims description 3
- 239000004568 cement Substances 0.000 abstract description 4
- 239000011159 matrix material Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 230000006835 compression Effects 0.000 abstract description 3
- 238000007906 compression Methods 0.000 abstract description 3
- 230000035939 shock Effects 0.000 abstract description 3
- 229920002678 cellulose Polymers 0.000 abstract 1
- 239000001913 cellulose Substances 0.000 abstract 1
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 238000005336 cracking Methods 0.000 description 5
- 238000005507 spraying Methods 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 3
- 238000010410 dusting Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000004575 stone Substances 0.000 description 3
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- AFCARXCZXQIEQB-UHFFFAOYSA-N N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(CCNC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 AFCARXCZXQIEQB-UHFFFAOYSA-N 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- NKWPZUCBCARRDP-UHFFFAOYSA-L calcium bicarbonate Chemical compound [Ca+2].OC([O-])=O.OC([O-])=O NKWPZUCBCARRDP-UHFFFAOYSA-L 0.000 description 1
- 229910000020 calcium bicarbonate Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- MOUPNEIJQCETIW-UHFFFAOYSA-N lead chromate Chemical compound [Pb+2].[O-][Cr]([O-])(=O)=O MOUPNEIJQCETIW-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000007581 slurry coating method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/34—Filling pastes
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Paints Or Removers (AREA)
Abstract
The present invention relates to the development technique fields of putty for building, disclose a kind of water-fast crack resistence wall putty, are made in parts by weight of following component:270 300 parts of portland cement, 70 80 parts of quartz sand, 45 55 parts of lotion, 30 40 parts of fly ash float, 25 30 parts of ceramic powder, dicalcium powder 15 20,35 parts of dispersant, 23 parts of wetting agent, 1.5 2.0 parts of modified cellulose, 1.0 2.0 parts of organic silicon defoamer, 1.0 1.5 parts of mould inhibitor, 340 350 parts of water, the present invention enhances compression strength, the shock resistance of putty body using modified fibre, it can solve the problems, such as that the brittleness of cement matrix is big, easy to crack, fly ash float, the ceramic powder used combines, hydrophobicity is strong, solves seepage problem.
Description
Technical field
The invention belongs to the development technique fields of putty for building, and in particular to a kind of water-fast crack resistence wall putty.
Background technology
Putty (fillering) is a kind of decoration type material of smooth surface of wall, is a kind of thick slurry coating material, is coating painting
A kind of preceding essential product.Painting is imposed on priming paint or is directly applied and imposes on object, to remove height on coated article surface
Uneven defect.It is formulated using a small amount of paint base, auxiliary agent, mass filler and suitable coloring pigment, pigment used is mainly
Iron oxide red, carbon black, chrome yellow etc..Filler is mainly calcium bicarbonate, talcum powder etc..Part, which can be filled up, the working surface of recess, also may be used
It is struck off in all surfaces, typically after prime coat parches, is applied over primer coat surface.It is required that adhesion is good, in baking process
It does not crack.
Building coating has been widely used in the beautification and protection of building.But in practice, it has been found that even if the property of coating
Can be excellent again, elasticity is good again, if the putty performance between wall and coating is bad, if itself cracking or dusting, then table
The coating of layer cannot prevent this inherent cracking and dusting, therefore, often can see the blistering of coating, dusting, fall off,
Phenomena such as infiltration, cracking, the aesthetics and quality of wall is seriously affected.Especially in moist basement, bathroom, such case
It is more serious.These defects are caused by some are putty poor quality in fact.
Invention content
The purpose of the present invention is for existing problem, providing a kind of water-fast crack resistence wall putty, modified fibre is utilized
Compression strength, the shock resistance of dimension enhancing putty body, can solve the problems, such as that the brittleness of cement matrix is big, easy to crack, use
Fly ash float, ceramic powder combination, hydrophobicity is strong, solves seepage problem.
The present invention is achieved by the following technical solutions:
A kind of water-fast crack resistence wall putty, is made of following component in parts by weight:Portland cement 270-300
Part, 70-80 parts of quartz sand, 45-55 parts of lotion, 30-40 parts of fly ash float, 25-30 parts of ceramic powder, dicalcium powder 15-20, dispersion
3-5 parts of agent, 2-3 parts of wetting agent, 1.5-2.0 parts of modified fibre, 1.0-2.0 parts of organic silicon defoamer, 1.0-1.5 parts of mould inhibitor,
340-350 parts of water stirs said components, dry-storage in blender;
The modified fibre is the composite material that addition mass fraction is 4-6% on the basis of original polypropylene fibre,
The preparation method of the modified fibre is:
(1)The nano silicon oxide that particle size is 10-20 nanometers is prepared using liquid phase deposition, into the nano silicon oxide
The deionized water of 2-3 times of volume is added, heating water bath carries out hydration reaction at this temperature to 50-60 DEG C, reacts 1-2 hours
Afterwards, ultrasonic vibration 20-30 minutes in ultrasonic cleaner,
(2)After solution becomes white, the poly-vinyl alcohol solution and quality percentage that mass percent is its 30-40% is added
Than the titanium tetrachloride for its 5-8%, continue ultrasonic vibration 20-25 minutes, white mixture obtained by the reaction is passed through into Buchner funnel
Filtering, obtained filtrate are put into baking oven and dry 2-3 hours;
(3)Polypropylene fibre is melted at high temperature, by the nano silicon oxide being prepared-organotitanium polymer hetero-junctions
Structure spraying is dispersed in fused fiber, is drawn on high speed wiredrawing bench, and immediately in 120-130 DEG C of electric drying oven with forced convection
6-8 hours dry, it is 10-15 millimeters to cut out to length, is cooled down up to the modified fibre.
It is further described as to said program, the fly ash float density is in 0.44-0.46g/cm3Range, grain
Diameter size is in 40-60 mesh ranges.
It is further described as to said program, 2MgOSiO in the ceramic powder270-80% is accounted for, remaining as oxidation
Aluminium powder.
The present invention has the following advantages compared with prior art:It is unstable in order to solve existing wall putty performance, it is water-fast
The poor problem of heat resistance, the present invention provides a kind of water-fast crack resistence wall putties, enhance putty body using modified fibre
Compression strength, shock resistance, form space multistory network structure with cement-hydrate so that putty become one it is fine and close
It is whole, it can solve the problems, such as that the brittleness of cement matrix is big, easy to crack, while improving the solar heat protection cracking performance of putty, use
Fly ash float, ceramic powder combination, hydrophobicity is strong, solves seepage problem, and the putty applicability is good, easy for construction, be applicable in
In inner-outer wall.
Specific implementation mode
The present invention is further explained in the light of specific embodiments.
Embodiment 1
A kind of water-fast crack resistence wall putty, is made of following component in parts by weight:270 parts of portland cement, stone
70 parts of sand, 30 parts of fly ash float, 25 parts of ceramic powder, dicalcium powder 15,3 parts of dispersant, 2 parts of wetting agent, is modified 45 parts of lotion
1.5 parts of fiber, 1.0 parts of organic silicon defoamer, 1.0 parts of mould inhibitor, 340 parts of water, said components are sufficiently stirred in blender
Uniformly, dry-storage;
The modified fibre is the composite material that addition mass fraction is 4% on the basis of original polypropylene fibre, should
The preparation method of modified fibre is:
(1)The nano silicon oxide that particle size is 10 nanometers is prepared using liquid phase deposition, is added into the nano silicon oxide
Enter the deionized water of 2 times of volumes, heating water bath carries out hydration reaction at this temperature to 50 DEG C, after reacting 1 hour, in ultrasound
Ultrasonic vibration 20 minutes in wave washer,
(2)After solution becomes white, addition mass percent is its 30% poly-vinyl alcohol solution and mass percent is
Its 5% titanium tetrachloride, continues ultrasonic vibration 20 minutes, by white mixture obtained by the reaction by filtered on buchner funnel, obtains
Filtrate be put into baking oven and dry 2 hours;
(3)Polypropylene fibre is melted at high temperature, by the nano silicon oxide being prepared-organotitanium polymer hetero-junctions
Structure spraying is dispersed in fused fiber, is drawn on high speed wiredrawing bench, and dry in 120 DEG C of electric drying oven with forced convection immediately
6 hours, it was 10 millimeters to cut out to length, is cooled down up to the modified fibre.
It is further described as to said program, the fly ash float density is in 0.44-0.46g/cm3Range, grain
Diameter size is in 40-60 mesh ranges.
It is further described as to said program, 2MgOSiO in the ceramic powder270% is accounted for, remaining as aluminium oxide
Powder.
Embodiment 2
A kind of water-fast crack resistence wall putty, is made of following component in parts by weight:280 parts of portland cement, stone
75 parts of sand, 35 parts of fly ash float, 28 parts of ceramic powder, dicalcium powder 18,4 parts of dispersant, 2.5 parts of wetting agent, changes 50 parts of lotion
1.8 parts of fiber of property, 1.5 parts of organic silicon defoamer, 1.2 parts of mould inhibitor, 345 parts of water, said components are fully stirred in blender
It mixes uniformly, dry-storage;
The modified fibre is the composite material that addition mass fraction is 5% on the basis of original polypropylene fibre, should
The preparation method of modified fibre is:
(1)The nano silicon oxide that particle size is 15 nanometers is prepared using liquid phase deposition, is added into the nano silicon oxide
Entering the deionized water of 2.5 times of volumes, heating water bath carries out hydration reaction at this temperature to 55 DEG C, after reacting 1.5 hours,
Ultrasonic vibration 25 minutes in ultrasonic cleaner,
(2)After solution becomes white, addition mass percent is its 35% poly-vinyl alcohol solution and mass percent is
Its 6% titanium tetrachloride, continues ultrasonic vibration 22 minutes, by white mixture obtained by the reaction by filtered on buchner funnel, obtains
Filtrate be put into baking oven and dry 2.5 hours;
(3)Polypropylene fibre is melted at high temperature, by the nano silicon oxide being prepared-organotitanium polymer hetero-junctions
Structure spraying is dispersed in fused fiber, is drawn on high speed wiredrawing bench, and dry in 125 DEG C of electric drying oven with forced convection immediately
7 hours, it was 12 millimeters to cut out to length, is cooled down up to the modified fibre.
It is further described as to said program, the fly ash float density is in 0.44-0.46g/cm3Range, grain
Diameter size is in 40-60 mesh ranges.
It is further described as to said program, 2MgOSiO in the ceramic powder275% is accounted for, remaining as aluminium oxide
Powder.
Embodiment 3
A kind of water-fast crack resistence wall putty, is made of following component in parts by weight:300 parts of portland cement, stone
80 parts of sand, 40 parts of fly ash float, 30 parts of ceramic powder, dicalcium powder 20,5 parts of dispersant, 3 parts of wetting agent, is modified 55 parts of lotion
2.0 parts of fiber, 2.0 parts of organic silicon defoamer, 1.5 parts of mould inhibitor, 350 parts of water, said components are sufficiently stirred in blender
Uniformly, dry-storage;
The modified fibre is the composite material that addition mass fraction is 6% on the basis of original polypropylene fibre, should
The preparation method of modified fibre is:
(1)The nano silicon oxide that particle size is 20 nanometers is prepared using liquid phase deposition, is added into the nano silicon oxide
Enter the deionized water of 3 times of volumes, heating water bath carries out hydration reaction at this temperature to 60 DEG C, after reacting 2 hours, in ultrasound
Ultrasonic vibration 30 minutes in wave washer,
(2)After solution becomes white, addition mass percent is its 40% poly-vinyl alcohol solution and mass percent is
Its 8% titanium tetrachloride, continues ultrasonic vibration 25 minutes, by white mixture obtained by the reaction by filtered on buchner funnel, obtains
Filtrate be put into baking oven and dry 3 hours;
(3)Polypropylene fibre is melted at high temperature, by the nano silicon oxide being prepared-organotitanium polymer hetero-junctions
Structure spraying is dispersed in fused fiber, is drawn on high speed wiredrawing bench, and dry in 130 DEG C of electric drying oven with forced convection immediately
8 hours, it was 15 millimeters to cut out to length, is cooled down up to the modified fibre.
It is further described as to said program, the fly ash float density is in 0.44-0.46g/cm3Range, grain
Diameter size is in 40-60 mesh ranges.
It is further described as to said program, 2MgOSiO in the ceramic powder280% is accounted for, remaining as aluminium oxide
Powder.
Comparative example 1
With differing only in for embodiment 1, modified fibre is omitted in raw material, remaining is consistent.
Comparative example 2
With differing only in for embodiment 2, non-modified polypropylene fibre is used in raw material, remaining is consistent.
Contrast experiment
Use the water-fast crack resistence wall putty of method processing and fabricating of embodiment 1-3 and comparative example 1-2, use existing respectively
Containing diatomite ingredient as waterproof material putty as a control group, carry out metope application using the putty that is prepared in each group,
The wall covering used is identical, carries out performance comparison to each group putty, the results are shown in table below:
It can be seen that by comparing:Water-fast crack resistence wall putty prepared by the present invention, can solve the crisp of cement matrix
Property problem big, easy to crack, while improving the solar heat protection cracking performance of putty.
Claims (3)
1. a kind of water-fast crack resistence wall putty, which is characterized in that be made in parts by weight of following component:Portland cement
270-300 parts, 70-80 parts of quartz sand, 45-55 parts of lotion, 30-40 parts of fly ash float, 25-30 parts of ceramic powder, dicalcium powder 15-
20, dispersant 3-5 parts, 2-3 parts of wetting agent, 1.5-2.0 parts of modified fibre, 1.0-2.0 parts of organic silicon defoamer, mould inhibitor 1.0-
1.5 parts, 340-350 parts of water, said components are stirred in blender, dry-storage;
The modified fibre is on the basis of original polypropylene fibre, and the composite material that addition mass fraction is 4-6%, this changes
The preparation method of property fiber is:
(1)The nano silicon oxide that particle size is 10-20 nanometers is prepared using liquid phase deposition, is added into the nano silicon oxide
The deionized water of 2-3 times of volume, heating water bath carries out hydration reaction at this temperature to 50-60 DEG C, after reacting 1-2 hours,
Ultrasonic vibration 20-30 minutes in ultrasonic cleaner;
(2)After solution becomes white, poly-vinyl alcohol solution and mass percent that addition mass percent is its 30-40% are
The titanium tetrachloride of its 5-8%, continues ultrasonic vibration 20-25 minutes, and white mixture obtained by the reaction is passed through Buchner funnel mistake
Filter, obtained filtrate are put into baking oven and dry 2-3 hours;
(3)Polypropylene fibre is melted at high temperature, the nano silicon oxide being prepared-organotitanium polymer heterojunction structure is sprayed
Painting is dispersed in fused fiber, is drawn on high speed wiredrawing bench, and dry in 120-130 DEG C of electric drying oven with forced convection immediately
6-8 hours, it was 10-15 millimeters to cut out to length, is cooled down up to the modified fibre.
2. a kind of water-fast crack resistence wall putty as described in claim 1, which is characterized in that the fly ash float density exists
0.44-0.46g/cm3Range, particle size is in 40-60 mesh ranges.
3. a kind of water-fast crack resistence wall putty as described in claim 1, which is characterized in that 2MgOSiO in the ceramic powder2
70-80% is accounted for, remaining as alumina powder.
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CN107841180A (en) * | 2017-11-06 | 2018-03-27 | 安徽福瑞尔铝业科技有限公司 | A kind of fireproof heat insulating putty for building and preparation method thereof |
CN113667343A (en) * | 2021-08-03 | 2021-11-19 | 中冶武汉冶金建筑研究院有限公司 | External wall heat-insulating waterproof putty and preparation method thereof |
CN114231075A (en) * | 2021-11-29 | 2022-03-25 | 浙江杰林新材料科技股份有限公司 | Mildew-proof, damp-proof and antibacterial putty powder and preparation process thereof |
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CN101041751A (en) * | 2006-11-02 | 2007-09-26 | 董善刚 | Highly dynamic cracking resistant type elastic putty |
CN103555042A (en) * | 2013-11-25 | 2014-02-05 | 扬州大学 | Thermal insulating putty for exterior wall of building and preparation method thereof |
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CN101041751A (en) * | 2006-11-02 | 2007-09-26 | 董善刚 | Highly dynamic cracking resistant type elastic putty |
CN103555042A (en) * | 2013-11-25 | 2014-02-05 | 扬州大学 | Thermal insulating putty for exterior wall of building and preparation method thereof |
CN104559414A (en) * | 2015-01-20 | 2015-04-29 | 广州协堡建材有限公司 | Two-component elastic anti-cracking waterproof putty for exterior walls |
CN106905744A (en) * | 2017-02-23 | 2017-06-30 | 马清浩 | A kind of crack resistance type exterior wall powder of lacquer putty for use on |
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